CA2608542A1 - Hybrid vapor compression-absorption cycle - Google Patents
Hybrid vapor compression-absorption cycle Download PDFInfo
- Publication number
- CA2608542A1 CA2608542A1 CA002608542A CA2608542A CA2608542A1 CA 2608542 A1 CA2608542 A1 CA 2608542A1 CA 002608542 A CA002608542 A CA 002608542A CA 2608542 A CA2608542 A CA 2608542A CA 2608542 A1 CA2608542 A1 CA 2608542A1
- Authority
- CA
- Canada
- Prior art keywords
- refrigerant
- vapor
- pressure
- hfc
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000010521 absorption reaction Methods 0.000 title abstract description 92
- 239000003507 refrigerant Substances 0.000 claims abstract description 370
- 239000002608 ionic liquid Substances 0.000 claims abstract description 133
- 238000000034 method Methods 0.000 claims abstract description 48
- 238000010438 heat treatment Methods 0.000 claims abstract description 31
- 238000001816 cooling Methods 0.000 claims abstract description 30
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000203 mixture Substances 0.000 claims description 182
- RWRIWBAIICGTTQ-UHFFFAOYSA-N difluoromethane Chemical compound FCF RWRIWBAIICGTTQ-UHFFFAOYSA-N 0.000 claims description 179
- 239000007788 liquid Substances 0.000 claims description 129
- 239000002250 absorbent Substances 0.000 claims description 96
- 230000002745 absorbent Effects 0.000 claims description 92
- -1 cyclic alkenes Chemical class 0.000 claims description 58
- 239000006096 absorbing agent Substances 0.000 claims description 50
- GTLACDSXYULKMZ-UHFFFAOYSA-N pentafluoroethane Chemical compound FC(F)C(F)(F)F GTLACDSXYULKMZ-UHFFFAOYSA-N 0.000 claims description 42
- 230000008569 process Effects 0.000 claims description 41
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 claims description 40
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 claims description 36
- 150000001450 anions Chemical class 0.000 claims description 35
- UJPMYEOUBPIPHQ-UHFFFAOYSA-N 1,1,1-trifluoroethane Chemical compound CC(F)(F)F UJPMYEOUBPIPHQ-UHFFFAOYSA-N 0.000 claims description 32
- 229910052757 nitrogen Inorganic materials 0.000 claims description 27
- 150000001768 cations Chemical class 0.000 claims description 23
- 239000000460 chlorine Substances 0.000 claims description 23
- 229910052731 fluorine Inorganic materials 0.000 claims description 21
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 18
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims description 18
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 18
- 150000001924 cycloalkanes Chemical class 0.000 claims description 17
- WXGNWUVNYMJENI-UHFFFAOYSA-N 1,1,2,2-tetrafluoroethane Chemical compound FC(F)C(F)F WXGNWUVNYMJENI-UHFFFAOYSA-N 0.000 claims description 16
- 230000009467 reduction Effects 0.000 claims description 16
- 150000001336 alkenes Chemical class 0.000 claims description 15
- 229910052801 chlorine Inorganic materials 0.000 claims description 15
- 125000005842 heteroatom Chemical group 0.000 claims description 14
- 229910052794 bromium Inorganic materials 0.000 claims description 13
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 claims description 13
- 235000019404 dichlorodifluoromethane Nutrition 0.000 claims description 13
- 125000001072 heteroaryl group Chemical group 0.000 claims description 13
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 claims description 13
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 claims description 12
- 229910052710 silicon Inorganic materials 0.000 claims description 12
- 229910052717 sulfur Inorganic materials 0.000 claims description 12
- OHMHBGPWCHTMQE-UHFFFAOYSA-N 2,2-dichloro-1,1,1-trifluoroethane Chemical compound FC(F)(F)C(Cl)Cl OHMHBGPWCHTMQE-UHFFFAOYSA-N 0.000 claims description 11
- 239000004215 Carbon black (E152) Substances 0.000 claims description 11
- UHCBBWUQDAVSMS-UHFFFAOYSA-N fluoroethane Chemical compound CCF UHCBBWUQDAVSMS-UHFFFAOYSA-N 0.000 claims description 11
- 229930195733 hydrocarbon Natural products 0.000 claims description 11
- 150000002430 hydrocarbons Chemical class 0.000 claims description 11
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 10
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 claims description 10
- LVZWSLJZHVFIQJ-UHFFFAOYSA-N Cyclopropane Chemical compound C1CC1 LVZWSLJZHVFIQJ-UHFFFAOYSA-N 0.000 claims description 9
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 9
- 239000001273 butane Substances 0.000 claims description 9
- 229910052740 iodine Inorganic materials 0.000 claims description 9
- 239000001282 iso-butane Substances 0.000 claims description 9
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 9
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- 239000001294 propane Substances 0.000 claims description 9
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 8
- 238000001704 evaporation Methods 0.000 claims description 8
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 8
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 7
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 7
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 238000009833 condensation Methods 0.000 claims description 5
- 230000005494 condensation Effects 0.000 claims description 5
- 239000000314 lubricant Substances 0.000 claims description 5
- 125000004122 cyclic group Chemical group 0.000 claims description 4
- 125000001424 substituent group Chemical group 0.000 claims description 4
- 125000003107 substituted aryl group Chemical group 0.000 claims description 4
- 101100283604 Caenorhabditis elegans pigk-1 gene Proteins 0.000 claims description 3
- 239000004338 Dichlorodifluoromethane Substances 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- 239000005977 Ethylene Substances 0.000 claims description 3
- 125000003342 alkenyl group Chemical group 0.000 claims description 3
- WMIYKQLTONQJES-UHFFFAOYSA-N hexafluoroethane Chemical compound FC(F)(F)C(F)(F)F WMIYKQLTONQJES-UHFFFAOYSA-N 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 2
- QLULGSLAHXLKSR-UHFFFAOYSA-N azane;phosphane Chemical compound N.P QLULGSLAHXLKSR-UHFFFAOYSA-N 0.000 claims description 2
- 125000002619 bicyclic group Chemical group 0.000 claims description 2
- 230000007797 corrosion Effects 0.000 claims description 2
- 238000005260 corrosion Methods 0.000 claims description 2
- 239000000975 dye Substances 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 239000003112 inhibitor Substances 0.000 claims description 2
