WO2007111738A3 - The use of mofs in pressure swing adsorption - Google Patents

The use of mofs in pressure swing adsorption Download PDF

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Publication number
WO2007111738A3
WO2007111738A3 PCT/US2006/062038 US2006062038W WO2007111738A3 WO 2007111738 A3 WO2007111738 A3 WO 2007111738A3 US 2006062038 W US2006062038 W US 2006062038W WO 2007111738 A3 WO2007111738 A3 WO 2007111738A3
Authority
WO
WIPO (PCT)
Prior art keywords
metal organic
organic framework
swing adsorption
pressure swing
framework material
Prior art date
Application number
PCT/US2006/062038
Other languages
French (fr)
Other versions
WO2007111738A2 (en
WO2007111738B1 (en
Inventor
Mark M Davis
John J Low
Original Assignee
Uop Llc
Mark M Davis
John J Low
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uop Llc, Mark M Davis, John J Low filed Critical Uop Llc
Priority to CA002633652A priority Critical patent/CA2633652A1/en
Priority to AU2006340774A priority patent/AU2006340774A1/en
Priority to EP06850286A priority patent/EP1963766A2/en
Priority to JP2008547688A priority patent/JP2009521320A/en
Publication of WO2007111738A2 publication Critical patent/WO2007111738A2/en
Publication of WO2007111738A3 publication Critical patent/WO2007111738A3/en
Publication of WO2007111738B1 publication Critical patent/WO2007111738B1/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B01D2253/204—Metal organic frameworks (MOF's)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/306—Surface area, e.g. BET-specific surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/308—Pore size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/24—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/24—Hydrocarbons
    • B01D2256/245—Methane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40077—Direction of flow
    • B01D2259/40081—Counter-current
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

A pressure swing adsorption process for removing light hydrocarbons from a hydrogen stream wherein the process passes the hydrogen stream over a metal organic framework material at a high adsorption pressure, generating an effluent stream with reduced hydrocarbon content. The process then reduces the pressure over the metal organic framework material and releases the hydrocarbon From the material, and generates a stream having hydrocarbons. Further, the process uses multiple adsorption beds comprising the metal organic framework material and cycles the pressures sequentially through the beds to produce a continuous process.
PCT/US2006/062038 2005-12-21 2006-12-13 The use of mofs in pressure swing adsorption WO2007111738A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CA002633652A CA2633652A1 (en) 2005-12-21 2006-12-13 The use of mofs in pressure swing adsorption
AU2006340774A AU2006340774A1 (en) 2005-12-21 2006-12-13 The use of MOFs in pressure swing adsorption
EP06850286A EP1963766A2 (en) 2005-12-21 2006-12-13 The use of mofs in pressure swing adsorption
JP2008547688A JP2009521320A (en) 2005-12-21 2006-12-13 Use of MOF in pressure swing adsorption

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US75245105P 2005-12-21 2005-12-21
US60/752,451 2005-12-21

Publications (3)

Publication Number Publication Date
WO2007111738A2 WO2007111738A2 (en) 2007-10-04
WO2007111738A3 true WO2007111738A3 (en) 2008-01-10
WO2007111738B1 WO2007111738B1 (en) 2008-02-21

Family

ID=38541596

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/062038 WO2007111738A2 (en) 2005-12-21 2006-12-13 The use of mofs in pressure swing adsorption

Country Status (7)

Country Link
EP (1) EP1963766A2 (en)
JP (1) JP2009521320A (en)
CN (1) CN101346183A (en)
AU (1) AU2006340774A1 (en)
CA (1) CA2633652A1 (en)
RU (1) RU2008129692A (en)
WO (1) WO2007111738A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
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US9017457B2 (en) 2011-03-01 2015-04-28 Exxonmobil Upstream Research Company Apparatus and systems having a reciprocating valve head assembly and swing adsorption processes related thereto

