CA2443763A1 - Pickle liquor acid analyzer - Google Patents
Pickle liquor acid analyzer Download PDFInfo
- Publication number
- CA2443763A1 CA2443763A1 CA002443763A CA2443763A CA2443763A1 CA 2443763 A1 CA2443763 A1 CA 2443763A1 CA 002443763 A CA002443763 A CA 002443763A CA 2443763 A CA2443763 A CA 2443763A CA 2443763 A1 CA2443763 A1 CA 2443763A1
- Authority
- CA
- Canada
- Prior art keywords
- module
- concentration
- analyzer
- modules
- oxidizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000002253 acid Substances 0.000 title claims abstract description 84
- 235000021110 pickles Nutrition 0.000 title claims abstract description 32
- 238000004458 analytical method Methods 0.000 claims abstract description 55
- 229910021645 metal ion Inorganic materials 0.000 claims abstract description 33
- 239000007800 oxidant agent Substances 0.000 claims abstract description 33
- 239000000523 sample Substances 0.000 claims description 61
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- 239000003153 chemical reaction reagent Substances 0.000 claims description 27
- 239000000243 solution Substances 0.000 claims description 24
- 238000005259 measurement Methods 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 22
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 18
- 150000007513 acids Chemical class 0.000 claims description 18
- 150000002500 ions Chemical class 0.000 claims description 17
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 16
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 15
- 229910052742 iron Inorganic materials 0.000 claims description 14
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 12
- 239000012895 dilution Substances 0.000 claims description 12
- 238000010790 dilution Methods 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 239000003446 ligand Substances 0.000 claims description 9
- 239000000470 constituent Substances 0.000 claims description 8
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 5
- 238000001514 detection method Methods 0.000 claims description 5
- 229910017604 nitric acid Inorganic materials 0.000 claims description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 4
- 239000011651 chromium Substances 0.000 claims description 4
- 239000012286 potassium permanganate Substances 0.000 claims description 4
- 239000012488 sample solution Substances 0.000 claims description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 2
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 claims description 2
- DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical compound C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims description 2
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 claims description 2
- 238000001228 spectrum Methods 0.000 claims description 2
- 150000001450 anions Chemical class 0.000 claims 2
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 claims 1
- 229910001430 chromium ion Inorganic materials 0.000 claims 1
- 238000007865 diluting Methods 0.000 claims 1
- 229910001453 nickel ion Inorganic materials 0.000 claims 1
- 238000004445 quantitative analysis Methods 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 29
- 239000012470 diluted sample Substances 0.000 description 13
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 12
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 12
- 239000004327 boric acid Substances 0.000 description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
- 230000031700 light absorption Effects 0.000 description 12
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 10
- 238000010521 absorption reaction Methods 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 238000004364 calculation method Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000005554 pickling Methods 0.000 description 6
- 229910001448 ferrous ion Inorganic materials 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 4
- 229910001447 ferric ion Inorganic materials 0.000 description 4
- 230000003993 interaction Effects 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 229960002413 ferric citrate Drugs 0.000 description 3
- NPFOYSMITVOQOS-UHFFFAOYSA-K iron(III) citrate Chemical compound [Fe+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NPFOYSMITVOQOS-UHFFFAOYSA-K 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000012937 correction Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 238000011002 quantification Methods 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000013026 undiluted sample Substances 0.000 description 2
- 229910004039 HBF4 Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000012445 acidic reagent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000012864 cross contamination Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000002572 peristaltic effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000012086 standard solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/02—Food
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/08—Iron or steel
