CA2602347A1 - Additive mixtures for agricultural articles - Google Patents
Additive mixtures for agricultural articles Download PDFInfo
- Publication number
- CA2602347A1 CA2602347A1 CA002602347A CA2602347A CA2602347A1 CA 2602347 A1 CA2602347 A1 CA 2602347A1 CA 002602347 A CA002602347 A CA 002602347A CA 2602347 A CA2602347 A CA 2602347A CA 2602347 A1 CA2602347 A1 CA 2602347A1
- Authority
- CA
- Canada
- Prior art keywords
- substituted
- group
- c10alkyl
- hydroxy
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 112
- 239000000654 additive Substances 0.000 title claims abstract description 75
- 230000000996 additive effect Effects 0.000 title claims abstract description 67
- 229920000620 organic polymer Polymers 0.000 claims abstract description 29
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 claims abstract description 26
- 150000003839 salts Chemical class 0.000 claims abstract description 23
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 19
- 150000003624 transition metals Chemical class 0.000 claims abstract description 19
- 150000002978 peroxides Chemical class 0.000 claims abstract description 17
- 239000003504 photosensitizing agent Substances 0.000 claims abstract description 12
- -1 copper peroxide Chemical class 0.000 claims description 161
- 239000001257 hydrogen Substances 0.000 claims description 62
- 229910052739 hydrogen Inorganic materials 0.000 claims description 62
- 229920000642 polymer Polymers 0.000 claims description 60
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 58
- 229920001577 copolymer Polymers 0.000 claims description 53
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 31
- 150000002431 hydrogen Chemical class 0.000 claims description 31
- RZVHIXYEVGDQDX-UHFFFAOYSA-N 9,10-anthraquinone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C(=O)C2=C1 RZVHIXYEVGDQDX-UHFFFAOYSA-N 0.000 claims description 22
- 125000000623 heterocyclic group Chemical group 0.000 claims description 22
- 230000015556 catabolic process Effects 0.000 claims description 17
- 238000006731 degradation reaction Methods 0.000 claims description 17
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 17
- 229920006237 degradable polymer Polymers 0.000 claims description 16
- XXQBEVHPUKOQEO-UHFFFAOYSA-N potassium superoxide Chemical compound [K+].[K+].[O-][O-] XXQBEVHPUKOQEO-UHFFFAOYSA-N 0.000 claims description 16
- 239000002362 mulch Substances 0.000 claims description 15
- 235000019402 calcium peroxide Nutrition 0.000 claims description 14
- 229920000728 polyester Polymers 0.000 claims description 14
- GRWFGVWFFZKLTI-UHFFFAOYSA-N α-pinene Chemical compound CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 claims description 14
- 239000004698 Polyethylene Substances 0.000 claims description 13
- 229920001169 thermoplastic Polymers 0.000 claims description 13
- 239000004416 thermosoftening plastic Substances 0.000 claims description 13
- 239000004343 Calcium peroxide Substances 0.000 claims description 12
- 239000004743 Polypropylene Substances 0.000 claims description 12
- LHJQIRIGXXHNLA-UHFFFAOYSA-N calcium peroxide Chemical compound [Ca+2].[O-][O-] LHJQIRIGXXHNLA-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- 150000003097 polyterpenes Chemical class 0.000 claims description 12
- WTARULDDTDQWMU-RKDXNWHRSA-N (+)-β-pinene Chemical compound C1[C@H]2C(C)(C)[C@@H]1CCC2=C WTARULDDTDQWMU-RKDXNWHRSA-N 0.000 claims description 11
- FVHKMJAVMXGSOC-UHFFFAOYSA-N 1,2-bis(2-ethylhexoxy)anthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=C(OCC(CC)CCCC)C(OCC(CC)CCCC)=CC=C3C(=O)C2=C1 FVHKMJAVMXGSOC-UHFFFAOYSA-N 0.000 claims description 11
- 125000001931 aliphatic group Chemical group 0.000 claims description 11