- 239000003381 stabilizer Substances 0.000 claims description 2
- 229910021592 Copper(II) chloride Inorganic materials 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims 1
- 239000007789 gas Substances 0.000 abstract description 58
- 238000007906 compression Methods 0.000 abstract description 52
- 230000006835 compression Effects 0.000 abstract description 51
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 106
- IQQRAVYLUAZUGX-UHFFFAOYSA-N 1-butyl-3-methylimidazolium Chemical compound CCCCN1C=C[N+](C)=C1 IQQRAVYLUAZUGX-UHFFFAOYSA-N 0.000 description 90
- 239000000243 solution Substances 0.000 description 73
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 53
- 229910001868 water Inorganic materials 0.000 description 51
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 44
- IAZDPXIOMUYVGZ-WFGJKAKNSA-N Dimethyl sulfoxide Chemical compound [2H]C([2H])([2H])S(=O)C([2H])([2H])[2H] IAZDPXIOMUYVGZ-WFGJKAKNSA-N 0.000 description 32
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 31
- 238000002955 isolation Methods 0.000 description 26
- 239000003921 oil Substances 0.000 description 25
- 229910052799 carbon Inorganic materials 0.000 description 23
- 238000003786 synthesis reaction Methods 0.000 description 22
- 239000002244 precipitate Substances 0.000 description 21
- 230000015572 biosynthetic process Effects 0.000 description 20
- 239000000047 product Substances 0.000 description 20
- 238000004364 calculation method Methods 0.000 description 19
- 238000006243 chemical reaction Methods 0.000 description 19
- 150000001875 compounds Chemical class 0.000 description 18
- 238000010586 diagram Methods 0.000 description 18
- 238000009792 diffusion process Methods 0.000 description 17
- 239000007787 solid Substances 0.000 description 17
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 16
- 239000008367 deionised water Substances 0.000 description 16
- 229910021641 deionized water Inorganic materials 0.000 description 16
- 241000894007 species Species 0.000 description 16
- 238000004458 analytical method Methods 0.000 description 15
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 15
- 238000005057 refrigeration Methods 0.000 description 15
- NJMWOUFKYKNWDW-UHFFFAOYSA-N 1-ethyl-3-methylimidazolium Chemical compound CCN1C=C[N+](C)=C1 NJMWOUFKYKNWDW-UHFFFAOYSA-N 0.000 description 14
- 238000004293 19F NMR spectroscopy Methods 0.000 description 14
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 14
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 description 14
- 238000009835 boiling Methods 0.000 description 14
- 230000000694 effects Effects 0.000 description 14
- 229910002092 carbon dioxide Inorganic materials 0.000 description 13
- 239000003153 chemical reaction reagent Substances 0.000 description 13
- 239000011521 glass Substances 0.000 description 13
- 238000004448 titration Methods 0.000 description 13
- ZCQWOFVYLHDMMC-UHFFFAOYSA-O hydron;1,3-oxazole Chemical compound C1=COC=[NH+]1 ZCQWOFVYLHDMMC-UHFFFAOYSA-O 0.000 description 12
- 238000005481 NMR spectroscopy Methods 0.000 description 11
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 11
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 11
- WTKZEGDFNFYCGP-UHFFFAOYSA-O Pyrazolium Chemical compound C1=CN[NH+]=C1 WTKZEGDFNFYCGP-UHFFFAOYSA-O 0.000 description 11
- 239000011541 reaction mixture Substances 0.000 description 11
- 238000005160 1H NMR spectroscopy Methods 0.000 description 10
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 10
- 239000011737 fluorine Substances 0.000 description 10
- CZPWVGJYEJSRLH-UHFFFAOYSA-O hydron;pyrimidine Chemical compound C1=CN=C[NH+]=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-O 0.000 description 10
- 239000012071 phase Substances 0.000 description 10
- PBMFSQRYOILNGV-UHFFFAOYSA-N pyridazine Chemical compound C1=CC=NN=C1 PBMFSQRYOILNGV-UHFFFAOYSA-N 0.000 description 10
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 description 10
- BMQZYMYBQZGEEY-UHFFFAOYSA-M 1-ethyl-3-methylimidazolium chloride Chemical compound [Cl-].CCN1C=C[N+](C)=C1 BMQZYMYBQZGEEY-UHFFFAOYSA-M 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 230000008859 change Effects 0.000 description 9
- 239000010432 diamond Substances 0.000 description 9
- 239000012530 fluid Substances 0.000 description 9
- 229910052739 hydrogen Inorganic materials 0.000 description 9
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 9
- 230000003993 interaction Effects 0.000 description 9
- 239000010410 layer Substances 0.000 description 9
- 230000002829 reductive effect Effects 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- WXMVWUBWIHZLMQ-UHFFFAOYSA-N 3-methyl-1-octylimidazolium Chemical compound CCCCCCCCN1C=C[N+](C)=C1 WXMVWUBWIHZLMQ-UHFFFAOYSA-N 0.000 description 8
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 8
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 8
- 235000019341 magnesium sulphate Nutrition 0.000 description 8
- 229910052698 phosphorus Inorganic materials 0.000 description 8
- BVZFTIYNEUGOHK-UHFFFAOYSA-M potassium;1,1,2,2-tetrafluoroethanesulfonate Chemical compound [K+].[O-]S(=O)(=O)C(F)(F)C(F)F BVZFTIYNEUGOHK-UHFFFAOYSA-M 0.000 description 8
- 238000010992 reflux Methods 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- MEUAVGJWGDPTLF-UHFFFAOYSA-N 4-(5-benzenesulfonylamino-1-methyl-1h-benzoimidazol-2-ylmethyl)-benzamidine Chemical compound N=1C2=CC(NS(=O)(=O)C=3C=CC=CC=3)=CC=C2N(C)C=1CC1=CC=C(C(N)=N)C=C1 MEUAVGJWGDPTLF-UHFFFAOYSA-N 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 229910021529 ammonia Inorganic materials 0.000 description 7
- 238000012937 correction Methods 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- 239000000706 filtrate Substances 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 6
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- CCIVGXIOQKPBKL-UHFFFAOYSA-M ethanesulfonate Chemical compound CCS([O-])(=O)=O CCIVGXIOQKPBKL-UHFFFAOYSA-M 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
- 239000012467 final product Substances 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 229910001220 stainless steel Inorganic materials 0.000 description 5
- 239000010935 stainless steel Substances 0.000 description 5
- 238000000967 suction filtration Methods 0.000 description 5
- 125000001425 triazolyl group Chemical group 0.000 description 5
- FXJMBXFCCFVKKI-UHFFFAOYSA-M 1,3-dioctylimidazol-1-ium;iodide Chemical compound [I-].CCCCCCCCN1C=C[N+](CCCCCCCC)=C1 FXJMBXFCCFVKKI-UHFFFAOYSA-M 0.000 description 4
