CA2677820A1 - Process for preparing composites comprising epoxy resin formulations - Google Patents

Process for preparing composites comprising epoxy resin formulations Download PDF

Info

Publication number
CA2677820A1
CA2677820A1 CA002677820A CA2677820A CA2677820A1 CA 2677820 A1 CA2677820 A1 CA 2677820A1 CA 002677820 A CA002677820 A CA 002677820A CA 2677820 A CA2677820 A CA 2677820A CA 2677820 A1 CA2677820 A1 CA 2677820A1
Authority
CA
Canada
Prior art keywords
reaction mixture
hot reaction
mold
epoxy resin
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002677820A
Other languages
English (en)
French (fr)
Inventor
Asjad Shafi
Nikhil Eapen Verghese
Allan James
John Joseph Penkala
Scott Burr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2677820A1 publication Critical patent/CA2677820A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/40—Shaping or impregnating by compression not applied
    • B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
    • B29C70/46—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
    • B29C70/48—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs and impregnating the reinforcements in the closed mould, e.g. resin transfer moulding [RTM], e.g. by vacuum
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C39/00—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/5033—Amines aromatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B29C2035/0283—Thermal pretreatment of the plastics material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/40—Shaping or impregnating by compression not applied
    • B29C70/50—Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • B29C70/52—Pultrusion, i.e. forming and compressing by continuously pulling through a die
    • B29C70/521—Pultrusion, i.e. forming and compressing by continuously pulling through a die and impregnating the reinforcement before the die
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2063/00—Use of EP, i.e. epoxy resins or derivatives thereof, as moulding material

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Composite Materials (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Thermal Sciences (AREA)
  • Reinforced Plastic Materials (AREA)
  • Epoxy Resins (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Moulding By Coating Moulds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
CA002677820A 2007-02-16 2008-02-05 Process for preparing composites comprising epoxy resin formulations Abandoned CA2677820A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US90203507P 2007-02-16 2007-02-16
US60/902,035 2007-02-16
PCT/US2008/052973 WO2008100730A1 (en) 2007-02-16 2008-02-05 Process for preparing composites comprising epoxy resin formulations

Publications (1)

Publication Number Publication Date
CA2677820A1 true CA2677820A1 (en) 2008-08-21

Family

ID=39528000

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002677820A Abandoned CA2677820A1 (en) 2007-02-16 2008-02-05 Process for preparing composites comprising epoxy resin formulations

Country Status (10)

