CA2615398C - Fiber network layers and flexible penetration resistant articles comprising same - Google Patents
Fiber network layers and flexible penetration resistant articles comprising same Download PDFInfo
- Publication number
- CA2615398C CA2615398C CA2615398A CA2615398A CA2615398C CA 2615398 C CA2615398 C CA 2615398C CA 2615398 A CA2615398 A CA 2615398A CA 2615398 A CA2615398 A CA 2615398A CA 2615398 C CA2615398 C CA 2615398C
- Authority
- CA
- Canada
- Prior art keywords
- yarns
- fiber network
- polymer
- network layer
- layers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 72
- 230000035515 penetration Effects 0.000 title claims abstract description 13
- 229920000642 polymer Polymers 0.000 claims abstract description 42
- 229920002577 polybenzoxazole Polymers 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 13
- 239000004952 Polyamide Substances 0.000 claims description 7
- 229920002647 polyamide Polymers 0.000 claims description 7
- 229920000098 polyolefin Polymers 0.000 claims description 6
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 5
- 239000010410 layer Substances 0.000 description 55
- 239000004744 fabric Substances 0.000 description 31
- 230000000052 comparative effect Effects 0.000 description 18
- -1 poly(p-phenylene-2,6-benzobisoxazole) Polymers 0.000 description 18
- 239000004760 aramid Substances 0.000 description 15
- 229920003235 aromatic polyamide Polymers 0.000 description 14
- 235000004879 dioscorea Nutrition 0.000 description 11
- 229920005992 thermoplastic resin Polymers 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 239000004698 Polyethylene Substances 0.000 description 7
- 239000002131 composite material Substances 0.000 description 7
- 239000011159 matrix material Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 229920000573 polyethylene Polymers 0.000 description 7
- 239000000178 monomer Substances 0.000 description 6
- 150000001805 chlorine compounds Chemical group 0.000 description 5
- 150000004985 diamines Chemical group 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 229920000137 polyphosphoric acid Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000004634 thermosetting polymer Substances 0.000 description 5
- OYFRNYNHAZOYNF-UHFFFAOYSA-N 2,5-dihydroxyterephthalic acid Chemical compound OC(=O)C1=CC(O)=C(C(O)=O)C=C1O OYFRNYNHAZOYNF-UHFFFAOYSA-N 0.000 description 4
- 229920000271 Kevlar® Polymers 0.000 description 4
- 229920003373 Kevlar® 129 Polymers 0.000 description 4
- 239000004761 kevlar Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 229920001187 thermosetting polymer Polymers 0.000 description 4
- 238000009941 weaving Methods 0.000 description 4
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 3
- 229920001096 M5 fiber Polymers 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 239000006096 absorbing agent Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 229920006231 aramid fiber Polymers 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 239000002356 single layer Substances 0.000 description 3
- LXEJRKJRKIFVNY-UHFFFAOYSA-N terephthaloyl chloride Chemical compound ClC(=O)C1=CC=C(C(Cl)=O)C=C1 LXEJRKJRKIFVNY-UHFFFAOYSA-N 0.000 description 3
- 239000002759 woven fabric Substances 0.000 description 3
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- 235000009967 Erodium cicutarium Nutrition 0.000 description 2
- 240000003759 Erodium cicutarium Species 0.000 description 2
- 239000004696 Poly ether ether ketone Substances 0.000 description 2
- 239000004642 Polyimide Substances 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 229920003366 poly(p-phenylene terephthalamide) Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 229920002530 polyetherether ketone Polymers 0.000 description 2
- 229920001721 polyimide Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- IAYUQKZZQKUOFL-UHFFFAOYSA-N pyridine-2,3,5,6-tetramine Chemical compound NC1=CC(N)=C(N)N=C1N IAYUQKZZQKUOFL-UHFFFAOYSA-N 0.000 description 2
