CA2332765A1 - Method of preparing alkyl carboxylic acids by carboxylation of lower alkanes methane - Google Patents

Method of preparing alkyl carboxylic acids by carboxylation of lower alkanes methane Download PDF

Info

Publication number
CA2332765A1
CA2332765A1 CA002332765A CA2332765A CA2332765A1 CA 2332765 A1 CA2332765 A1 CA 2332765A1 CA 002332765 A CA002332765 A CA 002332765A CA 2332765 A CA2332765 A CA 2332765A CA 2332765 A1 CA2332765 A1 CA 2332765A1
Authority
CA
Canada
Prior art keywords
catalyst
methane
acetic acid
transition metal
carbon dioxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002332765A
Other languages
English (en)
French (fr)
Inventor
James J. Spivey
Makarand R. Gogate
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Research Triangle Institute
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2332765A1 publication Critical patent/CA2332765A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/15—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction of organic compounds with carbon dioxide, e.g. Kolbe-Schmitt synthesis

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA002332765A 1998-05-15 1999-05-14 Method of preparing alkyl carboxylic acids by carboxylation of lower alkanes methane Abandoned CA2332765A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US8563298P 1998-05-15 1998-05-15
US60/085,632 1998-05-15
PCT/US1999/010709 WO1999059952A1 (en) 1998-05-15 1999-05-14 Method of preparing alkyl carboxylic acids by carboxylation of lower alkanes methane

Publications (1)

Publication Number Publication Date
CA2332765A1 true CA2332765A1 (en) 1999-11-25

Family

ID=22192913

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002332765A Abandoned CA2332765A1 (en) 1998-05-15 1999-05-14 Method of preparing alkyl carboxylic acids by carboxylation of lower alkanes methane

Country Status (11)

Country Link
EP (1) EP1080063A1 (zh)
JP (1) JP2002515472A (zh)
KR (1) KR20010071265A (zh)
CN (1) CN1307554A (zh)
AU (1) AU3992999A (zh)
BR (1) BR9911058A (zh)
CA (1) CA2332765A1 (zh)
ID (1) ID28542A (zh)
NO (1) NO20005764L (zh)
WO (1) WO1999059952A1 (zh)
YU (1) YU71100A (zh)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6441222B1 (en) * 2000-05-22 2002-08-27 Eastman Chemical Company Vapor phase carbonylation process using iridium-gold co-catalysts
CN1103330C (zh) * 2000-09-30 2003-03-19 太原理工大学 一种非均相催化体系中合成乙酸的方法
KR101446758B1 (ko) * 2012-11-16 2014-10-01 아주대학교산학협력단 아세틸렌 카르복실화 반응을 이용한 이산화탄소의 처리방법
EP3027310B1 (en) * 2013-07-31 2023-04-05 Research Triangle Institute Mixed metal iron oxides and uses thereof
CN106215957A (zh) * 2016-07-12 2016-12-14 巨化集团技术中心 一种用于制备羧酸乙烯酯的多相催化体系及其使用方法
CN111195514B (zh) * 2018-11-20 2021-03-30 中国科学院大连化学物理研究所 一种单原子分散的铑基催化剂、其制备方法及在甲烷低温氧化反应中的应用
CN111377813B (zh) * 2018-12-31 2023-02-03 中国石油化工股份有限公司 一种合成苯丙炔酸的催化剂、其制备方法及其应用
CN111978170A (zh) * 2019-05-24 2020-11-24 贵州新天鑫化工有限公司 一种苯乙酸的绿色可循环合成方法
CN112892588B (zh) * 2019-12-03 2022-03-29 中国科学院大连化学物理研究所 一种用于低温催化氧化甲烷制备乙酸的原子级单分散的过渡金属催化剂的制备方法与应用
CN113117757B (zh) * 2019-12-31 2023-04-07 中国石油化工股份有限公司 一种合成苯丙炔酸的体相催化剂及其制备和工艺
CN113117726B (zh) * 2019-12-31 2023-04-07 中国石油化工股份有限公司 一种合成苯丙炔酸的成型催化剂及其制备和应用
CA3181051A1 (en) * 2020-06-09 2021-12-16 Nova Chemicals Corporation Forming acetic acid by the selective oxidation of methane
EP4001250A1 (en) * 2020-11-18 2022-05-25 B. Braun Surgical, S.A. Process for producing functionalized organic molecules and a use thereof
CN115806479A (zh) * 2022-11-18 2023-03-17 南京工业大学 一种转化ch4和co2直接制乙酸的方法

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5659077A (en) * 1996-03-22 1997-08-19 Natural Resources Canada Production of acetic acid from methane

Also Published As

Publication number Publication date
YU71100A (sh) 2002-10-18
NO20005764D0 (no) 2000-11-14
NO20005764L (no) 2001-01-15
CN1307554A (zh) 2001-08-08
BR9911058A (pt) 2001-10-30
AU3992999A (en) 1999-12-06
ID28542A (id) 2001-05-31
KR20010071265A (ko) 2001-07-28
EP1080063A1 (en) 2001-03-07
JP2002515472A (ja) 2002-05-28
WO1999059952A1 (en) 1999-11-25

Similar Documents

Publication Publication Date Title
Lee et al. Methyl formate as a new building block in C1 chemistry
US6380444B1 (en) Process for the catalytic oxidation of hydrocarbons
CA2332765A1 (en) Method of preparing alkyl carboxylic acids by carboxylation of lower alkanes methane
US20100004494A1 (en) Conversion of methane into c3˜c13 hydrocarbons
TW413674B (en) Process for the preparation of acetic acid
EP2072488A1 (en) Process for the conversion of hydrocarbon to ethanol
US4175115A (en) Process for the production of synthesis gas by the catalyzed decomposition of methanol
EP2072487A1 (en) Process for the conversion of hydrocarbons to ethanol
US20120203035A1 (en) Hydrocarbon selective oxidation with heterogenous gold catalysts
WO1996018573A1 (en) Process for producing hydrogen and carbon oxides from dimethyl ether
EP0013008B1 (en) Process for producing alcohols
Beguin et al. Hydrocondensation of CO2: II. Reaction of carbon dioxide and carbon monoxide with [HCuPPh3] 6
US4386009A (en) Method and system for ethanol production
CN115430418A (zh) 一种催化剂及其制备方法及应用该催化剂制备乙酸的方法
Wang et al. The synthesis of acetic acid from methane via oxidative bromination, carbonylation, and hydrolysis
AU2010265170A1 (en) Process for the preparation of hydrocarbons from synthesis gas
CA2249310C (en) Production of acetic acid from methane
JPS593450B2 (ja) アルコ−ルの製造方法
JPH0470245B2 (zh)
JPH0121138B2 (zh)
JPS6036431A (ja) エタノールおよび／または酢酸エチルの製造方法
Ekstrom et al. The reactions of cobalt surface carbides with water and their implications for the mechanism of the Fischer-Tropsch reaction
Nelson et al. Activation of Methane under Mild Conditions
KR920001987B1 (ko) 재철부생가스를 이용한 초산제조 공정
JPS624373B2 (zh)

Legal Events

Date Code Title Description
FZDE Dead