CA2576078A1 - Electrolyte composition for nickel-zinc batteries - Google Patents
Electrolyte composition for nickel-zinc batteries Download PDFInfo
- Publication number
- CA2576078A1 CA2576078A1 CA002576078A CA2576078A CA2576078A1 CA 2576078 A1 CA2576078 A1 CA 2576078A1 CA 002576078 A CA002576078 A CA 002576078A CA 2576078 A CA2576078 A CA 2576078A CA 2576078 A1 CA2576078 A1 CA 2576078A1
- Authority
- CA
- Canada
- Prior art keywords
- electrolyte
- zinc
- cell
- battery cell
- hydroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000003792 electrolyte Substances 0.000 title claims abstract description 185
- QELJHCBNGDEXLD-UHFFFAOYSA-N nickel zinc Chemical compound [Ni].[Zn] QELJHCBNGDEXLD-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 239000000203 mixture Substances 0.000 title claims abstract description 32
- 239000011701 zinc Substances 0.000 claims abstract description 45
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 43
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 43
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 17
- 229910019142 PO4 Inorganic materials 0.000 claims description 62
- 239000010452 phosphate Substances 0.000 claims description 60
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 57
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 55
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 47
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 39
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 15
- VDZOOKBUILJEDG-UHFFFAOYSA-M tetrabutylammonium hydroxide Chemical compound [OH-].CCCC[N+](CCCC)(CCCC)CCCC VDZOOKBUILJEDG-UHFFFAOYSA-M 0.000 claims description 14
- 229910052738 indium Inorganic materials 0.000 claims description 12
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 10
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 8
- -1 alkyl phosphate ester Chemical class 0.000 claims description 8
- 229910000337 indium(III) sulfate Inorganic materials 0.000 claims description 7
- 150000002894 organic compounds Chemical class 0.000 claims description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- XGCKLPDYTQRDTR-UHFFFAOYSA-H indium(iii) sulfate Chemical compound [In+3].[In+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O XGCKLPDYTQRDTR-UHFFFAOYSA-H 0.000 claims description 6
- 150000004679 hydroxides Chemical class 0.000 claims description 5
- 150000002472 indium compounds Chemical class 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 229910052700 potassium Inorganic materials 0.000 claims description 4
- 239000011591 potassium Substances 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims description 3
- 229920000098 polyolefin Polymers 0.000 claims description 3
- RMSOEGBYNWXXBG-UHFFFAOYSA-N 1-chloronaphthalen-2-ol Chemical compound C1=CC=CC2=C(Cl)C(O)=CC=C21 RMSOEGBYNWXXBG-UHFFFAOYSA-N 0.000 claims description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 2
- VBXWCGWXDOBUQZ-UHFFFAOYSA-K diacetyloxyindiganyl acetate Chemical compound [In+3].CC([O-])=O.CC([O-])=O.CC([O-])=O VBXWCGWXDOBUQZ-UHFFFAOYSA-K 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- 229910052744 lithium Inorganic materials 0.000 claims description 2
- 229910000480 nickel oxide Inorganic materials 0.000 claims description 2
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 2
- 150000003752 zinc compounds Chemical class 0.000 claims description 2
- 210000004027 cell Anatomy 0.000 abstract description 162
- 239000000463 material Substances 0.000 abstract description 9