- KRLZUNVVBLGDJV-UHFFFAOYSA-M 1-methyl-3-octylimidazol-1-ium;iodide Chemical compound [I-].CCCCCCCC[N+]=1C=CN(C)C=1 KRLZUNVVBLGDJV-UHFFFAOYSA-M 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 238000004378 air conditioning Methods 0.000 description 4
- XOZHIVUWCICHSQ-UHFFFAOYSA-N bis(trifluoromethylsulfonyl)azanide;1,2-dimethyl-3-propylimidazol-1-ium Chemical compound CCCN1C=C[N+](C)=C1C.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F XOZHIVUWCICHSQ-UHFFFAOYSA-N 0.000 description 4
- JNHAYTMSFWSOHN-UHFFFAOYSA-N bis(trifluoromethylsulfonyl)azanide;3-methyl-1-propylpyridin-1-ium Chemical compound CCC[N+]1=CC=CC(C)=C1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F JNHAYTMSFWSOHN-UHFFFAOYSA-N 0.000 description 4
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 4
- 239000012230 colorless oil Substances 0.000 description 4
- 230000003247 decreasing effect Effects 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- RWPGFSMJFRPDDP-UHFFFAOYSA-L potassium metabisulfite Chemical compound [K+].[K+].[O-]S(=O)S([O-])(=O)=O RWPGFSMJFRPDDP-UHFFFAOYSA-L 0.000 description 4
- 229940043349 potassium metabisulfite Drugs 0.000 description 4
- 235000010263 potassium metabisulphite Nutrition 0.000 description 4
- VNRSMDFCJQLUIR-UHFFFAOYSA-M potassium;1,1,2-trifluoro-2-(1,1,2,2,2-pentafluoroethoxy)ethanesulfonate Chemical compound [K+].[O-]S(=O)(=O)C(F)(F)C(F)OC(F)(F)C(F)(F)F VNRSMDFCJQLUIR-UHFFFAOYSA-M 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000010926 purge Methods 0.000 description 4
- 230000003068 static effect Effects 0.000 description 4
- 230000036962 time dependent Effects 0.000 description 4
- JWPAOAULUAPZTP-UHFFFAOYSA-N 1,3-dioctylimidazol-1-ium Chemical compound CCCCCCCCN1C=C[N+](CCCCCCCC)=C1 JWPAOAULUAPZTP-UHFFFAOYSA-N 0.000 description 3
- MXDXOYOYMBHGQD-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;1,1,2,3,3,3-hexafluoropropane-1-sulfonate Chemical compound CCCC[N+]=1C=CN(C)C=1.[O-]S(=O)(=O)C(F)(F)C(F)C(F)(F)F MXDXOYOYMBHGQD-UHFFFAOYSA-M 0.000 description 3
- FHDQNOXQSTVAIC-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;chloride Chemical compound [Cl-].CCCCN1C=C[N+](C)=C1 FHDQNOXQSTVAIC-UHFFFAOYSA-M 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 241001541138 Cypho Species 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-FIBGUPNXSA-N acetonitrile-d3 Chemical compound [2H]C([2H])([2H])C#N WEVYAHXRMPXWCK-FIBGUPNXSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 229910052786 argon Inorganic materials 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- SUDHVXIPIDQEIT-UHFFFAOYSA-N bis(1,1,2,2,2-pentafluoroethylsulfonyl)azanide;1-ethyl-3-methylimidazol-3-ium Chemical compound CCN1C=C[N+](C)=C1.FC(F)(F)C(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)C(F)(F)F SUDHVXIPIDQEIT-UHFFFAOYSA-N 0.000 description 3
- LUWJQOLQUXTUGM-UHFFFAOYSA-N bis(trifluoromethylsulfonyl)methylsulfonyl-trifluoromethane;1,2-dimethyl-3-propylimidazol-1-ium Chemical compound CCCN1C=C[N+](C)=C1C.FC(F)(F)S(=O)(=O)[C-](S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F LUWJQOLQUXTUGM-UHFFFAOYSA-N 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 239000012043 crude product Substances 0.000 description 3
- 150000001923 cyclic compounds Chemical class 0.000 description 3
- 230000001419 dependent effect Effects 0.000 description 3
- IUIPTNGBJURBMZ-UHFFFAOYSA-L dipotassium;sulfite;hydrate Chemical compound O.[K+].[K+].[O-]S([O-])=O IUIPTNGBJURBMZ-UHFFFAOYSA-L 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 3
- 238000004255 ion exchange chromatography Methods 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 238000005086 pumping Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 239000012808 vapor phase Substances 0.000 description 3
- YFMFNYKEUDLDTL-UHFFFAOYSA-N 1,1,1,2,3,3,3-heptafluoropropane Chemical compound FC(F)(F)C(F)C(F)(F)F YFMFNYKEUDLDTL-UHFFFAOYSA-N 0.000 description 2
- NSGXIBWMJZWTPY-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropane Chemical compound FC(F)(F)CC(F)(F)F NSGXIBWMJZWTPY-UHFFFAOYSA-N 0.000 description 2
- BGGUZIZLOYTWFU-UHFFFAOYSA-M 1,1,2,3,3,3-hexafluoropropane-1-sulfonate;tributyl(tetradecyl)phosphanium Chemical compound [O-]S(=O)(=O)C(F)(F)C(F)C(F)(F)F.CCCCCCCCCCCCCC[P+](CCCC)(CCCC)CCCC BGGUZIZLOYTWFU-UHFFFAOYSA-M 0.000 description 2
- WJTASHROPQRUQG-UHFFFAOYSA-N 1,1,2-trifluoro-2-(1,1,2,2,2-pentafluoroethoxy)ethanesulfonic acid Chemical compound OS(=O)(=O)C(F)(F)C(F)OC(F)(F)C(F)(F)F WJTASHROPQRUQG-UHFFFAOYSA-N 0.000 description 2
- MXLZUALXSYVAIV-UHFFFAOYSA-N 1,2-dimethyl-3-propylimidazol-1-ium Chemical compound CCCN1C=C[N+](C)=C1C MXLZUALXSYVAIV-UHFFFAOYSA-N 0.000 description 2
- MIQNTLMZSDFZQY-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;1,1,2-trifluoro-2-(trifluoromethoxy)ethanesulfonate Chemical compound CCCC[N+]=1C=CN(C)C=1.[O-]S(=O)(=O)C(F)(F)C(F)OC(F)(F)F MIQNTLMZSDFZQY-UHFFFAOYSA-M 0.000 description 2
- BGHQBDVUMIWVAR-UHFFFAOYSA-M 1-dodecyl-3-methylimidazol-3-ium;1,1,2,2-tetrafluoroethanesulfonate Chemical compound [O-]S(=O)(=O)C(F)(F)C(F)F.CCCCCCCCCCCC[N+]=1C=CN(C)C=1 BGHQBDVUMIWVAR-UHFFFAOYSA-M 0.000 description 2
- UWLHSHAHTBJTBA-UHFFFAOYSA-N 1-iodooctane Chemical compound CCCCCCCCI UWLHSHAHTBJTBA-UHFFFAOYSA-N 0.000 description 2
- LCXGSWXECDJESI-UHFFFAOYSA-M 1-methyl-3-octadecylimidazol-1-ium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCN1C=C[N+](C)=C1 LCXGSWXECDJESI-UHFFFAOYSA-M 0.000 description 2
- OBBLBTCBHPSIMJ-UHFFFAOYSA-N 3-methyl-1-propylpyridin-1-ium Chemical compound CCC[N+]1=CC=CC(C)=C1 OBBLBTCBHPSIMJ-UHFFFAOYSA-N 0.000 description 2
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 2
- 241001432959 Chernes Species 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 230000002596 correlated effect Effects 0.000 description 2
- YMWUJEATGCHHMB-DICFDUPASA-N dichloromethane-d2 Chemical compound [2H]C([2H])(Cl)Cl YMWUJEATGCHHMB-DICFDUPASA-N 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000000806 fluorine-19 nuclear magnetic resonance spectrum Methods 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 229910000856 hastalloy Inorganic materials 0.000 description 2
- 238000003760 magnetic stirring Methods 0.000 description 2
- QYSGYZVSCZSLHT-UHFFFAOYSA-N octafluoropropane Chemical compound FC(F)(F)C(F)(F)C(F)(F)F QYSGYZVSCZSLHT-UHFFFAOYSA-N 0.000 description 2
- 125000002524 organometallic group Chemical group 0.000 description 2
