CA2700765A1 - Production de compositions contenant du carbonate a partir d'un materiau comportant des silicates metalliques - Google Patents
Production de compositions contenant du carbonate a partir d'un materiau comportant des silicates metalliques Download PDFInfo
- Publication number
- CA2700765A1 CA2700765A1 CA2700765A CA2700765A CA2700765A1 CA 2700765 A1 CA2700765 A1 CA 2700765A1 CA 2700765 A CA2700765 A CA 2700765A CA 2700765 A CA2700765 A CA 2700765A CA 2700765 A1 CA2700765 A1 CA 2700765A1
- Authority
- CA
- Canada
- Prior art keywords
- precipitation
- acid
- proton
- carbonate
- microns
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000463 material Substances 0.000 title claims abstract description 682
- 229910052914 metal silicate Inorganic materials 0.000 title claims abstract description 199
- 239000000203 mixture Substances 0.000 title claims abstract description 99
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 title claims abstract description 97
- 238000004519 manufacturing process Methods 0.000 title description 20
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 267
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 212
- 150000001768 cations Chemical class 0.000 claims abstract description 189
- 238000000034 method Methods 0.000 claims abstract description 174
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 157
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 133
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 115
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 92
- 230000029087 digestion Effects 0.000 claims abstract description 71
- 239000002210 silicon-based material Substances 0.000 claims abstract description 61
- 238000001556 precipitation Methods 0.000 claims description 475
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 107
- 235000010755 mineral Nutrition 0.000 claims description 107
- 239000011707 mineral Substances 0.000 claims description 107
- 239000007864 aqueous solution Substances 0.000 claims description 79
- 239000002245 particle Substances 0.000 claims description 78
- 239000007787 solid Substances 0.000 claims description 75
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 71
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 63
- 239000011541 reaction mixture Substances 0.000 claims description 58
- 229910052681 coesite Inorganic materials 0.000 claims description 56
- 229910052906 cristobalite Inorganic materials 0.000 claims description 56
- 229910052682 stishovite Inorganic materials 0.000 claims description 56
- 229910052905 tridymite Inorganic materials 0.000 claims description 56
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 48
- 229910052609 olivine Inorganic materials 0.000 claims description 48
- -1 alkaline earth metal cations Chemical class 0.000 claims description 46
- 239000004568 cement Substances 0.000 claims description 44
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 44
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 44
- 239000001095 magnesium carbonate Substances 0.000 claims description 40
- 235000012239 silicon dioxide Nutrition 0.000 claims description 40
- 235000014380 magnesium carbonate Nutrition 0.000 claims description 38
- 239000007921 spray Substances 0.000 claims description 36
- 239000002253 acid Substances 0.000 claims description 32
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 30
- 238000000926 separation method Methods 0.000 claims description 29
- 239000002002 slurry Substances 0.000 claims description 28
- 229910052742 iron Inorganic materials 0.000 claims description 26
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 24
- 239000004035 construction material Substances 0.000 claims description 24
- 239000011435 rock Substances 0.000 claims description 24
- 239000003546 flue gas Substances 0.000 claims description 21
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 21
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 20
- 238000001035 drying Methods 0.000 claims description 20
- 239000010881 fly ash Substances 0.000 claims description 20
- 239000000843 powder Substances 0.000 claims description 20
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 18
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 18
- 239000003929 acidic solution Substances 0.000 claims description 18
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 18
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 18
- 238000012545 processing Methods 0.000 claims description 17
- 239000002893 slag Substances 0.000 claims description 17
- 239000002956 ash Substances 0.000 claims description 16
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 14
- 239000003637 basic solution Substances 0.000 claims description 13
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 12
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 12
- 229910001424 calcium ion Inorganic materials 0.000 claims description 12
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 12
- 239000000347 magnesium hydroxide Substances 0.000 claims description 12
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 12
- 235000012254 magnesium hydroxide Nutrition 0.000 claims description 12
- 229910052615 phyllosilicate Inorganic materials 0.000 claims description 12
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 11
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 11
- 238000009826 distribution Methods 0.000 claims description 11
- 239000002918 waste heat Substances 0.000 claims description 11
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims description 10
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 10