- 210000001787 dendrite Anatomy 0.000 abstract description 7
- 235000021317 phosphate Nutrition 0.000 description 59
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 29
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 20
- 239000000243 solution Substances 0.000 description 18
- 239000001569 carbon dioxide Substances 0.000 description 14
- 229910002092 carbon dioxide Inorganic materials 0.000 description 14
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 13
- 229910017052 cobalt Inorganic materials 0.000 description 11
- 239000010941 cobalt Substances 0.000 description 11
- 230000007797 corrosion Effects 0.000 description 11
- 238000005260 corrosion Methods 0.000 description 11
- 239000008363 phosphate buffer Substances 0.000 description 11
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 10
- 239000000654 additive Substances 0.000 description 9
- 239000000872 buffer Substances 0.000 description 9
- 230000001351 cycling effect Effects 0.000 description 9
- 238000012545 processing Methods 0.000 description 9
- 238000002474 experimental method Methods 0.000 description 7
- 239000011368 organic material Substances 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- 230000002829 reductive effect Effects 0.000 description 6
- 239000011787 zinc oxide Substances 0.000 description 6
- 230000008859 change Effects 0.000 description 5
- 238000013461 design Methods 0.000 description 5
- 238000007599 discharging Methods 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 230000022131 cell cycle Effects 0.000 description 4
- 239000007772 electrode material Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000011800 void material Substances 0.000 description 4
- DJHGAFSJWGLOIV-UHFFFAOYSA-K Arsenate3- Chemical compound [O-][As]([O-])([O-])=O DJHGAFSJWGLOIV-UHFFFAOYSA-K 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 230000003139 buffering effect Effects 0.000 description 3
- OJIJEKBXJYRIBZ-UHFFFAOYSA-N cadmium nickel Chemical compound [Ni].[Cd] OJIJEKBXJYRIBZ-UHFFFAOYSA-N 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 150000004673 fluoride salts Chemical class 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 230000000670 limiting effect Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 3
- 239000011698 potassium fluoride Substances 0.000 description 3
- 229910000162 sodium phosphate Inorganic materials 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000004135 Bone phosphate Chemical class 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 229940000489 arsenate Drugs 0.000 description 2
- 229910021538 borax Inorganic materials 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 239000006172 buffering agent Substances 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 239000008151 electrolyte solution Substances 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 150000002471 indium Chemical class 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-M oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC([O-])=O ZQPPMHVWECSIRJ-KTKRTIGZSA-M 0.000 description 2
- 229940049964 oleate Drugs 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 235000003270 potassium fluoride Nutrition 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 239000001488 sodium phosphate Substances 0.000 description 2
- 235000011008 sodium phosphates Nutrition 0.000 description 2
- 235000010339 sodium tetraborate Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 2