- C23G1/086—Iron or steel solutions containing HF
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/08—Iron or steel
- C23G1/081—Iron or steel solutions containing H2SO4
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/02—Devices for withdrawing samples
- G01N1/10—Devices for withdrawing samples in the liquid or fluent state
- G01N1/14—Suction devices, e.g. pumps; Ejector devices
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/15—Inorganic acid or base [e.g., hcl, sulfuric acid, etc. ]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/17—Nitrogen containing
- Y10T436/177692—Oxides of nitrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/20—Oxygen containing
- Y10T436/206664—Ozone or peroxide
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Pathology (AREA)
- Immunology (AREA)
- General Physics & Mathematics (AREA)
- General Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- Physics & Mathematics (AREA)
- Molecular Biology (AREA)
- Food Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
- Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US28256601P | 2001-04-09 | 2001-04-09 | |
| US60/282,566 | 2001-04-09 | ||
| PCT/US2002/011141 WO2002081778A1 (en) | 2001-04-09 | 2002-04-09 | Pickle liquor acid analyzer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2443763A1 true CA2443763A1 (en) | 2002-10-17 |
Family
ID=23082087
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002443763A Abandoned CA2443763A1 (en) | 2001-04-09 | 2002-04-09 | Pickle liquor acid analyzer |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20020146348A1 (enExample) |
| EP (1) | EP1386021A1 (enExample) |
| JP (1) | JP2004526967A (enExample) |
| KR (1) | KR20030094327A (enExample) |
| CN (1) | CN1518610A (enExample) |
| BR (1) | BR0208750A (enExample) |
| CA (1) | CA2443763A1 (enExample) |
| MX (1) | MXPA03009174A (enExample) |
| WO (1) | WO2002081778A1 (enExample) |
| ZA (1) | ZA200307741B (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090229995A1 (en) * | 2008-03-14 | 2009-09-17 | Eci Technology, Inc. | Analysis of fluoride at low concentrations in acidic processing solutions |
| RU2010145224A (ru) * | 2008-04-28 | 2012-06-10 | П2В Лтд (IL) | Объединенный электролитический и химический способ получения чистой обработанной воды, концентрация цианидов в которой меньше 1 миллиграмма на литр |
| KR101641736B1 (ko) * | 2009-12-23 | 2016-07-21 | 주식회사 포스코 | 혼산농도 자동측정장치 및 그 방법 |
| CN101776630A (zh) * | 2010-03-12 | 2010-07-14 | 清华大学 | 一种溴化锂水溶液的浓度测量方法及装置 |
| KR101242877B1 (ko) * | 2010-12-28 | 2013-03-12 | 주식회사 포스코 | 근적외선-적정법을 이용한 Ｏｎ-ｌｉｎｅ 산액 분석 방법 |
| JP5919920B2 (ja) | 2011-03-28 | 2016-05-18 | Ｊｆｅスチール株式会社 | Ｓｉ含有冷延鋼板の製造方法及び装置 |
| CN103487550A (zh) * | 2013-09-23 | 2014-01-01 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种测定钛板酸洗液中硝酸含量的方法 |
| US10444208B2 (en) * | 2016-06-17 | 2019-10-15 | Myron L Company | Method for measuring the concentration of a chemical species using a reagent baseline |
| KR102131004B1 (ko) * | 2018-07-25 | 2020-07-07 | 주식회사 포스코 | 금속 산세용 혼산 용액의 성분 농도 측정 장치 |
| CN109490142A (zh) * | 2018-11-28 | 2019-03-19 | 武汉钢铁有限公司 | 一种冷轧酸洗液的浓度分析仪 |
| CN109923415B (zh) * | 2019-01-24 | 2021-06-22 | 香港应用科技研究院有限公司 | 用于确定溶液中物质浓度的系统和方法 |
| US11340205B2 (en) | 2019-01-24 | 2022-05-24 | Hong Kong Applied Science And Technology Research Institute Co., Ltd. | Systems and methods for determining concentrations of materials in solutions |
| CN115060765A (zh) * | 2022-05-10 | 2022-09-16 | 首钢京唐钢铁联合有限责任公司 | 酸分析仪检测系统 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5175502A (en) * | 1990-09-14 | 1992-12-29 | Armco Steel Company, L.P. | Method and apparatus for determining acid concentration |
| IT1303814B1 (it) * | 1998-12-02 | 2001-02-23 | Henkel Kgaa | Apparecchiatura e metodo per controllare processi di decapaggio peracciaio. |
| JP2001021548A (ja) * | 1999-07-06 | 2001-01-26 | Kawasaki Steel Corp | ふっ酸含有溶液中の遊離ふっ素の分析方法および分析装置 |
-
2002
- 2002-04-09 KR KR10-2003-7013141A patent/KR20030094327A/ko not_active Abandoned
- 2002-04-09 US US10/119,339 patent/US20020146348A1/en not_active Abandoned
- 2002-04-09 BR BR0208750-2A patent/BR0208750A/pt not_active IP Right Cessation
- 2002-04-09 MX MXPA03009174A patent/MXPA03009174A/es unknown
- 2002-04-09 EP EP02719473A patent/EP1386021A1/en not_active Withdrawn
- 2002-04-09 JP JP2002579537A patent/JP2004526967A/ja not_active Abandoned
- 2002-04-09 CA CA002443763A patent/CA2443763A1/en not_active Abandoned
- 2002-04-09 WO PCT/US2002/011141 patent/WO2002081778A1/en not_active Ceased
- 2002-04-09 CN CNA028088298A patent/CN1518610A/zh active Pending
-
2004
- 2004-10-03 ZA ZA200307741A patent/ZA200307741B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP1386021A1 (en) | 2004-02-04 |
| WO2002081778A1 (en) | 2002-10-17 |
| CN1518610A (zh) | 2004-08-04 |
| MXPA03009174A (es) | 2004-11-22 |
| KR20030094327A (ko) | 2003-12-11 |
| ZA200307741B (en) | 2004-10-04 |
| US20020146348A1 (en) | 2002-10-10 |
| JP2004526967A (ja) | 2004-09-02 |
| BR0208750A (pt) | 2004-06-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |