CA2678528A1 - Azeotropic fumigant compositions of methyl iodide - Google Patents
Azeotropic fumigant compositions of methyl iodide Download PDFInfo
- Publication number
- CA2678528A1 CA2678528A1 CA002678528A CA2678528A CA2678528A1 CA 2678528 A1 CA2678528 A1 CA 2678528A1 CA 002678528 A CA002678528 A CA 002678528A CA 2678528 A CA2678528 A CA 2678528A CA 2678528 A1 CA2678528 A1 CA 2678528A1
- Authority
- CA
- Canada
- Prior art keywords
- composition
- fumigant
- fluorocarbon
- hydrofluorocarbon
- methyl iodide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 134
- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical group IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 title claims abstract description 66
- 239000002316 fumigant Substances 0.000 title claims abstract description 60
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims abstract description 36
- MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000002689 soil Substances 0.000 claims description 41
- 238000009835 boiling Methods 0.000 claims description 25
- 238000000034 method Methods 0.000 claims description 15
- 238000003958 fumigation Methods 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 12
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 9
- CDOOAUSHHFGWSA-UPHRSURJSA-N (z)-1,3,3,3-tetrafluoroprop-1-ene Chemical compound F\C=C/C(F)(F)F CDOOAUSHHFGWSA-UPHRSURJSA-N 0.000 claims description 5
- WZLFPVPRZGTCKP-UHFFFAOYSA-N 1,1,1,3,3-pentafluorobutane Chemical compound CC(F)(F)CC(F)(F)F WZLFPVPRZGTCKP-UHFFFAOYSA-N 0.000 claims description 5
- 238000010792 warming Methods 0.000 claims description 5
- 239000002023 wood Substances 0.000 claims description 2
- GZUXJHMPEANEGY-UHFFFAOYSA-N bromomethane Chemical compound BrC GZUXJHMPEANEGY-UHFFFAOYSA-N 0.000 abstract description 64
- 229940102396 methyl bromide Drugs 0.000 abstract description 32
- 239000007789 gas Substances 0.000 description 12
- 241000196324 Embryophyta Species 0.000 description 11
- 241000607479 Yersinia pestis Species 0.000 description 8
- 239000007788 liquid Substances 0.000 description 7
- LFHISGNCFUNFFM-UHFFFAOYSA-N chloropicrin Chemical compound [O-][N+](=O)C(Cl)(Cl)Cl LFHISGNCFUNFFM-UHFFFAOYSA-N 0.000 description 6
- 230000002939 deleterious effect Effects 0.000 description 5
- 201000010099 disease Diseases 0.000 description 5
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 239000010813 municipal solid waste Substances 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- UOORRWUZONOOLO-OWOJBTEDSA-N (E)-1,3-dichloropropene Chemical compound ClC\C=C\Cl UOORRWUZONOOLO-OWOJBTEDSA-N 0.000 description 2
- AWTOFSDLNREIFS-UHFFFAOYSA-N 1,1,2,2,3-pentafluoropropane Chemical compound FCC(F)(F)C(F)F AWTOFSDLNREIFS-UHFFFAOYSA-N 0.000 description 2
- AHFMSNDOYCFEPH-UHFFFAOYSA-N 1,2-difluoroethane Chemical compound FCCF AHFMSNDOYCFEPH-UHFFFAOYSA-N 0.000 description 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 description 2
- 241000244206 Nematoda Species 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 description 2
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000003973 irrigation Methods 0.000 description 2
