CA2470113A1 - Preparation de dispersions de nanotubes stables dans des liquides - Google Patents
Preparation de dispersions de nanotubes stables dans des liquides Download PDFInfo
- Publication number
- CA2470113A1 CA2470113A1 CA002470113A CA2470113A CA2470113A1 CA 2470113 A1 CA2470113 A1 CA 2470113A1 CA 002470113 A CA002470113 A CA 002470113A CA 2470113 A CA2470113 A CA 2470113A CA 2470113 A1 CA2470113 A1 CA 2470113A1
- Authority
- CA
- Canada
- Prior art keywords
- dispersant
- oil
- group
- acid
- liquid medium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007788 liquid Substances 0.000 title claims abstract 24
- 239000006185 dispersion Substances 0.000 title claims abstract 7
- 239000002071 nanotube Substances 0.000 title claims abstract 7
- 238000000034 method Methods 0.000 claims abstract 31
- 239000002270 dispersing agent Substances 0.000 claims abstract 28
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract 9
- 239000002245 particle Substances 0.000 claims abstract 7
- 239000004094 surface-active agent Substances 0.000 claims abstract 6
- 238000013019 agitation Methods 0.000 claims abstract 3
- -1 ester carboxyl Chemical class 0.000 claims 21
- 239000003921 oil Substances 0.000 claims 18
- 235000019198 oils Nutrition 0.000 claims 18
- 239000002480 mineral oil Substances 0.000 claims 9
- 235000010446 mineral oil Nutrition 0.000 claims 9
- 239000011852 carbon nanoparticle Substances 0.000 claims 8
- 239000007787 solid Substances 0.000 claims 5
- 239000000725 suspension Substances 0.000 claims 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 4
- 229910019142 PO4 Inorganic materials 0.000 claims 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims 4
- 229910052799 carbon Inorganic materials 0.000 claims 4
- 150000002430 hydrocarbons Chemical group 0.000 claims 4
- 239000002086 nanomaterial Substances 0.000 claims 4
- 239000010452 phosphate Substances 0.000 claims 4
- 235000015112 vegetable and seed oil Nutrition 0.000 claims 4
- 239000008158 vegetable oil Substances 0.000 claims 4
- 239000004215 Carbon black (E152) Substances 0.000 claims 3
- 239000004166 Lanolin Substances 0.000 claims 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims 3
- 239000002253 acid Substances 0.000 claims 3
- 150000002148 esters Chemical class 0.000 claims 3
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- 229940039717 lanolin Drugs 0.000 claims 3
- 235000019388 lanolin Nutrition 0.000 claims 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 3
- 229920000728 polyester Polymers 0.000 claims 3
- 229920000642 polymer Polymers 0.000 claims 3
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 claims 2
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 claims 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims 2
- IPRJXAGUEGOFGG-UHFFFAOYSA-N N-butylbenzenesulfonamide Chemical compound CCCCNS(=O)(=O)C1=CC=CC=C1 IPRJXAGUEGOFGG-UHFFFAOYSA-N 0.000 claims 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 claims 2
- 239000001361 adipic acid Substances 0.000 claims 2
- 235000011037 adipic acid Nutrition 0.000 claims 2
- ZDWGXBPVPXVXMQ-UHFFFAOYSA-N bis(2-ethylhexyl) nonanedioate Chemical compound CCCCC(CC)COC(=O)CCCCCCCC(=O)OCC(CC)CCCC ZDWGXBPVPXVXMQ-UHFFFAOYSA-N 0.000 claims 2
- YKGYQYOQRGPFTO-UHFFFAOYSA-N bis(8-methylnonyl) hexanedioate Chemical compound CC(C)CCCCCCCOC(=O)CCCCC(=O)OCCCCCCCC(C)C YKGYQYOQRGPFTO-UHFFFAOYSA-N 0.000 claims 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims 2