- 230000003252 repetitive effect Effects 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- ZZPLGBZOTXYEQS-UHFFFAOYSA-N 2,3-dichlorobenzene-1,4-dicarbonyl chloride Chemical compound ClC(=O)C1=CC=C(C(Cl)=O)C(Cl)=C1Cl ZZPLGBZOTXYEQS-UHFFFAOYSA-N 0.000 description 1
- RLXBOUUYEFOFSW-UHFFFAOYSA-N 2,5-diaminobenzene-1,4-diol Chemical compound NC1=CC(O)=C(N)C=C1O RLXBOUUYEFOFSW-UHFFFAOYSA-N 0.000 description 1
- ZBMISJGHVWNWTE-UHFFFAOYSA-N 3-(4-aminophenoxy)aniline Chemical compound C1=CC(N)=CC=C1OC1=CC=CC(N)=C1 ZBMISJGHVWNWTE-UHFFFAOYSA-N 0.000 description 1
- DPYROBMRMXHROQ-UHFFFAOYSA-N 4,6-diaminobenzene-1,3-diol Chemical compound NC1=CC(N)=C(O)C=C1O DPYROBMRMXHROQ-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 150000004984 aromatic diamines Chemical class 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 125000002529 biphenylenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C12)* 0.000 description 1
- 125000002837 carbocyclic group Chemical group 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 238000007539 photo-oxidation reaction Methods 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920005594 polymer fiber Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 125000005551 pyridylene group Chemical group 0.000 description 1
- CYVYLVVUKPNYKL-UHFFFAOYSA-N quinoline-2,6-dicarboxylic acid Chemical compound N1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 CYVYLVVUKPNYKL-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 125000005628 tolylene group Chemical group 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/08—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D1/00—Woven fabrics designed to make specified articles
- D03D1/0035—Protective fabrics
- D03D1/0052—Antiballistic fabrics
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F41—WEAPONS
- F41H—ARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
- F41H5/00—Armour; Armour plates
- F41H5/02—Plate construction
- F41H5/04—Plate construction composed of more than one layer
- F41H5/0471—Layered armour containing fibre- or fabric-reinforced layers
- F41H5/0485—Layered armour containing fibre- or fabric-reinforced layers all the layers being only fibre- or fabric-reinforced layers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3179—Woven fabric is characterized by a particular or differential weave other than fabric in which the strand denier or warp/weft pick count is specified
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Ceramic Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Woven Fabrics (AREA)
- Aiming, Guidance, Guns With A Light Source, Armor, Camouflage, And Targets (AREA)
- Laminated Bodies (AREA)
- Manufacturing Of Multi-Layer Textile Fabrics (AREA)
- Nonwoven Fabrics (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US70720005P | 2005-08-10 | 2005-08-10 | |
| US60/707,200 | 2005-08-10 | ||
| US72089805P | 2005-09-27 | 2005-09-27 | |
| US60/720,898 | 2005-09-27 | ||
| PCT/US2006/031010 WO2008016363A2 (en) | 2005-08-10 | 2006-08-08 | Fiber network layers and flexible penetration resistant articles comprising same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2615398A1 CA2615398A1 (en) | 2007-02-10 |
| CA2615398C true CA2615398C (en) | 2016-05-10 |
Family
ID=38997598
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2615398A Expired - Fee Related CA2615398C (en) | 2005-08-10 | 2006-08-08 | Fiber network layers and flexible penetration resistant articles comprising same |
Country Status (8)
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI487820B (zh) * | 2008-05-26 | 2015-06-11 | Teijin Aramid Gmbh | 阻礙穿刺之物品 |
| KR101017930B1 (ko) * | 2008-12-23 | 2011-03-04 | 주식회사 대유신소재 | 경량화 알루미늄 휠의 제조방법 및 그 알루미늄 휠 |
| US8898821B2 (en) | 2009-05-19 | 2014-12-02 | Southern Mills, Inc. | Flame resistant fabric with anisotropic properties |
| US9386816B2 (en) | 2012-02-14 | 2016-07-12 | International Textile Group, Inc. | Fire resistant garments containing a high lubricity thermal liner |
| ITFI20120261A1 (it) * | 2012-11-28 | 2014-05-29 | Manifattura Pri Ma Tex S R L | Tessuto per abbigliamento protettivo. |
