CA2411063C - Composite ceramic membrane oxygen separation method - Google Patents
Composite ceramic membrane oxygen separation method Download PDFInfo
- Publication number
- CA2411063C CA2411063C CA002411063A CA2411063A CA2411063C CA 2411063 C CA2411063 C CA 2411063C CA 002411063 A CA002411063 A CA 002411063A CA 2411063 A CA2411063 A CA 2411063A CA 2411063 C CA2411063 C CA 2411063C
- Authority
- CA
- Canada
- Prior art keywords
- layer
- oxygen
- porous
- thickness
- active
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000001301 oxygen Substances 0.000 title claims abstract description 154
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 154
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 140
- 239000012528 membrane Substances 0.000 title claims abstract description 72
- 239000002131 composite material Substances 0.000 title claims abstract description 35
- 239000000919 ceramic Substances 0.000 title description 7
- 238000000926 separation method Methods 0.000 title description 7
- 239000011148 porous material Substances 0.000 claims abstract description 158
- 239000007789 gas Substances 0.000 claims abstract description 58
- 238000009826 distribution Methods 0.000 claims abstract description 41
- 238000000034 method Methods 0.000 claims abstract description 35
- -1 oxygen ions Chemical class 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims description 34
- 239000000047 product Substances 0.000 claims description 13
- 230000007423 decrease Effects 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 7
- 239000012466 permeate Substances 0.000 claims description 6
- 230000004907 flux Effects 0.000 abstract description 57
- 239000010410 layer Substances 0.000 description 195
- 239000012071 phase Substances 0.000 description 22
- 230000004913 activation Effects 0.000 description 16
- 238000009792 diffusion process Methods 0.000 description 13
- 150000002500 ions Chemical class 0.000 description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 239000007790 solid phase Substances 0.000 description 10
- 230000032258 transport Effects 0.000 description 10
- 239000000126 substance Substances 0.000 description 9
- 239000000446 fuel Substances 0.000 description 7
- 230000037427 ion transport Effects 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000002407 reforming Methods 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 6
- 230000003247 decreasing effect Effects 0.000 description 5
- 229910044991 metal oxide Inorganic materials 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 238000010926 purge Methods 0.000 description 5
- 239000001307 helium Substances 0.000 description 4
- 229910052734 helium Inorganic materials 0.000 description 4
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 239000012465 retentate Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000003467 diminishing effect Effects 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000002459 porosimetry Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000011157 advanced composite material Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000002902 bimodal effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000005094 computer simulation Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000007770 graphite material Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000010206 sensitivity analysis Methods 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
- B01D69/1216—Three or more layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/024—Oxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/02—Preparation of oxygen
- C01B13/0229—Purification or separation processes
- C01B13/0248—Physical processing only
- C01B13/0251—Physical processing only by making use of membranes
- C01B13/0255—Physical processing only by making use of membranes characterised by the type of membrane