- OKFMRBZZUDSEFE-UHFFFAOYSA-M potassium;1,1,2,3,3,3-hexafluoropropane-1-sulfonate Chemical compound [K+].[O-]S(=O)(=O)C(F)(F)C(F)C(F)(F)F OKFMRBZZUDSEFE-UHFFFAOYSA-M 0.000 description 2
- HOYITZNTNKOLOY-UHFFFAOYSA-M potassium;1,1,2-trifluoro-2-(trifluoromethoxy)ethanesulfonate Chemical compound [K+].[O-]S(=O)(=O)C(F)(F)C(F)OC(F)(F)F HOYITZNTNKOLOY-UHFFFAOYSA-M 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000005297 pyrex Substances 0.000 description 2
- 238000010223 real-time analysis Methods 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- RVKZDIDATLDTNR-UHFFFAOYSA-N sulfanylideneeuropium Chemical compound [Eu]=S RVKZDIDATLDTNR-UHFFFAOYSA-N 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 2
- PYVOHVLEZJMINC-UHFFFAOYSA-N trihexyl(tetradecyl)phosphanium Chemical compound CCCCCCCCCCCCCC[P+](CCCCCC)(CCCCCC)CCCCCC PYVOHVLEZJMINC-UHFFFAOYSA-N 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- RPGGYYVWJTWVMS-ZPSVQYCPSA-N (8r,9s,10r,13s,14s,17r)-17-ethynyl-10,13-dimethyl-1,2,3,6,7,8,9,11,12,14,15,16-dodecahydrocyclopenta[a]phenanthren-17-ol;(8r,9s,13s,14s,17r)-17-ethynyl-13-methyl-7,8,9,11,12,14,15,16-octahydro-6h-cyclopenta[a]phenanthrene-3,17-diol Chemical compound OC1=CC=C2[C@H]3CC[C@](C)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1.C1CC[C@]2(C)[C@H]3CC[C@](C)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1 RPGGYYVWJTWVMS-ZPSVQYCPSA-N 0.000 description 1
- GWTYBAOENKSFAY-UHFFFAOYSA-N 1,1,1,2,2-pentafluoro-2-(1,2,2-trifluoroethenoxy)ethane Chemical compound FC(F)=C(F)OC(F)(F)C(F)(F)F GWTYBAOENKSFAY-UHFFFAOYSA-N 0.000 description 1
- DOYSIZKQWJYULQ-UHFFFAOYSA-N 1,1,2,2,2-pentafluoro-n-(1,1,2,2,2-pentafluoroethylsulfonyl)ethanesulfonamide Chemical compound FC(F)(F)C(F)(F)S(=O)(=O)NS(=O)(=O)C(F)(F)C(F)(F)F DOYSIZKQWJYULQ-UHFFFAOYSA-N 0.000 description 1
- BLTXWCKMNMYXEA-UHFFFAOYSA-N 1,1,2-trifluoro-2-(trifluoromethoxy)ethene Chemical compound FC(F)=C(F)OC(F)(F)F BLTXWCKMNMYXEA-UHFFFAOYSA-N 0.000 description 1
- HVVRUQBMAZRKPJ-UHFFFAOYSA-N 1,3-dimethylimidazolium Chemical compound CN1C=C[N+](C)=C1 HVVRUQBMAZRKPJ-UHFFFAOYSA-N 0.000 description 1
- FWCNCCLDVGDQAB-UHFFFAOYSA-N 1-(1,1,2,2-tetrafluoroethyl)imidazole Chemical compound FC(F)C(F)(F)N1C=CN=C1 FWCNCCLDVGDQAB-UHFFFAOYSA-N 0.000 description 1
- VMKOFRJSULQZRM-UHFFFAOYSA-N 1-bromooctane Chemical compound CCCCCCCCBr VMKOFRJSULQZRM-UHFFFAOYSA-N 0.000 description 1
- XUAXVBUVQVRIIQ-UHFFFAOYSA-N 1-butyl-2,3-dimethylimidazol-3-ium Chemical compound CCCCN1C=C[N+](C)=C1C XUAXVBUVQVRIIQ-UHFFFAOYSA-N 0.000 description 1
- HIKOQOQWZDKNLH-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;1,1,2,2-tetrafluoro-2-(1,2,2,2-tetrafluoroethoxy)ethanesulfonate Chemical compound CCCC[N+]=1C=CN(C)C=1.[O-]S(=O)(=O)C(F)(F)C(F)(F)OC(F)C(F)(F)F HIKOQOQWZDKNLH-UHFFFAOYSA-M 0.000 description 1
- KUWPEQAOGNPMOP-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;1,1,2,2-tetrafluoroethanesulfonate Chemical compound CCCC[N+]=1C=CN(C)C=1.[O-]S(=O)(=O)C(F)(F)C(F)F KUWPEQAOGNPMOP-UHFFFAOYSA-M 0.000 description 1
- ZIPFNZZMKGEBFU-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;1,1,2-trifluoro-2-(1,1,2,2,2-pentafluoroethoxy)ethanesulfonate Chemical compound CCCC[N+]=1C=CN(C)C=1.[O-]S(=O)(=O)C(F)(F)C(F)OC(F)(F)C(F)(F)F ZIPFNZZMKGEBFU-UHFFFAOYSA-M 0.000 description 1
- PUHVBRXUKOGSBC-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;methanesulfonate Chemical compound CS([O-])(=O)=O.CCCC[N+]=1C=CN(C)C=1 PUHVBRXUKOGSBC-UHFFFAOYSA-M 0.000 description 1
- SIXHYMZEOJSYQH-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;thiocyanate Chemical compound [S-]C#N.CCCCN1C=C[N+](C)=C1 SIXHYMZEOJSYQH-UHFFFAOYSA-M 0.000 description 1
- DADKKHHMGSWSPH-UHFFFAOYSA-N 1-butyl-3-methylpyridin-1-ium Chemical compound CCCC[N+]1=CC=CC(C)=C1 DADKKHHMGSWSPH-UHFFFAOYSA-N 0.000 description 1
- OPXNHKQUEXEWAM-UHFFFAOYSA-M 1-dodecyl-3-methylimidazol-3-ium;chloride Chemical compound [Cl-].CCCCCCCCCCCCN1C=C[N+](C)=C1 OPXNHKQUEXEWAM-UHFFFAOYSA-M 0.000 description 1
- ILQHIGIKULUQFQ-UHFFFAOYSA-N 1-dodecyl-3-methylimidazolium Chemical compound CCCCCCCCCCCCN1C=C[N+](C)=C1 ILQHIGIKULUQFQ-UHFFFAOYSA-N 0.000 description 1
- CTEAXVWYCINNCA-UHFFFAOYSA-M 1-ethyl-3-methylimidazol-3-ium;1,1,2,2-tetrafluoroethanesulfonate Chemical compound CC[N+]=1C=CN(C)C=1.[O-]S(=O)(=O)C(F)(F)C(F)F CTEAXVWYCINNCA-UHFFFAOYSA-M 0.000 description 1
- SEGKWNUGNNFXPC-UHFFFAOYSA-M 1-ethyl-3-methylimidazol-3-ium;1,1,2,3,3,3-hexafluoropropane-1-sulfonate Chemical compound CC[N+]=1C=CN(C)C=1.[O-]S(=O)(=O)C(F)(F)C(F)C(F)(F)F SEGKWNUGNNFXPC-UHFFFAOYSA-M 0.000 description 1
- FCZZZYZIQDHCIW-UHFFFAOYSA-N 1-heptyl-3-methylimidazol-3-ium Chemical compound CCCCCCC[N+]=1C=CN(C)C=1 FCZZZYZIQDHCIW-UHFFFAOYSA-N 0.000 description 1
- VYJKCESBXIRRDM-UHFFFAOYSA-M 1-heptyl-3-methylimidazol-3-ium;1,1,2,2-tetrafluoroethanesulfonate Chemical compound [O-]S(=O)(=O)C(F)(F)C(F)F.CCCCCCC[N+]=1C=CN(C)C=1 VYJKCESBXIRRDM-UHFFFAOYSA-M 0.000 description 1
- NMTQMLQLFDSIDE-UHFFFAOYSA-L 1-hexadecyl-3-methylimidazol-3-ium 1,1,2,2-tetrafluoroethanesulfonate chloride Chemical compound [Cl-].C(CCCCCCCCCCCCCCC)[N+]1=CN(C=C1)C.FC(C(F)F)(S(=O)(=O)[O-])F.C(CCCCCCCCCCCCCCC)[N+]1=CN(C=C1)C NMTQMLQLFDSIDE-UHFFFAOYSA-L 0.000 description 1
- ZCPPLZJPPBIWRU-UHFFFAOYSA-M 1-hexadecyl-3-methylimidazol-3-ium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCN1C=C[N+](C)=C1 ZCPPLZJPPBIWRU-UHFFFAOYSA-M 0.000 description 1
- CCVJDXYTHLIIKO-UHFFFAOYSA-L 1-hexyl-3-methylimidazol-3-ium 1,1,2,2-tetrafluoroethanesulfonate chloride Chemical compound [Cl-].C(CCCCC)[N+]1=CN(C=C1)C.FC(C(F)F)(S(=O)(=O)[O-])F.C(CCCCC)[N+]1=CN(C=C1)C CCVJDXYTHLIIKO-UHFFFAOYSA-L 0.000 description 1
- RVEJOWGVUQQIIZ-UHFFFAOYSA-N 1-hexyl-3-methylimidazolium Chemical compound CCCCCCN1C=C[N+](C)=C1 RVEJOWGVUQQIIZ-UHFFFAOYSA-N 0.000 description 1
- NKRASMXHSQKLHA-UHFFFAOYSA-M 1-hexyl-3-methylimidazolium chloride Chemical compound [Cl-].CCCCCCN1C=C[N+](C)=C1 NKRASMXHSQKLHA-UHFFFAOYSA-M 0.000 description 1
- MMJMYYUZGLJBST-UHFFFAOYSA-N 1-methyl-3-octadecylimidazol-1-ium Chemical compound CCCCCCCCCCCCCCCCCCN1C=C[N+](C)=C1 MMJMYYUZGLJBST-UHFFFAOYSA-N 0.000 description 1
- MCTWTZJPVLRJOU-UHFFFAOYSA-O 1-methylimidazole Chemical compound CN1C=C[NH+]=C1 MCTWTZJPVLRJOU-UHFFFAOYSA-O 0.000 description 1
- GUOYLZDGXYFRER-UHFFFAOYSA-M 1-propyl-3-(1,1,2,2-tetrafluoroethyl)imidazol-1-ium;iodide Chemical compound [I-].CCC[N+]=1C=CN(C(F)(F)C(F)F)C=1 GUOYLZDGXYFRER-UHFFFAOYSA-M 0.000 description 1