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WO2009064569A1 (en) 2007-11-12 2009-05-22 Exxonmobil Upstream Research Company Methods of generating and utilizing utility gas
JP5577324B2 (en) 2008-04-30 2014-08-20 エクソンモービル アップストリーム リサーチ カンパニー Method and apparatus for removing oil from a utility gas stream
US8425674B2 (en) 2008-10-24 2013-04-23 Exxonmobil Research And Engineering Company System using unutilized heat for cooling and/or power generation
ES2511049T3 (en) * 2009-03-20 2014-10-22 Basf Se Procedure for the separation of acid gases with the help of organometallic structure materials impregnated with amines
GB201000824D0 (en) 2010-01-19 2010-03-03 Univ East Anglia Material for storing hydrogen
US20110219802A1 (en) 2010-03-09 2011-09-15 Exxonmobil Research And Engineering Company Sorption systems having improved cycle times
US8500887B2 (en) 2010-03-25 2013-08-06 Exxonmobil Research And Engineering Company Method of protecting a solid adsorbent and a protected solid adsorbent
US20110232305A1 (en) 2010-03-26 2011-09-29 Exxonmobil Research And Engineering Company Systems and methods for generating power and chilling using unutilized heat
US20110239692A1 (en) 2010-04-01 2011-10-06 Exxonmobil Research And Engineering Company Utilization of waste heat using fiber sorbent system and method of using same
WO2011149640A1 (en) 2010-05-28 2011-12-01 Exxonmobil Upstream Research Company Integrated adsorber head and valve design and swing adsorption methods related thereto
US8580018B2 (en) 2010-11-12 2013-11-12 Exxonmobil Research And Engineering Company Recovery of greenhouse gas and pressurization for transport
US20120118004A1 (en) 2010-11-12 2012-05-17 Exxonmobil Research And Engineering Company Adsorption chilling for compressing and transporting gases
TWI495501B (en) 2010-11-15 2015-08-11 Exxonmobil Upstream Res Co Kinetic fractionators, and cycling processes for fractionation of gas mixtures
US9352269B2 (en) 2011-03-01 2016-05-31 Exxonmobil Upstream Research Company Apparatus and systems having a rotary valve assembly and swing adsorption processes related thereto
AU2012223571B2 (en) 2011-03-01 2016-08-25 Exxonmobil Upstream Research Company Apparatus and systems having an encased adsorbent contactor and swing adsorption processes related thereto
EA024199B1 (en) 2011-03-01 2016-08-31 Эксонмобил Апстрим Рисерч Компани Method of removing contaminants from a natural gas stream by swing adsorption
AU2012223486A1 (en) 2011-03-01 2013-08-15 Exxonmobil Upstream Research Company Apparatus and systems having a rotary valve assembly and swing adsorption processes related thereto
AU2012259377B2 (en) 2011-03-01 2016-12-01 Exxonmobil Upstream Research Company Methods of removing contaminants from a hydrocarbon stream by swing adsorption and related apparatus and systems
CA2824994A1 (en) 2011-03-01 2012-09-07 Exxonmobil Upstream Research Company Apparatus and systems having compact configuration multiple swing adsorption beds and methods related thereto
CN102423600B (en) * 2011-10-28 2014-04-02 中国石油大学(北京) Method for improving adsorption separation efficiency of CO2-containing mixed gas
WO2014015383A1 (en) * 2012-07-26 2014-01-30 Commonwealth Scientific And Industrial Research Organisation Gas separation processes
US9034078B2 (en) 2012-09-05 2015-05-19 Exxonmobil Upstream Research Company Apparatus and systems having an adsorbent contactor and swing adsorption processes related thereto
WO2014056164A1 (en) * 2012-10-10 2014-04-17 南京工业大学 Regeneration method for cu-btc material
JP6575050B2 (en) * 2014-08-12 2019-09-18 株式会社Ihi Carbon dioxide recovery method and recovery apparatus
US9751041B2 (en) 2015-05-15 2017-09-05 Exxonmobil Upstream Research Company Apparatus and system for swing adsorption processes related thereto
EA201792488A1 (en) 2015-05-15 2018-03-30 Эксонмобил Апстрим Рисерч Компани APPARATUS AND SYSTEM FOR PROCESSES OF SHORT-CYCLE ADSORPTION, ASSOCIATED WITH IT, CONTAINING SYSTEMS OF THE BLOWING OF THE MIDDLE LAYER
US11285455B2 (en) 2016-10-17 2022-03-29 Korea Research Institute Of Chemical Technology Organic-inorganic hybrid nanoporous material containing intramolecular acid anhydride functional group, composition for adsorption comprising the same, and use thereof for separation of hydrocarbon gas mixture
EP3897921B1 (en) 2018-12-21 2024-05-01 Massey University Method for co2 adsorption on metal organic framework
CN115803919A (en) 2020-05-22 2023-03-14 纽麦特技术有限公司 Method for purifying hydrogen for use in a fuel cell
CN113145078B (en) * 2021-03-28 2023-04-07 桂林理工大学 Composite MOFs material with high-dispersion nanometer Rh component and suitable for adsorption separation of NO in smoke
WO2023248967A1 (en) * 2022-06-20 2023-12-28 日本碍子株式会社 Regeneration method for acidic gas adsorption device, and manufacturing method for acidic gas adsorption device
US20230415088A1 (en) * 2022-06-24 2023-12-28 International Business Machines Corporation Voltage-swing method for carbon capture using porous carbons

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5042995A (en) * 1989-12-28 1991-08-27 Uop Pressure swing adsorption with intermediate product recovery using two adsorption zones
US20050192175A1 (en) * 2001-04-30 2005-09-01 Yaghi Omar M. Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5042995A (en) * 1989-12-28 1991-08-27 Uop Pressure swing adsorption with intermediate product recovery using two adsorption zones
US20050192175A1 (en) * 2001-04-30 2005-09-01 Yaghi Omar M. Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9017457B2 (en) 2011-03-01 2015-04-28 Exxonmobil Upstream Research Company Apparatus and systems having a reciprocating valve head assembly and swing adsorption processes related thereto

Also Published As

Publication number Publication date
WO2007111738A2 (en) 2007-10-04
RU2008129692A (en) 2010-01-27
JP2009521320A (en) 2009-06-04
AU2006340774A1 (en) 2007-10-04
EP1963766A2 (en) 2008-09-03
WO2007111738B1 (en) 2008-02-21
CA2633652A1 (en) 2007-10-04
CN101346183A (en) 2009-01-14

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