CA2501283A1 - Low-viscosity beam-hardened and thermally hardened polyisocyanates containing oxadiazintrion groups - Google Patents

Low-viscosity beam-hardened and thermally hardened polyisocyanates containing oxadiazintrion groups Download PDF

Info

Publication number
CA2501283A1
CA2501283A1 CA 2501283 CA2501283A CA2501283A1 CA 2501283 A1 CA2501283 A1 CA 2501283A1 CA 2501283 CA2501283 CA 2501283 CA 2501283 A CA2501283 A CA 2501283A CA 2501283 A1 CA2501283 A1 CA 2501283A1
Authority
CA
Canada
Prior art keywords
polyisocyanate
mixture
process according
groups
allophanate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA 2501283
Other languages
English (en)
French (fr)
Inventor
Thomas Faecke
Jan Weikard
Wolfgang Fischer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Covestro Deutschland AG
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2501283A1 publication Critical patent/CA2501283A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
    • C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
    • C08G18/6237—Polymers of esters containing glycidyl groups of alpha-beta ethylenically unsaturated carboxylic acids; reaction products thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/284—Compounds containing ester groups, e.g. oxyalkylated monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3206—Polyhydroxy compounds aliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/721—Two or more polyisocyanates not provided for in one single group C08G18/73 - C08G18/80
    • C08G18/725—Combination of polyisocyanates of C08G18/78 with other polyisocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/7875—Nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring
    • C08G18/7887—Nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring having two nitrogen atoms in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/81—Unsaturated isocyanates or isothiocyanates
    • C08G18/8141—Unsaturated isocyanates or isothiocyanates masked
    • C08G18/815—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen
    • C08G18/8158—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen
    • C08G18/8175—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen with esters of acrylic or alkylacrylic acid having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31547—Of polyisocyanurate
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31591—Next to cellulosic
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31598—Next to silicon-containing [silicone, cement, etc.] layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31605—Next to free metal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
CA 2501283 2002-10-04 2003-09-22 Low-viscosity beam-hardened and thermally hardened polyisocyanates containing oxadiazintrion groups Abandoned CA2501283A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE2002146512 DE10246512A1 (de) 2002-10-04 2002-10-04 Niedrigviskose strahlenhärtende und thermisch härtende Polyisocyanate
DE10246512.6 2002-10-04
PCT/EP2003/010499 WO2004033522A1 (de) 2002-10-04 2003-09-22 Niedrigviskose strahlenhärtende und thermisch härtende polyisocyanate enthaltend oxadiazintriongruppen

Publications (1)

Publication Number Publication Date
CA2501283A1 true CA2501283A1 (en) 2004-04-22

Family

ID=32010274

Family Applications (1)

Application Number Title Priority Date Filing Date
CA 2501283 Abandoned CA2501283A1 (en) 2002-10-04 2003-09-22 Low-viscosity beam-hardened and thermally hardened polyisocyanates containing oxadiazintrion groups

Country Status (9)

