CA2381888C - Formulation components resistant towards decomposition by aromatization, compositions and laundry methods employing same - Google Patents
Formulation components resistant towards decomposition by aromatization, compositions and laundry methods employing same Download PDFInfo
- Publication number
- CA2381888C CA2381888C CA002381888A CA2381888A CA2381888C CA 2381888 C CA2381888 C CA 2381888C CA 002381888 A CA002381888 A CA 002381888A CA 2381888 A CA2381888 A CA 2381888A CA 2381888 C CA2381888 C CA 2381888C
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- CA
- Canada
- Prior art keywords
- group
- substituted
- alkyl
- unsubstituted
- bleach
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 350
- 238000000034 method Methods 0.000 title claims abstract description 53
- 238000000354 decomposition reaction Methods 0.000 title abstract description 15
- 238000009472 formulation Methods 0.000 title description 19
- 238000005899 aromatization reaction Methods 0.000 title description 9
- 239000007844 bleaching agent Substances 0.000 claims abstract description 221
- 238000004061 bleaching Methods 0.000 claims abstract description 184
- 150000001875 compounds Chemical class 0.000 claims abstract description 136
- -1 imine cations Chemical class 0.000 claims abstract description 105
- 102000004190 Enzymes Human genes 0.000 claims abstract description 86
- 108090000790 Enzymes Proteins 0.000 claims abstract description 86
- 239000004094 surface-active agent Substances 0.000 claims abstract description 52
- 239000004744 fabric Substances 0.000 claims abstract description 50
- 239000000654 additive Substances 0.000 claims abstract description 32
- 230000000996 additive effect Effects 0.000 claims abstract description 29
- 229920000831 ionic polymer Polymers 0.000 claims abstract description 20
- 238000004900 laundering Methods 0.000 claims abstract description 15
- 125000000217 alkyl group Chemical group 0.000 claims description 123
- 125000003118 aryl group Chemical group 0.000 claims description 76
- 125000000623 heterocyclic group Chemical group 0.000 claims description 66
- 239000012190 activator Substances 0.000 claims description 62
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 61
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 60
- 239000002253 acid Substances 0.000 claims description 51
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 46
- 125000003545 alkoxy group Chemical group 0.000 claims description 45
- 229910052739 hydrogen Inorganic materials 0.000 claims description 45
- 150000003839 salts Chemical class 0.000 claims description 45
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 44
- 125000002947 alkylene group Chemical group 0.000 claims description 26
- SJGALSBBFTYSBA-UHFFFAOYSA-N oxaziridine Chemical compound C1NO1 SJGALSBBFTYSBA-UHFFFAOYSA-N 0.000 claims description 26
- 150000007513 acids Chemical class 0.000 claims description 25
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 claims description 23
- 229930194542 Keto Natural products 0.000 claims description 22
- 150000001768 cations Chemical class 0.000 claims description 22
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 22
- 125000000468 ketone group Chemical group 0.000 claims description 22
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 22
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 15
- 239000002738 chelating agent Substances 0.000 claims description 14
- 229920006395 saturated elastomer Polymers 0.000 claims description 14
- 125000003368 amide group Chemical group 0.000 claims description 11
- 125000005129 aryl carbonyl group Chemical group 0.000 claims description 11
- 125000002837 carbocyclic group Chemical group 0.000 claims description 11
- 125000004181 carboxyalkyl group Chemical group 0.000 claims description 11
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical class [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 claims description 11
