CA2494611C - Catalyst comprising bridged indeno[1,2-b]indolyl metal complex - Google Patents

Catalyst comprising bridged indeno[1,2-b]indolyl metal complex Download PDF

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Publication number
CA2494611C
CA2494611C CA2494611A CA2494611A CA2494611C CA 2494611 C CA2494611 C CA 2494611C CA 2494611 A CA2494611 A CA 2494611A CA 2494611 A CA2494611 A CA 2494611A CA 2494611 C CA2494611 C CA 2494611C
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CA
Canada
Prior art keywords
complex
indolyl
open architecture
supported
complexes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA2494611A
Other languages
English (en)
French (fr)
Other versions
CA2494611A1 (en
Inventor
Shaotian Wang
Clifford C. Lee
Mark P. Mack
Gregory G. Hlatky
Sandor Nagy
Barbara M. Tsuie
Craig C. Meverden
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Equistar Chemicals LP
Original Assignee
Equistar Chemicals LP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US10/211,085 external-priority patent/US6559251B1/en
Application filed by Equistar Chemicals LP filed Critical Equistar Chemicals LP
Priority to CA2758167A priority Critical patent/CA2758167C/en
Publication of CA2494611A1 publication Critical patent/CA2494611A1/en
Application granted granted Critical
Publication of CA2494611C publication Critical patent/CA2494611C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CA2494611A 2002-08-02 2003-07-10 Catalyst comprising bridged indeno[1,2-b]indolyl metal complex Expired - Fee Related CA2494611C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA2758167A CA2758167C (en) 2002-08-02 2003-07-10 Copolymerization of ethylene using constrained geometry indenoindolyl complexes

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US10/211,085 2002-08-02
US10/211,085 US6559251B1 (en) 2002-08-02 2002-08-02 Process for making low-density polyolefins
US10/382,233 US6838410B2 (en) 2002-08-02 2003-03-05 Catalysts for making polyolefins
US10/382,233 2003-03-05
PCT/US2003/021540 WO2004013194A2 (en) 2002-08-02 2003-07-10 Catalysts and process for making polyolefins

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CA2758167A Division CA2758167C (en) 2002-08-02 2003-07-10 Copolymerization of ethylene using constrained geometry indenoindolyl complexes

Publications (2)

Publication Number Publication Date
CA2494611A1 CA2494611A1 (en) 2004-02-12
CA2494611C true CA2494611C (en) 2012-01-24

Family

ID=31498031

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2494611A Expired - Fee Related CA2494611C (en) 2002-08-02 2003-07-10 Catalyst comprising bridged indeno[1,2-b]indolyl metal complex

Country Status (8)

Country Link
EP (1) EP1525228A2 (zh)
KR (1) KR20050034728A (zh)
CN (1) CN100429240C (zh)
AU (1) AU2003248919A1 (zh)
BR (1) BR0313308A (zh)
CA (1) CA2494611C (zh)
MX (1) MXPA05001075A (zh)
WO (1) WO2004013194A2 (zh)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6818713B1 (en) * 2003-08-11 2004-11-16 Equistar Chemicals, Lp Process for making polyethylene
EP1735354A1 (en) * 2004-04-16 2006-12-27 Exxonmobil Chemical Company Inc. Heterocyclic substituted metallocene compounds for olefin polymerization
US6995220B2 (en) * 2004-04-29 2006-02-07 Equistar Chemicals, Lp Ethylene polymerization process
US7273914B2 (en) * 2005-08-03 2007-09-25 Equistar Chemicals, Lp Olefin polymerization methods
US7868197B2 (en) 2005-12-14 2011-01-11 Exxonmobil Chemical Patents Inc. Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization
US7429635B2 (en) 2006-09-28 2008-09-30 Equistar Chemicals, Lp Preparation of ultra high molecular weight linear low density polyethylene
US7812104B2 (en) 2008-01-18 2010-10-12 Exxonmobil Chemical Patents Inc. Production of propylene-based polymers
CA2760264C (en) 2011-12-05 2018-08-21 Nova Chemicals Corporation Passivated supports for use with olefin polymerization catalysts
CN112920227B (zh) * 2021-02-18 2022-09-23 山东京博石油化工有限公司 一种含茚并吲哚结构的茂金属化合物及其制备方法、应用以及α-烯烃的制备方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5495035A (en) 1994-06-01 1996-02-27 University Of Iowa Research Foundation Synthesis of ANSA-metallocene catalysts
HUP0001331A2 (hu) 1997-11-12 2000-08-28 Montell Technology Company B.V. Metallocének, áthidalt ligandumok, olefinpolimerizációs katalizátorok és eljárás olefinek polimerizálására
US6239062B1 (en) * 1999-09-02 2001-05-29 Equistar Chemicals, L.P. Olefin polymerization catalysts containing indolyl-amido ligands
US6232260B1 (en) 1999-10-14 2001-05-15 Equistar Chemicals, L.P. Single-site catalysts for olefin polymerization
ES2326537T3 (es) * 2000-01-18 2009-10-14 Basell Polyolefine Gmbh Ligando para un catalizador metaloceno para fabricar polimeros basados en propileno y metodo de obtencion del mismo.
US6559251B1 (en) * 2002-08-02 2003-05-06 Equistar Chemicals, Lp Process for making low-density polyolefins

Also Published As

Publication number Publication date
CN1681848A (zh) 2005-10-12
KR20050034728A (ko) 2005-04-14
AU2003248919A8 (en) 2004-02-23
CA2494611A1 (en) 2004-02-12
BR0313308A (pt) 2005-07-12
WO2004013194A3 (en) 2004-07-15
WO2004013194A2 (en) 2004-02-12
AU2003248919A1 (en) 2004-02-23
EP1525228A2 (en) 2005-04-27
CN100429240C (zh) 2008-10-29
MXPA05001075A (es) 2005-06-06

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Effective date: 20150710

MKLA Lapsed

Effective date: 20150710