Country Link
US (1) US7323532B2 (enExample)
EP (1) EP1551897B1 (enExample)
JP (1) JP2006502261A (enExample)
CN (1) CN1310994C (enExample)
AU (1) AU2003270236A1 (enExample)
CA (1) CA2501283A1 (enExample)
DE (1) DE10246512A1 (enExample)
MX (1) MXPA05003567A (enExample)
WO (1) WO2004033522A1 (enExample)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004048873A1 (de) * 2004-10-07 2006-04-13 Bayer Materialscience Ag Verfahren zur Herstellung von niedrigviskosen Allophanaten mit aktinisch härtbaren Gruppen
DE102004063102A1 (de) 2004-12-22 2006-07-13 Basf Ag Strahlungshärtbare Verbindungen
US20080182080A1 (en) * 2005-02-24 2008-07-31 Basf Aktiengesellschaft Pigments That Are At Least Partially Sheathed In Radiation-Curable Polyurethane, Their Production And Use
DE102005057682A1 (de) 2005-12-01 2007-06-06 Basf Ag Strahlungshärtbare wasserelmulgierbare Polyisocyanate
DE102005057683A1 (de) 2005-12-01 2007-06-06 Basf Ag Strahlungshärtbare wasserelmulgierbare Polyisocyanate
CN101522740A (zh) * 2006-10-09 2009-09-02 巴斯夫欧洲公司 可辐照固化的化合物
DE102007040240A1 (de) 2007-08-25 2009-02-26 Bayer Materialscience Ag Verfahren zur Herstellung von niedrigviskosen Allophanaten mit aktinisch härtbaren Gruppen
DE102007040239A1 (de) 2007-08-25 2009-05-07 Bayer Materialscience Ag Verfahren zur Herstellung von niedrigviskosen Allophanaten mit aktinisch härtbaren Gruppen
DE102009008569A1 (de) 2009-02-12 2010-08-19 Bayer Materialscience Ag Verfahren zur Herstellung von besonders reaktiven und niedrigviskosen Allophanaten mit aktinisch härtbaren Gruppen und deren Verwendung zur Herstellung besonders kratzfester Beschichtungen
PL2581398T3 (pl) 2011-10-14 2015-02-27 Allnex Ip Sarl Sposób wytwarzania emulgowalnych w wodzie allofanianów o małej lepkości z grupami utwardzalnymi promieniowaniem
EP2581397B1 (de) 2011-10-14 2014-12-10 Allnex IP S.à.r.l. Verfahren zur herstellung von niedrigviskosen, wasserverdünnbaren urethan(meth)acrylaten
JP5892799B2 (ja) * 2012-02-03 2016-03-23 新中村化学工業株式会社 伸びがあり耐傷つき性に優れる硬化物を形成するウレタン（メタ）アクリレートおよびそれを含有する光硬化性樹脂組成物
US9296907B2 (en) 2012-05-30 2016-03-29 Basf Se Radiation-curable compounds
CN107011498B (zh) 2012-05-30 2020-05-12 Igm集团公司 辐射可固化的化合物
CN104130686B (zh) * 2013-04-30 2017-09-19 旭化成株式会社 多异氰酸酯组合物及涂料组合物
CN109843961A (zh) * 2016-10-18 2019-06-04 科思创德国股份有限公司 含有催化交联的封闭型多异氰酸酯的线材涂层
WO2019092140A1 (de) 2017-11-09 2019-05-16 Covestro Deutschland Ag Verfahren zur herstellung eines gegenstandes und verwendung eines radikalisch vernetzbaren harzes in einem additiven fertigungsverfahren
CN110540633B (zh) * 2019-09-12 2021-06-29 万华化学集团股份有限公司 一种多异氰酸酯组合物及其制备方法
CN111072917B (zh) 2020-01-02 2021-06-29 万华化学集团股份有限公司 一种存储稳定的多异氰酸酯组合物及制备方法
CN111234177B (zh) * 2020-03-20 2022-02-18 万华化学集团股份有限公司 一种大分子单体稳定剂及其制备方法
CN112625227B (zh) * 2020-12-08 2023-06-13 绵阳麦思威尔科技有限公司 一种固化剂改性水性醇酸树脂及改性中间体
CN114316210B (zh) * 2022-01-05 2024-11-12 万华化学（宁波）有限公司 一种缩二脲多异氰酸酯组合物及其制备方法