- 230000002262 irrigation Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- UOORRWUZONOOLO-UHFFFAOYSA-N telone II Natural products ClCC=CCl UOORRWUZONOOLO-UHFFFAOYSA-N 0.000 description 2
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- CDOOAUSHHFGWSA-OWOJBTEDSA-N (e)-1,3,3,3-tetrafluoroprop-1-ene Chemical compound F\C=C\C(F)(F)F CDOOAUSHHFGWSA-OWOJBTEDSA-N 0.000 description 1
- LDTMPQQAWUMPKS-OWOJBTEDSA-N (e)-1-chloro-3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)\C=C\Cl LDTMPQQAWUMPKS-OWOJBTEDSA-N 0.000 description 1
- YQQHEHMVPLLOKE-UHFFFAOYSA-N 1,1,2,2-tetrafluoro-1-methoxyethane Chemical compound COC(F)(F)C(F)F YQQHEHMVPLLOKE-UHFFFAOYSA-N 0.000 description 1
- WGZYQOSEVSXDNI-UHFFFAOYSA-N 1,1,2-trifluoroethane Chemical compound FCC(F)F WGZYQOSEVSXDNI-UHFFFAOYSA-N 0.000 description 1
- FJSRPVWDOJSWBX-UHFFFAOYSA-N 1-chloro-4-[1-(4-chlorophenyl)-2,2,2-trifluoroethyl]benzene Chemical compound C=1C=C(Cl)C=CC=1C(C(F)(F)F)C1=CC=C(Cl)C=C1 FJSRPVWDOJSWBX-UHFFFAOYSA-N 0.000 description 1
- OHMHBGPWCHTMQE-UHFFFAOYSA-N 2,2-dichloro-1,1,1-trifluoroethane Chemical compound FC(F)(F)C(Cl)Cl OHMHBGPWCHTMQE-UHFFFAOYSA-N 0.000 description 1
- ZASBKNPRLPFSCA-UHFFFAOYSA-N 2-(difluoromethoxy)-1,1,1-trifluoroethane Chemical compound FC(F)OCC(F)(F)F ZASBKNPRLPFSCA-UHFFFAOYSA-N 0.000 description 1
- BIHPYCDDPGNWQO-UHFFFAOYSA-N 5-iai Chemical compound C1=C(I)C=C2CC(N)CC2=C1 BIHPYCDDPGNWQO-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241000256602 Isoptera Species 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 241000283984 Rodentia Species 0.000 description 1
- OKJPEAGHQZHRQV-UHFFFAOYSA-N Triiodomethane Natural products IC(I)I OKJPEAGHQZHRQV-UHFFFAOYSA-N 0.000 description 1
- 230000007059 acute toxicity Effects 0.000 description 1
- 231100000403 acute toxicity Toxicity 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000001069 nematicidal effect Effects 0.000 description 1
- 239000005645 nematicide Substances 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N29/00—Biocides, pest repellants or attractants, or plant growth regulators containing halogenated hydrocarbons
- A01N29/02—Acyclic compounds or compounds containing halogen attached to an aliphatic side-chain of a cycloaliphatic ring system
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/707,498 | 2007-02-16 | ||
| US11/707,498 US7544306B2 (en) | 2007-02-16 | 2007-02-16 | Azeotropic fumigant compositions of methyl iodide |
| PCT/US2008/053921 WO2008101054A1 (en) | 2007-02-16 | 2008-02-14 | Azeotropic fumigant compositions of methyl iodide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2678528A1 true CA2678528A1 (en) | 2008-08-21 |
Family
ID=39470263
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002678528A Abandoned CA2678528A1 (en) | 2007-02-16 | 2008-02-14 | Azeotropic fumigant compositions of methyl iodide |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US7544306B2 (ja) |
| EP (4) | EP2316266A1 (ja) |
| JP (1) | JP2010519210A (ja) |
| CN (1) | CN101657094A (ja) |
| AT (1) | ATE522137T1 (ja) |
| BR (1) | BRPI0807627A2 (ja) |
| CA (1) | CA2678528A1 (ja) |