- DJHGAFSJWGLOIV-UHFFFAOYSA-N Arsenic acid Chemical class O[As](O)(O)=O DJHGAFSJWGLOIV-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910001515 alkali metal fluoride Inorganic materials 0.000 description 1
- 229910001618 alkaline earth metal fluoride Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000001869 cobalt compounds Chemical class 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229940017705 formaldehyde sulfoxylate Drugs 0.000 description 1
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- SBGKURINHGJRFN-UHFFFAOYSA-N hydroxymethanesulfinic acid Chemical compound OCS(O)=O SBGKURINHGJRFN-UHFFFAOYSA-N 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 235000015110 jellies Nutrition 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- VIKNJXKGJWUCNN-XGXHKTLJSA-N norethisterone Chemical compound O=C1CC[C@@H]2[C@H]3CC[C@](C)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1 VIKNJXKGJWUCNN-XGXHKTLJSA-N 0.000 description 1
- 229940039748 oxalate Drugs 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- JVUYWILPYBCNNG-UHFFFAOYSA-N potassium;oxido(oxo)borane Chemical compound [K+].[O-]B=O JVUYWILPYBCNNG-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 229940114926 stearate Drugs 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 229940001496 tribasic sodium phosphate Drugs 0.000 description 1
- WUUHFRRPHJEEKV-UHFFFAOYSA-N tripotassium borate Chemical compound [K+].[K+].[K+].[O-]B([O-])[O-] WUUHFRRPHJEEKV-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/24—Alkaline accumulators
- H01M10/26—Selection of materials as electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0431—Cells with wound or folded electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/24—Alkaline accumulators
- H01M10/28—Construction or manufacture
- H01M10/286—Cells or batteries with wound or folded electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/24—Electrodes for alkaline accumulators
- H01M4/244—Zinc electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/24—Electrodes for alkaline accumulators
- H01M4/32—Nickel oxide or hydroxide electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/04—Cells with aqueous electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/04—Cells with aqueous electrolyte
- H01M6/045—Cells with aqueous electrolyte characterised by aqueous electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/24—Alkaline accumulators
- H01M10/30—Nickel accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0002—Aqueous electrolytes
- H01M2300/0014—Alkaline electrolytes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
- Primary Cells (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/346,861 | 2006-02-01 | ||
| US11/346,861 US7550230B2 (en) | 2001-03-15 | 2006-02-01 | Electrolyte composition for nickel-zinc batteries |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2576078A1 true CA2576078A1 (en) | 2007-08-01 |
Family
ID=37877264
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002576078A Abandoned CA2576078A1 (en) | 2006-02-01 | 2007-01-29 | Electrolyte composition for nickel-zinc batteries |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US7550230B2 (enExample) |
| EP (1) | EP1819002B1 (enExample) |
| JP (1) | JP5149511B2 (enExample) |
| CN (1) | CN101034762B (enExample) |
| AT (1) | ATE438205T1 (enExample) |
| CA (1) | CA2576078A1 (enExample) |
| DE (1) | DE602007001701D1 (enExample) |
Families Citing this family (60)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7550230B2 (en) * | 2001-03-15 | 2009-06-23 | Powergenix Systems, Inc. | Electrolyte composition for nickel-zinc batteries |