- 239000003945 anionic surfactant Substances 0.000 claims description 10
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 9
- FAGGUIDTQQXDSJ-UHFFFAOYSA-N 3-benzoylazepan-2-one Chemical compound C=1C=CC=CC=1C(=O)C1CCCCNC1=O FAGGUIDTQQXDSJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000003826 tablet Substances 0.000 claims description 7
- 125000002091 cationic group Chemical group 0.000 claims description 6
- 239000002552 dosage form Substances 0.000 claims description 6
- 125000005342 perphosphate group Chemical group 0.000 claims description 6
- FCJSHPDYVMKCHI-UHFFFAOYSA-N phenyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OC1=CC=CC=C1 FCJSHPDYVMKCHI-UHFFFAOYSA-N 0.000 claims description 6
- CDWQJRGVYJQAIT-UHFFFAOYSA-N 3-benzoylpiperidin-2-one Chemical compound C=1C=CC=CC=1C(=O)C1CCCNC1=O CDWQJRGVYJQAIT-UHFFFAOYSA-N 0.000 claims description 5
- 150000004968 peroxymonosulfuric acids Chemical class 0.000 claims description 5
- ZDKYIHHSXJTDKX-UHFFFAOYSA-N 2-dodecanoyloxybenzenesulfonic acid Chemical compound CCCCCCCCCCCC(=O)OC1=CC=CC=C1S(O)(=O)=O ZDKYIHHSXJTDKX-UHFFFAOYSA-N 0.000 claims description 4
- 239000007897 gelcap Substances 0.000 claims description 4
- KYVZSRPVPDAAKQ-UHFFFAOYSA-N 2-benzoyloxybenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1OC(=O)C1=CC=CC=C1 KYVZSRPVPDAAKQ-UHFFFAOYSA-N 0.000 claims description 3
- GGAVUMZUOHJGGM-UHFFFAOYSA-N 2-decanoyloxybenzenesulfonic acid Chemical compound CCCCCCCCCC(=O)OC1=CC=CC=C1S(O)(=O)=O GGAVUMZUOHJGGM-UHFFFAOYSA-N 0.000 claims description 3
- GZFRVDZZXXKIGR-UHFFFAOYSA-N 2-decanoyloxybenzoic acid Chemical compound CCCCCCCCCC(=O)OC1=CC=CC=C1C(O)=O GZFRVDZZXXKIGR-UHFFFAOYSA-N 0.000 claims description 3
- FNPBLXRYUROGSR-UHFFFAOYSA-N 2-undec-10-enoyloxybenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1OC(=O)CCCCCCCCC=C FNPBLXRYUROGSR-UHFFFAOYSA-N 0.000 claims description 3
- MQWCVVYEJGQDEL-UHFFFAOYSA-N 3-(4-nitrobenzoyl)azepan-2-one Chemical compound C1=CC([N+](=O)[O-])=CC=C1C(=O)C1C(=O)NCCCC1 MQWCVVYEJGQDEL-UHFFFAOYSA-N 0.000 claims description 3
- JNIYAMTYWPMEGP-UHFFFAOYSA-N ClC1=CC=CC(C(=O)C2C(NCCCC2)=O)=C1 Chemical compound ClC1=CC=CC(C(=O)C2C(NCCCC2)=O)=C1 JNIYAMTYWPMEGP-UHFFFAOYSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 239000006187 pill Substances 0.000 claims description 3
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 claims description 2
- MAZNCWGRSPCNGO-UHFFFAOYSA-M sodium;4-[6-(nonanoylamino)hexanoyloxy]benzenesulfonate Chemical compound [Na+].CCCCCCCCC(=O)NCCCCCC(=O)OC1=CC=C(S([O-])(=O)=O)C=C1 MAZNCWGRSPCNGO-UHFFFAOYSA-M 0.000 claims description 2
- 125000001475 halogen functional group Chemical group 0.000 claims 12
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims 6
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 claims 2
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 claims 1
- 239000007894 caplet Substances 0.000 claims 1
- XSXHWVKGUXMUQE-UHFFFAOYSA-N osmium dioxide Inorganic materials O=[Os]=O XSXHWVKGUXMUQE-UHFFFAOYSA-N 0.000 claims 1
- 229940088598 enzyme Drugs 0.000 description 84
- 108010055059 beta-Mannosidase Proteins 0.000 description 59
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- 239000000243 solution Substances 0.000 description 56
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- 230000000694 effects Effects 0.000 description 45
- 150000003254 radicals Chemical class 0.000 description 45
- 238000004140 cleaning Methods 0.000 description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 39
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 38
- 239000007788 liquid Substances 0.000 description 36
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- 239000000047 product Substances 0.000 description 36
- 229920002000 Xyloglucan Polymers 0.000 description 34
- 239000000463 material Substances 0.000 description 32
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- 239000003054 catalyst Substances 0.000 description 29