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- 239000000920 calcium hydroxide Substances 0.000 claims description 9
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 9
- 235000011116 calcium hydroxide Nutrition 0.000 claims description 9
- 238000005549 size reduction Methods 0.000 claims description 9
- 229910021532 Calcite Inorganic materials 0.000 claims description 8
- 230000002829 reductive effect Effects 0.000 claims description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 7
- 238000010923 batch production Methods 0.000 claims description 7
- 229910052610 inosilicate Inorganic materials 0.000 claims description 7
- 238000002955 isolation Methods 0.000 claims description 7
- 235000011118 potassium hydroxide Nutrition 0.000 claims description 7
- 230000009257 reactivity Effects 0.000 claims description 7
- 229910052645 tectosilicate Inorganic materials 0.000 claims description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- 235000011054 acetic acid Nutrition 0.000 claims description 6
- 235000010323 ascorbic acid Nutrition 0.000 claims description 6
- 239000011668 ascorbic acid Substances 0.000 claims description 6
- 229960005070 ascorbic acid Drugs 0.000 claims description 6
- 235000015165 citric acid Nutrition 0.000 claims description 6
- 235000006408 oxalic acid Nutrition 0.000 claims description 6
- 235000011007 phosphoric acid Nutrition 0.000 claims description 6
- 229910052616 serpentine group Inorganic materials 0.000 claims description 6
- 235000011149 sulphuric acid Nutrition 0.000 claims description 6
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 5
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims description 5
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 5
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 5
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 5
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 claims description 5
- 238000010924 continuous production Methods 0.000 claims description 5
- 235000019253 formic acid Nutrition 0.000 claims description 5
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 claims description 5
- 239000000174 gluconic acid Substances 0.000 claims description 5
- 235000012208 gluconic acid Nutrition 0.000 claims description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 5
- 239000004310 lactic acid Substances 0.000 claims description 5
- 235000014655 lactic acid Nutrition 0.000 claims description 5
- GXHFUVWIGNLZSC-UHFFFAOYSA-N meldrum's acid Chemical compound CC1(C)OC(=O)CC(=O)O1 GXHFUVWIGNLZSC-UHFFFAOYSA-N 0.000 claims description 5
- 229910017604 nitric acid Inorganic materials 0.000 claims description 5
- 229910021487 silica fume Inorganic materials 0.000 claims description 5
- 239000011975 tartaric acid Substances 0.000 claims description 5
- 235000002906 tartaric acid Nutrition 0.000 claims description 5
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 claims description 3
- 230000001376 precipitating effect Effects 0.000 claims description 3
- RAQDACVRFCEPDA-UHFFFAOYSA-L ferrous carbonate Chemical compound [Fe+2].[O-]C([O-])=O RAQDACVRFCEPDA-UHFFFAOYSA-L 0.000 claims description 2
- 239000011398 Portland cement Substances 0.000 abstract description 15
- 229910000323 aluminium silicate Inorganic materials 0.000 abstract description 7
- 150000004760 silicates Chemical class 0.000 abstract description 7
- 239000007789 gas Substances 0.000 description 107
- 239000000243 solution Substances 0.000 description 107
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 61
- 229910001868 water Inorganic materials 0.000 description 59
- 238000006243 chemical reaction Methods 0.000 description 53
- 239000010450 olivine Substances 0.000 description 45
- 239000011777 magnesium Substances 0.000 description 42
- 239000002699 waste material Substances 0.000 description 42
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 36
- 241000196324 Embryophyta Species 0.000 description 34
- 229910052749 magnesium Inorganic materials 0.000 description 34
- 239000000047 product Substances 0.000 description 32
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 30
- 235000010216 calcium carbonate Nutrition 0.000 description 30
- 239000006228 supernatant Substances 0.000 description 29
- 230000008569 process Effects 0.000 description 25
- WYTGDNHDOZPMIW-RCBQFDQVSA-N alstonine Natural products C1=CC2=C3C=CC=CC3=NC2=C2N1C[C@H]1[C@H](C)OC=C(C(=O)OC)[C@H]1C2 WYTGDNHDOZPMIW-RCBQFDQVSA-N 0.000 description 24
- 239000011575 calcium Substances 0.000 description 24
- 239000012071 phase Substances 0.000 description 24
- 229910052791 calcium Inorganic materials 0.000 description 23
- 239000013535 sea water Substances 0.000 description 23
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 21
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 20
- 239000013505 freshwater Substances 0.000 description 19
- 239000000523 sample Substances 0.000 description 19
- 239000003245 coal Substances 0.000 description 18
- 238000002360 preparation method Methods 0.000 description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 17
- 239000012267 brine Substances 0.000 description 17
- 238000002485 combustion reaction Methods 0.000 description 17
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 17
- 239000012615 aggregate Substances 0.000 description 16
- 229910052799 carbon Inorganic materials 0.000 description 16
- 239000004567 concrete Substances 0.000 description 16
- 239000007788 liquid Substances 0.000 description 16
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 14
- 230000000153 supplemental effect Effects 0.000 description 14
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 13
- 230000015572 biosynthetic process Effects 0.000 description 13