- ACVAUFCPHXVLQA-UHFFFAOYSA-N 1h-imidazole;1h-pyrazole Chemical compound C=1C=NNC=1.C1=CNC=N1 ACVAUFCPHXVLQA-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 101100024552 Danio rerio msxa gene Proteins 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 101150007144 Intu gene Proteins 0.000 description 1
- 244000162475 Juniperus rigida Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- 238000002159 adsorption--desorption isotherm Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229940101006 anhydrous sodium sulfite Drugs 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- 239000012455 biphasic mixture Substances 0.000 description 1
- NOFBAVDIGCEKOQ-UHFFFAOYSA-N bis(trifluoromethylsulfonyl)azanide;1-butyl-3-methylpyridin-1-ium Chemical compound CCCC[N+]1=CC=CC(C)=C1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F NOFBAVDIGCEKOQ-UHFFFAOYSA-N 0.000 description 1
- UQWLFOMXECTXNQ-UHFFFAOYSA-N bis(trifluoromethylsulfonyl)methylsulfonyl-trifluoromethane Chemical compound FC(F)(F)S(=O)(=O)[C-](S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F UQWLFOMXECTXNQ-UHFFFAOYSA-N 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 239000002134 carbon nanofiber Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004590 computer program Methods 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 239000013058 crude material Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical compound FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 238000013178 mathematical model Methods 0.000 description 1
- 238000005649 metathesis reaction Methods 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000012044 organic layer Substances 0.000 description 1
- 229960004065 perflutren Drugs 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- IWVSKNFJIVKXHH-UHFFFAOYSA-N pyrazine;pyrimidine Chemical compound C1=CN=CN=C1.C1=CN=CC=N1 IWVSKNFJIVKXHH-UHFFFAOYSA-N 0.000 description 1
- LDEZROSHPJRREZ-UHFFFAOYSA-N pyridazine;pyridine Chemical compound C1=CC=NC=C1.C1=CC=NN=C1 LDEZROSHPJRREZ-UHFFFAOYSA-N 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 1
- ZPHRQLVXRDQUPM-UHFFFAOYSA-M sodium;1,1,2,3,3,3-hexafluoropropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)C(F)(F)C(F)C(F)(F)F ZPHRQLVXRDQUPM-UHFFFAOYSA-M 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- VNLIOGKAEHVWAL-UHFFFAOYSA-M tetrabutylphosphanium;1,1,2-trifluoro-2-(1,1,2,2,2-pentafluoroethoxy)ethanesulfonate Chemical compound CCCC[P+](CCCC)(CCCC)CCCC.[O-]S(=O)(=O)C(F)(F)C(F)OC(F)(F)C(F)(F)F VNLIOGKAEHVWAL-UHFFFAOYSA-M 0.000 description 1
- RKHXQBLJXBGEKF-UHFFFAOYSA-M tetrabutylphosphanium;bromide Chemical compound [Br-].CCCC[P+](CCCC)(CCCC)CCCC RKHXQBLJXBGEKF-UHFFFAOYSA-M 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- AKUNSPZHHSNFFX-UHFFFAOYSA-M tributyl(tetradecyl)phosphanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[P+](CCCC)(CCCC)CCCC AKUNSPZHHSNFFX-UHFFFAOYSA-M 0.000 description 1
- JCQGIZYNVAZYOH-UHFFFAOYSA-M trihexyl(tetradecyl)phosphanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[P+](CCCCCC)(CCCCCC)CCCCCC JCQGIZYNVAZYOH-UHFFFAOYSA-M 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B25/00—Machines, plants or systems, using a combination of modes of operation covered by two or more of the groups F25B1/00 - F25B23/00
- F25B25/02—Compression-sorption machines, plants, or systems
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/047—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for absorption-type refrigeration systems
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B1/00—Compression machines, plants or systems with non-reversible cycle
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B25/00—Machines, plants or systems, using a combination of modes of operation covered by two or more of the groups F25B1/00 - F25B23/00
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Sorption Type Refrigeration Machines (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US68219105P | 2005-05-18 | 2005-05-18 | |
| US60/682,191 | 2005-05-18 | ||
| PCT/US2006/018733 WO2006124776A2 (en) | 2005-05-18 | 2006-05-16 | Hybrid vapor compression-absorption cycle |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2608542A1 true CA2608542A1 (en) | 2006-11-23 |
Family
ID=36975591
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002608542A Abandoned CA2608542A1 (en) | 2005-05-18 | 2006-05-16 | Hybrid vapor compression-absorption cycle |
Country Status (13)
| Country | Link |
|---|---|
| US (2) | US7765823B2 (cg-RX-API-DMAC7.html) |
| EP (2) | EP1882132A2 (cg-RX-API-DMAC7.html) |
| JP (1) | JP5270335B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR20080019235A (cg-RX-API-DMAC7.html) |
| CN (1) | CN100557343C (cg-RX-API-DMAC7.html) |
| AR (1) | AR053609A1 (cg-RX-API-DMAC7.html) |
| AU (1) | AU2006247417B2 (cg-RX-API-DMAC7.html) |
| BR (1) | BRPI0613266A2 (cg-RX-API-DMAC7.html) |
| CA (1) | CA2608542A1 (cg-RX-API-DMAC7.html) |
| MY (1) | MY143199A (cg-RX-API-DMAC7.html) |
| NO (1) | NO20076526L (cg-RX-API-DMAC7.html) |
| RU (1) | RU2007146973A (cg-RX-API-DMAC7.html) |
| WO (1) | WO2006124776A2 (cg-RX-API-DMAC7.html) |
Families Citing this family (112)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8463441B2 (en) | 2002-12-09 | 2013-06-11 | Hudson Technologies, Inc. | Method and apparatus for optimizing refrigeration systems |
| US7313926B2 (en) * | 2005-01-18 | 2008-01-01 | Rexorce Thermionics, Inc. | High efficiency absorption heat pump and methods of use |
| US8715521B2 (en) * | 2005-02-04 | 2014-05-06 | E I Du Pont De Nemours And Company | Absorption cycle utilizing ionic liquid as working fluid |
| US7834209B2 (en) * | 2005-06-07 | 2010-11-16 | E.I. Du Pont De Nemours And Company | Hydrofluoroalkanesulfonic acids from fluorovinyl ethers |
| US7683209B2 (en) | 2005-06-07 | 2010-03-23 | E.I. Du Pont De Nemours And Company | Manufacture of hydrofluoroalkanesulfonic acids |
| AR058054A1 (es) * | 2005-09-22 | 2008-01-23 | Du Pont | Utilizacion de liquidos ionicos para la separacion de hidrofluorocarburos |
| US8506839B2 (en) * | 2005-12-14 | 2013-08-13 | E I Du Pont De Nemours And Company | Absorption cycle utilizing ionic liquids and water as working fluids |
| EP2027225A2 (en) * | 2006-05-31 | 2009-02-25 | E.I. Du Pont De Nemours And Company | Vapor compression utilizing ionic liquid as compressor lubricant |
| US20100025619A1 (en) * | 2006-07-12 | 2010-02-04 | Solvay Fluor Gmbh | Method for heating and cooling using fluoroether compounds, compositions suitable therefore and their use |