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- 241000894007 species Species 0.000 description 27
- 238000002360 preparation method Methods 0.000 description 25
- 239000004365 Protease Substances 0.000 description 24
- 108020004414 DNA Proteins 0.000 description 22
- 241000228215 Aspergillus aculeatus Species 0.000 description 21
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical class [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 21
- 125000000539 amino acid group Chemical group 0.000 description 21
- 238000007792 addition Methods 0.000 description 20
- 239000000975 dye Substances 0.000 description 20
- 239000004615 ingredient Substances 0.000 description 20
- 150000001413 amino acids Chemical group 0.000 description 19
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 18
- 108090001060 Lipase Proteins 0.000 description 18
- 102000004882 Lipase Human genes 0.000 description 18
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 18
- 150000004965 peroxy acids Chemical class 0.000 description 18
- 239000004367 Lipase Substances 0.000 description 17
- 125000004432 carbon atom Chemical group C* 0.000 description 17
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 17
- 235000019421 lipase Nutrition 0.000 description 17
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- 102000005575 Cellulases Human genes 0.000 description 16
- 150000004985 diamines Chemical class 0.000 description 16
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 15
- 108091028043 Nucleic acid sequence Proteins 0.000 description 15
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- 125000003729 nucleotide group Chemical group 0.000 description 15
- 238000006467 substitution reaction Methods 0.000 description 15
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 14
- 235000014113 dietary fatty acids Nutrition 0.000 description 14
- 239000000194 fatty acid Substances 0.000 description 14
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- 150000004665 fatty acids Chemical class 0.000 description 14
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- 229910052751 metal Inorganic materials 0.000 description 13
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- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 12
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 12
- 229920000057 Mannan Polymers 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
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- 239000000344 soap Substances 0.000 description 12
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- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 11
- 235000011941 Tilia x europaea Nutrition 0.000 description 11
- 235000019418 amylase Nutrition 0.000 description 11
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- 125000002768 hydroxyalkyl group Chemical group 0.000 description 11
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 9
- 150000001412 amines Chemical class 0.000 description 9
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- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
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- AJTVWPGZWVJMEA-UHFFFAOYSA-N ruthenium tungsten Chemical compound [Ru].[Ru].[W].[W].[W] AJTVWPGZWVJMEA-UHFFFAOYSA-N 0.000 description 1
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- 238000002791 soaking Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- QSKQNALVHFTOQX-UHFFFAOYSA-M sodium nonanoyloxybenzenesulfonate Chemical compound [Na+].CCCCCCCCC(=O)OC1=CC=CC=C1S([O-])(=O)=O QSKQNALVHFTOQX-UHFFFAOYSA-M 0.000 description 1
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
- 235000019351 sodium silicates Nutrition 0.000 description 1
- GTVQYMAVKDFKNM-UHFFFAOYSA-M sodium;2-decanoyloxybenzenesulfonate Chemical compound [Na+].CCCCCCCCCC(=O)OC1=CC=CC=C1S([O-])(=O)=O GTVQYMAVKDFKNM-UHFFFAOYSA-M 0.000 description 1
- PEVPCUFZCODDGN-UHFFFAOYSA-M sodium;2-dodecanoyloxybenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCC(=O)OC1=CC=CC=C1S([O-])(=O)=O PEVPCUFZCODDGN-UHFFFAOYSA-M 0.000 description 1