- 239000011572 manganese Substances 0.000 claims description 11
- 229920005615 natural polymer Polymers 0.000 claims description 11
- 229920000573 polyethylene Polymers 0.000 claims description 11
- 229920005989 resin Polymers 0.000 claims description 11
- 239000011347 resin Substances 0.000 claims description 11
- 229910052783 alkali metal Inorganic materials 0.000 claims description 10
- 125000003118 aryl group Chemical group 0.000 claims description 10
- 229920001059 synthetic polymer Polymers 0.000 claims description 10
- 150000001340 alkali metals Chemical class 0.000 claims description 9
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 9
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 claims description 9
- 229910052802 copper Inorganic materials 0.000 claims description 9
- 239000010949 copper Substances 0.000 claims description 9
- DLINORNFHVEIFE-UHFFFAOYSA-N hydrogen peroxide;zinc Chemical compound [Zn].OO DLINORNFHVEIFE-UHFFFAOYSA-N 0.000 claims description 9
- 229920000098 polyolefin Polymers 0.000 claims description 9
- 229940105296 zinc peroxide Drugs 0.000 claims description 9
- DMCXAQHMLABASD-UHFFFAOYSA-N 1,5-bis(2-ethylhexoxy)anthracene-9,10-dione Chemical compound O=C1C2=C(OCC(CC)CCCC)C=CC=C2C(=O)C2=C1C=CC=C2OCC(CC)CCCC DMCXAQHMLABASD-UHFFFAOYSA-N 0.000 claims description 8
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 8
- 239000004611 light stabiliser Substances 0.000 claims description 8
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims description 8
- 229920001155 polypropylene Polymers 0.000 claims description 8
- KHJPIYGQRPXRRA-UHFFFAOYSA-N 1-[[4,6-bis(dibutylamino)-1,3,5-triazin-2-yl]amino]anthracene-9,10-dione Chemical compound CCCCN(CCCC)C1=NC(N(CCCC)CCCC)=NC(NC=2C=3C(=O)C4=CC=CC=C4C(=O)C=3C=CC=2)=N1 KHJPIYGQRPXRRA-UHFFFAOYSA-N 0.000 claims description 7
- RRUXFZNGRIWZRJ-UHFFFAOYSA-N 2,6-dioctadecoxyanthracene-9,10-dione Chemical compound CCCCCCCCCCCCCCCCCCOC1=CC=C2C(=O)C3=CC(OCCCCCCCCCCCCCCCCCC)=CC=C3C(=O)C2=C1 RRUXFZNGRIWZRJ-UHFFFAOYSA-N 0.000 claims description 7
- SPAGIJMPHSUYSE-UHFFFAOYSA-N Magnesium peroxide Chemical compound [Mg+2].[O-][O-] SPAGIJMPHSUYSE-UHFFFAOYSA-N 0.000 claims description 7
- WTARULDDTDQWMU-UHFFFAOYSA-N Pseudopinene Natural products C1C2C(C)(C)C1CCC2=C WTARULDDTDQWMU-UHFFFAOYSA-N 0.000 claims description 7
- 150000004056 anthraquinones Chemical class 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 229960004995 magnesium peroxide Drugs 0.000 claims description 7
- 229910052748 manganese Inorganic materials 0.000 claims description 7
- ICXSPBPHNKRBRV-UHFFFAOYSA-N n-dodecyl-9,10-dioxoanthracene-2-sulfonamide Chemical compound C1=CC=C2C(=O)C3=CC(S(=O)(=O)NCCCCCCCCCCCC)=CC=C3C(=O)C2=C1 ICXSPBPHNKRBRV-UHFFFAOYSA-N 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 claims description 7
- QEWDJHBTAPYZMH-UHFFFAOYSA-N 2-(2-ethylhexoxy)-1-octadecoxyanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC(OCC(CC)CCCC)=C2OCCCCCCCCCCCCCCCCCC QEWDJHBTAPYZMH-UHFFFAOYSA-N 0.000 claims description 6
- PZJKGBURXXFSEC-UHFFFAOYSA-N 2-[[4,6-bis(dibutylamino)-1,3,5-triazin-2-yl]amino]anthracene-9,10-dione Chemical compound CCCCN(CCCC)C1=NC(N(CCCC)CCCC)=NC(NC=2C=C3C(=O)C4=CC=CC=C4C(=O)C3=CC=2)=N1 PZJKGBURXXFSEC-UHFFFAOYSA-N 0.000 claims description 6
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 claims description 6
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims description 6
- 229930006722 beta-pinene Natural products 0.000 claims description 6
- 239000006229 carbon black Substances 0.000 claims description 6
- 235000013312 flour Nutrition 0.000 claims description 6
- 229910052720 vanadium Inorganic materials 0.000 claims description 6