| US20080166632A1 (en) * | 2003-08-18 | 2008-07-10 | Powergenix, Inc. | Method of manufacturing nickel zinc batteries |
| WO2005020353A2 (en) * | 2003-08-18 | 2005-03-03 | Powergenix Systems, Inc. | Method of manufacturing nickel zinc batteries |
| US8703330B2 (en) * | 2005-04-26 | 2014-04-22 | Powergenix Systems, Inc. | Nickel zinc battery design |
| US8048566B2 (en) * | 2008-02-07 | 2011-11-01 | Powergenix Systems, Inc. | Nickel hydroxide electrode for rechargeable batteries |
| KR101536031B1 (ko) * | 2008-04-02 | 2015-07-10 | 파워지닉스 시스템즈, 인코포레이티드 | 네거티브 캔을 포함하는 원통형 니켈-아연 전지 |
| US20100062347A1 (en) * | 2008-09-09 | 2010-03-11 | Lin-Feng Li | Rechargeable zinc cell with longitudinally-folded separator |
| US8501351B2 (en) * | 2009-05-18 | 2013-08-06 | Powergenix Systems, Inc. | Pasted zinc electrode for rechargeable nickel-zinc batteries |
| KR101938103B1 (ko) | 2009-08-07 | 2019-01-11 | 징크파이브 파워, 인크. | 탄소 섬유 아연 음극 |
| KR101785122B1 (ko) | 2009-09-08 | 2017-10-12 | 파워지닉스 시스템즈, 인코포레이티드 | 니켈 아연 전지용 분리막의 열 밀봉법 |
| US20110086252A1 (en) * | 2009-10-13 | 2011-04-14 | Powergenix Systems, Inc. | Cylindrical nickel-zinc cell with positive can |
| US10451897B2 (en) | 2011-03-18 | 2019-10-22 | Johnson & Johnson Vision Care, Inc. | Components with multiple energization elements for biomedical devices |
| CN105375070A (zh) | 2011-08-23 | 2016-03-02 | 株式会社日本触媒 | 凝胶电解质以及使用了该凝胶电解质的电池 |
| US8857983B2 (en) | 2012-01-26 | 2014-10-14 | Johnson & Johnson Vision Care, Inc. | Ophthalmic lens assembly having an integrated antenna structure |
| CN102832419A (zh) * | 2012-08-30 | 2012-12-19 | 上海锦众信息科技有限公司 | 一种碱性锌电池电解液的制备方法 |
| JP6647866B2 (ja) | 2012-12-20 | 2020-02-14 | ジンクファイブ・パワー・インコーポレーテッドＺｉｎｃＦｉｖｅ Ｐｏｗｅｒ，Ｉｎｃ． | 独立した電源を有するシステムにおける電池の充電状態の制御 |
| US9337683B2 (en) | 2012-12-20 | 2016-05-10 | Powergenix Systems, Inc. | Controlling battery states of charge in systems having separate power sources |
| WO2014110164A1 (en) | 2013-01-14 | 2014-07-17 | Powergenix Systems, Inc. | Pasted nickel hydroxide electrode and additives for rechargeable alkaline batteries |
| US10868338B2 (en) * | 2013-02-06 | 2020-12-15 | Encell Technology, Inc. | Nickel-iron battery with high power |
| WO2014124110A1 (en) * | 2013-02-06 | 2014-08-14 | Encell Technology, Inc. | Improved electrolyte for battery containing an iron electrode |
| US10854926B2 (en) * | 2013-02-06 | 2020-12-01 | Encell Technology, Inc. | Nickel-iron battery with high cycle life |
| US10804573B2 (en) * | 2013-02-06 | 2020-10-13 | Encell Technology, Inc. | Electrolyte for battery containing an iron electrode |
| US10847843B2 (en) | 2013-02-06 | 2020-11-24 | Encell Technology, Inc. | Electrolyte for a nickel-iron battery |
| JP6150383B2 (ja) * | 2013-03-28 | 2017-06-21 | 日産自動車株式会社 | アルカリ電池用電解質及びアルカリ電池 |
| US10333176B2 (en) * | 2013-08-12 | 2019-06-25 | The University Of Akron | Polymer electrolyte membranes for rechargeable batteries |
| WO2015026977A1 (en) * | 2013-08-20 | 2015-02-26 | Encell Technology, Inc. | Manganese and iron electrode cell |
| US20150162571A1 (en) * | 2013-12-10 | 2015-06-11 | Encell Technology, Inc. | Concave cell design for an alkaline battery with a comb spacer |
| US20150162572A1 (en) * | 2013-12-10 | 2015-06-11 | Encell Technology, Inc. | Cell design for an alkaline battery to remove gas |
| US20150162570A1 (en) * | 2013-12-10 | 2015-06-11 | Encell Technology, Inc. | Beveled cell design for an alkaline battery to remove gas |