| EP2086914A1 (en) | 2006-11-08 | 2009-08-12 | E.I. Du Pont De Nemours And Company | Process for the separation of tetrafluoroethylene from carbon dioxide using ionic liquids |
| JP5118340B2 (ja) * | 2006-12-01 | 2013-01-16 | サンデン株式会社 | 冷凍回路の往復動型圧縮機 |
| KR101049612B1 (ko) * | 2006-12-18 | 2011-07-14 | 주성대학산학협력단 | 반도체 산업용 냉동기 혼합냉매 조성물 |
| US20080153697A1 (en) * | 2006-12-22 | 2008-06-26 | E. I. Dupont De Nemours And Company | Mixtures of ammonia and ionic liquids |
| WO2008124087A1 (en) * | 2007-04-03 | 2008-10-16 | E. I. Du Pont De Nemours And Company | Heat transfer systems using mixtures of polyols and ionic liquids |
| WO2008138832A1 (de) * | 2007-05-11 | 2008-11-20 | Basf Se | Absorptionswärmepumpen, absorptionskältemaschinen und wärmetransformatoren mit schwefeldioxid als kältemittel |
| US8075777B2 (en) * | 2007-05-16 | 2011-12-13 | E. I. Du Pont De Nemours And Company | Process for the separation of diastereomers |
| US7964760B2 (en) * | 2007-05-25 | 2011-06-21 | E.I. Du Pont De Nemours And Company | Process for the separation of fluorocarbons using ionic liquids |
| DE102007046369A1 (de) * | 2007-09-27 | 2009-04-02 | Siemens Ag | Vorrichtung zum Kühlen eines Energiespeichers |
| EP2190488A1 (en) * | 2007-09-28 | 2010-06-02 | E. I. du Pont de Nemours and Company | Ionic liquid stabilizer compositions |
| US20110088418A1 (en) * | 2008-07-08 | 2011-04-21 | Konstantinos Kontomaris | Compositions comprising ionic liquids and fluoroolefins and use thereof in absorption cycle systems |
| US20100077792A1 (en) * | 2008-09-28 | 2010-04-01 | Rexorce Thermionics, Inc. | Electrostatic lubricant and methods of use |
| KR20110095282A (ko) * | 2008-11-07 | 2011-08-24 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 작동 유체로서 이온성 화합물 및/또는 비이온성 흡수제를 이용하는 흡수 사이클 |
| US7977426B2 (en) * | 2008-11-13 | 2011-07-12 | E. I. Du Pont De Nemours And Company | Fluoroalkyl ether sulfonate surfactants |
| JP2012510042A (ja) * | 2008-11-26 | 2012-04-26 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 二重吸収回路を有する吸収サイクルシステム |
| US8119818B2 (en) * | 2008-12-04 | 2012-02-21 | E. I. Du Pont De Nemours And Company | Functionalized N-substituted pyrrolidonium ionic liquids |
| WO2010065841A1 (en) | 2008-12-04 | 2010-06-10 | E. I. Du Pont De Nemours And Company | N-substituted pyrrolidonium ionic liquids with expanded linker |
| US8138354B2 (en) * | 2008-12-04 | 2012-03-20 | E. I. Du Pont De Nemours And Company | N-substituted pyrrolidonium ionic liquids |
| US8350056B2 (en) * | 2008-12-04 | 2013-01-08 | E I Du Pont De Nemours And Company | Functionalized N-substituted pyrrolidonium ionic liquids |
| US20100154419A1 (en) * | 2008-12-19 | 2010-06-24 | E. I. Du Pont De Nemours And Company | Absorption power cycle system |
| US8616323B1 (en) | 2009-03-11 | 2013-12-31 | Echogen Power Systems | Hybrid power systems |
| AU2010232728A1 (en) | 2009-03-31 | 2011-09-22 | E. I. Du Pont De Nemours And Company | Temperature adjustment device |
| US20120012779A1 (en) | 2009-03-31 | 2012-01-19 | E.I. Du Pont De Nemours And Company | Temperature adjustment device |
| EP2419621A4 (en) | 2009-04-17 | 2015-03-04 | Echogen Power Systems | SYSTEM AND METHOD FOR MANAGING HEAT PROBLEMS IN GAS TURBINE ENGINES |
| EP2246651A2 (de) | 2009-04-27 | 2010-11-03 | Basf Se | Absorptionswärmepumpen, Absorptionskältemaschinen und Absorptionswärmetransformatoren auf Basis EMIM-acetat / Methanol |
| DE102010027914A1 (de) | 2009-04-27 | 2011-08-04 | Basf Se, 67063 | Absorptionswärmepumpen, Absorptionskältemaschinen und Absorptionswärmetransformatoren mit einem C2 bis C4 Alkanol als Kältemittel |
| US8444873B2 (en) | 2009-06-12 | 2013-05-21 | Solvay Fluor Gmbh | Refrigerant composition |
| CA2766637A1 (en) | 2009-06-22 | 2010-12-29 | Echogen Power Systems Inc. | System and method for managing thermal issues in one or more industrial processes |
| WO2011017476A1 (en) | 2009-08-04 | 2011-02-10 | Echogen Power Systems Inc. | Heat pump with integral solar collector |
| US8813497B2 (en) | 2009-09-17 | 2014-08-26 | Echogen Power Systems, Llc | Automated mass management control |
| US8096128B2 (en) | 2009-09-17 | 2012-01-17 | Echogen Power Systems | Heat engine and heat to electricity systems and methods |
| US8613195B2 (en) | 2009-09-17 | 2013-12-24 | Echogen Power Systems, Llc | Heat engine and heat to electricity systems and methods with working fluid mass management control |
| US8869531B2 (en) | 2009-09-17 | 2014-10-28 | Echogen Power Systems, Llc | Heat engines with cascade cycles |
| PL2501925T3 (pl) * | 2009-11-18 | 2021-02-08 | Dariusz Krzysztof Iwanowski | Sposób i urządzenie do magazynowania energii odnawialnej w temperaturowo-ciśnieniowym zbiorniku energii i przetwarzania jej na energię elektryczną |
| DE102009047564A1 (de) * | 2009-12-07 | 2011-06-09 | Evonik Degussa Gmbh | Arbeitsmedium für eine Absorptionskältemaschine |
| US8544284B2 (en) * | 2010-06-25 | 2013-10-01 | Petrochina North China Petrochemical Company | Method and apparatus for waste heat recovery and absorption gases used as working fluid therein |
| CN101968288B (zh) * | 2010-10-22 | 2012-07-04 | 北京化工大学 | 一种吸收-压缩复合制冷循环系统 |
| US8857186B2 (en) | 2010-11-29 | 2014-10-14 | Echogen Power Systems, L.L.C. | Heat engine cycles for high ambient conditions |
| US8616001B2 (en) | 2010-11-29 | 2013-12-31 | Echogen Power Systems, Llc | Driven starter pump and start sequence |
| US8783034B2 (en) | 2011-11-07 | 2014-07-22 | Echogen Power Systems, Llc | Hot day cycle |
| ES2890330T3 (es) | 2010-12-27 | 2022-01-18 | Thermax Ltd | Refrigerador por absorción-compresión híbrido y un método relacionado para proporcionar efecto de refrigeración |
| US20120304686A1 (en) * | 2011-06-02 | 2012-12-06 | E. I. Du Pont De Nemours And Company | Absorption cycle system having dual absorption circuits |
| US20120304682A1 (en) * | 2011-06-02 | 2012-12-06 | E.I. Du Pont De Nemours And Company | Absorption Cycle System Having Dual Absorption Circuits |
| DE102011105742A1 (de) | 2011-06-24 | 2012-12-27 | Viessmann Werke Gmbh & Co Kg | Periodisch arbeitende Sorptionsvorrichtung |
| US20130269526A1 (en) | 2011-09-12 | 2013-10-17 | E I Du Pont De Nemours And Company | Methods and apparatus for carbon dixoide capture |
| US9062898B2 (en) | 2011-10-03 | 2015-06-23 | Echogen Power Systems, Llc | Carbon dioxide refrigeration cycle |
| US9181876B2 (en) * | 2012-01-04 | 2015-11-10 | General Electric Company | Method and apparatus for operating a gas turbine engine |