- WTARULDDTDQWMU-IUCAKERBSA-N (-)-Nopinene Natural products C1[C@@H]2C(C)(C)[C@H]1CCC2=C WTARULDDTDQWMU-IUCAKERBSA-N 0.000 claims description 5
- GRWFGVWFFZKLTI-IUCAKERBSA-N 1S,5S-(-)-alpha-Pinene Natural products CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 claims description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 5
- 239000005864 Sulphur Substances 0.000 claims description 5
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 5
- LCWMKIHBLJLORW-UHFFFAOYSA-N gamma-carene Natural products C1CC(=C)CC2C(C)(C)C21 LCWMKIHBLJLORW-UHFFFAOYSA-N 0.000 claims description 5
- 239000000049 pigment Substances 0.000 claims description 5
- 238000012545 processing Methods 0.000 claims description 5
- 239000002023 wood Substances 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- 239000011701 zinc Substances 0.000 claims description 5
- UPVYZGSKUDYLMH-UHFFFAOYSA-N (6-octadecanoyloxy-9,10-dioxoanthracen-2-yl) octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC1=CC=C2C(=O)C3=CC(OC(=O)CCCCCCCCCCCCCCCCC)=CC=C3C(=O)C2=C1 UPVYZGSKUDYLMH-UHFFFAOYSA-N 0.000 claims description 4
- 241000234295 Musa Species 0.000 claims description 4
- 235000018290 Musa x paradisiaca Nutrition 0.000 claims description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 4
- 239000003963 antioxidant agent Substances 0.000 claims description 4
- ZJRXSAYFZMGQFP-UHFFFAOYSA-N barium peroxide Chemical compound [Ba+2].[O-][O-] ZJRXSAYFZMGQFP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- 235000001510 limonene Nutrition 0.000 claims description 4
- 229940087305 limonene Drugs 0.000 claims description 4
- HPGPEWYJWRWDTP-UHFFFAOYSA-N lithium peroxide Chemical compound [Li+].[Li+].[O-][O-] HPGPEWYJWRWDTP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 239000011777 magnesium Substances 0.000 claims description 4
- SZINCDDYCOIOJQ-UHFFFAOYSA-L manganese(2+);octadecanoate Chemical compound [Mn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O SZINCDDYCOIOJQ-UHFFFAOYSA-L 0.000 claims description 4
- 239000005022 packaging material Substances 0.000 claims description 4
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 4
- 229920006149 polyester-amide block copolymer Polymers 0.000 claims description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
- 229910000144 sodium(I) superoxide Inorganic materials 0.000 claims description 4
- DMKQYXTXLIZIJC-UHFFFAOYSA-N 1,2-dioctadecoxyanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=C(OCCCCCCCCCCCCCCCCCC)C(OCCCCCCCCCCCCCCCCCC)=CC=C3C(=O)C2=C1 DMKQYXTXLIZIJC-UHFFFAOYSA-N 0.000 claims description 3
- XJSMQTGMZCUOGZ-UHFFFAOYSA-N 1,2-dioctoxyanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=C(OCCCCCCCC)C(OCCCCCCCC)=CC=C3C(=O)C2=C1 XJSMQTGMZCUOGZ-UHFFFAOYSA-N 0.000 claims description 3
- PIZZQZXADIZREL-UHFFFAOYSA-N 2,6-bis[[4,6-bis(dibutylamino)-1,3,5-triazin-2-yl]oxy]anthracene-9,10-dione Chemical compound CCCCN(CCCC)C1=NC(N(CCCC)CCCC)=NC(OC=2C=C3C(=O)C4=CC=C(OC=5N=C(N=C(N=5)N(CCCC)CCCC)N(CCCC)CCCC)C=C4C(=O)C3=CC=2)=N1 PIZZQZXADIZREL-UHFFFAOYSA-N 0.000 claims description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 3
- 229920002472 Starch Polymers 0.000 claims description 3
- 229910052792 caesium Inorganic materials 0.000 claims description 3
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- 239000000835 fiber Substances 0.000 claims description 3
- 229920000578 graft copolymer Polymers 0.000 claims description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 229910052744 lithium Inorganic materials 0.000 claims description 3
- 229920005606 polypropylene copolymer Polymers 0.000 claims description 3
- 239000012744 reinforcing agent Substances 0.000 claims description 3
