WO2007111739A3 - The use of mofs in pressure swing adsorption - Google Patents

The use of mofs in pressure swing adsorption Download PDF

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Publication number
WO2007111739A3
WO2007111739A3 PCT/US2006/062042 US2006062042W WO2007111739A3 WO 2007111739 A3 WO2007111739 A3 WO 2007111739A3 US 2006062042 W US2006062042 W US 2006062042W WO 2007111739 A3 WO2007111739 A3 WO 2007111739A3
Authority
WO
WIPO (PCT)
Prior art keywords
metal organic
organic framework
swing adsorption
pressure swing
framework material
Prior art date
Application number
PCT/US2006/062042
Other languages
French (fr)
Other versions
WO2007111739B1 (en
WO2007111739A2 (en
Inventor
Mark M Davis
John J Low
Original Assignee
Uop Llc
Mark M Davis
John J Low
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uop Llc, Mark M Davis, John J Low filed Critical Uop Llc
Priority to AU2006340775A priority Critical patent/AU2006340775A1/en
Priority to EP06850287A priority patent/EP1963767A4/en
Priority to CA2633676A priority patent/CA2633676C/en
Priority to NZ569159A priority patent/NZ569159A/en
Publication of WO2007111739A2 publication Critical patent/WO2007111739A2/en
Publication of WO2007111739A3 publication Critical patent/WO2007111739A3/en
Publication of WO2007111739B1 publication Critical patent/WO2007111739B1/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B01D2253/204—Metal organic frameworks (MOF's)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/16—Hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702—Hydrocarbons
    • B01D2257/7022—Aliphatic hydrocarbons
    • B01D2257/7025—Methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042—Purification by adsorption on solids
    • C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/048—Composition of the impurity the impurity being an organic compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/20—Capture or disposal of greenhouse gases of methane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
    • Y02P20/156—Methane [CH4]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

A pressure swing adsorption process for removing light hydrocarbons from a hydrogen stream wherein the process passes the hydrogen stream over a metal organic framework material at a high adsorption pressure, generating an effluent stream with reduced hydrocarbon content. The process then reduces the pressure over the metal organic framework material and releases the hydrocarbon from the material, and generates a stream having hydrocarbons. Further, the process uses multiple adsorption beds comprising the metal organic framework material and cycles the pressures sequentially through the beds to produce a continuous process.
PCT/US2006/062042 2005-12-21 2006-12-13 The use of mofs in pressure swing adsorption WO2007111739A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
AU2006340775A AU2006340775A1 (en) 2005-12-21 2006-12-13 The use of MOFs in pressure swing adsorption
EP06850287A EP1963767A4 (en) 2005-12-21 2006-12-13 The use of mofs in pressure swing adsorption
CA2633676A CA2633676C (en) 2005-12-21 2006-12-13 The use of mofs in pressure swing adsorption
NZ569159A NZ569159A (en) 2005-12-21 2006-12-13 The use of MOFS in pressure swing adsorption

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US75257405P 2005-12-21 2005-12-21
US60/752,574 2005-12-21

Publications (3)

Publication Number Publication Date
WO2007111739A2 WO2007111739A2 (en) 2007-10-04
WO2007111739A3 true WO2007111739A3 (en) 2007-12-21
WO2007111739B1 WO2007111739B1 (en) 2008-03-06

Family

ID=38541597

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/062042 WO2007111739A2 (en) 2005-12-21 2006-12-13 The use of mofs in pressure swing adsorption

Country Status (7)