| WO2013133802A1 (en) * | 2012-03-06 | 2013-09-12 | International Engine Intellectual Property Company, Llc | Ammonia canister having integral electric heating elements |
| TWI460385B (zh) * | 2012-05-30 | 2014-11-11 | Ind Tech Res Inst | 複合式製冷系統及其控制方法 |
| WO2014003718A1 (en) * | 2012-06-26 | 2014-01-03 | International Engine Intellectual Property Company, Llc | Modular exhaust treatment system |
| US9091278B2 (en) | 2012-08-20 | 2015-07-28 | Echogen Power Systems, Llc | Supercritical working fluid circuit with a turbo pump and a start pump in series configuration |
| US9118226B2 (en) | 2012-10-12 | 2015-08-25 | Echogen Power Systems, Llc | Heat engine system with a supercritical working fluid and processes thereof |
| US9341084B2 (en) | 2012-10-12 | 2016-05-17 | Echogen Power Systems, Llc | Supercritical carbon dioxide power cycle for waste heat recovery |
| CN102965082B (zh) * | 2012-11-30 | 2015-03-04 | 中国地质大学（武汉） | 用于热源温度在60℃至130℃之间的吸收式热循环系统的工作物质对 |
| WO2014117068A1 (en) | 2013-01-28 | 2014-07-31 | Echogen Power Systems, L.L.C. | Methods for reducing wear on components of a heat engine system at startup |
| KR20150122665A (ko) | 2013-01-28 | 2015-11-02 | 에코진 파워 시스템스, 엘엘씨 | 초임계 이산화탄소 랭킨 사이클 중에 동력 터빈 스로틀 밸브를 제어하기 위한 프로세스 |
| CN105008822B (zh) * | 2013-02-20 | 2017-05-17 | 松下知识产权经营株式会社 | 废热利用热泵系统和热机驱动式蒸气压缩式热泵系统 |
| AU2014225990B2 (en) | 2013-03-04 | 2018-07-26 | Echogen Power Systems, L.L.C. | Heat engine systems with high net power supercritical carbon dioxide circuits |
| CN105143788B (zh) * | 2013-04-11 | 2018-04-27 | 开利公司 | 组合蒸气吸收和机械压缩循环设计 |
| EP3017013A4 (en) * | 2013-05-28 | 2017-01-25 | Yanjie Xu | Refrigeration system with dual refrigerants and liquid working fluids |
| DE102013211084A1 (de) * | 2013-06-14 | 2014-12-18 | Siemens Aktiengesellschaft | Verfahren zum Betrieb einer Wärmepumpe und Wärmepumpe |
| DE102013107831A1 (de) | 2013-07-23 | 2015-01-29 | Viessmann Werke Gmbh & Co Kg | Periodisch arbeitende Absorptionsvorrichtung |
| EP3042135A4 (en) * | 2013-09-04 | 2017-07-05 | Climeon AB | A method for the conversion of energy using a thermodynamic cycle with a desorber and an absorber |
| SE1400492A1 (sv) | 2014-01-22 | 2015-07-23 | Climeon Ab | An improved thermodynamic cycle operating at low pressure using a radial turbine |
| JP6494659B2 (ja) * | 2014-04-16 | 2019-04-03 | ジョンソン コントロールズ テクノロジー カンパニーＪｏｈｎｓｏｎ Ｃｏｎｔｒｏｌｓ Ｔｅｃｈｎｏｌｏｇｙ Ｃｏｍｐａｎｙ | 冷却機を作動させる方法 |
| WO2016073252A1 (en) | 2014-11-03 | 2016-05-12 | Echogen Power Systems, L.L.C. | Active thrust management of a turbopump within a supercritical working fluid circuit in a heat engine system |
| CN104592940A (zh) * | 2014-12-24 | 2015-05-06 | 巨化集团技术中心 | 一种含氟碘代烃组合物及其制备方法 |
| US10648075B2 (en) * | 2015-03-23 | 2020-05-12 | Goodrich Corporation | Systems and methods for chemical vapor infiltration and densification of porous substrates |
| CN105953463B (zh) * | 2015-05-06 | 2020-05-22 | 李华玉 | 第一类热驱动压缩-吸收式热泵 |
| US10571165B2 (en) | 2015-05-29 | 2020-02-25 | Thermo King Corporation | Sorption system in a transport refrigeration system |
| DE102015212749A1 (de) * | 2015-07-08 | 2017-01-12 | Evonik Degussa Gmbh | Verfahren zur Entfeuchtung von feuchten Gasgemischen |
| CN106528900B (zh) * | 2015-09-10 | 2023-05-05 | 中国海洋石油总公司 | 一种朗肯循环系统及其流体工质材料构建方法 |
| KR102502102B1 (ko) * | 2015-11-13 | 2023-02-22 | 한국화학연구원 | 이산화탄소 흡수용 조성물, 이를 포함하는 냉매 조성물 및 이를 이용하는 냉방 시스템 |
| KR101689528B1 (ko) | 2016-04-29 | 2016-12-26 | 한국화학연구원 | 기체 및 이온성 액체를 이용한 냉난방장치 |
| US20170314825A1 (en) | 2016-04-29 | 2017-11-02 | Emerson Climate Technologies, Inc. | Co-fluid refrigeration system and method |
| RU2652702C2 (ru) * | 2016-10-19 | 2018-04-28 | Игорь Ву-Юнович Ван | Субатмосферная система теплохолодоснабжения |
| JP2018077001A (ja) * | 2016-11-09 | 2018-05-17 | 東洋エンジニアリング株式会社 | ケミカルヒートポンプシステム |
| CN119934718A (zh) | 2017-01-04 | 2025-05-06 | 山石科技有限公司 | 用于建筑物的具有混合式化石燃料电动多功能热泵的加热和冷却系统 |
| KR101890896B1 (ko) * | 2017-04-28 | 2018-08-22 | 주식회사 엔바이온 | 기체 및 이온성 액체를 이용한 냉난방장치 |
| US10648712B1 (en) * | 2017-08-16 | 2020-05-12 | Florida A&M University | Microwave assisted hybrid solar vapor absorption refrigeration systems |
| US20200355413A1 (en) * | 2017-08-23 | 2020-11-12 | Johnson Controls Technology Company | Systems and methods for purging a chiller system |
| CN107602424B (zh) * | 2017-09-06 | 2020-05-12 | 中国科学院过程工程研究所 | 一种离子液体、制备方法和用途 |
| US11660970B2 (en) * | 2018-01-05 | 2023-05-30 | Byton Limited | On-board liquid-cooled or gas-cooled charging cable for electric vehicles |
| DE102018109577B3 (de) * | 2018-04-20 | 2019-05-09 | Karlsruher Institut für Technologie | Hybrid-Wärmepumpe mit Kompressions- und Adsorptionskreislauf, sowie Verfahren zumBetrieb und Verwendung |
| CN110832051B (zh) * | 2018-06-13 | 2020-12-18 | 日立江森自控空调有限公司 | 制冷剂组合物以及使用其的冷冻循环装置 |
| US10883388B2 (en) | 2018-06-27 | 2021-01-05 | Echogen Power Systems Llc | Systems and methods for generating electricity via a pumped thermal energy storage system |
| US11221161B1 (en) | 2018-07-03 | 2022-01-11 | Kalindha Rashmi LLC | Heat-pump system with combined vapor expansion-compression stages and single-effect vapor absorption unit |
| US10612821B1 (en) | 2018-07-03 | 2020-04-07 | Kalindha Rashmi LLC | Heat-pump system with combined vapor expansion-compression stages and single-effect vapor absorption unit |
| CN109163917B (zh) * | 2018-07-19 | 2020-03-31 | 西安交通大学 | 一种跨临界co2热泵加速寿命实验系统及方法 |
| AU2019387370A1 (en) | 2018-11-30 | 2021-06-10 | Nuvation Bio Inc. | Pyrrole and pyrazole compounds and methods of use thereof |
| EP3935323A4 (en) | 2019-03-07 | 2022-12-07 | Emerson Climate Technologies, Inc. | AIR CONDITIONING SYSTEM WITH ABSORPTION COOLER |
| US11085675B2 (en) * | 2019-06-13 | 2021-08-10 | City University Of Hong Kong | Hybrid heat pump system |
| US11209190B2 (en) * | 2019-06-13 | 2021-12-28 | City University Of Hong Kong | Hybrid heat pump system |
| JP7088216B2 (ja) * | 2020-01-10 | 2022-06-21 | トヨタ自動車株式会社 | レファレンス治具 |
| CN111306787B (zh) * | 2020-03-17 | 2021-04-06 | 江苏科技大学 | 一种半开式高温热泵系统及其工作方法 |
| US11435120B2 (en) | 2020-05-05 | 2022-09-06 | Echogen Power Systems (Delaware), Inc. | Split expansion heat pump cycle |
| CN111981728A (zh) * | 2020-08-06 | 2020-11-24 | 浙大宁波理工学院 | 含有HCFO-1233zd(E)的溶液在吸收器中制热的方法 |
| CN111981727A (zh) * | 2020-08-06 | 2020-11-24 | 浙大宁波理工学院 | 含有HFO-1336mzz(Z)的溶液在吸收器中制热的方法 |
| MA61232A1 (fr) | 2020-12-09 | 2024-05-31 | Supercritical Storage Company Inc | Système de stockage d'énergie thermique électrique à trois réservoirs |
| CN113388371B (zh) * | 2021-06-07 | 2022-06-24 | 湖北瑞能华辉能源管理有限公司 | 一种可替代R22或R410a的四元混合制冷剂及其应用 |