- 229910052701 rubidium Inorganic materials 0.000 claims description 3
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims description 3
- 229910000108 silver(I,III) oxide Inorganic materials 0.000 claims description 3
- ZBNMBCAMIKHDAA-UHFFFAOYSA-N sodium superoxide Chemical compound [Na+].O=O ZBNMBCAMIKHDAA-UHFFFAOYSA-N 0.000 claims description 3
- 239000008107 starch Substances 0.000 claims description 3
- 235000019698 starch Nutrition 0.000 claims description 3
- UHCGLDSRFKGERO-UHFFFAOYSA-N strontium peroxide Chemical compound [Sr+2].[O-][O-] UHCGLDSRFKGERO-UHFFFAOYSA-N 0.000 claims description 3
- 150000003673 urethanes Chemical class 0.000 claims description 3
- MMNWSHJJPDXKCH-UHFFFAOYSA-N 9,10-dioxoanthracene-2-sulfonic acid Chemical compound C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 MMNWSHJJPDXKCH-UHFFFAOYSA-N 0.000 claims description 2
- 229920002101 Chitin Polymers 0.000 claims description 2
- 229920000881 Modified starch Polymers 0.000 claims description 2
- 239000004368 Modified starch Substances 0.000 claims description 2
- 229920006328 Styrofoam Polymers 0.000 claims description 2
- 230000003078 antioxidant effect Effects 0.000 claims description 2
- 235000013361 beverage Nutrition 0.000 claims description 2
- 238000000071 blow moulding Methods 0.000 claims description 2
- 238000003490 calendering Methods 0.000 claims description 2
- 238000005266 casting Methods 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims description 2
- 238000000748 compression moulding Methods 0.000 claims description 2
- 239000002537 cosmetic Substances 0.000 claims description 2
- 238000001125 extrusion Methods 0.000 claims description 2
- 238000010096 film blowing Methods 0.000 claims description 2
- 235000013305 food Nutrition 0.000 claims description 2
- 150000004676 glycans Chemical class 0.000 claims description 2
- 238000001746 injection moulding Methods 0.000 claims description 2
- 229920005610 lignin Polymers 0.000 claims description 2
- 235000019426 modified starch Nutrition 0.000 claims description 2
- 238000000465 moulding Methods 0.000 claims description 2
- 229920001282 polysaccharide Polymers 0.000 claims description 2
- 239000005017 polysaccharide Substances 0.000 claims description 2
- 238000010106 rotational casting Methods 0.000 claims description 2
- 238000001175 rotational moulding Methods 0.000 claims description 2
- 238000009987 spinning Methods 0.000 claims description 2
- 229920003179 starch-based polymer Polymers 0.000 claims description 2
- 239000004628 starch-based polymer Substances 0.000 claims description 2
- 239000008261 styrofoam Substances 0.000 claims description 2
- 238000003856 thermoforming Methods 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 24
- 125000000027 (C1-C10) alkoxy group Chemical group 0.000 claims 4
- 229910052782 aluminium Inorganic materials 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 description 106
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 54
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 32
- 229920000092 linear low density polyethylene Polymers 0.000 description 28
- 239000004707 linear low-density polyethylene Substances 0.000 description 28
- 150000003254 radicals Chemical class 0.000 description 28
- 229940044603 styrene Drugs 0.000 description 28
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 27
- 235000007586 terpenes Nutrition 0.000 description 23
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 21
- 238000006243 chemical reaction Methods 0.000 description 21
- 238000005336 cracking Methods 0.000 description 21
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 20
- 229910052757 nitrogen Inorganic materials 0.000 description 20