Country Link
EP (1) EP1963767A4 (en)
CN (1) CN101346182A (en)
AU (1) AU2006340775A1 (en)
CA (1) CA2633676C (en)
NZ (1) NZ569159A (en)
WO (1) WO2007111739A2 (en)
ZA (1) ZA200805557B (en)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008140788A1 (en) 2007-05-11 2008-11-20 The Regents Of The University Of California Adsorptive gas separation of multi-component gases
US8480792B2 (en) 2007-07-17 2013-07-09 The Regents Of The University Of California Preparation of functionalized zeolitic frameworks
EP2190662B1 (en) 2007-09-25 2018-12-26 The Regents of The University of California Edible and biocompatible metal-organic frameworks
US8946454B2 (en) 2008-06-05 2015-02-03 The Regents Of The University Of California Chemical framework compositions and methods of use
US20110277767A1 (en) * 2008-12-18 2011-11-17 The Regents Of The University Of California Metal organic frameworks (mofs) for air purification
WO2010080618A2 (en) 2008-12-18 2010-07-15 The Regents Of The University Of California Porous reactive frameworks
WO2010078337A1 (en) 2008-12-29 2010-07-08 The Regents Of The University Of California A gas sensor incorporating a porous framework
WO2010083418A1 (en) 2009-01-15 2010-07-22 The Regents Of The University Of California Conductive organometallic framework
WO2010088629A1 (en) * 2009-02-02 2010-08-05 The Regents Of The University Of California Reversible ethylene oxide capture in porous frameworks
EP2438073A4 (en) 2009-06-19 2013-01-02 Univ California Complex mixed ligand open framework materials
WO2010148276A2 (en) 2009-06-19 2010-12-23 The Regents Of The University Of California Carbon dioxide capture and storage using open frameworks
US8841471B2 (en) 2009-09-25 2014-09-23 The Regents Of The University Of California Open metal organic frameworks with exceptional surface area and high gas storage capacity
US9102609B2 (en) 2010-07-20 2015-08-11 The Regents Of The University Of California Functionalization of organic molecules using metal-organic frameworks (MOFS) as catalysts
JP2013540760A (en) 2010-09-27 2013-11-07 ザ レジェンツ オブ ザ ユニヴァースティ オブ カリフォルニア Conductive open skeleton
WO2012100224A2 (en) 2011-01-21 2012-07-26 The Regents Of The University Of California Preparation of metal-triazolate frameworks
US8742152B2 (en) 2011-02-04 2014-06-03 The Regents Of The University Of California Preparation of metal-catecholate frameworks
CN104302387B (en) 2011-10-13 2019-06-18 加利福尼亚大学董事会 Metal organic framework with especially big aperture
ES2768680T3 (en) 2014-02-19 2020-06-23 Univ California Organometallic frames that have resistance to acids, solvents, and thermal
EP3074405A2 (en) 2014-03-18 2016-10-05 The Regents of the University of California Mesoscopic materials comprised of ordered superlattices of microporous metal-organic frameworks
US10087205B2 (en) 2014-03-28 2018-10-02 The Regents Of The University Of California Metal organic frameworks comprising a plurality of SBUS with different metal ions and/or a plurality of organic linking ligands with different functional groups
KR20180087369A (en) 2015-11-27 2018-08-01 더 리젠츠 오브 더 유니버시티 오브 캘리포니아 Zeolite imidazolate framework
RU2607735C1 (en) * 2015-12-02 2017-01-10 Леонид Федорович Шестиперстов Separation of multicomponent gas mixtures by short-cycle unheated adsorption with three-stage extraction of target gas of high purity
US10315152B2 (en) 2017-06-08 2019-06-11 DK Engineering Consulting LLC Method and system for pressure swing adsorption
CN113830735B (en) * 2021-11-23 2022-07-12 清华大学 Medium-temperature purification hydrogen production method and equipment for reforming hydrocarbon fuel and fuel cell energy supply system

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5042995A (en) * 1989-12-28 1991-08-27 Uop Pressure swing adsorption with intermediate product recovery using two adsorption zones
US20050192175A1 (en) * 2001-04-30 2005-09-01 Yaghi Omar M. Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0684066A3 (en) * 1994-05-26 1996-05-22 Boc Group Inc Method of recovering a light element from a dilute feed.

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5042995A (en) * 1989-12-28 1991-08-27 Uop Pressure swing adsorption with intermediate product recovery using two adsorption zones
US20050192175A1 (en) * 2001-04-30 2005-09-01 Yaghi Omar M. Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP1963767A4 *

Also Published As

Publication number Publication date
ZA200805557B (en) 2009-12-30
NZ569159A (en) 2010-11-26
CN101346182A (en) 2009-01-14
WO2007111739B1 (en) 2008-03-06
EP1963767A4 (en) 2010-03-03
EP1963767A2 (en) 2008-09-03
CA2633676C (en) 2014-07-29
WO2007111739A2 (en) 2007-10-04
AU2006340775A1 (en) 2007-10-04
CA2633676A1 (en) 2007-10-04

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