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 13
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 13
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 12
- 230000002378 acidificating effect Effects 0.000 description 12
- 239000010795 gaseous waste Substances 0.000 description 12
- 238000004458 analytical method Methods 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 11
- 238000002848 electrochemical method Methods 0.000 description 11
- 239000002803 fossil fuel Substances 0.000 description 11
- 241000894007 species Species 0.000 description 11
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 10
- 229910052710 silicon Inorganic materials 0.000 description 10
- 235000002639 sodium chloride Nutrition 0.000 description 10
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 9
- 238000004090 dissolution Methods 0.000 description 9
- 230000036571 hydration Effects 0.000 description 9
- 238000006703 hydration reaction Methods 0.000 description 9
- 239000010703 silicon Substances 0.000 description 9
- 239000007858 starting material Substances 0.000 description 9
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 8
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 239000000567 combustion gas Substances 0.000 description 8
- 239000003345 natural gas Substances 0.000 description 8
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 8
- 150000007513 acids Chemical class 0.000 description 7
- 239000002585 base Substances 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- 239000000446 fuel Substances 0.000 description 7
- 239000011396 hydraulic cement Substances 0.000 description 7
- 150000004679 hydroxides Chemical class 0.000 description 7
- 239000002440 industrial waste Substances 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 239000004570 mortar (masonry) Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 6
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 6
- 239000012298 atmosphere Substances 0.000 description 6
- 230000005587 bubbling Effects 0.000 description 6
- 239000006227 byproduct Substances 0.000 description 6
- 229910052804 chromium Inorganic materials 0.000 description 6
- 239000011651 chromium Substances 0.000 description 6
- 239000000470 constituent Substances 0.000 description 6
- 238000002309 gasification Methods 0.000 description 6
- 238000000227 grinding Methods 0.000 description 6
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 6
- 239000000395 magnesium oxide Substances 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 230000020477 pH reduction Effects 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 238000001694 spray drying Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000000725 suspension Substances 0.000 description 6
- 239000002912 waste gas Substances 0.000 description 6
- 239000003643 water by type Substances 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 5
- 239000002154 agricultural waste Substances 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 229910021529 ammonia Inorganic materials 0.000 description 5
- 235000012241 calcium silicate Nutrition 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 239000003518 caustics Substances 0.000 description 5
- 239000000428 dust Substances 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
- 229910001385 heavy metal Inorganic materials 0.000 description 5
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 5
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 5
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 5
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 5
- 229910052753 mercury Inorganic materials 0.000 description 5
- 238000005065 mining Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-O oxonium Chemical compound [OH3+] XLYOFNOQVPJJNP-UHFFFAOYSA-O 0.000 description 5
- 239000002243 precursor Substances 0.000 description 5
- 229910052709 silver Inorganic materials 0.000 description 5
- 239000004332 silver Substances 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910052815 sulfur oxide Inorganic materials 0.000 description 5
- 238000004448 titration Methods 0.000 description 5
- 229910052882 wollastonite Inorganic materials 0.000 description 5
- 238000004846 x-ray emission Methods 0.000 description 5
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 229910015400 FeC13 Inorganic materials 0.000 description 4
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 4
- 238000013019 agitation Methods 0.000 description 4
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 4
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 4
- 229910052925 anhydrite Inorganic materials 0.000 description 4
- 238000013459 approach Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000010884 boiler slag Substances 0.000 description 4
- 239000010882 bottom ash Substances 0.000 description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 4
- HHSPVTKDOHQBKF-UHFFFAOYSA-J calcium;magnesium;dicarbonate Chemical compound [Mg+2].[Ca+2].[O-]C([O-])=O.[O-]C([O-])=O HHSPVTKDOHQBKF-UHFFFAOYSA-J 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 229910017052 cobalt Inorganic materials 0.000 description 4
- 239000010941 cobalt Substances 0.000 description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 238000003869 coulometry Methods 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 238000006477 desulfuration reaction Methods 0.000 description 4
- 230000023556 desulfurization Effects 0.000 description 4
- 229910001873 dinitrogen Inorganic materials 0.000 description 4
- 239000003344 environmental pollutant Substances 0.000 description 4
- 238000000605 extraction Methods 0.000 description 4