| JP6296542B2 (ja) * | 2014-03-28 | 2018-03-20 | 日産自動車株式会社 | 亜鉛二次電池用電解質及び亜鉛二次電池 |
| US9793536B2 (en) | 2014-08-21 | 2017-10-17 | Johnson & Johnson Vision Care, Inc. | Pellet form cathode for use in a biocompatible battery |
| US10361405B2 (en) | 2014-08-21 | 2019-07-23 | Johnson & Johnson Vision Care, Inc. | Biomedical energization elements with polymer electrolytes |
| US9599842B2 (en) | 2014-08-21 | 2017-03-21 | Johnson & Johnson Vision Care, Inc. | Device and methods for sealing and encapsulation for biocompatible energization elements |
| US10361404B2 (en) | 2014-08-21 | 2019-07-23 | Johnson & Johnson Vision Care, Inc. | Anodes for use in biocompatible energization elements |
| US9941547B2 (en) | 2014-08-21 | 2018-04-10 | Johnson & Johnson Vision Care, Inc. | Biomedical energization elements with polymer electrolytes and cavity structures |
| US10627651B2 (en) | 2014-08-21 | 2020-04-21 | Johnson & Johnson Vision Care, Inc. | Methods and apparatus to form biocompatible energization primary elements for biomedical devices with electroless sealing layers |
| US20160056508A1 (en) * | 2014-08-21 | 2016-02-25 | Johnson & Johnson Vision Care, Inc. | Electrolyte formulations for use in biocompatible energization elements |
| US9715130B2 (en) | 2014-08-21 | 2017-07-25 | Johnson & Johnson Vision Care, Inc. | Methods and apparatus to form separators for biocompatible energization elements for biomedical devices |
| US10381687B2 (en) | 2014-08-21 | 2019-08-13 | Johnson & Johnson Vision Care, Inc. | Methods of forming biocompatible rechargable energization elements for biomedical devices |
| US9383593B2 (en) | 2014-08-21 | 2016-07-05 | Johnson & Johnson Vision Care, Inc. | Methods to form biocompatible energization elements for biomedical devices comprising laminates and placed separators |
| SG10201902585QA (en) * | 2014-10-06 | 2019-04-29 | Eos Energy Storage Llc | Electrolyte for rechargeable electrochemical cell |
| CN105304946B (zh) * | 2015-09-21 | 2017-11-28 | 新乡市超力新能源有限公司 | 一种可充电锌镍电池用电解液、锌镍电池及其制备方法 |
| US10345620B2 (en) | 2016-02-18 | 2019-07-09 | Johnson & Johnson Vision Care, Inc. | Methods and apparatus to form biocompatible energization elements incorporating fuel cells for biomedical devices |
| US10892524B2 (en) | 2016-03-29 | 2021-01-12 | Eos Energy Storage, Llc | Electrolyte for rechargeable electrochemical cell |
| CN106848407A (zh) * | 2017-02-27 | 2017-06-13 | 安徽桑瑞斯环保新材料有限公司 | 一种用于可再充电碱性电化学电池的碱性电池电解质 |
| JP6989970B2 (ja) * | 2017-05-29 | 2022-01-12 | ナミックス株式会社 | 二次電池及び二次電池を含む装置 |
| CN107634266B (zh) * | 2017-08-18 | 2019-12-10 | 上海交通大学 | 一种锌二次电池用阻燃性电解液 |
| CN109818086A (zh) * | 2017-11-22 | 2019-05-28 | 王明煜 | 一种锌镍电池用碱性胶体电解质及其制备方法、应用 |
| WO2019142915A1 (ja) * | 2018-01-18 | 2019-07-25 | マクセルホールディングス株式会社 | アルカリ二次電池およびその充電方法ならびにアルカリ二次電池の充電装置 |
| JP7149079B2 (ja) * | 2018-03-01 | 2022-10-06 | マクセル株式会社 | アルカリ二次電池 |
| EP3787093A4 (en) | 2018-04-27 | 2022-04-06 | Kyocera Corporation | FLOW CELL, FLOW CELL SYSTEM AND CONTROL METHOD |
| CN110718719B (zh) * | 2018-07-13 | 2020-10-30 | 常熟理工学院 | 一种可充电的锌离子电池 |
| FR3099851B1 (fr) | 2019-08-09 | 2021-07-16 | Sunergy | générateurs ELECTROCHIMIQUES secondaires ALCALINS À anode de zinc |
| CN111048846A (zh) * | 2019-12-18 | 2020-04-21 | 陈发生 | 一种镍锌电池 |
| CN111463500B (zh) * | 2020-03-18 | 2021-06-22 | 山东合泰新能源有限公司 | 一种用于锌阳极碱性二次电池的电解液的制备方法 |
| CN111463499B (zh) * | 2020-03-18 | 2021-12-28 | 山东合泰新能源有限公司 | 二次锌镍电池用电解液 |
| CN112164832B (zh) * | 2020-03-19 | 2021-12-28 | 山东合泰新能源有限公司 | 一种电解液的配制方法及其应用的锌镍电池 |
| JP2021158028A (ja) * | 2020-03-27 | 2021-10-07 | 日本碍子株式会社 | 亜鉛二次電池 |
| US11628991B2 (en) * | 2020-08-07 | 2023-04-18 | Illinois Tool Works Inc. | Pressure relief assemblies and methods |
| WO2022232465A1 (en) * | 2021-04-29 | 2022-11-03 | Form Energy, Inc. | Electrolyte formulations and additives for iron anode electrochemical systems |
Family Cites Families (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3287166A (en) | 1965-01-27 | 1966-11-22 | Douglas Aircraft Co Inc | Battery electrode and battery, and process for preparing said electrode |
| US3287164A (en) | 1965-01-27 | 1966-11-22 | Douglas Aircraft Co Inc | Electrode and battery |
| US3558356A (en) | 1967-02-28 | 1971-01-26 | Texas Instruments Inc | Nickel-zinc battery system which is negative limited during charging thereof |
| US3870564A (en) | 1973-03-30 | 1975-03-11 | Tokyo Shibaura Electric Co | Alkaline cell |
| JPS5461B2 (enExample) | 1973-11-21 | 1979-01-05 | ||
| CS167146B1 (enExample) | 1974-05-21 | 1976-04-29 | ||
| JPS5626108B2 (enExample) | 1975-01-20 | 1981-06-16 | ||
| JPS5629345A (en) | 1979-08-18 | 1981-03-24 | Mitsubishi Electric Corp | Division of wafer |
| US4304828A (en) | 1980-06-27 | 1981-12-08 | Energy Research Corporation | Zinc electrode |
| US4273841A (en) | 1980-08-14 | 1981-06-16 | General Electric Company | Ternary electrolyte for secondary electrochemical cells |
| JPS58163171A (ja) | 1982-03-19 | 1983-09-27 | Sanyo Electric Co Ltd | アルカリ亜鉛蓄電池 |
| JPS59186255A (ja) * | 1983-04-08 | 1984-10-23 | Matsushita Electric Ind Co Ltd | アルカリ一次電池 |
| JPS6056368A (ja) | 1983-09-05 | 1985-04-01 | Sanyo Electric Co Ltd | アルカリ亜鉛蓄電池 |
| JPS60167264A (ja) | 1984-02-10 | 1985-08-30 | Sanyo Electric Co Ltd | アルカリ亜鉛蓄電池 |
| JPS61210192A (ja) | 1985-03-13 | 1986-09-18 | Toshiba Corp | 金属の腐食抑制剤 |
| JPS6235453A (ja) | 1985-08-06 | 1987-02-16 | Sanyo Electric Co Ltd | アルカリ亜鉛蓄電池 |
| US5168018A (en) | 1990-05-17 | 1992-12-01 | Matsushita Electric Industrial Co., Ltd. | Method of manufacturing zinc-alkaline batteries |
| US5215836A (en) | 1991-07-18 | 1993-06-01 | Electrochimica Corporation | Alkaline galvanic cells |
| JP3553104B2 (ja) * | 1992-08-04 | 2004-08-11 | 株式会社エスアイアイ・マイクロパーツ | アルカリ電池 |
| JP2918446B2 (ja) | 1994-04-27 | 1999-07-12 | 富士電気化学株式会社 | 電池の負極亜鉛缶 |
| US5556720A (en) | 1994-08-18 | 1996-09-17 | Energy Research Corporation | Sealed zinc secondary battery and zinc electrode therefor |
| JPH08185856A (ja) * | 1994-12-28 | 1996-07-16 | Sanyo Electric Co Ltd | 電池用希土類−ニッケル系水素吸蔵合金の表面改質処理法 |
| JP3370486B2 (ja) | 1995-07-21 | 2003-01-27 | 松下電器産業株式会社 | アルカリ電池 |
| EP0833397B1 (en) | 1996-09-20 | 2002-05-15 | Matsushita Electric Industrial Co., Ltd. | Positive electrode active material for alkaline storage batteries |
| US7829221B2 (en) | 2000-11-10 | 2010-11-09 | Powergenix Systems, Inc. | Cobalt containing positive electrode formulation for a nickel-zinc cell |
| CA2325640A1 (en) | 2000-11-10 | 2002-05-10 | Jeffrey Phillips | Positive and negative interactive electrode formulation for a zinc-containing cell having an alkaline elelctrolyte |
| CA2325791A1 (en) * | 2000-11-10 | 2002-05-10 | Jeffrey Phillips | Negative electrode formulation for a low toxicity zinc electrode having additives with redox potentials positive to zinc potential |
| CA2325595A1 (en) | 2000-11-10 | 2002-05-10 | Jeffrey Phillips | Charger for a rechargeable nickel-zinc battery |
| US7033700B2 (en) * | 2000-11-10 | 2006-04-25 | Powergenix Systems, Inc. | Formulation of zinc negative electrode for rechargeable cells having an alkaline electrolyte |