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE167066C (de) 1903-06-20 1906-01-15 W Halstenbach Verfahren zur herstellung von dekorationsborten
GB994890A (en) 1961-12-18 1965-06-10 Ici Ltd New organic polyisocyanates and their manufacture
US4342793A (en) 1977-01-14 1982-08-03 Henkel Corporation Interpenetrating dual cure resin compositions
DE2729990A1 (de) 1977-07-02 1979-01-18 Bayer Ag Verfahren zur herstellung von isocyanatgruppen aufweisenden allophanaten
JPS58109528A (ja) * 1981-12-23 1983-06-29 Takeda Chem Ind Ltd ポリウレタン樹脂用組成物
DE4416321A1 (de) 1994-05-09 1995-11-16 Bayer Ag Verfahren zur Herstellung von Allophanatgruppen aufweisenden lichtechten Polyisocyanaten
DE4417745A1 (de) * 1994-05-20 1995-11-23 Bayer Ag Olefinisch ungesättigte Polyisocyanate
DE4441176A1 (de) 1994-11-18 1996-05-23 Bayer Ag Allophanatgruppen aufweisende Polyisocyanate
DE19632951A1 (de) 1996-08-19 1998-02-26 Bayer Ag Verfahren zur Herstellung von aliphatischen und/oder cycloaliphatischen und/oder Isocyanatgruppen aufweisenden Allophanaten
US5739251A (en) 1997-03-27 1998-04-14 Bayer Corporation Low viscosity, ethylenically unsaturated polyurethanes containing allophanate groups
US5777024A (en) * 1997-04-30 1998-07-07 The Valspar Corporation Urethane resins and coating compositions and methods for their use
US5767220A (en) * 1997-08-25 1998-06-16 Bayer Corporation Low viscosity, ethylenically unsaturated polyurethanes containing allophanate groups
DE19800528A1 (de) 1998-01-09 1999-07-15 Bayer Ag Beschichtungssystem aus UV-härtenden Isocyanatgruppen aufweisenden Urethan(meth)acrylatisocyanaten
US6614413B2 (en) * 1998-04-22 2003-09-02 Pioneer Electronic Corporation Method of driving plasma display panel
DE19853569A1 (de) * 1998-11-20 2000-05-25 Bayer Ag Neue Urethanacrylate, Verfahren zu ihrer Herstellung sowie ihre Verwendung
DE19860041A1 (de) * 1998-12-23 2000-06-29 Basf Ag Durch Addition an Isocyanatgruppen als auch durch strahlungsinduzierte Addition an aktivierte C-C-Doppelbindungen härtbare Beschichtungsmittel
CN1238398C (zh) * 1999-09-30 2006-01-25 巴斯福股份公司 能够用紫外线和热硬化的聚氨酯水分散体,以及它们的用途
US6555596B1 (en) * 2000-11-06 2003-04-29 Arco Chemical Technology, L.P. Multifunctional allyl carbamates and coatings therefrom

Also Published As

Publication number Publication date
US7323532B2 (en) 2008-01-29
CN1688627A (zh) 2005-10-26
HK1084681A1 (en) 2006-08-04
CN1310994C (zh) 2007-04-18
DE10246512A1 (de) 2004-04-15
WO2004033522A1 (de) 2004-04-22
US20040068081A1 (en) 2004-04-08
AU2003270236A1 (en) 2004-05-04
JP2006502261A (ja) 2006-01-19
MXPA05003567A (es) 2007-10-18
EP1551897B1 (de) 2018-08-01
EP1551897A1 (de) 2005-07-13

Similar Documents

Publication Publication Date Title
US7323532B2 (en) Low-viscosity radiation-curing and thermally curing polyisocyanates
US8119245B2 (en) Dual-cure coating compositions based on polyaspartates polyisocyanates and acrylate-containing compounds
US8604097B2 (en) Low viscosity allophanates containing actinically curable groups
US8202618B2 (en) Radiation-curing binders and a process for their preparation
CA2559734C (en) Low-viscosity allophanates containing actinically curable groups
CA2559904A1 (en) Production of novel radiation-hardening binding agents
CN1746244B (zh) 包含光致固化基团的低粘度脲基甲酸酯
CN103044645A (zh) 制备低粘度、水可乳化的具有辐射可固化基团的脲基甲酸酯的方法
MXPA05006442A (es) Nuevos sistemas de doble curado.
US7641975B2 (en) Hardeners
US8957176B2 (en) Blocked polyisocyanates curing free from elimination products for dualcure systems
HK1084681B (en) Low-viscosity beam-hardened and thermally hardened polyisocyanates containing oxadiazintrion groups
HK1085236B (en) Low viscosity allophanates containing actinically curable groups
HK1085237A1 (en) Radiation-curing binders and a process for their preparation
HK1085237B (en) Radiation-curing binders and a process for their preparation
TW201333058A (zh) 用於製備低黏度且可水乳化之具有輻射可硬化之脲甲酸酯的方法

Legal Events

Date Code Title Description
EEER Examination request
FZDE Discontinued