- 229910052839 forsterite Inorganic materials 0.000 description 4
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- IBPRKWGSNXMCOI-UHFFFAOYSA-N trimagnesium;disilicate;hydrate Chemical compound O.[Mg+2].[Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IBPRKWGSNXMCOI-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/10—Clay
- C04B14/12—Expanded clay
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- B01D—SEPARATION
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- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/62—Carbon oxides
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- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1425—Regeneration of liquid absorbents
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- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1475—Removing carbon dioxide
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- B01D—SEPARATION
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- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1493—Selection of liquid materials for use as absorbents
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/60—Preparation of carbonates or bicarbonates in general
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- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
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- C01F11/181—Preparation of calcium carbonate by carbonation of aqueous solutions and characterised by control of the carbonation conditions
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
- C02F1/683—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water by addition of complex-forming compounds
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
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- C04B14/02—Granular materials, e.g. microballoons
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- C04B14/28—Carbonates of calcium
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- C—CHEMISTRY; METALLURGY
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/02—Treatment
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- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
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- C—CHEMISTRY; METALLURGY
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
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- C04B7/36—Manufacture of hydraulic cements in general
- C04B7/364—Avoiding environmental pollution during cement-manufacturing
- C04B7/367—Avoiding or minimising carbon dioxide emissions
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
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- C04B7/43—Heat treatment, e.g. precalcining, burning, melting; Cooling
- C04B7/436—Special arrangements for treating part or all of the cement kiln dust
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Applications Claiming Priority (21)
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US8276608P | 2008-07-22 | 2008-07-22 | |
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US8834708P | 2008-08-13 | 2008-08-13 | |
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US10162608P | 2008-09-30 | 2008-09-30 | |
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US12187208P | 2008-12-11 | 2008-12-11 | |
US61/121,872 | 2008-12-11 | ||
PCT/US2008/088246 WO2010074687A1 (fr) | 2008-12-23 | 2008-12-23 | Système et procédé de transfert de protons électrochimique à faible énergie |
USPCT/US2008/088246 | 2008-12-23 | ||
USPCT/US2008/088242 | 2008-12-23 | ||
PCT/US2008/088242 WO2010074686A1 (fr) | 2008-12-23 | 2008-12-23 | Système et procédé d'hydroxyde électrochimique à faible énergie |
US12/344,019 US7887694B2 (en) | 2007-12-28 | 2008-12-24 | Methods of sequestering CO2 |
US12/344,019 | 2008-12-24 | ||
US12/486,692 US7754169B2 (en) | 2007-12-28 | 2009-06-17 | Methods and systems for utilizing waste sources of metal oxides |
US12/486,692 | 2009-06-17 | ||
PCT/US2009/050223 WO2010006242A1 (fr) | 2008-07-10 | 2009-07-10 | Production de compositions contenant du carbonate à partir d'un matériau comportant des silicates métalliques |
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CA2700765A Abandoned CA2700765A1 (fr) | 2008-07-10 | 2009-07-10 | Production de compositions contenant du carbonate a partir d'un materiau comportant des silicates metalliques |
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JP (1) | JP2011527664A (fr) |
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CN (1) | CN101878060A (fr) |
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BR (1) | BRPI0915447A2 (fr) |
CA (1) | CA2700765A1 (fr) |
WO (1) | WO2010006242A1 (fr) |
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-
2009
- 2009-07-10 AU AU2009268397A patent/AU2009268397A1/en not_active Abandoned
- 2009-07-10 JP JP2011517648A patent/JP2011527664A/ja not_active Withdrawn
- 2009-07-10 KR KR1020117003141A patent/KR20110061546A/ko not_active Application Discontinuation
- 2009-07-10 WO PCT/US2009/050223 patent/WO2010006242A1/fr active Application Filing
- 2009-07-10 BR BRPI0915447A patent/BRPI0915447A2/pt not_active Application Discontinuation
- 2009-07-10 CN CN2009801012200A patent/CN101878060A/zh active Pending
- 2009-07-10 CA CA2700765A patent/CA2700765A1/fr not_active Abandoned
- 2009-07-10 EP EP09795228A patent/EP2200732A4/fr not_active Withdrawn
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AU2009268397A1 (en) | 2010-01-14 |
BRPI0915447A2 (pt) | 2015-11-10 |
KR20110061546A (ko) | 2011-06-09 |
WO2010006242A1 (fr) | 2010-01-14 |
EP2200732A4 (fr) | 2012-01-25 |
CN101878060A (zh) | 2010-11-03 |
JP2011527664A (ja) | 2011-11-04 |
EP2200732A1 (fr) | 2010-06-30 |
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