- PXDLHKPVKLUIJV-UHFFFAOYSA-M sodium;2-octanoyloxybenzenesulfonate Chemical compound [Na+].CCCCCCCC(=O)OC1=CC=CC=C1S([O-])(=O)=O PXDLHKPVKLUIJV-UHFFFAOYSA-M 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
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- 229940037312 stearamide Drugs 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
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- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
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- 108010038851 tannase Proteins 0.000 description 1
- FBWNMEQMRUMQSO-UHFFFAOYSA-N tergitol NP-9 Chemical compound CCCCCCCCCC1=CC=C(OCCOCCOCCOCCOCCOCCOCCOCCOCCO)C=C1 FBWNMEQMRUMQSO-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- MSLRPWGRFCKNIZ-UHFFFAOYSA-J tetrasodium;hydrogen peroxide;dicarbonate Chemical compound [Na+].[Na+].[Na+].[Na+].OO.OO.OO.[O-]C([O-])=O.[O-]C([O-])=O MSLRPWGRFCKNIZ-UHFFFAOYSA-J 0.000 description 1
- 125000000341 threoninyl group Chemical group [H]OC([H])(C([H])([H])[H])C([H])(N([H])[H])C(*)=O 0.000 description 1
- 210000001541 thymus gland Anatomy 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000000606 toothpaste Substances 0.000 description 1
- 229940034610 toothpaste Drugs 0.000 description 1
- 125000005208 trialkylammonium group Chemical group 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 description 1
- 239000004474 valine Substances 0.000 description 1
- 125000002987 valine group Chemical group [H]N([H])C([H])(C(*)=O)C([H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
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- 239000002888 zwitterionic surfactant Substances 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
- C11D3/3917—Nitrogen-containing compounds
- C11D3/3927—Quarternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15117599P | 1999-08-27 | 1999-08-27 | |
| US60/151,175 | 1999-08-27 | ||
| PCT/US2000/023315 WO2001016273A1 (en) | 1999-08-27 | 2000-08-25 | Formulation components resistant towards decomposition by aromatization, compositions and laundry methods employing same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2381888A1 CA2381888A1 (en) | 2001-03-08 |
| CA2381888C true CA2381888C (en) | 2008-04-15 |
Family
ID=22537630
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002381888A Expired - Fee Related CA2381888C (en) | 1999-08-27 | 2000-08-25 | Formulation components resistant towards decomposition by aromatization, compositions and laundry methods employing same |
Country Status (15)
| Country | Link |
|---|---|
| EP (1) | EP1206515B1 (pt) |
| JP (1) | JP2003508584A (pt) |
| CN (1) | CN1250692C (pt) |
| AR (1) | AR027845A1 (pt) |
| AT (1) | ATE323147T1 (pt) |
| AU (1) | AU771521B2 (pt) |
| BR (1) | BR0014149B1 (pt) |
| CA (1) | CA2381888C (pt) |
| CZ (1) | CZ2002688A3 (pt) |
| DE (1) | DE60027307T2 (pt) |
| ES (1) | ES2262534T3 (pt) |
| MA (1) | MA25605A1 (pt) |
| MX (1) | MXPA02002127A (pt) |
| TR (1) | TR200200459T2 (pt) |
| WO (1) | WO2001016273A1 (pt) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7169744B2 (en) | 2002-06-06 | 2007-01-30 | Procter & Gamble Company | Organic catalyst with enhanced solubility |
| US7557076B2 (en) | 2002-06-06 | 2009-07-07 | The Procter & Gamble Company | Organic catalyst with enhanced enzyme compatibility |
| DE10257279A1 (de) | 2002-12-07 | 2004-06-24 | Clariant Gmbh | Flüssige Bleichmittelkomponenten enthaltend amphiphile Polymere |
| AR051659A1 (es) | 2005-06-17 | 2007-01-31 | Procter & Gamble | Una composicion que comprende un catalizador organico con compatibilidada enzimatica mejorada |
| CA2611428C (en) * | 2005-06-17 | 2017-02-21 | Basf Aktiengesellschaft | Process of producing bleach boosters |
| JP4813551B2 (ja) * | 2005-06-17 | 2011-11-09 | ザ プロクター アンド ギャンブル カンパニー | 強化酵素適合性を有する有機触媒 |
| CN101370921B (zh) | 2006-01-23 | 2014-08-13 | 宝洁公司 | 包含脂肪酶和漂白催化剂的组合物 |