| CA2325308A1 (en) | 2000-11-10 | 2002-05-10 | Jeffrey Phillips | Negative electrode formulation for a low toxicity zinc electrode having additives with redox potentials negative to zinc potential |
| CA2377065A1 (en) | 2001-03-15 | 2002-09-15 | Powergenix Systems Inc. | Alkaline cells having low toxicity rechargeable zinc electrodes |
| US6790559B2 (en) * | 2001-03-15 | 2004-09-14 | Powergenix Systems, Inc. | Alkaline cells having positive nickel hydroxide electrodes with fluoride salt additives |
| US7550230B2 (en) * | 2001-03-15 | 2009-06-23 | Powergenix Systems, Inc. | Electrolyte composition for nickel-zinc batteries |
| US7008723B2 (en) * | 2001-08-21 | 2006-03-07 | Ecosol Solar Technologies Inc. | Method of manufacture of an anode composition for use in a rechargeable electrochemical cell |
| US7049030B2 (en) | 2003-03-06 | 2006-05-23 | The Gillette Company | Battery |
| CN1283022C (zh) | 2003-03-10 | 2006-11-01 | 华南理工大学 | 锌镍二次电池及其制备方法 |
| CN2632866Y (zh) | 2003-07-17 | 2004-08-11 | 比亚迪股份有限公司 | 锌镍电池 |
| WO2005020353A2 (en) | 2003-08-18 | 2005-03-03 | Powergenix Systems, Inc. | Method of manufacturing nickel zinc batteries |
| US20050153203A1 (en) * | 2004-01-13 | 2005-07-14 | Stauffer John E. | Lead-zinc battery |
| US7785740B2 (en) * | 2004-04-09 | 2010-08-31 | Air Products And Chemicals, Inc. | Overcharge protection for electrochemical cells |
| US8703330B2 (en) | 2005-04-26 | 2014-04-22 | Powergenix Systems, Inc. | Nickel zinc battery design |
-
2006
- 2006-02-01 US US11/346,861 patent/US7550230B2/en not_active Expired - Lifetime
-
2007
- 2007-01-29 CA CA002576078A patent/CA2576078A1/en not_active Abandoned
- 2007-01-31 EP EP07250401A patent/EP1819002B1/en active Active
- 2007-01-31 DE DE602007001701T patent/DE602007001701D1/de active Active
- 2007-01-31 AT AT07250401T patent/ATE438205T1/de not_active IP Right Cessation
- 2007-01-31 CN CN2007100923030A patent/CN101034762B/zh active Active
- 2007-01-31 JP JP2007020646A patent/JP5149511B2/ja active Active
-
2009
- 2009-06-01 US US12/476,166 patent/US7816030B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN101034762B (zh) | 2010-12-08 |
| EP1819002A3 (en) | 2007-08-22 |
| JP2007214125A (ja) | 2007-08-23 |
| US20090246623A1 (en) | 2009-10-01 |
| EP1819002B1 (en) | 2009-07-29 |
| US7816030B2 (en) | 2010-10-19 |
| DE602007001701D1 (de) | 2009-09-10 |
| CN101034762A (zh) | 2007-09-12 |
| JP5149511B2 (ja) | 2013-02-20 |
| ATE438205T1 (de) | 2009-08-15 |
| EP1819002A2 (en) | 2007-08-15 |
| US7550230B2 (en) | 2009-06-23 |
| US20060127761A1 (en) | 2006-06-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP1819002B1 (en) | Electrolyte composition for nickel-zinc batteries | |
| KR101769630B1 (ko) | 이차 아연 배터리용의 페이스트된 아연 전극 | |
| CN101939863B (zh) | 用于可再充电的镍锌电池的涂膏氢氧化镍电极 | |
| JP5624323B2 (ja) | 充電可能なニッケル・亜鉛バッテリセルおよび陰極 | |
| CN102422478B (zh) | 用于可再充电蓄电池的氢氧化镍电极 | |
| KR20090065539A (ko) | 니켈-아연 배터리 팩 충전 방법 | |
| CN100524909C (zh) | 用于碱性电池的阴极材料和添加剂 | |
| CA3156653C (en) | Electrolyte-solution composition and secondary battery using same | |
| EP1412996B1 (en) | Optimised alkaline electrochemical cells | |
| US20100062327A1 (en) | Non-toxic alkaline electrolyte with additives for rechargeable zinc cells | |
| Coates et al. | The electrochemical deposition of additives to the nickel electrode | |
| HK1062227B (en) | Optimised alkaline electrochemical cells |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |
Effective date: 20141010 |