- 239000000047 product Substances 0.000 description 19
- 150000001875 compounds Chemical class 0.000 description 18
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 18
- 238000002360 preparation method Methods 0.000 description 18
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 17
- 239000005977 Ethylene Substances 0.000 description 17
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 17
- 150000002148 esters Chemical class 0.000 description 17
- 229940093470 ethylene Drugs 0.000 description 17
- 238000002844 melting Methods 0.000 description 17
- 230000008018 melting Effects 0.000 description 17
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 15
- 239000007787 solid Substances 0.000 description 15
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 14
- APAJFZPFBHMFQR-UHFFFAOYSA-N anthraflavic acid Chemical compound OC1=CC=C2C(=O)C3=CC(O)=CC=C3C(=O)C2=C1 APAJFZPFBHMFQR-UHFFFAOYSA-N 0.000 description 14
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 14
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 13
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 13
- 229910052751 metal Inorganic materials 0.000 description 13
- 239000002184 metal Substances 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- 239000004952 Polyamide Substances 0.000 description 11
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 10
- 150000001412 amines Chemical class 0.000 description 10
- 239000000178 monomer Substances 0.000 description 10
- 229920002647 polyamide Polymers 0.000 description 10
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 9
- 239000005062 Polybutadiene Substances 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 150000001993 dienes Chemical class 0.000 description 9
- 229920001684 low density polyethylene Polymers 0.000 description 9
- 239000004702 low-density polyethylene Substances 0.000 description 9
- 229920002857 polybutadiene Polymers 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- 239000002244 precipitate Substances 0.000 description 9
- 150000003505 terpenes Chemical class 0.000 description 9
- 229920002554 vinyl polymer Polymers 0.000 description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 8
- 239000004700 high-density polyethylene Substances 0.000 description 8
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 7
- 239000002253 acid Substances 0.000 description 7
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 7
- 239000008187 granular material Substances 0.000 description 7
- 229920001903 high density polyethylene Polymers 0.000 description 7
- 238000004128 high performance liquid chromatography Methods 0.000 description 7
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 7
- 229920006324 polyoxymethylene Polymers 0.000 description 7
- 238000010992 reflux Methods 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 7
- QGEXFGIPDGFMTD-UHFFFAOYSA-N 2,6-bis(2-ethylhexoxy)anthracene-9,10-dione Chemical compound CCCCC(CC)COC1=CC=C2C(=O)C3=CC(OCC(CC)CCCC)=CC=C3C(=O)C2=C1 QGEXFGIPDGFMTD-UHFFFAOYSA-N 0.000 description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
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Classifications
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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| AU2013203151B2 (en) * | 2007-04-09 | 2015-05-21 | Wake Forest University Health Sciences | Oxygen-generating compositions for enhancing cell and tissue survival in vivo |
| WO2009135813A1 (en) * | 2008-05-07 | 2009-11-12 | Basf Se | Degradable material |
| SG172111A1 (en) * | 2008-12-12 | 2011-07-28 | Ingenia Polymers Inc | Compacted pelletized additive blends for polymers |
| US9441066B2 (en) * | 2009-12-02 | 2016-09-13 | Basf Se | Use of photosensitive molecules and metal complexes as oxygen scavenger elements |