| CN113859549A (zh) * | 2021-11-23 | 2021-12-31 | 南京航空航天大学 | 一种飞机座舱加温系统 |
| CN114857802B (zh) * | 2022-05-09 | 2024-09-20 | 北京工业大学 | 一种水和空气混合压缩式制冷系统 |
| US12331664B2 (en) | 2023-02-07 | 2025-06-17 | Supercritical Storage Company, Inc. | Waste heat integration into pumped thermal energy storage |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4013712A (en) * | 1975-03-06 | 1977-03-22 | Texaco Trinidad, Inc. | Process for making alkane-1,2-diol diesters |
| US4031712A (en) * | 1975-12-04 | 1977-06-28 | The University Of Delaware | Combined absorption and vapor-compression refrigeration system |
| DE2855434A1 (de) | 1978-12-21 | 1980-06-26 | Alefeld Georg | Arbeitsstoffe fuer absorptionswaermepumpen- und kaeltemaschinen |
| US4388812A (en) * | 1979-03-08 | 1983-06-21 | Clark Silas W | Variable valve for refrigeration system |
| DE3623680A1 (de) | 1986-07-12 | 1988-01-14 | Univ Essen | Stoffsysteme fuer sorptionsprozesse |
| CN86106784A (zh) * | 1986-10-09 | 1987-04-22 | 杨晓宇 | 压缩-吸收式制冷系统 |
| US5643492A (en) | 1990-12-17 | 1997-07-01 | E. I. Du Pont De Nemours And Company | Constant boiling compositions of HFC-32, HFC-125 and HFC-134 A |
| US20020000534A1 (en) * | 1998-02-09 | 2002-01-03 | Richard Robert G | Non-azeotropic refrigerant compositions comprising difluoromethane or 1,1,1,-trifluorethane |
| US5417871A (en) * | 1994-03-11 | 1995-05-23 | E. I. Du Pont De Nemours And Company | Hydrofluorocarbon compositions |
| RU2079071C1 (ru) | 1994-03-31 | 1997-05-10 | Ильиных Вадим Вадимович | Способ получения холода в абсорбционно-диффузионном холодильном агрегате (варианты) и устройство для его осуществления (варианты) |
| DE4415199A1 (de) | 1994-04-30 | 1995-11-02 | Inst Luft Und Kaeltetechnik Gm | Kälteanlage |
| US5582020A (en) * | 1994-11-23 | 1996-12-10 | Mainstream Engineering Corporation | Chemical/mechanical system and method using two-phase/two-component compression heat pump |
| KR100204173B1 (ko) * | 1996-12-19 | 1999-06-15 | 윤종용 | 왕복동형 냉매 압축기 |
| US6946081B2 (en) * | 2001-12-31 | 2005-09-20 | Poseidon Resources Corporation | Desalination system |
| US20070181473A1 (en) * | 2003-01-22 | 2007-08-09 | Thomas Manth | Water desalination installation |
| DE10316418A1 (de) * | 2003-04-10 | 2004-10-21 | Basf Ag | Verwendung einer ionischen Flüssigkeit |
| WO2005007657A2 (de) | 2003-07-11 | 2005-01-27 | Solvay Fluor Gmbh | Verwendung von dbn und dbu-salzen als ionische flüssigkeiten |
| ATE542878T1 (de) * | 2003-10-10 | 2012-02-15 | Idemitsu Kosan Co | Verwendung einer ionischen flüssigkeit als basisöl einer schmierstoffzusammensetzung |
| DE102004024967A1 (de) | 2004-05-21 | 2005-12-08 | Basf Ag | Neue Absorptionsmedien für Absorptionswärmepumpen, Absorptionskältemaschinen und Wärmetransformatoren |
| US20060065597A1 (en) * | 2004-09-29 | 2006-03-30 | Sisyan, R.L. De C.V. | Hybrid, reverse osmosis, water desalinization apparatus and method with energy recuperation assembly |
| US7313926B2 (en) * | 2005-01-18 | 2008-01-01 | Rexorce Thermionics, Inc. | High efficiency absorption heat pump and methods of use |
| US8715521B2 (en) | 2005-02-04 | 2014-05-06 | E I Du Pont De Nemours And Company | Absorption cycle utilizing ionic liquid as working fluid |
| DE102005028451B4 (de) | 2005-06-17 | 2017-02-16 | Evonik Degussa Gmbh | Verfahren zum Transport von Wärme |
| AR058054A1 (es) * | 2005-09-22 | 2008-01-23 | Du Pont | Utilizacion de liquidos ionicos para la separacion de hidrofluorocarburos |
| US8506839B2 (en) * | 2005-12-14 | 2013-08-13 | E I Du Pont De Nemours And Company | Absorption cycle utilizing ionic liquids and water as working fluids |
| EP2027225A2 (en) * | 2006-05-31 | 2009-02-25 | E.I. Du Pont De Nemours And Company | Vapor compression utilizing ionic liquid as compressor lubricant |
-
2006
- 2006-05-16 CN CNB200680017067XA patent/CN100557343C/zh not_active Expired - Fee Related
- 2006-05-16 AU AU2006247417A patent/AU2006247417B2/en not_active Ceased
- 2006-05-16 BR BRPI0613266-9A patent/BRPI0613266A2/pt not_active IP Right Cessation
- 2006-05-16 CA CA002608542A patent/CA2608542A1/en not_active Abandoned
- 2006-05-16 EP EP06759840A patent/EP1882132A2/en not_active Withdrawn
- 2006-05-16 RU RU2007146973/06A patent/RU2007146973A/ru not_active Application Discontinuation
- 2006-05-16 JP JP2008512405A patent/JP5270335B2/ja not_active Expired - Fee Related
- 2006-05-16 KR KR1020077029420A patent/KR20080019235A/ko not_active Abandoned
- 2006-05-16 EP EP11182017.1A patent/EP2437011A3/en not_active Withdrawn
- 2006-05-16 WO PCT/US2006/018733 patent/WO2006124776A2/en not_active Ceased
- 2006-05-16 US US11/435,352 patent/US7765823B2/en not_active Expired - Fee Related
- 2006-05-17 MY MYPI20062264A patent/MY143199A/en unknown
- 2006-05-18 AR ARP060102024A patent/AR053609A1/es unknown
-
2007
- 2007-12-18 NO NO20076526A patent/NO20076526L/no not_active Application Discontinuation
-
2010
- 2010-06-22 US US12/820,635 patent/US8707720B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| NO20076526L (no) | 2008-02-18 |
| RU2007146973A (ru) | 2009-06-27 |
| BRPI0613266A2 (pt) | 2010-12-28 |
| EP1882132A2 (en) | 2008-01-30 |
| WO2006124776A3 (en) | 2007-04-05 |
| JP2008541006A (ja) | 2008-11-20 |
| US20100257879A1 (en) | 2010-10-14 |
| JP5270335B2 (ja) | 2013-08-21 |
| EP2437011A2 (en) | 2012-04-04 |
| MY143199A (en) | 2011-03-31 |
| AU2006247417B2 (en) | 2011-06-30 |
| CN101175953A (zh) | 2008-05-07 |
| US20070019708A1 (en) | 2007-01-25 |
| US8707720B2 (en) | 2014-04-29 |
| AU2006247417A2 (en) | 2006-11-23 |
| AR053609A1 (es) | 2007-05-09 |
| AU2006247417A1 (en) | 2006-11-23 |
| WO2006124776A9 (en) | 2008-01-24 |
| EP2437011A3 (en) | 2013-10-30 |
| US7765823B2 (en) | 2010-08-03 |
| CN100557343C (zh) | 2009-11-04 |
| WO2006124776A2 (en) | 2006-11-23 |
| KR20080019235A (ko) | 2008-03-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| AU2006247417B2 (en) | Hybrid vapor compression-absorption cycle | |
| AU2006210403B2 (en) | Absorption cycle utilizing ionic liquid as working fluid | |
| CN101454420B (zh) | 利用离子液体作为压缩机润滑剂的蒸汽压缩 | |
| US8506839B2 (en) | Absorption cycle utilizing ionic liquids and water as working fluids | |
| HK1118092A (en) | Hybrid vapor compression-absorption cycle | |
| HK1121487A (en) | Absorption cycle utilizing ionic liquid as working fluid | |
| HK1133031A (en) | Vapor compression utilizing ionic liquid as compressor lubricant |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |