CA2562492A1 - Process and catalysts for the opening of naphthene rings - Google Patents

Process and catalysts for the opening of naphthene rings Download PDF

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Publication number
CA2562492A1
CA2562492A1 CA002562492A CA2562492A CA2562492A1 CA 2562492 A1 CA2562492 A1 CA 2562492A1 CA 002562492 A CA002562492 A CA 002562492A CA 2562492 A CA2562492 A CA 2562492A CA 2562492 A1 CA2562492 A1 CA 2562492A1
Authority
CA
Canada
Prior art keywords
ranging
silico
process according
alumina
atm
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002562492A
Other languages
English (en)
French (fr)
Inventor
Vincenzo Calemma
Angela Carati
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eni SpA
Original Assignee
Eni S.P.A.
Vincenzo Calemma
Angela Carati
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eni S.P.A., Vincenzo Calemma, Angela Carati filed Critical Eni S.P.A.
Publication of CA2562492A1 publication Critical patent/CA2562492A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/468—Iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/041—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41
    • B01J29/042—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41 containing iron group metals, noble metals or copper
    • B01J29/043—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B01J29/7469—MTW-type, e.g. ZSM-12, NU-13, TPZ-12 or Theta-3
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/7869—MTW-type, e.g. ZSM-12, NU-13, TPZ-12 or Theta-3
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/62—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing platinum group metals or compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CA002562492A 2004-04-23 2005-04-19 Process and catalysts for the opening of naphthene rings Abandoned CA2562492A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ITMI2004A000798 2004-04-23
IT000798A ITMI20040798A1 (it) 2004-04-23 2004-04-23 Processo e catalizzatori per l'apertura di anelli naftenici
PCT/EP2005/004157 WO2005103207A1 (en) 2004-04-23 2005-04-19 Process and catalysts for the opening of naphthene rings

Publications (1)

Publication Number Publication Date
CA2562492A1 true CA2562492A1 (en) 2005-11-03

Family

ID=34956025

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002562492A Abandoned CA2562492A1 (en) 2004-04-23 2005-04-19 Process and catalysts for the opening of naphthene rings

Country Status (8)

Country Link
US (1) US20080035529A1 (it)
EP (1) EP1737935A1 (it)
JP (1) JP2007533807A (it)
BR (1) BRPI0509983A (it)
CA (1) CA2562492A1 (it)
IT (1) ITMI20040798A1 (it)
MX (1) MXPA06012223A (it)
WO (1) WO2005103207A1 (it)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITMI20051295A1 (it) * 2005-07-08 2007-01-09 Eni Spa Processo per migliorare le qualita' come carburante di miscele idrocarburiche idrotrattate
US8871669B2 (en) * 2008-05-19 2014-10-28 General Electric Company Catalyst and method of manufacture
IT1392194B1 (it) 2008-12-12 2012-02-22 Eni Spa Processo per la produzione di idrocarburi, utili per autotrazione, da miscele di origine biologica
IT1396939B1 (it) 2009-12-09 2012-12-20 Eni Spa Composizione idrocarburica utile come carburante o combustibile
US20110203253A1 (en) * 2010-02-23 2011-08-25 General Electric Company Advanced fuel compositions from renewable sources, and related methods for making and using the fuel
IT1401697B1 (it) 2010-09-10 2013-08-02 Eni Spa Processo e catalizzatori per migliorare le qualita' come carburante di miscele idrocarburiche
IT1403895B1 (it) 2010-12-29 2013-11-08 Eni Spa Processo e sistema catalitico per migliorare le qualita' come carburante di miscele idrocarburiche
EP2589434A1 (en) 2011-11-04 2013-05-08 ENI S.p.A. Process and catalysts for enhancing the fuel quality of hydrocarbon blends
DE102011118482A1 (de) * 2011-11-12 2013-05-16 Volkswagen Aktiengesellschaft Verfahren zur Cetanzahlanhebung von Naphtha
ITMI20112411A1 (it) 2011-12-28 2013-06-29 Eni Spa Metodo per individuare catalizzatori adatti a migliorare le qualità come carburante di miscele idrocarburiche e processo di upgrading che li utilizza
WO2015181744A1 (en) 2014-05-29 2015-12-03 Eni S.P.A. Process for producing a diesel hydrocarbon fraction starting from a renewable feedstock
RS61562B1 (sr) 2014-05-29 2021-04-29 Eni Spa Proces proizvodnje dizel frakcije ugljovodovodnika polazeći od obnovljivih sirovina
EP4257662A3 (en) 2014-05-29 2023-12-27 ENI S.p.A. Process for producing a diesel hydrocarbon fraction starting from a renewable feedstock
CA3073502A1 (en) * 2017-08-23 2019-02-28 Phillips 66 Company Processes for selective naphtha reforming

