CA2599510A1 - Method for obtaining sodium carbonate crystals - Google Patents
Method for obtaining sodium carbonate crystals Download PDFInfo
- Publication number
- CA2599510A1 CA2599510A1 CA002599510A CA2599510A CA2599510A1 CA 2599510 A1 CA2599510 A1 CA 2599510A1 CA 002599510 A CA002599510 A CA 002599510A CA 2599510 A CA2599510 A CA 2599510A CA 2599510 A1 CA2599510 A1 CA 2599510A1
- Authority
- CA
- Canada
- Prior art keywords
- sodium carbonate
- aqueous
- carbon dioxide
- sodium hydroxide
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 title claims abstract description 80
- 229910000029 sodium carbonate Inorganic materials 0.000 title claims abstract description 38
- 239000013078 crystal Substances 0.000 title claims abstract description 25
- 238000000034 method Methods 0.000 title claims description 35
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 111
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 51
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 46
- 239000011780 sodium chloride Substances 0.000 claims abstract description 27
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 23
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 23
- 239000002002 slurry Substances 0.000 claims abstract description 20
- 239000012452 mother liquor Substances 0.000 claims abstract description 15
- 238000004519 manufacturing process Methods 0.000 claims abstract description 9
- 239000000243 solution Substances 0.000 claims description 40
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims description 35
- 229940001593 sodium carbonate Drugs 0.000 claims description 33
- 235000002639 sodium chloride Nutrition 0.000 claims description 27
- 239000012267 brine Substances 0.000 claims description 22
- 239000007789 gas Substances 0.000 claims description 18
- 239000007864 aqueous solution Substances 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- MQRJBSHKWOFOGF-UHFFFAOYSA-L disodium;carbonate;hydrate Chemical compound O.[Na+].[Na+].[O-]C([O-])=O MQRJBSHKWOFOGF-UHFFFAOYSA-L 0.000 claims description 16
- 229940076133 sodium carbonate monohydrate Drugs 0.000 claims description 16
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 13
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 13
- 238000009434 installation Methods 0.000 claims description 11
- 239000012528 membrane Substances 0.000 claims description 11
- 239000000460 chlorine Substances 0.000 claims description 10
- 229910052801 chlorine Inorganic materials 0.000 claims description 10
- 238000001704 evaporation Methods 0.000 claims description 9
- 230000008020 evaporation Effects 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 230000001105 regulatory effect Effects 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 235000019738 Limestone Nutrition 0.000 claims description 5
- 238000005868 electrolysis reaction Methods 0.000 claims description 5
- 150000002500 ions Chemical class 0.000 claims description 5
- 239000006028 limestone Substances 0.000 claims description 5
- 238000005192 partition Methods 0.000 claims description 5
- 150000001804 chlorine Chemical class 0.000 claims description 4
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims description 4
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 4
- -1 which are separated Substances 0.000 claims description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 2
- 239000003546 flue gas Substances 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 235000017550 sodium carbonate Nutrition 0.000 description 29
- 235000011121 sodium hydroxide Nutrition 0.000 description 29
- 238000002425 crystallisation Methods 0.000 description 7
