CA2553693A1 - Radiopaque coating for biomedical devices - Google Patents
Radiopaque coating for biomedical devices Download PDFInfo
- Publication number
- CA2553693A1 CA2553693A1 CA002553693A CA2553693A CA2553693A1 CA 2553693 A1 CA2553693 A1 CA 2553693A1 CA 002553693 A CA002553693 A CA 002553693A CA 2553693 A CA2553693 A CA 2553693A CA 2553693 A1 CA2553693 A1 CA 2553693A1
- Authority
- CA
- Canada
- Prior art keywords
- coating
- voltage
- period
- radiopaque
- target
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 66
- 239000011248 coating agent Substances 0.000 title claims abstract description 47
- 230000032798 delamination Effects 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims description 20
- 238000004544 sputter deposition Methods 0.000 claims description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 8
- 238000000151 deposition Methods 0.000 claims description 8
- 230000008021 deposition Effects 0.000 claims description 6
- 238000005240 physical vapour deposition Methods 0.000 claims description 6
- 239000011261 inert gas Substances 0.000 claims description 4
- 229910000990 Ni alloy Inorganic materials 0.000 claims description 3
- 229910001069 Ti alloy Inorganic materials 0.000 claims description 3
- 230000000930 thermomechanical effect Effects 0.000 abstract description 4
- 230000002411 adverse Effects 0.000 abstract description 3
- 238000007740 vapor deposition Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 description 10
- 229910001000 nickel titanium Inorganic materials 0.000 description 9
- HLXZNVUGXRDIFK-UHFFFAOYSA-N nickel titanium Chemical compound [Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni] HLXZNVUGXRDIFK-UHFFFAOYSA-N 0.000 description 9
- 239000000758 substrate Substances 0.000 description 9
- 230000008901 benefit Effects 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910000734 martensite Inorganic materials 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 230000036760 body temperature Effects 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000001755 magnetron sputter deposition Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 208000024172 Cardiovascular disease Diseases 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 210000001367 artery Anatomy 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 210000002302 brachial artery Anatomy 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 238000000541 cathodic arc deposition Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 1
- 210000001105 femoral artery Anatomy 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000002324 minimally invasive surgery Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000001356 surgical procedure Methods 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 238000002207 thermal evaporation Methods 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/16—Metallic material, boron or silicon on metallic substrates or on substrates of boron or silicon
- C23C14/165—Metallic material, boron or silicon on metallic substrates or on substrates of boron or silicon by cathodic sputtering
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L31/00—Materials for other surgical articles, e.g. stents, stent-grafts, shunts, surgical drapes, guide wires, materials for adhesion prevention, occluding devices, surgical gloves, tissue fixation devices
- A61L31/08—Materials for coatings
- A61L31/082—Inorganic materials
- A61L31/088—Other specific inorganic materials not covered by A61L31/084 or A61L31/086
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L31/00—Materials for other surgical articles, e.g. stents, stent-grafts, shunts, surgical drapes, guide wires, materials for adhesion prevention, occluding devices, surgical gloves, tissue fixation devices
- A61L31/14—Materials characterised by their function or physical properties, e.g. injectable or lubricating compositions, shape-memory materials, surface modified materials
- A61L31/18—Materials at least partially X-ray or laser opaque
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/02—Pretreatment of the material to be coated