| WO2014143346A1 (en) | 2012-12-21 | 2014-09-18 | Southern Mills, Inc. | Fabrics with ballistic protection and garments made from same |
| US9243354B2 (en) * | 2013-03-15 | 2016-01-26 | Honeywell International Inc. | Stab and ballistic resistant articles |
| US10405594B2 (en) | 2015-05-21 | 2019-09-10 | International Textile Group, Inc. | Inner lining fabric |
| CA3135175C (en) | 2019-03-28 | 2022-10-18 | Southern Mills, Inc. | Flame resistant fabrics |
| JP7488107B2 (ja) * | 2020-05-19 | 2024-05-21 | 帝人株式会社 | 布帛および繊維製品 |
| JP7597600B2 (ja) * | 2021-02-09 | 2024-12-10 | 帝人株式会社 | 布帛および繊維製品 |
| KR20240037351A (ko) | 2021-08-10 | 2024-03-21 | 써던 밀즈, 인코포레이티드 | 방염성 직물 |
| CN114717714A (zh) * | 2022-04-29 | 2022-07-08 | 河北普凡防护科技有限公司 | 一种防弹机织物的织造方法 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3094511A (en) * | 1958-11-17 | 1963-06-18 | Du Pont | Wholly aromatic polyamides |
| US3354127A (en) * | 1966-04-18 | 1967-11-21 | Du Pont | Aromatic copolyamides |
| US3819587A (en) * | 1969-05-23 | 1974-06-25 | Du Pont | Wholly aromatic carbocyclic polycarbonamide fiber having orientation angle of less than about 45{20 |
| US3673143A (en) * | 1970-06-24 | 1972-06-27 | Du Pont | Optically anisotropic spinning dopes of polycarbonamides |
| US3869429A (en) * | 1971-08-17 | 1975-03-04 | Du Pont | High strength polyamide fibers and films |
| JPS53294A (en) * | 1976-06-23 | 1978-01-05 | Teijin Ltd | Preparation of aromatic polyamide with high degree of polymerization |
| JPH03219509A (ja) * | 1989-11-25 | 1991-09-26 | Seiko Epson Corp | スイッチ基板及びスイッチ基板製造方法 |
| US5180880A (en) * | 1990-02-28 | 1993-01-19 | Zufle T Tyler | Soft body armor |
| US5187003A (en) * | 1991-11-26 | 1993-02-16 | E. I. Du Pont De Nemours And Company | Hybrid ballistic fabric |
| US5456974A (en) * | 1993-03-12 | 1995-10-10 | Lundblad; Wayne E. | Ballistic resistant article comprising a three dimensional interlocking woven fabric |
| JPH10102346A (ja) * | 1996-09-25 | 1998-04-21 | Akizo Katsukura | 織 物 |
| US6155306A (en) * | 1996-09-25 | 2000-12-05 | Shozo Katsukura | Bulletproof woven fabric, and method and apparatus for weaving same |
| JP2001181941A (ja) * | 1999-12-22 | 2001-07-03 | Toyobo Co Ltd | 防護材料 |
| US6610619B2 (en) * | 1999-12-29 | 2003-08-26 | Kimberly-Clark Worldwide, Inc. | Patterned felts for bulk and visual aesthetic development of a tissue basesheet |
| CA2313995A1 (en) * | 2000-02-22 | 2001-08-22 | Lincoln Fabrics, Ltd. | Ballistic resistant fabric |
| RU2295107C2 (ru) * | 2001-05-03 | 2007-03-10 | Баррдэй, Инк. | Квазиоднонаправленная ткань для баллистического применения |
| US7241709B2 (en) * | 2002-08-26 | 2007-07-10 | E. I Du Pont De Nemours And Company | Penetration resistant life protection articles |
| US20040092183A1 (en) * | 2002-11-12 | 2004-05-13 | Shalom Geva | Antiballistic composite material comprising combinations of distinct types of fibers |
| US7100490B2 (en) * | 2003-07-01 | 2006-09-05 | Muller Jr Robert L | Body armor |
-
2006
- 2006-08-08 CA CA2615398A patent/CA2615398C/en not_active Expired - Fee Related
- 2006-08-08 JP JP2008527960A patent/JP2009504941A/ja active Pending
- 2006-08-08 BR BRPI0616521-4A patent/BRPI0616521A2/pt not_active Application Discontinuation
- 2006-08-08 EP EP20060851428 patent/EP1945844A2/en not_active Withdrawn
- 2006-08-08 KR KR1020087005607A patent/KR101290449B1/ko not_active Expired - Fee Related
- 2006-08-08 CN CN2006800367419A patent/CN101389796B/zh not_active Expired - Fee Related
- 2006-08-08 WO PCT/US2006/031010 patent/WO2008016363A2/en active Application Filing
- 2006-08-08 US US11/990,284 patent/US20100143683A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| EP1945844A2 (en) | 2008-07-23 |
| US20100143683A1 (en) | 2010-06-10 |
| CN101389796A (zh) | 2009-03-18 |
| JP2009504941A (ja) | 2009-02-05 |
| CA2615398A1 (en) | 2007-02-10 |
| WO2008016363A3 (en) | 2008-05-15 |
| KR20080034501A (ko) | 2008-04-21 |
| CN101389796B (zh) | 2012-12-05 |
| WO2008016363A2 (en) | 2008-02-07 |
| BRPI0616521A2 (pt) | 2011-06-21 |
| KR101290449B1 (ko) | 2013-07-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20170808 |