CA2503986A1 - New catalyst structure for olefin polymerization - Google Patents

New catalyst structure for olefin polymerization Download PDF

Info

Publication number
CA2503986A1
CA2503986A1 CA002503986A CA2503986A CA2503986A1 CA 2503986 A1 CA2503986 A1 CA 2503986A1 CA 002503986 A CA002503986 A CA 002503986A CA 2503986 A CA2503986 A CA 2503986A CA 2503986 A1 CA2503986 A1 CA 2503986A1
Authority
CA
Canada
Prior art keywords
bonded
heteroatoms
heteroatom
different
same
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002503986A
Other languages
English (en)
French (fr)
Inventor
Abbas Razavi
Margarito Lopez
Didier Baekelmans
Vladimir Marin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fina Technology Inc
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US10/301,884 external-priority patent/US20040102311A1/en
Application filed by Individual filed Critical Individual
Publication of CA2503986A1 publication Critical patent/CA2503986A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/02—Iron compounds
    • C07F15/025—Iron compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70—Iron group metals, platinum group metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0258—Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Pyridine Compounds (AREA)
CA002503986A 2002-11-21 2003-11-12 New catalyst structure for olefin polymerization Abandoned CA2503986A1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US10/301,884 2002-11-21
US10/301,884 US20040102311A1 (en) 2002-11-21 2002-11-21 Bridged metallocene catalyst component, method of making, polyolefin catalyst having C1, C2, or Cs symmetry, methods of making, methods of polymerizing, olefins and products made thereof
US10/692,068 US6894180B2 (en) 2002-11-21 2003-10-23 Catalyst structure for olefin polymerization
US10/692,068 2003-10-23
PCT/US2003/036049 WO2004047972A2 (en) 2002-11-21 2003-11-12 New catalyst structure for olefin polymerization

Publications (1)

Publication Number Publication Date
CA2503986A1 true CA2503986A1 (en) 2004-06-10

Family

ID=32396700

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002503986A Abandoned CA2503986A1 (en) 2002-11-21 2003-11-12 New catalyst structure for olefin polymerization

Country Status (6)

Country Link
EP (1) EP1562705A4 (https=)
JP (1) JP4977322B2 (https=)
KR (1) KR20050085108A (https=)
AU (1) AU2003285202A1 (https=)
CA (1) CA2503986A1 (https=)
WO (1) WO2004047972A2 (https=)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7034157B2 (en) * 2003-10-23 2006-04-25 Fina Technology, Inc. Catalyst components, process for their preparation and their use as catalyst components in polymerization of olefins
WO2006078576A2 (en) * 2005-01-19 2006-07-27 Merck & Co., Inc. Aminomethyl beta-secretase inhibitors for the treatment of alzheimer's disease
EP1746111A1 (en) * 2005-07-19 2007-01-24 Total Petrochemicals Research Feluy Polymerisation catalyst system based on dioxime ligands
AR124328A1 (es) * 2020-12-15 2023-03-15 Shell Int Research Un catalizador de oligomerización, método de preparación y proceso para usar el catalizador
CN114874362B (zh) * 2022-03-18 2023-05-23 中国科学院青岛生物能源与过程研究所 一种吡啶亚胺肟铁催化剂及其制备方法和在共轭二烯聚合中的应用

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR9708335A (pt) * 1996-03-27 1999-08-03 Dow Chemical Co Processo de polimerização em solução para polimerizar olefinas
AU6018198A (en) * 1997-01-13 1998-08-03 E.I. Du Pont De Nemours And Company Polymerization of propylene
KR100379134B1 (ko) * 1998-06-16 2003-04-08 미쓰이 가가쿠 가부시키가이샤 올레핀 중합용 촉매 및 올레핀의 중합 방법
JP2000001512A (ja) * 1998-06-16 2000-01-07 Mitsui Chemicals Inc オレフィン重合用触媒およびオレフィンの重合方法
WO2001017967A1 (fr) * 1999-09-02 2001-03-15 Idemitsu Petrochemical Co., Ltd. Composes a base de metaux de transition, catalyseurs servant a la production d'alpha-olefines et procede associe
CN1164534C (zh) * 2001-07-20 2004-09-01 中国科学院化学研究所 一种铁系催化剂及其制法和应用
CN1255419C (zh) * 2001-08-01 2006-05-10 国际壳牌研究有限公司 乙烯低聚生产直链α烯烃用配位体及其催化剂体系
JP2003206308A (ja) * 2001-11-09 2003-07-22 Idemitsu Petrochem Co Ltd ビニル化合物重合触媒、ビニル化合物の重合体及びその製造方法並びに該重合体よりなる複合樹脂

Also Published As

Publication number Publication date
AU2003285202A8 (en) 2004-06-18
WO2004047972A3 (en) 2004-12-09
EP1562705A2 (en) 2005-08-17
AU2003285202A1 (en) 2004-06-18
JP4977322B2 (ja) 2012-07-18
WO2004047972A2 (en) 2004-06-10
JP2006507345A (ja) 2006-03-02
EP1562705A4 (en) 2007-04-25
KR20050085108A (ko) 2005-08-29

Similar Documents

Publication Publication Date Title
RU2514405C2 (ru) Пиридилдиамидные комплексы переходных металлов, их получение и применение
US8252875B2 (en) Process for the preparation of unsymmetric bis(imino) compounds
US7102006B2 (en) Preparation of metal complexes
AU764658B2 (en) Production of half-sandwich substituted catalyst precursors
FI121958B (fi) Metallikomplekseja, jotka sisältävät 2,6-diasyylipyridiiniligandin, ja niiden käyttö eteenin polymeroinnissa
Röder et al. Lithium Complexes of N-Donor-Functionalized Cyclopentadienyl A Pyrazolate-Based Bimetallic Version
US6313331B1 (en) Carbene transition metal catalysts
US6180552B1 (en) Transition metal complexes containing neutral, multidentate azacyclic ligands
CA2503986A1 (en) New catalyst structure for olefin polymerization
JP2002543210A (ja) 不飽和化合物重合用有機金属触媒
Kettunen et al. Chiral Zirconium Complexes with Bianiline-Based N4-Donor Ligands
Chen et al. Synthesis and catalytic properties of oxalic amidinato complexes
US6894180B2 (en) Catalyst structure for olefin polymerization
EP1997834A1 (en) Catalysts
US6087290A (en) Si-N-Si-bridged metallocenes, their production and use
US6391988B1 (en) Tris(pyrazoyl) based anions
WO2006052427A1 (en) Highly soluble ferrocenyl compounds
Pyridine—Alkoxide plexes of Tin (II), Gallium (HI), and Indium (III). Syntheses of [(ME) 2ATI] 2GaI and [(Me) 2AT1] 2InCl Using the T in (III)

Legal Events

Date Code Title Description
FZDE Discontinued