- VJHINFRRDQUWOJ-UHFFFAOYSA-N dioctyl sebacate Chemical compound CCCCC(CC)COC(=O)CCCCCCCCC(=O)OCC(CC)CCCC VJHINFRRDQUWOJ-UHFFFAOYSA-N 0.000 claims 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims 2
- LZJUZSYHFSVIGJ-UHFFFAOYSA-N ditridecyl hexanedioate Chemical compound CCCCCCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCCCCCCC LZJUZSYHFSVIGJ-UHFFFAOYSA-N 0.000 claims 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims 2
- 125000000524 functional group Chemical group 0.000 claims 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 claims 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 2
- 239000002563 ionic surfactant Substances 0.000 claims 2
- 239000000314 lubricant Substances 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 claims 2
- 239000002736 nonionic surfactant Substances 0.000 claims 2
- 239000004014 plasticizer Substances 0.000 claims 2
- 229920001748 polybutylene Polymers 0.000 claims 2
- 229940116351 sebacate Drugs 0.000 claims 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 claims 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims 2
- BJDAUCLANVMIOB-UHFFFAOYSA-N (3-decanoyloxy-2,2-dimethylpropyl) decanoate Chemical compound CCCCCCCCCC(=O)OCC(C)(C)COC(=O)CCCCCCCCC BJDAUCLANVMIOB-UHFFFAOYSA-N 0.000 claims 1
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 claims 1
- CIRMGZKUSBCWRL-LHLOQNFPSA-N (e)-10-[2-(7-carboxyheptyl)-5,6-dihexylcyclohex-3-en-1-yl]dec-9-enoic acid Chemical compound CCCCCCC1C=CC(CCCCCCCC(O)=O)C(\C=C\CCCCCCCC(O)=O)C1CCCCCC CIRMGZKUSBCWRL-LHLOQNFPSA-N 0.000 claims 1
- RDAGYWUMBWNXIC-UHFFFAOYSA-N 1,2-bis(2-ethylhexyl)benzene Chemical compound CCCCC(CC)CC1=CC=CC=C1CC(CC)CCCC RDAGYWUMBWNXIC-UHFFFAOYSA-N 0.000 claims 1
- YEYQUBZGSWAPGE-UHFFFAOYSA-N 1,2-di(nonyl)benzene Chemical compound CCCCCCCCCC1=CC=CC=C1CCCCCCCCC YEYQUBZGSWAPGE-UHFFFAOYSA-N 0.000 claims 1
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 claims 1
- RLPSARLYTKXVSE-UHFFFAOYSA-N 1-(1,3-thiazol-5-yl)ethanamine Chemical compound CC(N)C1=CN=CS1 RLPSARLYTKXVSE-UHFFFAOYSA-N 0.000 claims 1
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 claims 1
- PTJWCLYPVFJWMP-UHFFFAOYSA-N 2-[[3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)COCC(CO)(CO)CO PTJWCLYPVFJWMP-UHFFFAOYSA-N 0.000 claims 1
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 claims 1
- WHHSHXMIKFVAEK-UHFFFAOYSA-N 2-o-benzyl 1-o-octyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 WHHSHXMIKFVAEK-UHFFFAOYSA-N 0.000 claims 1
- NUCFNMOPTGEHQA-UHFFFAOYSA-N 3-bromo-2h-pyrazolo[4,3-c]pyridine Chemical compound C1=NC=C2C(Br)=NNC2=C1 NUCFNMOPTGEHQA-UHFFFAOYSA-N 0.000 claims 1
- HBTAOSGHCXUEKI-UHFFFAOYSA-N 4-chloro-n,n-dimethyl-3-nitrobenzenesulfonamide Chemical compound CN(C)S(=O)(=O)C1=CC=C(Cl)C([N+]([O-])=O)=C1 HBTAOSGHCXUEKI-UHFFFAOYSA-N 0.000 claims 1
- PCUXMDACXTVDGR-UHFFFAOYSA-N 4-methylpentyl 2,2-dimethylpropanoate Chemical compound CC(C)CCCOC(=O)C(C)(C)C PCUXMDACXTVDGR-UHFFFAOYSA-N 0.000 claims 1
- ODMZDMMTKHXXKA-QXMHVHEDSA-N 8-methylnonyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCCCCCC(C)C ODMZDMMTKHXXKA-QXMHVHEDSA-N 0.000 claims 1
- 229920000049 Carbon (fiber) Polymers 0.000 claims 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims 1
- 102000008186 Collagen Human genes 0.000 claims 1
- 108010035532 Collagen Proteins 0.000 claims 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims 1
- XTJFFFGAUHQWII-UHFFFAOYSA-N Dibutyl adipate Chemical compound CCCCOC(=O)CCCCC(=O)OCCCC XTJFFFGAUHQWII-UHFFFAOYSA-N 0.000 claims 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 1
- 102000011782 Keratins Human genes 0.000 claims 1
