CA2633676C - The use of mofs in pressure swing adsorption - Google Patents

The use of mofs in pressure swing adsorption Download PDF

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Publication number
CA2633676C
CA2633676C CA2633676A CA2633676A CA2633676C CA 2633676 C CA2633676 C CA 2633676C CA 2633676 A CA2633676 A CA 2633676A CA 2633676 A CA2633676 A CA 2633676A CA 2633676 C CA2633676 C CA 2633676C
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CA
Canada
Prior art keywords
adsorption
pressure
adsorbent
desorption
bed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA2633676A
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English (en)
French (fr)
Other versions
CA2633676A1 (en
Inventor
Mark Mchale Davis
John James Low
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honeywell UOP LLC
Original Assignee
UOP LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by UOP LLC filed Critical UOP LLC
Publication of CA2633676A1 publication Critical patent/CA2633676A1/en
Application granted granted Critical
Publication of CA2633676C publication Critical patent/CA2633676C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B01D2253/204—Metal organic frameworks (MOF's)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/16—Hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702—Hydrocarbons
    • B01D2257/7022—Aliphatic hydrocarbons
    • B01D2257/7025—Methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042—Purification by adsorption on solids
    • C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/048—Composition of the impurity the impurity being an organic compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/20—Capture or disposal of greenhouse gases of methane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
    • Y02P20/156—Methane [CH4]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CA2633676A 2005-12-21 2006-12-13 The use of mofs in pressure swing adsorption Expired - Fee Related CA2633676C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US75257405P 2005-12-21 2005-12-21
US60/752,574 2005-12-21
PCT/US2006/062042 WO2007111739A2 (en) 2005-12-21 2006-12-13 The use of mofs in pressure swing adsorption

Publications (2)

Publication Number Publication Date
CA2633676A1 CA2633676A1 (en) 2007-10-04
CA2633676C true CA2633676C (en) 2014-07-29

Family

ID=38541597

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2633676A Expired - Fee Related CA2633676C (en) 2005-12-21 2006-12-13 The use of mofs in pressure swing adsorption

Country Status (7)

