CA2648969C - Multiple stage method of reforming a gas containing tarry impurities employing a zirconium-based catalyst - Google Patents

Multiple stage method of reforming a gas containing tarry impurities employing a zirconium-based catalyst Download PDF

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Publication number
CA2648969C
CA2648969C CA2648969A CA2648969A CA2648969C CA 2648969 C CA2648969 C CA 2648969C CA 2648969 A CA2648969 A CA 2648969A CA 2648969 A CA2648969 A CA 2648969A CA 2648969 C CA2648969 C CA 2648969C
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CA
Canada
Prior art keywords
zirconium
gas
catalyst
reforming
metal catalyst
Prior art date
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Active
Application number
CA2648969A
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English (en)
French (fr)
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CA2648969A1 (en
Inventor
Pekka Simell
Esa Kurkela
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VTT Technical Research Centre of Finland Ltd
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VTT Technical Research Centre of Finland Ltd
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Publication of CA2648969A1 publication Critical patent/CA2648969A1/en
Application granted granted Critical
Publication of CA2648969C publication Critical patent/CA2648969C/en
Active legal-status Critical Current
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/34—Purifying combustible gases containing carbon monoxide by catalytic conversion of impurities to more readily removable materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Multi-step processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1023—Catalysts in the form of a monolith or honeycomb
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C01B2203/1058—Nickel catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C01B2203/107—Platinum catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Industrial Gases (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
CA2648969A 2006-04-10 2007-04-10 Multiple stage method of reforming a gas containing tarry impurities employing a zirconium-based catalyst Active CA2648969C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FI20060346A FI118647B (fi) 2006-04-10 2006-04-10 Menetelmä tervamaisia epäpuhtauksia sisältävän kaasun reformoimiseksi
FI20060346 2006-04-10
PCT/FI2007/000090 WO2007116121A1 (en) 2006-04-10 2007-04-10 Multiple stage method of reforming a gas containing tarry impurities employing a zirconium-based catalyst

Publications (2)

Publication Number Publication Date
CA2648969A1 CA2648969A1 (en) 2007-10-18
CA2648969C true CA2648969C (en) 2015-05-26

Family

ID=36293743

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2648969A Active CA2648969C (en) 2006-04-10 2007-04-10 Multiple stage method of reforming a gas containing tarry impurities employing a zirconium-based catalyst

Country Status (9)