- C23C14/021—Cleaning or etching treatments
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F2/00—Filters implantable into blood vessels; Prostheses, i.e. artificial substitutes or replacements for parts of the body; Appliances for connecting them with the body; Devices providing patency to, or preventing collapsing of, tubular structures of the body, e.g. stents
- A61F2/82—Devices providing patency to, or preventing collapsing of, tubular structures of the body, e.g. stents
- A61F2/86—Stents in a form characterised by the wire-like elements; Stents in the form characterised by a net-like or mesh-like structure
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M25/00—Catheters; Hollow probes
- A61M25/01—Introducing, guiding, advancing, emplacing or holding catheters
- A61M25/09—Guide wires
- A61M2025/09108—Methods for making a guide wire
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Vascular Medicine (AREA)
- Surgery (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Epidemiology (AREA)
- General Health & Medical Sciences (AREA)
- Heart & Thoracic Surgery (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Materials For Medical Uses (AREA)
- Physical Vapour Deposition (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US53874904P | 2004-01-22 | 2004-01-22 | |
| US60/538,749 | 2004-01-22 | ||
| PCT/US2005/001572 WO2005072189A2 (en) | 2004-01-22 | 2005-01-21 | Radiopaque coating for biomedical devices |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2553693A1 true CA2553693A1 (en) | 2005-08-11 |
Family
ID=34826013
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002553693A Abandoned CA2553693A1 (en) | 2004-01-22 | 2005-01-21 | Radiopaque coating for biomedical devices |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20050165472A1 (enExample) |
| EP (1) | EP1706068A4 (enExample) |
| JP (1) | JP2007518528A (enExample) |
| CA (1) | CA2553693A1 (enExample) |
| WO (1) | WO2005072189A2 (enExample) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8002822B2 (en) * | 2004-01-22 | 2011-08-23 | Isoflux, Inc. | Radiopaque coating for biomedical devices |
| US20070106374A1 (en) * | 2004-01-22 | 2007-05-10 | Isoflux, Inc. | Radiopaque coating for biomedical devices |
| JP4620109B2 (ja) * | 2004-03-23 | 2011-01-26 | イソフラックス・インコーポレイテッド | バイオメディカル装置用の放射線不透過性コーティング |
| JP2008504104A (ja) * | 2004-06-28 | 2008-02-14 | イソフラックス・インコーポレイテッド | 生物医学的インプラント用多孔性コーティング |
| US8932345B2 (en) * | 2007-02-07 | 2015-01-13 | Cook Medical Technologies Llc | Medical device coatings for releasing a therapeutic agent at multiple rates |
| US9265636B2 (en) * | 2007-05-25 | 2016-02-23 | C. R. Bard, Inc. | Twisted stent |
| US8048471B2 (en) | 2007-12-21 | 2011-11-01 | Innovatech, Llc | Marked precoated medical device and method of manufacturing same |
| US8231927B2 (en) | 2007-12-21 | 2012-07-31 | Innovatech, Llc | Marked precoated medical device and method of manufacturing same |
| US7811623B2 (en) | 2007-12-21 | 2010-10-12 | Innovatech, Llc | Marked precoated medical device and method of manufacturing same |
| US7714217B2 (en) | 2007-12-21 | 2010-05-11 | Innovatech, Llc | Marked precoated strings and method of manufacturing same |
| US8231926B2 (en) | 2007-12-21 | 2012-07-31 | Innovatech, Llc | Marked precoated medical device and method of manufacturing same |
| US8053020B2 (en) * | 2008-02-28 | 2011-11-08 | Cook Medical Technologies Llc | Process for coating a portion of an implantable medical device |
| DK2361059T3 (da) * | 2008-11-24 | 2014-08-18 | Vascular Graft Solutions Ltd | Ekstern stent |
| US8900652B1 (en) | 2011-03-14 | 2014-12-02 | Innovatech, Llc | Marked fluoropolymer surfaces and method of manufacturing same |
| EP2714196B1 (en) * | 2011-06-01 | 2016-09-21 | Nucletron Operations B.V. | Brachytherapy source assembly |
| US20140379069A1 (en) * | 2012-01-30 | 2014-12-25 | Hipokrat | Negatively charged vascular stent |
| JP6279488B2 (ja) | 2012-02-07 | 2018-02-14 | ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア | タンタルでコーティングされたナノ構造を有する製品とその製作法および使用法 |