- 108010076876 Keratins Proteins 0.000 claims 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims 1
- CGSLYBDCEGBZCG-UHFFFAOYSA-N Octicizer Chemical compound C=1C=CC=CC=1OP(=O)(OCC(CC)CCCC)OC1=CC=CC=C1 CGSLYBDCEGBZCG-UHFFFAOYSA-N 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 239000002202 Polyethylene glycol Substances 0.000 claims 1
- 239000004743 Polypropylene Substances 0.000 claims 1
- 239000004372 Polyvinyl alcohol Substances 0.000 claims 1
- 229920002125 Sokalan® Polymers 0.000 claims 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- VDEUTRIMVYSCKW-UHFFFAOYSA-N acetyl octadecaneperoxoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OOC(C)=O VDEUTRIMVYSCKW-UHFFFAOYSA-N 0.000 claims 1
- 239000000654 additive Substances 0.000 claims 1
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- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
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- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 claims 1
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- JZALLXAUNPOCEU-UHFFFAOYSA-N tetradecylbenzene Chemical compound CCCCCCCCCCCCCCC1=CC=CC=C1 JZALLXAUNPOCEU-UHFFFAOYSA-N 0.000 claims 1
- 239000002562 thickening agent Substances 0.000 claims 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims 1
- 239000013638 trimer Substances 0.000 claims 1
- WMYJOZQKDZZHAC-UHFFFAOYSA-H trizinc;dioxido-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S WMYJOZQKDZZHAC-UHFFFAOYSA-H 0.000 claims 1
- 239000001993 wax Substances 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000002041 carbon nanotube Substances 0.000 abstract 3
- 229910021393 carbon nanotube Inorganic materials 0.000 abstract 3
- 239000003208 petroleum Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 238000002525 ultrasonication Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M171/00—Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredients which are physically well-defined but for which the chemical nature is either unspecified or only very vaguely indicated
- C10M171/06—Particles of special shape or size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
- C10M125/02—Carbon; Graphite
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/041—Carbon; Graphite; Carbon black
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Nanotechnology (AREA)
- Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- Thermal Sciences (AREA)
- Textile Engineering (AREA)
- Lubricants (AREA)
- Carbon And Carbon Compounds (AREA)
- Colloid Chemistry (AREA)
Abstract
Selon l'invention, l'introduction de nanotubes dans un liquide permet de modifier les propriétés physiques et/ou chimiques de ce liquide. En effet, la dispersion de nanotubes dans des liquides permet de réaliser des améliorations en termes de transfert de chaleur, de propriétés électriques, de viscosité et de pouvoir lubrifiant. Toutefois, les nanotubes réagissent comme des particules hydrophobes et tendent à s'agglomérer dans les liquides. L'invention concerne des procédés destinés à préparer des dispersions stables de nanotubes et consistant à identifier des tensioactifs/dispersants pouvant disperser les nanotubes de carbone dans un milieu liquide aqueux ou à base de pétrole. Un dispersant approprié est choisi pour le nanotube de carbone et le milieu à base d'eau ou d'huile, ce dispersant étant dissous dans le milieu liquide, d'où la formation d'une solution. On ajoute alors le nanotube de carbone au dispersant contenant la solution par agitation, ultrasonication et/ou des combinaisons correspondantes.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/021,767 | 2001-12-12 | ||