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3832449A (en) * 1971-03-18 1974-08-27 Mobil Oil Corp Crystalline zeolite zsm{14 12
US4238316A (en) * 1978-07-06 1980-12-09 Atlantic Richfield Company Two-stage catalytic process to produce lubricating oils
US4374296A (en) * 1980-02-14 1983-02-15 Mobil Oil Corporation Isomerization of paraffin hydrocarbons using zeolites with high steam-enhanced acidity
JPS58193739A (ja) * 1982-05-07 1983-11-11 Osaka Gas Co Ltd 触媒の再生方法
IT1219692B (it) * 1988-05-06 1990-05-24 Eniricerche Spa Gel di silice e allumina cataliticamente attivo e procedimento per la sua preparazione
US5282958A (en) * 1990-07-20 1994-02-01 Chevron Research And Technology Company Use of modified 5-7 a pore molecular sieves for isomerization of hydrocarbons
WO1992013045A1 (en) * 1991-01-25 1992-08-06 Chevron Research And Technology Company Reforming naphtha with large-pore zeolites
IT1256084B (it) 1992-07-31 1995-11-27 Eniricerche Spa Catalizzatore per la idroisomerizzazione di normal-paraffine a catena lunga e procedimento per la sua preparazione
AU4737896A (en) * 1994-11-23 1996-06-17 Exxon Chemical Patents Inc. Hydrocarbon conversion process using a zeolite bound zeolite catalyst
TW504501B (en) * 1995-02-10 2002-10-01 Mobil Oil Corp Process for converting feedstock comprising C9+ aromatic hydrocarbons to lighter aromatic products
US5763731A (en) * 1995-09-05 1998-06-09 Exxon Research And Engineering Company Process for selectively opening naphthenic rings
RU2235115C2 (ru) * 1998-11-16 2004-08-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ каталитической депарафинизации и каталитическая композиция для его осуществления
IT1312337B1 (it) * 1999-05-07 2002-04-15 Agip Petroli Composizione catalitica per l'upgrading di idrocarburi aventi punti di ebollizione nell'intervallo della nafta
EP1101813B1 (en) * 1999-11-19 2014-03-19 ENI S.p.A. Process for the preparation of middle distillates starting from linear paraffins
US6589416B2 (en) * 2000-07-21 2003-07-08 Exxonmobil Research And Engineering Company Method and catalyst for opening naphthenic rings of naphthenic ring-containing compounds
US6656342B2 (en) * 2001-04-04 2003-12-02 Chevron U.S.A. Inc. Graded catalyst bed for split-feed hydrocracking/hydrotreating
US7323100B2 (en) * 2004-07-16 2008-01-29 Conocophillips Company Combination of amorphous materials for hydrocracking catalysts

Also Published As

Publication number Publication date
JP2007533807A (ja) 2007-11-22
ITMI20040798A1 (it) 2004-07-23
BRPI0509983A (pt) 2007-10-16
US20080035529A1 (en) 2008-02-14
WO2005103207A1 (en) 2005-11-03
EP1737935A1 (en) 2007-01-03
MXPA06012223A (es) 2007-04-12

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Effective date: 20130419