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/104—Oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/26—Electrical properties
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2210/00—Purification or separation of specific gases
- C01B2210/0043—Impurity removed
- C01B2210/0046—Nitrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2210/00—Purification or separation of specific gases
- C01B2210/0043—Impurity removed
- C01B2210/0051—Carbon dioxide
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
- Inert Electrodes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/589,425 | 2000-06-07 | ||
| US09/589,425 US6368383B1 (en) | 1999-06-08 | 2000-06-07 | Method of separating oxygen with the use of composite ceramic membranes |
| PCT/US2001/016790 WO2001093987A1 (en) | 2000-06-07 | 2001-05-24 | Composite ceramic membrane oxygen separation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2411063A1 CA2411063A1 (en) | 2001-12-13 |
| CA2411063C true CA2411063C (en) | 2006-10-03 |
Family
ID=24357967
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002411063A Expired - Fee Related CA2411063C (en) | 2000-06-07 | 2001-05-24 | Composite ceramic membrane oxygen separation method |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6368383B1 (enExample) |
| EP (1) | EP1289626A4 (enExample) |
| JP (1) | JP2003534906A (enExample) |
| CN (1) | CN1235665C (enExample) |
| AU (2) | AU7492501A (enExample) |
| BR (1) | BR0111331A (enExample) |
| CA (1) | CA2411063C (enExample) |
| NO (1) | NO20025848L (enExample) |
| WO (1) | WO2001093987A1 (enExample) |
| ZA (1) | ZA200208858B (enExample) |
Families Citing this family (50)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6682842B1 (en) * | 1999-07-31 | 2004-01-27 | The Regents Of The University Of California | Composite electrode/electrolyte structure |
| US6605316B1 (en) | 1999-07-31 | 2003-08-12 | The Regents Of The University Of California | Structures and fabrication techniques for solid state electrochemical devices |
| US7163713B2 (en) * | 1999-07-31 | 2007-01-16 | The Regents Of The University Of California | Method for making dense crack free thin films |
| US7553573B2 (en) | 1999-07-31 | 2009-06-30 | The Regents Of The University Of California | Solid state electrochemical composite |
| US6514314B2 (en) * | 2000-12-04 | 2003-02-04 | Praxair Technology, Inc. | Ceramic membrane structure and oxygen separation method |
| US6887361B1 (en) | 2001-03-22 | 2005-05-03 | The Regents Of The University Of California | Method for making thin-film ceramic membrane on non-shrinking continuous or porous substrates by electrophoretic deposition |
| US20030054154A1 (en) * | 2001-09-14 | 2003-03-20 | Hancun Chen | Method of making a porous green form and oxygen transport membrane |
| US6565632B1 (en) * | 2001-12-17 | 2003-05-20 | Praxair Technology, Inc. | Ion-transport membrane assembly incorporating internal support |
| US6921557B2 (en) * | 2001-12-18 | 2005-07-26 | The Regents Of The University Of California | Process for making dense thin films |
| AU2002357342A1 (en) | 2001-12-18 | 2003-06-30 | The Regents Of The University Of California | Metal current collect protected by oxide film |
| US7232626B2 (en) * | 2002-04-24 | 2007-06-19 | The Regents Of The University Of California | Planar electrochemical device assembly |
| US20040023101A1 (en) * | 2002-05-07 | 2004-02-05 | The Regents Of The University Of California | Electrochemical cell stack assembly |
| US7338624B2 (en) * | 2002-07-31 | 2008-03-04 | Praxair Technology Inc. | Ceramic manufacture for a composite ion transport membrane |
| CN1720633A (zh) * | 2002-10-04 | 2006-01-11 | 加利福尼亚大学董事会 | 氟分离和生成装置 |
| US7279027B2 (en) * | 2003-03-21 | 2007-10-09 | Air Products And Chemicals, Inc. | Planar ceramic membrane assembly and oxidation reactor system |