| ES (1) | ES2369719T3 (ja) |
| MX (1) | MX2009008654A (ja) |
| PT (1) | PT2117299E (ja) |
| WO (1) | WO2008101054A1 (ja) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5109556B2 (ja) * | 2006-11-01 | 2012-12-26 | セントラル硝子株式会社 | １，１，２，２−テトラフルオロ−１−メトキシエタンを含む共沸及び共沸様組成物 |
| US7544306B2 (en) * | 2007-02-16 | 2009-06-09 | Honeywell International Inc. | Azeotropic fumigant compositions of methyl iodide |
| KR101086215B1 (ko) * | 2008-03-07 | 2011-11-24 | 알케마 인코포레이티드 | 개선된 오일 리턴을 갖는 할로겐화 알켄 열 전달 조성물 |
| JP5435192B2 (ja) | 2008-07-29 | 2014-03-05 | セイコーエプソン株式会社 | 記録方法、記録物、インクジェット記録装置および識別方法 |
| EP2179649A1 (en) * | 2008-10-27 | 2010-04-28 | Honeywell International | Azeotrope-like compositions of 1-chloro-3,3,3,-trifluoropropene and methyl iodide |
| US20100135914A1 (en) * | 2008-12-03 | 2010-06-03 | Andrew Joseph Poss | Azeotropic fumigant compositions and methods of controlling pests |
| PL2464716T3 (pl) * | 2009-08-13 | 2017-02-28 | Arkema Inc. | Azeotropowe i podobne do azeotropowych kompozycje 1-chloro-3,3,3-trifluoropropenu i hfc-123 |
| US9267065B2 (en) | 2009-08-17 | 2016-02-23 | Arkema Inc. | Azeotrope and azeotrope-like compositions of 1-chloro-3,3,3-trifluoropropene and HFC-245eb |
| NZ627520A (en) * | 2010-03-10 | 2015-10-30 | Astrazeneca Ab | 4-phenyl pyridine analogues as protein kinase inhibitors |
| US20110252694A1 (en) * | 2010-04-19 | 2011-10-20 | Honeywell International, Inc. | Compositions for drip fumigation |
| US20120064208A1 (en) * | 2010-09-13 | 2012-03-15 | Honeywell International Inc. | Azeotropic post-harvest fumigation compositions of methyl iodide |
| US8734671B2 (en) * | 2010-11-19 | 2014-05-27 | Honeywell International Inc. | Azeotrope-like compositions comprising 1-chloro-3,3,3-trifluoropropene |
| US20120213861A1 (en) * | 2011-02-22 | 2012-08-23 | Honeywell International Inc. | 2-chloropentafluoropropene compositions and method of use for extermination of rodentia |
| US9232788B2 (en) * | 2011-11-02 | 2016-01-12 | Honeywell International Inc. | Fumigation methods |
| TWI619437B (zh) | 2012-06-08 | 2018-04-01 | Earth Chemical Co Ltd | 害蟲防除劑 |
| JP5618110B2 (ja) * | 2013-10-15 | 2014-11-05 | セイコーエプソン株式会社 | 記録方法、記録物、インクジェット記録装置および識別方法 |
| US10330364B2 (en) | 2014-06-26 | 2019-06-25 | Hudson Technologies, Inc. | System and method for retrofitting a refrigeration system from HCFC to HFC refrigerant |
| WO2017015160A1 (en) * | 2015-07-17 | 2017-01-26 | Honeywell International Inc. | Compositions and methods of fumigation |
| US11147260B2 (en) * | 2018-03-13 | 2021-10-19 | John Stephen Godbehere | Cold gas system for fumigating soil |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5158617A (en) * | 1991-04-18 | 1992-10-27 | Allied-Signal Inc. | Method of cleaning using hydrochlorofluorocarbons having 3 to 5 carbon atoms |
| US5316690A (en) * | 1991-04-18 | 1994-05-31 | Allied Signal Inc. | Hydrochlorofluorocarbons having OH rate constants which do not contribute substantially to ozone depletion and global warming |
| US5518692A (en) | 1994-10-20 | 1996-05-21 | The Regents Of The University Of California | Methyl iodide as a soil fumigant |