Country Link
EP (1) EP1963767A4 (de)
CN (1) CN101346182A (de)
AU (1) AU2006340775A1 (de)
CA (1) CA2633676C (de)
NZ (1) NZ569159A (de)
WO (1) WO2007111739A2 (de)
ZA (1) ZA200805557B (de)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8540802B2 (en) 2007-05-11 2013-09-24 The Regents Of The University Of California Adsorptive gas separation of multi-component gases
WO2009020745A2 (en) 2007-07-17 2009-02-12 The Regents Of The University Of California Preparation of functionalized zeolitic frameworks
JP5730574B2 (ja) 2007-09-25 2015-06-10 ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア 食用に適した生体適合性金属有機構造体
WO2009149381A2 (en) 2008-06-05 2009-12-10 The Regents Of University Of California Chemical framework compositions and methods of use
WO2010090683A1 (en) * 2008-12-18 2010-08-12 The Regents Of The University Of California Metal organic frameworks (mofs ) for gas purification
WO2010080618A2 (en) 2008-12-18 2010-07-15 The Regents Of The University Of California Porous reactive frameworks
EP2356072A1 (de) 2008-12-29 2011-08-17 The Regents of the University of California Gassensor mit poröser struktur
US8674128B2 (en) 2009-01-15 2014-03-18 The Regents Of The University Of California Conductive organometallic framework
EP2384237A1 (de) * 2009-02-02 2011-11-09 The Regents of The University of California Reversibles einfangen von ethylenoxid in porösen gerüsten
WO2010148276A2 (en) 2009-06-19 2010-12-23 The Regents Of The University Of California Carbon dioxide capture and storage using open frameworks
CN102482294B (zh) 2009-06-19 2016-02-03 加利福尼亚大学董事会 复杂的混合配体开放骨架材料
EP2467388A4 (de) 2009-09-25 2014-12-17 Univ California Offene metalloorganische rahmenwerke mit besonderem oberflächenbereich und hoher gasspeicherungskapazität
RU2406558C1 (ru) * 2009-10-29 2010-12-20 Общество с ограниченной ответственностью "ЭНВАЙРОКЕТ" Адсорбент для удаления углеводородов из выхлопных газов автомобиля
JP2013533272A (ja) 2010-07-20 2013-08-22 ザ レジェンツ オブ ザ ユニヴァースティ オブ カリフォルニア 触媒として金属有機構造体（ｍｏｆ）を使用する有機分子の官能基化
CA2812294A1 (en) 2010-09-27 2012-06-21 The Regents Of The University Of California Conductive open frameworks
AU2012207079A1 (en) 2011-01-21 2013-07-04 The Regents Of The University Of California Preparation of metal-triazolate frameworks
KR20140041445A (ko) 2011-02-04 2014-04-04 더 리젠츠 오브 더 유니버시티 오브 캘리포니아 금속-카테콜레이트 골격체의 제조
CN104302387B (zh) 2011-10-13 2019-06-18 加利福尼亚大学董事会 具有格外大的孔口的金属有机骨架
JP6717749B2 (ja) 2014-02-19 2020-07-01 ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア 耐酸性、耐溶剤性、及び耐熱性金属−有機骨格
CN107148422A (zh) 2014-03-18 2017-09-08 加利福尼亚大学董事会 包含微孔金属有机骨架的有序超晶格的介观材料
US10087205B2 (en) 2014-03-28 2018-10-02 The Regents Of The University Of California Metal organic frameworks comprising a plurality of SBUS with different metal ions and/or a plurality of organic linking ligands with different functional groups
JP2018538282A (ja) 2015-11-27 2018-12-27 ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア ゼオライト様イミダゾレート構造体
RU2607735C1 (ru) * 2015-12-02 2017-01-10 Леонид Федорович Шестиперстов Разделение многокомпонентных газовых смесей способом короткоцикловой безнагревной адсорбции с трехэтапным извлечением целевого газа высокой чистоты
US10315152B2 (en) 2017-06-08 2019-06-11 DK Engineering Consulting LLC Method and system for pressure swing adsorption
US12551863B2 (en) 2020-02-24 2026-02-17 ExxonMobil Technology and Engineering Company Systems and methods for gas storage and transportation
CN116036798B (zh) * 2021-10-28 2024-08-02 中国石油化工股份有限公司 一种分离氢气混合气体的方法及系统和应用
CN113830735B (zh) * 2021-11-23 2022-07-12 清华大学 碳氢燃料重整中温净化制氢方法、设备和燃料电池供能系统

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5042995A (en) * 1989-12-28 1991-08-27 Uop Pressure swing adsorption with intermediate product recovery using two adsorption zones
EP0684066A3 (de) * 1994-05-26 1996-05-22 Boc Group Inc Verfahren zur Zurückgewinnung eines leichten Elementes aus einem verdünnten Rohgas.
ATE334992T1 (de) * 2001-04-30 2006-08-15 Univ Michigan Isoretikuläre organometallische grundstrukturen, verfahren zu deren bildung und systematische entwicklung von deren porengrösse und funktionalität, mit anwendung für die gasspeicherung

Also Published As

Publication number Publication date
CA2633676A1 (en) 2007-10-04
EP1963767A4 (de) 2010-03-03
CN101346182A (zh) 2009-01-14
EP1963767A2 (de) 2008-09-03
AU2006340775A1 (en) 2007-10-04
WO2007111739A3 (en) 2007-12-21
NZ569159A (en) 2010-11-26
WO2007111739A2 (en) 2007-10-04
ZA200805557B (en) 2009-12-30
WO2007111739B1 (en) 2008-03-06

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Effective date: 20171213