| GB0310281D0 (en) * | 2003-05-03 | 2003-06-11 | Univ Robert Gordon | A membrane apparatus and method of preparing a membrane and a method of producing synthetic gas |
| DE10325413B4 (de) * | 2003-06-05 | 2015-03-05 | Audi Ag | Verfahren zum Betreiben einer Brennkraftmaschine eines Fahrzeuges, insbesondere eines Kraftfahtzeuges sowie Vorrichtung zur Durchführung eines derartigen Verfahrens |
| EP1648601A2 (en) * | 2003-07-10 | 2006-04-26 | Praxair Technology, Inc. | Method of forming ion transport membrane structure |
| JP2007527468A (ja) * | 2003-07-10 | 2007-09-27 | プラクスエア・テクノロジー・インコーポレイテッド | 酸素イオン輸送複合体要素 |
| US7901730B2 (en) * | 2004-04-26 | 2011-03-08 | Johnson Research & Development Co., Inc. | Thin film ceramic proton conducting electrolyte |
| RU2403136C2 (ru) * | 2004-11-30 | 2010-11-10 | Члены Правления Университета Калифорнии | Паяная система с согласованными коэффициентами термического расширения |
| JP2008522370A (ja) * | 2004-11-30 | 2008-06-26 | ザ、リージェンツ、オブ、ザ、ユニバーシティ、オブ、カリフォルニア | 電気化学装置用封止ジョイント構造 |
| FR2879185B1 (fr) * | 2004-12-10 | 2007-03-09 | Air Liquide | Reacteur catalytique membranaire |
| US7279025B2 (en) * | 2004-12-21 | 2007-10-09 | Praxair Technology, Inc. | Separation and reaction method utilizing an oxygen ion transport element |
| US7595019B2 (en) * | 2005-03-01 | 2009-09-29 | Air Products And Chemicals, Inc. | Method of making an ion transport membrane oxygen separation device |
| RU2403655C9 (ru) * | 2005-04-21 | 2011-04-20 | Члены Правления Университета Калифорнии | Инфильтрация исходного материала и способ покрытия |
| JPWO2007052497A1 (ja) * | 2005-11-07 | 2009-04-30 | 国立大学法人広島大学 | 複合分離膜およびその製造方法、並びに当該複合分離膜を用いる有機液体混合物の分離方法 |
| JP4745048B2 (ja) * | 2005-12-22 | 2011-08-10 | 東京瓦斯株式会社 | 水素透過膜モジュール |
| JP4745049B2 (ja) * | 2005-12-22 | 2011-08-10 | 東京瓦斯株式会社 | 水素透過膜モジュールの作製方法 |
| JP2009544502A (ja) * | 2006-07-28 | 2009-12-17 | ザ、リージェンツ、オブ、ザ、ユニバーシティ、オブ、カリフォルニア | 接合された同心管 |
| RU2480864C9 (ru) * | 2007-07-25 | 2013-08-27 | Члены Правления Университета Калифорнии | Высокотемпературное электрохимическое устройство со структурой с взаимосцеплением |
| WO2009067171A1 (en) * | 2007-11-20 | 2009-05-28 | Corning Incorporated | Oxygen-ion conducting membrane structure |
| US10593963B2 (en) * | 2007-12-04 | 2020-03-17 | Ceramtec Gmbh | Blocking layer |
| US20090145761A1 (en) * | 2007-12-11 | 2009-06-11 | Van Hassel Bart A | Oxygen separation element and method |
| ATE540133T1 (de) * | 2008-02-04 | 2012-01-15 | Univ California | Cermet auf cu-basis für hochtemperatur- brennstoffzelle |
| DE102008016158A1 (de) * | 2008-03-28 | 2009-10-01 | Forschungszentrum Jülich GmbH | Sauerstoff durchlässige Membran sowie Verfahren zu dessen Herstellung |
| US8486580B2 (en) * | 2008-04-18 | 2013-07-16 | The Regents Of The University Of California | Integrated seal for high-temperature electrochemical device |
| WO2011107898A1 (en) * | 2010-03-05 | 2011-09-09 | Koninklijke Philips Electronics N.V. | Oxygen separation membrane |
| JP5817330B2 (ja) * | 2010-08-24 | 2015-11-18 | 東レ株式会社 | 分離膜および分離膜エレメント |
| US8834604B2 (en) * | 2010-09-16 | 2014-09-16 | Volt Research, Llc | High temperature gas processing system and method for making the same |
| WO2012052915A1 (en) * | 2010-10-22 | 2012-04-26 | Koninklijke Philips Electronics N.V. | Arrangement and method for separating oxygen |
| KR101780185B1 (ko) | 2010-12-10 | 2017-09-21 | 삼성전자주식회사 | 흡착셀 및 그 제조방법 |
| DE102011083501A1 (de) * | 2011-09-27 | 2013-03-28 | Siemens Aktiengesellschaft | Komposit-Anode für Batterie-Zelle |
| DE102012006744A1 (de) | 2012-04-04 | 2013-10-10 | Forschungszentrum Jülich GmbH | Gemischt Ionen und Elektronen leitende Membran zur Gastrennung sowie Verfahren zur Herstellung derselben |
| KR101471615B1 (ko) * | 2012-12-11 | 2014-12-11 | 한국에너지기술연구원 | 수소 분리막 및 그의 제조 방법 |