| WO2012174204A2 (en) | 2011-06-17 | 2012-12-20 | Fiberweb, Inc. | Vapor permeable, substantially water impermeable multilayer article |
| US10369769B2 (en) | 2011-06-23 | 2019-08-06 | Fiberweb, Inc. | Vapor-permeable, substantially water-impermeable multilayer article |
| EP2723568B1 (en) | 2011-06-23 | 2017-09-27 | Fiberweb, LLC | Vapor permeable, substantially water impermeable multilayer article |
| US9765459B2 (en) | 2011-06-24 | 2017-09-19 | Fiberweb, Llc | Vapor-permeable, substantially water-impermeable multilayer article |
| JP5693689B2 (ja) * | 2012-09-24 | 2015-04-01 | 富士フイルム株式会社 | セルロースアシレートフィルム、それを用いた偏光板および液晶表示装置 |
| TWI447154B (zh) | 2012-11-27 | 2014-08-01 | Ind Tech Res Inst | 聚氯乙烯製品與其表面處理方法 |
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| CN107488302B (zh) * | 2017-09-19 | 2021-02-23 | 四川大学 | 降解膜制备工艺 |
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| WO1996025538A1 (en) * | 1995-02-14 | 1996-08-22 | Chisso Corporation | Biodegradable fiber and nonwoven fabric |
| US5776361A (en) * | 1995-02-15 | 1998-07-07 | Chevron Chemical Company | Multi-component oxygen scavenging composition |
| WO2001053369A1 (en) * | 2000-01-21 | 2001-07-26 | Mitsui Chemicals, Inc. | Olefin block copolymers, production processes of the same and use thereof |
| CA2406951C (en) * | 2000-05-31 | 2010-01-12 | Ciba Specialty Chemicals Holding Inc. | Stabilizer mixtures |
| US6638644B2 (en) * | 2001-08-28 | 2003-10-28 | Eastman Kodak Company | Electroluminescent devices having diarylanthracene polymers |
| JP2003073505A (ja) * | 2001-09-05 | 2003-03-12 | Shin Etsu Polymer Co Ltd | 生分解性フィルム乃至シート |
| US6607795B1 (en) * | 2001-12-19 | 2003-08-19 | Chevron Phillips Chemical Company Lp | Oxygen scavenging compositions comprising polymers derived from aromatic difunctional monomers |
| US20030236325A1 (en) * | 2002-05-30 | 2003-12-25 | Michela Bonora | Agricultural articles |
| DE60319695T2 (de) * | 2002-05-30 | 2009-03-26 | Ciba Holding Inc. | Stabilisierte gegenstände |
| US6899963B1 (en) * | 2004-02-25 | 2005-05-31 | Eastman Kodak Company | Electroluminescent devices having pendant naphthylanthracene-based polymers |
-
2006
- 2006-03-27 KR KR1020077022400A patent/KR20070116841A/ko not_active Withdrawn
- 2006-03-27 EP EP06725318A patent/EP1866367A2/en not_active Withdrawn
- 2006-03-27 JP JP2008504734A patent/JP2008534759A/ja active Pending
- 2006-03-27 CA CA002602347A patent/CA2602347A1/en not_active Abandoned
- 2006-03-27 US US11/887,499 patent/US20090076206A1/en not_active Abandoned
- 2006-03-27 WO PCT/EP2006/061048 patent/WO2006106049A2/en not_active Ceased
- 2006-03-27 CN CNA2006800107125A patent/CN101151315A/zh active Pending
- 2006-03-27 BR BRPI0607782-0A patent/BRPI0607782A2/pt not_active IP Right Cessation
- 2006-04-03 TW TW095111767A patent/TW200708546A/zh unknown
- 2006-04-03 AR ARP060101313A patent/AR055768A1/es unknown
-
2007
- 2007-09-11 IL IL185928A patent/IL185928A0/en unknown
-
2010
- 2010-09-27 US US12/890,837 patent/US20110015295A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| EP1866367A2 (en) | 2007-12-19 |
| CN101151315A (zh) | 2008-03-26 |
| BRPI0607782A2 (pt) | 2009-06-13 |
| JP2008534759A (ja) | 2008-08-28 |
| AR055768A1 (es) | 2007-09-05 |
| WO2006106049A3 (en) | 2006-11-30 |
| IL185928A0 (en) | 2008-01-06 |
| TW200708546A (en) | 2007-03-01 |
| US20090076206A1 (en) | 2009-03-19 |
| KR20070116841A (ko) | 2007-12-11 |
| US20110015295A1 (en) | 2011-01-20 |
| WO2006106049A2 (en) | 2006-10-12 |
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| Date | Code | Title | Description |
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| FZDE | Discontinued |