US10/021,767 US6783746B1 (en) | 2000-12-12 | 2001-12-12 | Preparation of stable nanotube dispersions in liquids |
PCT/US2002/038643 WO2003050332A1 (fr) | 2001-12-12 | 2002-12-06 | Preparation de dispersions de nanotubes de carbone stables dans les liquides |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2470113A1 true CA2470113A1 (fr) | 2003-06-19 |
CA2470113C CA2470113C (fr) | 2011-01-25 |
Family
ID=21806039
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2470113A Expired - Lifetime CA2470113C (fr) | 2001-12-12 | 2002-12-06 | Preparation de dispersions de nanotubes stables dans des liquides |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP1495171A4 (fr) |
CN (1) | CN1304657C (fr) |
AU (1) | AU2002357065B2 (fr) |
BR (1) | BR0215135B1 (fr) |
CA (1) | CA2470113C (fr) |
MX (1) | MXPA04005761A (fr) |
NZ (1) | NZ533941A (fr) |
WO (1) | WO2003050332A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005118688A1 (fr) * | 2004-06-01 | 2005-12-15 | Mcgill University | Procede de fabrication de nanotiges polymeres intrinsequement conductrices |
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Publication number | Priority date | Publication date | Assignee | Title |
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JP2001515341A (ja) * | 1995-06-07 | 2001-09-18 | ザ ピリスベリー コムパニー | 低水分活性卵製品 |
MXPA04011927A (es) * | 2002-05-30 | 2005-03-31 | Ashland Inc | Conductividad termica mejorada de fluidos con nanoparticulas de grafito y nanotubo de carbono. |
US7052618B2 (en) | 2004-01-28 | 2006-05-30 | Agilent Technologies, Inc. | Nanostructures and methods of making the same |
AU2005323492A1 (en) * | 2004-04-07 | 2006-07-13 | Eikos, Inc. | Fugitive viscosity and stability modifiers for carbon nanotube compositions |
DE102004021812A1 (de) * | 2004-04-30 | 2005-12-08 | KLüBER LUBRICATION MüNCHEN KG | Schmierfett, Verfahren zu dessen Herstellung und dessen Verwendung |
US8765488B2 (en) | 2004-07-22 | 2014-07-01 | The Board Of Trustees Of The University Of Illinois | Sensors employing single-walled carbon nanotubes |
WO2007011369A2 (fr) * | 2004-08-23 | 2007-01-25 | E.I. Dupont De Nemours And Company | Procede d'elaboration de dispersions de nanotube en carbone/polyaniline (cnt/pani) |
EP1980609A4 (fr) * | 2006-01-31 | 2011-04-13 | Nissan Motor | Compositions d'huile lubrifiante contenant des nanoparticules |
WO2007093081A1 (fr) * | 2006-02-16 | 2007-08-23 | Dalian Institute Of Chemical Physics Chinese Academy Of Sciences | Catalyseur et procédé de conversion de gaz de synthèse |
CN1847374B (zh) * | 2006-04-14 | 2011-02-09 | 杨东彤 | 一种碳纳米管减磨增强剂的制备方法 |
FR2901154B1 (fr) | 2006-05-18 | 2008-07-18 | Arkema France | Utilisation de materiaux composites a base de nanotubes de carbone comme agents viscosifiants de solutions aqueuses |
KR100854967B1 (ko) * | 2006-08-16 | 2008-08-28 | 금호석유화학 주식회사 | 탄소나노소재 분산액 및 그의 제조방법 |
US7935767B2 (en) | 2006-12-21 | 2011-05-03 | E. I. Du Pont De Nemours And Company | Multiblock polymer dispersions of carbon nanotubes |
FR2916364B1 (fr) | 2007-05-22 | 2009-10-23 | Arkema France | Procede de preparation de pre-composites a base de nanotubes notamment de carbone |
CN101225247B (zh) * | 2007-12-27 | 2011-04-06 | 江苏奈特纳米科技有限公司 | 纳米材料添加剂 |
CN101485962B (zh) * | 2008-11-06 | 2011-05-04 | 青岛大学 | 一种分散碳纳米管的简易方法 |
CN101457019B (zh) * | 2009-01-04 | 2011-06-08 | 上海大学 | 碳纳米管/聚砜酰胺纳米复合材料及其制备方法 |
FR2950628B1 (fr) * | 2009-09-25 | 2013-11-01 | Arkema France | Melange-maitre pour la fabrication de fluide de forage |