- 230000008025 crystallization Effects 0.000 description 7
- 238000000746 purification Methods 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 150000001768 cations Chemical class 0.000 description 5
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- 229910001424 calcium ion Inorganic materials 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- 229910001425 magnesium ion Inorganic materials 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 238000011282 treatment Methods 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 238000006298 dechlorination reaction Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 150000004682 monohydrates Chemical group 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 241001625808 Trona Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 235000011182 sodium carbonates Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D7/00—Carbonates of sodium, potassium or alkali metals in general
- C01D7/07—Preparation from the hydroxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D7/00—Carbonates of sodium, potassium or alkali metals in general
- C01D7/22—Purification
- C01D7/24—Crystallisation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/20—Halides
- C01F11/24—Chlorides
- C01F11/28—Chlorides by chlorination of alkaline-earth metal compounds
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/14—Alkali metal compounds
- C25B1/16—Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/24—Halogens or compounds thereof
- C25B1/26—Chlorine; Compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Metallurgy (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR05.02371 | 2005-03-08 | ||
| FR0502371A FR2882998B1 (fr) | 2005-03-08 | 2005-03-08 | Procede pour l'obtention de cristaux de carbonate de sodium |
| PCT/EP2006/060524 WO2006094982A1 (en) | 2005-03-08 | 2006-03-07 | Method for obtaining sodium carbonate crystals |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2599510A1 true CA2599510A1 (en) | 2006-09-14 |
Family
ID=35058135
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002599510A Abandoned CA2599510A1 (en) | 2005-03-08 | 2006-03-07 | Method for obtaining sodium carbonate crystals |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US7708972B2 (https=) |
| EP (1) | EP1858807A1 (https=) |
| JP (1) | JP2008532904A (https=) |
| KR (1) | KR20070108897A (https=) |
| CN (1) | CN101137580B (https=) |
| BR (1) | BRPI0608574A2 (https=) |
| CA (1) | CA2599510A1 (https=) |
| EA (1) | EA013633B1 (https=) |
| FR (1) | FR2882998B1 (https=) |
| WO (1) | WO2006094982A1 (https=) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2883008B1 (fr) * | 2005-03-08 | 2007-04-27 | Solvay | Procede pour l'obtention conjointe de chlore et de cristaux de carbonate monohydrate |
| EP1900688A1 (en) * | 2006-09-14 | 2008-03-19 | SOLVAY (Société Anonyme) | Method for obtaining sodium carbonate crystals |
| PL2205341T3 (pl) | 2007-09-20 | 2012-08-31 | Skyonic Corp | Usuwanie dwutlenku węgla ze strumieni gazów spalinowych poprzez współwytwarzanie minerałów węglanów i/lub wodorowęglanów |
| US9527753B1 (en) | 2009-04-24 | 2016-12-27 | Geothermal Energy Project, Llc | Production of zinc chloride and zinc sulfate from geothermal brines |
| US9034294B1 (en) | 2009-04-24 | 2015-05-19 | Simbol, Inc. | Preparation of lithium carbonate from lithium chloride containing brines |
| US8637428B1 (en) | 2009-12-18 | 2014-01-28 | Simbol Inc. | Lithium extraction composition and method of preparation thereof |
| US10190030B2 (en) | 2009-04-24 | 2019-01-29 | Alger Alternative Energy, Llc | Treated geothermal brine compositions with reduced concentrations of silica, iron and lithium |
| US8741256B1 (en) | 2009-04-24 | 2014-06-03 | Simbol Inc. | Preparation of lithium carbonate from lithium chloride containing brines |
| US12168748B2 (en) | 2009-04-24 | 2024-12-17 | Terralithium Llc | Treated geothermal brine compositions with reduced concentration of silica, iron and lithium |
| US9051827B1 (en) | 2009-09-02 | 2015-06-09 | Simbol Mining Corporation | Selective removal of silica from silica containing brines |
| US10683563B2 (en) | 2009-06-24 | 2020-06-16 | Terralithium Llc | Treated geothermal brine compositions with reduced concentrations of silica, iron and manganese |
| US10935006B2 (en) | 2009-06-24 | 2021-03-02 | Terralithium Llc | Process for producing geothermal power, selective removal of silica and iron from brines, and improved injectivity of treated brines |
| MY153091A (en) * | 2009-07-14 | 2014-12-31 | Ceramatec Inc | Systems and methods for removing catalyst and recovering free carboxylic acids from transesterification reaction |
| US8247585B2 (en) * | 2009-07-14 | 2012-08-21 | Ceramatec, Inc | Systems and methods for removing catalyst and recovering free carboxylic acids after transesterification reaction |
| IL200860A (en) * | 2009-09-10 | 2015-07-30 | Green Future Ltd | Galvanic wastewater treatment and the production of iron oxide sized nanoparticles |
| RS59835B1 (sr) | 2010-02-17 | 2020-02-28 | All American Lithium LLC | Postupak za dobijanje veoma čistog litijum karbonata i drugih jedinjenja koja sadrže veoma čist litijum |
| MX2013000265A (es) | 2010-07-08 | 2013-05-30 | Skyonic Corp | Retiros de dioxido de carbono que involucran procesos termoliticos basados en dos sales. |
| US20130216467A1 (en) * | 2012-02-22 | 2013-08-22 | Idea International Investment And Development Company | Method of producing soda ash and calcium chloride |
| WO2014006741A1 (ja) * | 2012-07-06 | 2014-01-09 | 株式会社日立製作所 | 塩排水の処理方法及び装置 |
| JP2014014743A (ja) * | 2012-07-06 | 2014-01-30 | Hitachi Ltd | 塩排水の処理方法及びその処理装置 |
| US9249030B2 (en) | 2013-03-20 | 2016-02-02 | New York Synthetics, Inc. | Method of making sodium carbonate and/or sodium bicarbonate |
| CA2937108A1 (en) | 2014-01-17 | 2015-07-23 | Skyonic Corporation | Acid gas removal from a gaseous stream |
| EA201790890A1 (ru) | 2014-10-21 | 2017-10-31 | Скайоник Корпорейшн | Обработка сточных вод до уровня, пригодного для повторного использования в способе удаления co, и система |
| CA2977650C (en) | 2015-02-23 | 2023-03-21 | Carbonfree Chemicals Holdings, Llc | Carbon dioxide sequestration with magnesium hydroxide and regeneration of magnesium hydroxide |
| CN106976894B (zh) * | 2017-05-10 | 2018-10-23 | 东北大学 | 一种氯化锂电转化直接制备碳酸锂的方法 |
| US10604414B2 (en) | 2017-06-15 | 2020-03-31 | Energysource Minerals Llc | System and process for recovery of lithium from a geothermal brine |
| CN109809437A (zh) * | 2017-11-20 | 2019-05-28 | 内蒙古博源控股集团有限公司 | 新型节能环保重质纯碱生产工艺及系统 |
| SG11202105804QA (en) | 2019-03-27 | 2021-06-29 | Ptt Public Company Ltd | A preparation of sodium bicarbonate from carbon dioxide |
| EP3995205A1 (en) | 2020-11-10 | 2022-05-11 | Universidad de Castilla La Mancha | Co2 capture using alkaline media for the preparation of sodium carbonate |
| EP4008686A1 (en) * | 2020-12-03 | 2022-06-08 | Université catholique de Louvain | Continuous process and system for the production of sodium bicarbonate crystals |
| JP7774419B2 (ja) * | 2021-10-28 | 2025-11-21 | 株式会社トクヤマ | 炭酸ナトリウムの製造方法 |
| CN114751434B (zh) * | 2022-04-28 | 2023-11-24 | 中国地质科学院郑州矿产综合利用研究所 | 一种沉积型锂资源的综合回收利用方法 |