| US9566071B2 (en) * | 2013-04-11 | 2017-02-14 | Blockade Medical, LLC | Systems and devices for cerebral aneurysm repair |
| WO2018125791A1 (en) | 2016-12-27 | 2018-07-05 | Cardiac Pacemakers, Inc. | Leadless delivery catheter with conductive pathway |
| US10806931B2 (en) | 2016-12-27 | 2020-10-20 | Cardiac Pacemakers, Inc. | Delivery devices and methods for leadless cardiac devices |
| US10485981B2 (en) | 2016-12-27 | 2019-11-26 | Cardiac Pacemakers, Inc. | Fixation methods for leadless cardiac devices |
| WO2018136203A1 (en) | 2016-12-27 | 2018-07-26 | Cardiac Pacemakers, Inc. | Delivery devices and methods for leadless cardiac devices |
| US10773089B2 (en) | 2017-01-26 | 2020-09-15 | Cardiac Pacemakers, Inc. | Delivery devices and methods for leadless cardiac devices |
| EP3592418B1 (en) | 2017-03-10 | 2023-08-23 | Cardiac Pacemakers, Inc. | Fixation for leadless cardiac devices |
| US10737092B2 (en) | 2017-03-30 | 2020-08-11 | Cardiac Pacemakers, Inc. | Delivery devices and methods for leadless cardiac devices |
| US11577085B2 (en) | 2017-08-03 | 2023-02-14 | Cardiac Pacemakers, Inc. | Delivery devices and methods for leadless cardiac devices |
| EP3946568B1 (en) | 2019-03-29 | 2024-11-20 | Cardiac Pacemakers, Inc. | Systems for treating cardiac arrhythmias |
| WO2020205397A1 (en) | 2019-03-29 | 2020-10-08 | Cardiac Pacemakers, Inc. | Systems and methods for treating cardiac arrhythmias |
| CN114364431B (zh) | 2019-09-11 | 2025-09-12 | 心脏起搏器股份公司 | 用于植入和/或取回具有螺旋固定件的无导线心脏起搏装置的工具和系统 |
| EP4028117B1 (en) | 2019-09-11 | 2024-04-24 | Cardiac Pacemakers, Inc. | Systems for implanting and/or retrieving a leadless cardiac pacing device with helix fixation |
| LU101505B1 (en) * | 2019-11-29 | 2021-06-03 | Imc Int Medical Contrivances Sa | Biocompatible coating for medical implant with tantalum radio-opaque adhesion layer |
| CN111411336A (zh) * | 2020-03-27 | 2020-07-14 | 温州医科大学附属口腔医院 | 一种人工种植体 |
Family Cites Families (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0054781B1 (de) * | 1980-12-23 | 1984-10-10 | Kontron Ag | Implantierbare Elektrode |
| DE3300694A1 (de) * | 1983-01-11 | 1984-08-09 | Siemens AG, 1000 Berlin und 8000 München | Bipolare elektrode fuer medizinische anwendungen |
| DE3300668A1 (de) * | 1983-01-11 | 1984-07-12 | Siemens AG, 1000 Berlin und 8000 München | Elektrode fuer medizinische anwendungen |
| US4844099A (en) * | 1986-11-24 | 1989-07-04 | Telectronics, N.V. | Porous pacemaker electrode tip using a porous substrate |
| US4784161A (en) * | 1986-11-24 | 1988-11-15 | Telectronics, N.V. | Porous pacemaker electrode tip using a porous substrate |
| JPH0753853Y2 (ja) * | 1988-07-11 | 1995-12-13 | 三菱マテリアル株式会社 | ボールエンドミル |
| US5282844A (en) * | 1990-06-15 | 1994-02-01 | Medtronic, Inc. | High impedance, low polarization, low threshold miniature steriod eluting pacing lead electrodes |
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| US6641607B1 (en) * | 2000-12-29 | 2003-11-04 | Advanced Cardiovascular Systems, Inc. | Double tube stent |
| US6635082B1 (en) * | 2000-12-29 | 2003-10-21 | Advanced Cardiovascular Systems Inc. | Radiopaque stent |
| DK174876B1 (da) * | 2001-02-26 | 2004-01-12 | Danfoss As | Implantat og implantatoverflademodificeringsproces |
| US20020138136A1 (en) * | 2001-03-23 | 2002-09-26 | Scimed Life Systems, Inc. | Medical device having radio-opacification and barrier layers |
| US6638301B1 (en) * | 2002-10-02 | 2003-10-28 | Scimed Life Systems, Inc. | Medical device with radiopacity |
-
2005
- 2005-01-21 CA CA002553693A patent/CA2553693A1/en not_active Abandoned
- 2005-01-21 US US11/040,433 patent/US20050165472A1/en not_active Abandoned
- 2005-01-21 WO PCT/US2005/001572 patent/WO2005072189A2/en not_active Ceased
- 2005-01-21 EP EP05705865A patent/EP1706068A4/en not_active Withdrawn
- 2005-01-21 JP JP2006551204A patent/JP2007518528A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JP2007518528A (ja) | 2007-07-12 |
| US20050165472A1 (en) | 2005-07-28 |
| EP1706068A4 (en) | 2008-10-15 |
| WO2005072189A3 (en) | 2006-11-30 |
| EP1706068A2 (en) | 2006-10-04 |
| WO2005072189A2 (en) | 2005-08-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |