CA2373402A1 - Methode de production de magnesium et de chlore a partir de solutions de chlorure de magnesium contenant du chlorure d'ammonium - Google Patents
Methode de production de magnesium et de chlore a partir de solutions de chlorure de magnesium contenant du chlorure d'ammonium Download PDFInfo
- Publication number
- CA2373402A1 CA2373402A1 CA 2373402 CA2373402A CA2373402A1 CA 2373402 A1 CA2373402 A1 CA 2373402A1 CA 2373402 CA2373402 CA 2373402 CA 2373402 A CA2373402 A CA 2373402A CA 2373402 A1 CA2373402 A1 CA 2373402A1
- Authority
- CA
- Canada
- Prior art keywords
- magnesium
- chloride
- chlorine
- anhydrous
- ammonium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 title claims abstract description 117
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 title claims abstract description 49
- 229910001629 magnesium chloride Inorganic materials 0.000 title claims abstract description 48
- 238000000034 method Methods 0.000 title claims abstract description 45
- 235000019270 ammonium chloride Nutrition 0.000 title claims abstract description 27
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 26
- 229910052749 magnesium Inorganic materials 0.000 title claims abstract description 25
- 239000011777 magnesium Substances 0.000 title claims abstract description 25
- 239000000460 chlorine Substances 0.000 title claims abstract description 17
- 229910052801 chlorine Inorganic materials 0.000 title claims abstract description 17
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title claims abstract description 16
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical class N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 39
- PALNZFJYSCMLBK-UHFFFAOYSA-K magnesium;potassium;trichloride;hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[Cl-].[Cl-].[Cl-].[K+] PALNZFJYSCMLBK-UHFFFAOYSA-K 0.000 claims abstract description 39
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 37
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 32
- 238000000354 decomposition reaction Methods 0.000 claims abstract description 21
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims abstract description 20
- QGZNMXOKPQPNMY-UHFFFAOYSA-N [Mg].[Cl] Chemical compound [Mg].[Cl] QGZNMXOKPQPNMY-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 14
- 239000007787 solid Substances 0.000 claims abstract description 7
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 5
- 238000005202 decontamination Methods 0.000 claims abstract description 4
- 230000003588 decontaminative effect Effects 0.000 claims abstract description 4
- 239000007921 spray Substances 0.000 claims description 27
- 239000007789 gas Substances 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 230000018044 dehydration Effects 0.000 claims description 12
- 238000006297 dehydration reaction Methods 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 6
- 239000000446 fuel Substances 0.000 claims description 4
- 238000010521 absorption reaction Methods 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 150000002430 hydrocarbons Chemical class 0.000 claims description 2
- 239000011244 liquid electrolyte Substances 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 47
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 18
- 229940091250 magnesium supplement Drugs 0.000 description 18
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 9
- 239000000155 melt Substances 0.000 description 8
- 238000002844 melting Methods 0.000 description 7
- 230000008018 melting Effects 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- 239000003792 electrolyte Substances 0.000 description 6
- 238000002386 leaching Methods 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 239000013078 crystal Substances 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000006096 absorbing agent Substances 0.000 description 4
- 238000005868 electrolysis reaction Methods 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 230000007062 hydrolysis Effects 0.000 description 4
- 238000006460 hydrolysis reaction Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 4
- 150000003863 ammonium salts Chemical group 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 239000000395 magnesium oxide Substances 0.000 description 3
- 229960000869 magnesium oxide Drugs 0.000 description 3
- 235000012245 magnesium oxide Nutrition 0.000 description 3
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000012266 salt solution Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 239000003546 flue gas Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000005979 thermal decomposition reaction Methods 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- GANNOFFDYMSBSZ-UHFFFAOYSA-N [AlH3].[Mg] Chemical compound [AlH3].[Mg] GANNOFFDYMSBSZ-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000004508 fractional distillation Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Landscapes
- Electrolytic Production Of Metals (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RU2001105602 | 2001-02-27 | ||
| RU2001105602A RU2200704C2 (ru) | 2001-02-27 | 2001-02-27 | Способ получения магния и хлора из растворов хлористого магния, содержащих хлористый аммоний |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2373402A1 true CA2373402A1 (fr) | 2002-08-27 |
Family
ID=20246646
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA 2373402 Abandoned CA2373402A1 (fr) | 2001-02-27 | 2002-02-26 | Methode de production de magnesium et de chlore a partir de solutions de chlorure de magnesium contenant du chlorure d'ammonium |
Country Status (2)
| Country | Link |
|---|---|
| CA (1) | CA2373402A1 (fr) |
| RU (1) | RU2200704C2 (fr) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102534196A (zh) * | 2010-12-14 | 2012-07-04 | 贵阳铝镁设计研究院有限公司 | 菱镁矿轻烧干法压制成球氯化工艺 |
| CN104278293A (zh) * | 2013-07-12 | 2015-01-14 | 中国科学院过程工程研究所 | 一种K3NaMgCl6、制备方法及其用途 |
| CN105236446A (zh) * | 2015-11-24 | 2016-01-13 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种废盐酸的回收再利用方法 |
| CN113008726A (zh) * | 2021-04-09 | 2021-06-22 | 河北大有镁业有限责任公司 | 一种铵光卤石脱水料成分的测定装置及方法 |
| CN113044862A (zh) * | 2021-04-09 | 2021-06-29 | 河北大有镁业有限责任公司 | 一种利用不同铵光卤石物料间的协同耦合作用对其进行脱水的方法 |
| CN113479917A (zh) * | 2021-08-02 | 2021-10-08 | 青海盐湖工业股份有限公司 | 一种制备无水氯化镁的方法和系统 |
-
2001
- 2001-02-27 RU RU2001105602A patent/RU2200704C2/ru not_active IP Right Cessation
-
2002
- 2002-02-26 CA CA 2373402 patent/CA2373402A1/fr not_active Abandoned
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102534196A (zh) * | 2010-12-14 | 2012-07-04 | 贵阳铝镁设计研究院有限公司 | 菱镁矿轻烧干法压制成球氯化工艺 |
| CN104278293A (zh) * | 2013-07-12 | 2015-01-14 | 中国科学院过程工程研究所 | 一种K3NaMgCl6、制备方法及其用途 |
| CN105236446A (zh) * | 2015-11-24 | 2016-01-13 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种废盐酸的回收再利用方法 |
| CN113008726A (zh) * | 2021-04-09 | 2021-06-22 | 河北大有镁业有限责任公司 | 一种铵光卤石脱水料成分的测定装置及方法 |
| CN113044862A (zh) * | 2021-04-09 | 2021-06-29 | 河北大有镁业有限责任公司 | 一种利用不同铵光卤石物料间的协同耦合作用对其进行脱水的方法 |
| CN113044862B (zh) * | 2021-04-09 | 2022-07-08 | 河北大有镁业有限责任公司 | 一种利用不同铵光卤石物料间的协同耦合作用对其进行脱水的方法 |
| CN113008726B (zh) * | 2021-04-09 | 2023-04-25 | 河北大有镁业有限责任公司 | 一种铵光卤石脱水料成分的测定装置及方法 |
| CN113479917A (zh) * | 2021-08-02 | 2021-10-08 | 青海盐湖工业股份有限公司 | 一种制备无水氯化镁的方法和系统 |
Also Published As
| Publication number | Publication date |
|---|---|
| RU2200704C2 (ru) | 2003-03-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Dead |