| DE102022119806A1 (de) * | 2022-08-05 | 2024-02-08 | Metaliq GmbH | Verfahren und System zur Natriumcarbonatherstellung |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2383674A (en) * | 1941-08-21 | 1945-08-28 | Hooker Electrochemical Co | Process for production of sodium bicarbonate |
| GB895690A (en) * | 1959-04-28 | 1962-05-09 | Struthers Wells Corp | Improvements in or relating to the preparation of sodium carbonate |
| GB1143844A (https=) * | 1967-02-10 | 1900-01-01 | ||
| DE1811168C3 (de) * | 1968-11-27 | 1980-01-10 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Soda |
| FR2092543A5 (https=) * | 1970-04-08 | 1972-01-21 | Zieren Chemiebau Gmbh Dr A | |
| DE2132922B2 (de) * | 1971-07-02 | 1972-12-14 | Zieren Chemiebau Gmbh Dr A | Verfahren zur herstellung von natriumcarbonat-monohydrat aus einer nach dem diaphragmen-verfahren gebildeten natronlauge |
| US3855397A (en) * | 1973-04-12 | 1974-12-17 | Allied Chem | Method of producing sodium carbonate and bicarbonate spherules from brine |
| JPS50118993A (https=) * | 1974-03-01 | 1975-09-18 | ||
| FR2272036A1 (en) * | 1974-05-22 | 1975-12-19 | Rhone Poulenc Ind | Sodium bi-carbonate prodn. from chloride electrolysis prod. - by continuous 2-stage treatment with carbon dioxide and cooling |
| AR208406A1 (es) * | 1974-05-22 | 1976-12-27 | Rhone Poulenc Ind | Procedimiento y aparato para obtener bicarbonato de sodio |
| FR2373614A1 (fr) | 1976-12-09 | 1978-07-07 | Solvay | Procede pour la production de chlore et de carbonate de sodium monohydrate |
| FR2384717A1 (fr) * | 1977-03-25 | 1978-10-20 | Solvay | Procede pour l'obtention de cristaux de carbonate de sodium monohydrate |
| DE2743753A1 (de) * | 1977-09-29 | 1979-04-12 | Metallgesellschaft Ag | Verfahren zum regenerieren von aus der entschwefelung heisser gase erhaltenen alkalicarbonatloesungen |
| US4219396A (en) * | 1979-08-03 | 1980-08-26 | Allied Chemical Corporation | Electrodialytic process |
| FR2590561B1 (fr) * | 1985-11-25 | 1988-01-29 | Solvay | Procede pour la preparation d'une solution aqueuse de chlorure de sodium et procede pour la production de bicarbonate de sodium |
| JP2001026418A (ja) * | 1999-07-16 | 2001-01-30 | Taiheiyo Cement Corp | 工業的に有用な無機材料の回収方法及び該回収方法によって回収した工業的に有用な無機材料 |
| JP4620143B2 (ja) | 2008-06-03 | 2011-01-26 | 株式会社三共 | 遊技機 |
-
2005
- 2005-03-08 FR FR0502371A patent/FR2882998B1/fr not_active Expired - Fee Related
-
2006
- 2006-03-07 BR BRPI0608574-1A patent/BRPI0608574A2/pt not_active IP Right Cessation
- 2006-03-07 EP EP06708673A patent/EP1858807A1/en not_active Withdrawn
- 2006-03-07 KR KR1020077020421A patent/KR20070108897A/ko not_active Abandoned
- 2006-03-07 US US11/817,736 patent/US7708972B2/en not_active Expired - Fee Related
- 2006-03-07 CN CN2006800075618A patent/CN101137580B/zh not_active Expired - Fee Related
- 2006-03-07 EA EA200701909A patent/EA013633B1/ru not_active IP Right Cessation
- 2006-03-07 CA CA002599510A patent/CA2599510A1/en not_active Abandoned
- 2006-03-07 JP JP2008500186A patent/JP2008532904A/ja active Pending
- 2006-03-07 WO PCT/EP2006/060524 patent/WO2006094982A1/en not_active Ceased
-
2010
- 2010-02-25 US US12/712,386 patent/US8202659B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| FR2882998B1 (fr) | 2007-06-08 |
| CN101137580A (zh) | 2008-03-05 |
| EP1858807A1 (en) | 2007-11-28 |
| FR2882998A1 (fr) | 2006-09-15 |
| US7708972B2 (en) | 2010-05-04 |
| BRPI0608574A2 (pt) | 2010-11-16 |
| CN101137580B (zh) | 2011-04-13 |
| EA200701909A1 (ru) | 2008-02-28 |
| JP2008532904A (ja) | 2008-08-21 |
| US20080193365A1 (en) | 2008-08-14 |
| KR20070108897A (ko) | 2007-11-13 |
| US20100147698A1 (en) | 2010-06-17 |
| WO2006094982A1 (en) | 2006-09-14 |
| EA013633B1 (ru) | 2010-06-30 |
| US8202659B2 (en) | 2012-06-19 |
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