WO2011072228A1 (fr) | 2009-12-11 | 2011-06-16 | Massachusetts Institute Of Technology | Imagerie spectrale de matériaux photoluminescents |
CN101886022A (zh) * | 2010-07-08 | 2010-11-17 | 东南大学 | 基于碳纳米管的高效水基润滑液的制备方法 |
FR2965274A1 (fr) * | 2010-09-28 | 2012-03-30 | Total Raffinage Marketing | Composition lubrifiante |
EP2739977A1 (fr) | 2011-08-01 | 2014-06-11 | Massachusetts Institute of Technology | Capteurs à base de nanostructures photoluminescentes |
CN102627727B (zh) * | 2012-03-29 | 2017-05-31 | 江南大学 | 一种光敏性聚合物基碳纳米管分散助剂的制备方法和用途 |
EP2650325A1 (fr) | 2012-04-10 | 2013-10-16 | ContiTech AG | Mélange de polymères, mélange de caoutchouc comprenant le mélange de polymères et procédé de préparation du mélange de caoutchouc |
CN103896247B (zh) * | 2014-03-12 | 2016-04-20 | 复旦大学 | 一种水溶性富勒烯纳米颗粒的制备方法 |
WO2015191389A2 (fr) | 2014-06-13 | 2015-12-17 | Massachusetts Institute Of Tecnology | Nanocapteurs optiques sensibles au saccharide |
CN104307429B (zh) * | 2014-10-13 | 2016-09-28 | 南京大学 | 碳纳米材料/水/梳状聚醚嵌段聚丙烯酸共聚物悬浮液及其制备方法 |
CN104559397A (zh) * | 2014-12-25 | 2015-04-29 | 天津弘业万博电子有限公司 | 一种导静电涂料的制备方法 |
CN104591125A (zh) * | 2014-12-30 | 2015-05-06 | 广州聚能生物科技有限公司 | 一种一维或二维纳米材料的分散方法 |
CN104672783B (zh) * | 2015-03-10 | 2017-01-04 | 北京化工大学 | 一种高性能碳纳米管/环氧树脂的制备方法 |
CN105713235B (zh) * | 2016-01-22 | 2017-10-31 | 西南大学 | 一种提高多壁碳纳米管在水溶液中分散性的方法 |
CN106398803A (zh) * | 2016-08-31 | 2017-02-15 | 四川碳世界科技有限公司 | 一种碳纳米管和石墨烯复配润滑油的制备方法 |
CN110894068A (zh) * | 2018-11-12 | 2020-03-20 | 江苏天奈科技股份有限公司 | 一种易分散碳纳米管粉末的制备方法及碳纳米管粉末 |
CN111015021B (zh) * | 2019-12-30 | 2021-12-07 | 苏州优诺电子材料科技有限公司 | 一种低温无铅焊锡膏及制备方法 |
CN111171430B (zh) * | 2020-02-18 | 2022-03-25 | 江西铜业技术研究院有限公司 | 一种易分散碳纳米管母粒及其制备方法和应用 |
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JPH0823031B2 (ja) * | 1989-02-17 | 1996-03-06 | 旭硝子株式会社 | 潤滑油組成物 |
JPH0822733B2 (ja) * | 1993-08-04 | 1996-03-06 | 工業技術院長 | カーボンナノチューブの分離精製方法 |
ATE240906T1 (de) * | 1998-04-09 | 2003-06-15 | Horcom Ltd | Zusammensetzung enthaltend nanoröhren und eine organische verbindung |
US6531513B2 (en) * | 1998-10-02 | 2003-03-11 | University Of Kentucky Research Foundation | Method of solubilizing carbon nanotubes in organic solutions |
JP2001011344A (ja) * | 1999-06-30 | 2001-01-16 | Nec Corp | 塗料とそれを用いて形成された膜及びそれらの製造方法 |
-
2002
- 2002-12-06 CA CA2470113A patent/CA2470113C/fr not_active Expired - Lifetime
- 2002-12-06 AU AU2002357065A patent/AU2002357065B2/en not_active Expired - Fee Related
- 2002-12-06 CN CNB028280075A patent/CN1304657C/zh not_active Expired - Fee Related
- 2002-12-06 NZ NZ533941A patent/NZ533941A/en unknown
- 2002-12-06 EP EP02804723A patent/EP1495171A4/fr not_active Ceased
- 2002-12-06 MX MXPA04005761A patent/MXPA04005761A/es active IP Right Grant
- 2002-12-06 WO PCT/US2002/038643 patent/WO2003050332A1/fr not_active Application Discontinuation
- 2002-12-06 BR BRPI0215135-9A patent/BR0215135B1/pt active IP Right Grant
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005118688A1 (fr) * | 2004-06-01 | 2005-12-15 | Mcgill University | Procede de fabrication de nanotiges polymeres intrinsequement conductrices |
Also Published As
Publication number | Publication date |
---|---|
AU2002357065B2 (en) | 2008-09-04 |
AU2002357065A1 (en) | 2003-06-23 |
WO2003050332A1 (fr) | 2003-06-19 |
NZ533941A (en) | 2006-09-29 |
BR0215135B1 (pt) | 2014-12-16 |
MXPA04005761A (es) | 2004-11-01 |
BR0215135A (pt) | 2005-01-04 |
EP1495171A4 (fr) | 2008-04-02 |
CA2470113C (fr) | 2011-01-25 |
CN1617958A (zh) | 2005-05-18 |
EP1495171A1 (fr) | 2005-01-12 |
CN1304657C (zh) | 2007-03-14 |
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