| DE602006013778D1 (de) | 2006-01-23 | 2010-06-02 | Procter & Gamble | Zusammensetzung enthaltend vorgeformte Persäure und einen Bleichmittelkatalysator |
| EP1979457A2 (en) | 2006-01-23 | 2008-10-15 | The Procter and Gamble Company | A composition comprising a lipase and a bleach catalyst |
| WO2008007319A2 (en) | 2006-07-07 | 2008-01-17 | The Procter & Gamble Company | A composition comprising a cellulase and a bleach catalyst |
| CN104334705A (zh) | 2012-04-03 | 2015-02-04 | 巴斯夫欧洲公司 | 包含酞菁颗粒的组合物 |
| PL2841506T3 (pl) | 2012-04-27 | 2016-09-30 | Cząstki ftaloizocyjaniny i ich zastosowanie | |
| FR3046170B1 (fr) * | 2015-12-23 | 2020-02-07 | L'oreal | Utilisation de derives de dihydroisoquinolinium double pour le traitement des matieres keratiniques, compositions et procedes de mise en oeuvre |
| FR3046169B1 (fr) | 2015-12-23 | 2022-05-20 | Oreal | Utilisation de sels de dihydroisoquinolinium pour le traitement des matieres keratiniques, compositions et procedes de mise en oeuvre |
| FR3046168B1 (fr) | 2015-12-23 | 2019-11-01 | L'oreal | Utilisation de sels de dihydroisoquinolinium substitue pour le traitement des matieres keratiniques, compositions et procedes de mise en oeuvre |
| EP3790953A1 (en) * | 2018-05-11 | 2021-03-17 | Diversey, Inc. | Formulations, method and system for reducing energy and water usage in an institutional laundry |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR9408039A (pt) * | 1993-11-12 | 1996-12-24 | Unilever Nv | Composição de branqueamento e processo para branquear um substrato manchado |
| AU8060994A (en) * | 1993-11-12 | 1995-05-29 | Unilever Plc | Imine quaternary salts as bleach catalysts |
| US5370826A (en) * | 1993-11-12 | 1994-12-06 | Lever Brothers Company, Division Of Conopco, Inc. | Quaternay oxaziridinium salts as bleaching compounds |
| US5576282A (en) * | 1995-09-11 | 1996-11-19 | The Procter & Gamble Company | Color-safe bleach boosters, compositions and laundry methods employing same |
| US5817614A (en) * | 1996-08-29 | 1998-10-06 | Procter & Gamble Company | Color-safe bleach boosters, compositions and laundry methods employing same |
-
2000
- 2000-08-25 MX MXPA02002127A patent/MXPA02002127A/es active IP Right Grant
- 2000-08-25 EP EP00957786A patent/EP1206515B1/en not_active Expired - Lifetime
- 2000-08-25 TR TR2002/00459T patent/TR200200459T2/xx unknown
- 2000-08-25 CA CA002381888A patent/CA2381888C/en not_active Expired - Fee Related
- 2000-08-25 DE DE60027307T patent/DE60027307T2/de not_active Expired - Lifetime
- 2000-08-25 JP JP2001520821A patent/JP2003508584A/ja active Pending
- 2000-08-25 ES ES00957786T patent/ES2262534T3/es not_active Expired - Lifetime
- 2000-08-25 CZ CZ2002688A patent/CZ2002688A3/cs unknown
- 2000-08-25 AU AU69354/00A patent/AU771521B2/en not_active Ceased
- 2000-08-25 CN CN00814987.9A patent/CN1250692C/zh not_active Expired - Fee Related
- 2000-08-25 AT AT00957786T patent/ATE323147T1/de not_active IP Right Cessation
- 2000-08-25 BR BRPI0014149-6A patent/BR0014149B1/pt not_active IP Right Cessation
- 2000-08-25 WO PCT/US2000/023315 patent/WO2001016273A1/en active IP Right Grant
- 2000-08-28 AR ARP000104454A patent/AR027845A1/es unknown
-
2002
- 2002-02-27 MA MA26535A patent/MA25605A1/fr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| MA25605A1 (fr) | 2002-12-31 |
| CA2381888A1 (en) | 2001-03-08 |
| AU6935400A (en) | 2001-03-26 |
| JP2003508584A (ja) | 2003-03-04 |
| CN1250692C (zh) | 2006-04-12 |
| ATE323147T1 (de) | 2006-04-15 |
| WO2001016273A1 (en) | 2001-03-08 |
| ES2262534T3 (es) | 2006-12-01 |
| CN1384865A (zh) | 2002-12-11 |
| AU771521B2 (en) | 2004-03-25 |
| BR0014149A (pt) | 2002-05-14 |
| CZ2002688A3 (cs) | 2002-09-11 |
| DE60027307D1 (de) | 2006-05-24 |
| DE60027307T2 (de) | 2007-03-15 |
| EP1206515B1 (en) | 2006-04-12 |
| MXPA02002127A (es) | 2002-09-18 |
| EP1206515A1 (en) | 2002-05-22 |
| TR200200459T2 (tr) | 2002-06-21 |
| BR0014149B1 (pt) | 2011-02-22 |
| AR027845A1 (es) | 2003-04-16 |
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