Country Link
US (1) US8100995B2 (enExample)
EP (1) EP2010630B1 (enExample)
JP (1) JP5606064B2 (enExample)
CN (1) CN101454427B (enExample)
AU (1) AU2007235899B2 (enExample)
BR (1) BRPI0710144B1 (enExample)
CA (1) CA2648969C (enExample)
FI (1) FI118647B (enExample)
WO (1) WO2007116121A1 (enExample)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008021081A1 (de) 2008-04-28 2009-10-29 Süd-Chemie AG Verfahren zur katalytischen Verringerung des Teergehalts in Gasen aus Vergasungsprozessen unter Verwendung eines Katalysators auf Edelmetallbasis
DE102008021084A1 (de) * 2008-04-28 2009-10-29 Süd-Chemie AG Verwendung eines Katalysators auf Edelmetallbasis zur Verringerung des Teergehalts in Gasen aus Vergasungsprozessen
JP2010111779A (ja) * 2008-11-06 2010-05-20 Takuma Co Ltd タール分解方法およびタール分解設備
US20100187479A1 (en) * 2009-01-23 2010-07-29 Carbona Oy Process and apparatus for reforming of heavy and light hydrocarbons from product gas of biomass gasification
DE102010007588A1 (de) * 2010-02-05 2011-08-11 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V., 80686 Herstellungsverfahren für ein Synthesegas aus einer Biomasse
FI123686B (fi) * 2010-03-03 2013-09-30 Neste Oil Oyj Menetelmä kaasutuskaasun reformoimiseksi
BR112013001807B1 (pt) 2010-07-27 2019-05-21 Curtin University Of Technology Método para gaseificar material carbonáceo e um sistema de gaseificação
GB201013984D0 (en) 2010-08-20 2010-10-06 Magnesium Elektron Ltd Catalytic purification of gases
US20120255301A1 (en) * 2011-04-06 2012-10-11 Bell Peter S System for generating power from a syngas fermentation process
EP2565155B1 (en) * 2011-09-02 2018-12-05 Neste Oyj Method of reforming gasification gas
JP5974363B2 (ja) * 2012-06-15 2016-08-23 株式会社Ihi ガス化ガス生成装置、および、タール改質装置
CN102816613B (zh) * 2012-07-25 2014-03-05 中国科学院广州能源研究所 一种均温的生物质粗燃气电催化辅助重整净化装置
FI20165493A7 (fi) 2016-06-14 2017-12-15 Teknologian Tutkimuskeskus Vtt Oy Menetelmä ja reaktori hiilivetyjen osittaiseen katalyyttiseen hapetukseen
SI25770A (sl) * 2019-01-07 2020-07-31 Teos Perne Postopek uplinjanja trdnih materialov z vsebnostjo ogljika, s poudarjeno koncentracijo katranov in njihovo katalitsko pretvorbo v ogljikov monoksid in vodik
WO2021069799A1 (en) * 2019-10-08 2021-04-15 Teknologian Tutkimuskeskus Vtt Oy Method and apparatus for removing impurities from gasification gas and use
EP3805340B1 (de) * 2019-10-09 2023-06-07 Reissner, Markus Verfahren und verwendung einer anlage zur erzeugung eines kohlenwasserstoff- und wasserstoff-haltigen gasgemisches aus kunststoff
CN112029539B (zh) * 2020-09-08 2021-04-06 广州卓邦科技有限公司 一种固体废弃物处理用水平固定式气化炉
CN117645580A (zh) * 2022-09-02 2024-03-05 中国石油化工股份有限公司 一种促进剂m焦油的回收利用方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3759678A (en) * 1971-04-08 1973-09-18 Du Pont Reformer catalyst
JPS606986B2 (ja) 1982-02-03 1985-02-21 大阪瓦斯株式会社 都市ガスの製造方法
US4865625A (en) * 1988-05-02 1989-09-12 Battelle Memorial Institute Method of producing pyrolysis gases from carbon-containing materials
US5977013A (en) * 1996-12-19 1999-11-02 Battelle Memorial Institute Catalyst and method for aqueous phase reactions
EP1142981A3 (de) 2000-03-23 2003-04-02 Fraunhofer-Gesellschaft Zur Förderung Der Angewandten Forschung E.V. Vorrichtung zur Stromerzeugung aus Biomasse durch Vergasung mit anschliessender katalytischer Beseitigung von Teerverbindungen aus dem Brenngas
FI110691B (fi) 2001-06-21 2003-03-14 Valtion Teknillinen Menetelmä kaasutuskaasun puhdistamiseksi
JP4304025B2 (ja) 2002-12-25 2009-07-29 大阪瓦斯株式会社 改質ガス製造装置の運転方法
JP2004292720A (ja) 2003-03-28 2004-10-21 Hachinohe Institute Of Technology 流動床ガス化炉、ガス燃料製造方法、およびガス発電システム
MY151832A (en) 2004-06-28 2014-07-14 Osaka Gas Co Ltd Reformed gas production method and reformed gas production apparatus
KR100569120B1 (ko) * 2004-08-05 2006-04-10 한국에너지기술연구원 바이오메스 정제연료의 저온 촉매가스화 장치 및가스제조방법

Also Published As

Publication number Publication date
AU2007235899A1 (en) 2007-10-18
US20090324471A1 (en) 2009-12-31
WO2007116121A1 (en) 2007-10-18
JP2009533514A (ja) 2009-09-17
JP5606064B2 (ja) 2014-10-15
US8100995B2 (en) 2012-01-24
EP2010630A4 (en) 2011-10-05
CN101454427B (zh) 2016-02-10
EP2010630B1 (en) 2018-05-30
CN101454427A (zh) 2009-06-10
FI20060346A0 (fi) 2006-04-10
CA2648969A1 (en) 2007-10-18
AU2007235899B2 (en) 2011-05-26
FI118647B (fi) 2008-01-31
BRPI0710144A2 (pt) 2011-08-02
EP2010630A1 (en) 2009-01-07
FI20060346L (fi) 2007-10-11
BRPI0710144B1 (pt) 2016-06-14

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