Country Link
US (1) US20080197526A1 (OSRAM)
EP (1) EP2112974A1 (OSRAM)
JP (1) JP2010519067A (OSRAM)
KR (1) KR20090119908A (OSRAM)
CN (1) CN101616802A (OSRAM)
BR (1) BRPI0807323A2 (OSRAM)
CA (1) CA2677820A1 (OSRAM)
MX (1) MX2009008748A (OSRAM)
RU (1) RU2009134483A (OSRAM)
WO (1) WO2008100730A1 (OSRAM)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI121370B (fi) * 2007-11-02 2010-10-29 Exel Oyj Menetelmä profiilien, putkien tai levyjen valmistamiseksi
WO2010121853A1 (en) * 2009-04-24 2010-10-28 Huntsman Advanced Materials (Switzerland) Gmbh Method of making chemically resistant moulds and tools
WO2011064707A2 (en) * 2009-11-24 2011-06-03 The Director General, Defence Research & Development Organisation (Drdo) Fiber reinforced polymeric composites with tailorable electrical resistivities and process for preparing the same
US9840648B2 (en) * 2009-12-29 2017-12-12 Saint-Gobain Abrasives, Inc. Smear-free nonwoven composite abrasives
US20110218270A1 (en) * 2010-03-02 2011-09-08 Basf Se Use of linear triethylentetramine as curing agent for epoxy resins
WO2011107512A1 (en) 2010-03-02 2011-09-09 Basf Se The use of linear triethylentetramine as curing agent for epoxy resins
US20130203894A1 (en) * 2010-03-11 2013-08-08 Huntsman Petrochemical Llc Cycloaliphatic carbonates as reactive diluents in epoxy resins
TWI506010B (zh) * 2010-05-21 2015-11-01 Dow Global Technologies Llc 用於可熱固樹脂組成物之硬化劑
GB201009851D0 (en) * 2010-06-14 2010-07-21 Hexcel Composites Ltd Improvements in composite materials
RU2600058C2 (ru) * 2011-04-22 2016-10-20 Феи Компани Автоматизированное приготовление образцов
JP6008958B2 (ja) * 2011-06-30 2016-10-19 ダウ グローバル テクノロジーズ エルエルシー アミン硬化剤の混合物及び過剰のエポキシ基を含む硬化性エポキシ樹脂系
EP2864418B1 (en) * 2012-06-26 2017-08-16 Dow Global Technologies LLC Insulating composites for power transmission and distribution
US9370902B2 (en) * 2013-10-03 2016-06-21 Comerstone Research Group, Inc. Fiber-reinforced epoxy composites and methods of making same without the use of oven or autoclave
US9908993B1 (en) 2014-10-06 2018-03-06 Cornerstone Research Group, Inc. Hybrid fiber layup and fiber-reinforced polymeric composites produced therefrom
US12337768B2 (en) * 2015-11-30 2025-06-24 Zephyros, Inc. Adhesive resins and films for composites and tapes and methods of using the same
WO2017160310A1 (en) 2016-03-18 2017-09-21 Danny Warren Bpa free sprayable epoxy resin
WO2018079427A1 (ja) * 2016-10-28 2018-05-03 シャープ株式会社 シール材組成物、液晶セル及び走査アンテナ
US10946594B1 (en) 2017-01-06 2021-03-16 Cornerstone Research Group, Inc. Reinforced polymer-infused fiber composite repair system and methods for repairing composite materials
CN113119368A (zh) * 2019-12-31 2021-07-16 脉通医疗科技(嘉兴)有限公司 一种环氧树脂基纤维复合材料及其制备方法
FR3126335B1 (fr) * 2021-08-27 2024-03-22 Safran Aircraft Engines Procede de fabrication d’une piece composite, en particulier aeronautique et installation associee
CN116512642B (zh) * 2023-07-05 2023-09-12 河北润晟复合材料有限公司 复合高强度玻璃钢拉挤型材及其制备方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2951822A (en) * 1956-11-23 1960-09-06 Union Carbide Corp Preparation of polyglycidyl aromatic amines and resinous compositions made therefrom
US3668177A (en) * 1962-08-31 1972-06-06 Koninkl Nv Molding masses for producing fiber reinforced plastic articles, methods of preparing such molding masses, and articles produced therefrom
US3975479A (en) * 1973-03-09 1976-08-17 Mcclean Anderson, Inc. Method of fabricating a reinforced plastic article
US4692291A (en) * 1980-04-14 1987-09-08 Union Carbide Corporation Molding method using fast curing fiber reinforced, low viscosity thermosetting resin
GB8629361D0 (en) * 1986-12-09 1987-01-21 Shell Int Research Preparation of fibre-reinforced composites
US5730922A (en) * 1990-12-10 1998-03-24 The Dow Chemical Company Resin transfer molding process for composites
US5427725A (en) * 1993-05-07 1995-06-27 The Dow Chemical Company Process for resin transfer molding and preform used in the process
ES2106537T3 (es) * 1993-05-07 1997-11-01 Dow Chemical Co Procedimiento mejorado para moldeo por transferencia de resina.
TW297046B (OSRAM) * 1993-06-15 1997-02-01 Dow Chemical Co
US5698318A (en) * 1995-05-23 1997-12-16 The Dow Chemical Company Process for resin transfer molding and formulations useful to practice it
AU732583B2 (en) * 1996-09-20 2001-04-26 Vantico Ag Resin transfer molding process using stable epoxy resin compositions
EP1094087B1 (en) * 1999-03-11 2004-09-08 Toray Industries, Inc. Epoxy resin composition, epoxy resin composition for fiber-reinforced composite, and fiber-reinforced composite containing the same
US6437026B1 (en) * 2001-01-05 2002-08-20 Cookson Singapore Pte Ltd. Hardener for epoxy molding compounds

Also Published As

Publication number Publication date
MX2009008748A (es) 2009-10-26
KR20090119908A (ko) 2009-11-20
US20080197526A1 (en) 2008-08-21
CN101616802A (zh) 2009-12-30
RU2009134483A (ru) 2011-03-27
JP2010519067A (ja) 2010-06-03
WO2008100730A1 (en) 2008-08-21
EP2112974A1 (en) 2009-11-04
BRPI0807323A2 (pt) 2014-07-01

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Legal Events

Date Code Title Description
FZDE Discontinued

Effective date: 20130205