| CN105188893B (zh) * | 2013-04-26 | 2018-11-20 | 科廷科技大学 | 带通道的制品及其制造方法 |
| US9797054B2 (en) | 2014-07-09 | 2017-10-24 | Carleton Life Support Systems Inc. | Pressure driven ceramic oxygen generation system with integrated manifold and tubes |
| US10441922B2 (en) * | 2015-06-29 | 2019-10-15 | Praxair Technology, Inc. | Dual function composite oxygen transport membrane |
| CN109865436B (zh) * | 2017-12-01 | 2021-07-27 | 中国科学院大连化学物理研究所 | 一种板状透氧膜组件的制备方法 |
| US11136238B2 (en) | 2018-05-21 | 2021-10-05 | Praxair Technology, Inc. | OTM syngas panel with gas heated reformer |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1685759A (en) * | 1924-05-22 | 1928-09-25 | Ver Fur Chemische Ind Ag | Diffusion reaction |
| US5240480A (en) * | 1992-09-15 | 1993-08-31 | Air Products And Chemicals, Inc. | Composite mixed conductor membranes for producing oxygen |
| US5534471A (en) * | 1994-01-12 | 1996-07-09 | Air Products And Chemicals, Inc. | Ion transport membranes with catalyzed mixed conducting porous layer |
| US5569633A (en) * | 1994-01-12 | 1996-10-29 | Air Products And Chemicals, Inc. | Ion transport membranes with catalyzed dense layer |
| US5681373A (en) * | 1995-03-13 | 1997-10-28 | Air Products And Chemicals, Inc. | Planar solid-state membrane module |
| JPH09100179A (ja) * | 1995-07-26 | 1997-04-15 | Sumitomo Electric Ind Ltd | 窒化ケイ素質多孔体およびその製造方法 |
| ID19327A (id) * | 1996-12-31 | 1998-07-02 | Praxiar Technology Inc | Membran elektrolit padat dengan unsur pokok pemertinggi secara mekanik dan pemertinggi secara katalitik yang bersifat dapat menyerap |
| US6235187B1 (en) * | 1996-12-31 | 2001-05-22 | Praxair Technology Inc. | Oxygen separation method using a mixed conducting cubic perovskite ceramic ion transport membrane |
| US5938822A (en) | 1997-05-02 | 1999-08-17 | Praxair Technology, Inc. | Solid electrolyte membrane with porous catalytically-enhancing constituents |
| US5846641A (en) | 1997-03-20 | 1998-12-08 | Exxon Research And Engineering Company | Multi-layer membrane composites and their use in hydrocarbon partical oxidation |
| US5888272A (en) * | 1997-06-05 | 1999-03-30 | Praxair Technology, Inc. | Process for enriched combustion using solid electrolyte ionic conductor systems |
| US5965010A (en) * | 1997-07-15 | 1999-10-12 | Niagara Mohawk Power Corporation | Electrochemical autothermal reformer |
| JP2981884B1 (ja) * | 1998-06-29 | 1999-11-22 | 工業技術院長 | ゼオライト膜の製造方法 |
-
2000
- 2000-06-07 US US09/589,425 patent/US6368383B1/en not_active Expired - Lifetime
-
2001
- 2001-05-24 AU AU7492501A patent/AU7492501A/xx active Pending
- 2001-05-24 BR BR0111331-3A patent/BR0111331A/pt active Search and Examination
- 2001-05-24 AU AU2001274925A patent/AU2001274925B2/en not_active Ceased
- 2001-05-24 JP JP2002501554A patent/JP2003534906A/ja active Pending
- 2001-05-24 EP EP01941586A patent/EP1289626A4/en not_active Withdrawn
- 2001-05-24 WO PCT/US2001/016790 patent/WO2001093987A1/en not_active Ceased
- 2001-05-24 CA CA002411063A patent/CA2411063C/en not_active Expired - Fee Related
- 2001-05-24 CN CN01810834.2A patent/CN1235665C/zh not_active Expired - Fee Related
-
2002
- 2002-10-31 ZA ZA200208858A patent/ZA200208858B/xx unknown
- 2002-12-05 NO NO20025848A patent/NO20025848L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| JP2003534906A (ja) | 2003-11-25 |
| AU7492501A (en) | 2001-12-17 |
| WO2001093987A1 (en) | 2001-12-13 |
| US6368383B1 (en) | 2002-04-09 |
| CA2411063A1 (en) | 2001-12-13 |
| NO20025848D0 (no) | 2002-12-05 |
| NO20025848L (no) | 2002-12-05 |
| CN1235665C (zh) | 2006-01-11 |
| ZA200208858B (en) | 2003-08-19 |
| AU2001274925B2 (en) | 2005-11-17 |
| EP1289626A1 (en) | 2003-03-12 |
| BR0111331A (pt) | 2003-06-03 |
| EP1289626A4 (en) | 2009-03-11 |
| CN1434741A (zh) | 2003-08-06 |
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