| US5753183A (en) | 1994-10-20 | 1998-05-19 | The Regents Of The University Of California | Methyl iodide as a fumigant |
| AU2686399A (en) | 1998-02-19 | 1999-09-06 | Allied-Signal Inc. | Sterilizing compositions of pentafluoropropane and ethylene oxide |
| JP4389389B2 (ja) * | 1998-11-13 | 2009-12-24 | ダイキン工業株式会社 | １，１，１，３，３−ペンタフルオロプロパンおよび１，１，１−トリフルオロ−３−クロロ−２−プロペンから成る共沸組成物およびそれを用いる分離精製方法、ならびに１，１，１，３，３−ペンタフルオロプロパンおよび１，１，１−トリフルオロ−３−クロロ−２−プロペンの製造方法 |
| US6465527B1 (en) | 1999-09-14 | 2002-10-15 | Auburn University | Iodinated hydrocarbon pesticide |
| US6984768B2 (en) * | 2002-05-21 | 2006-01-10 | Battelle Energy Alliance, Llc | Method for destroying halocarbon compositions using a critical solvent |
| MXPA06011589A (es) * | 2004-04-08 | 2006-12-20 | Dow Agrosciences Llc | Sulfoximinas n-sustituidas insecticidas. |
| JP2006076951A (ja) | 2004-09-10 | 2006-03-23 | Yashima Sangyo Kk | 木材寄生線虫用くん蒸剤および木材くん蒸方法 |
| US20080110833A1 (en) * | 2006-11-14 | 2008-05-15 | Samuels George J | Iodine removal with activated carbon |
| US20080111099A1 (en) * | 2006-11-14 | 2008-05-15 | Singh Rajiv R | Heat transfer compositions with a hydrofluoroalkene, an iodocarbon and additives |
| US7544306B2 (en) * | 2007-02-16 | 2009-06-09 | Honeywell International Inc. | Azeotropic fumigant compositions of methyl iodide |
-
2007
- 2007-02-16 US US11/707,498 patent/US7544306B2/en not_active Expired - Fee Related
-
2008
- 2008-02-14 WO PCT/US2008/053921 patent/WO2008101054A1/en active Application Filing
- 2008-02-14 PT PT08729829T patent/PT2117299E/pt unknown
- 2008-02-14 BR BRPI0807627-8A2A patent/BRPI0807627A2/pt not_active IP Right Cessation
- 2008-02-14 MX MX2009008654A patent/MX2009008654A/es active IP Right Grant
- 2008-02-14 AT AT08729829T patent/ATE522137T1/de not_active IP Right Cessation
- 2008-02-14 JP JP2009549713A patent/JP2010519210A/ja not_active Withdrawn
- 2008-02-14 EP EP10015167A patent/EP2316266A1/en not_active Withdrawn
- 2008-02-14 EP EP10015166A patent/EP2308298A1/en not_active Withdrawn
- 2008-02-14 EP EP08729829A patent/EP2117299B1/en not_active Not-in-force
- 2008-02-14 CN CN200880011685A patent/CN101657094A/zh active Pending
- 2008-02-14 CA CA002678528A patent/CA2678528A1/en not_active Abandoned
- 2008-02-14 EP EP10015168A patent/EP2327303A1/en not_active Withdrawn
- 2008-02-14 ES ES08729829T patent/ES2369719T3/es active Active
- 2008-10-27 US US12/258,537 patent/US7695635B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| MX2009008654A (es) | 2009-08-31 |
| JP2010519210A (ja) | 2010-06-03 |
| US7544306B2 (en) | 2009-06-09 |
| CN101657094A (zh) | 2010-02-24 |
| EP2308298A1 (en) | 2011-04-13 |
| EP2327303A1 (en) | 2011-06-01 |
| US20090041677A1 (en) | 2009-02-12 |
| BRPI0807627A2 (pt) | 2014-06-10 |
| EP2117299B1 (en) | 2011-08-31 |
| ES2369719T3 (es) | 2011-12-05 |
| ATE522137T1 (de) | 2011-09-15 |
| WO2008101054A1 (en) | 2008-08-21 |
| PT2117299E (pt) | 2011-10-19 |
| US20080199408A1 (en) | 2008-08-21 |
| EP2316266A1 (en) | 2011-05-04 |
| EP2117299A1 (en) | 2009-11-18 |
| US7695635B2 (en) | 2010-04-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |
Effective date: 20140214 |