CA2317395A1 - Production d'hydrogene par le craquage direct d'hydrocarbures - Google Patents

Production d'hydrogene par le craquage direct d'hydrocarbures Download PDF

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Publication number
CA2317395A1
CA2317395A1 CA002317395A CA2317395A CA2317395A1 CA 2317395 A1 CA2317395 A1 CA 2317395A1 CA 002317395 A CA002317395 A CA 002317395A CA 2317395 A CA2317395 A CA 2317395A CA 2317395 A1 CA2317395 A1 CA 2317395A1
Authority
CA
Canada
Prior art keywords
catalyst
nickel
carbon
hydrogen
methane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002317395A
Other languages
English (en)
Inventor
Cicero A. Bernales
Michael D. Amiridis
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Niagara Mohawk Power Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Niagara Mohawk Power Corp filed Critical Niagara Mohawk Power Corp
Publication of CA2317395A1 publication Critical patent/CA2317395A1/fr
Abandoned legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/26—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0266—Processes for making hydrogen or synthesis gas containing a decomposition step
    • C01B2203/0277—Processes for making hydrogen or synthesis gas containing a decomposition step containing a catalytic decomposition step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1076—Copper or zinc-based catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/84—Energy production
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Nanotechnology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Thermal Sciences (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Catalysts (AREA)

Abstract

Le procédé faisant l'objet de cette invention, qui sert à produire de l'hydrogène sensiblement pur, consiste à mettre en contact un flux d'hydrocarbure gazeux avec un catalyseur à teneur en nickel ou en cuivre-nickel à une température comprise entre environ 400 et 900 ·C. On obtient ainsi la conversion de l'hydrocarbure gazeux en hydrogène sensiblement pur, ce procédé étant prolongé jusqu'à ce que le catalyseur soit désactivé en raison du dépôt de carbone sur ledit catalyseur. Le catalyseur ainsi désactivé peut être régénéré par oxydation dans de l'air ou par gazéification à la vapeur du carbone déposé. Le carbone déposé sur le catalyseur a également une utilité séparée dans des applications électrochimiques et de stockage de carburant et il peut être récupéré pour un usage ultérieur.
CA002317395A 1998-02-24 1999-02-19 Production d'hydrogene par le craquage direct d'hydrocarbures Abandoned CA2317395A1 (fr)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US7581998P 1998-02-24 1998-02-24
US60/075,819 1998-02-24
US23186399A 1999-01-14 1999-01-14
US09/231,863 1999-01-14
PCT/US1999/003556 WO1999043608A1 (fr) 1998-02-24 1999-02-19 Production d'hydrogene par le craquage direct d'hydrocarbures

Publications (1)

Publication Number Publication Date
CA2317395A1 true CA2317395A1 (fr) 1999-09-02

Family

ID=26757315

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002317395A Abandoned CA2317395A1 (fr) 1998-02-24 1999-02-19 Production d'hydrogene par le craquage direct d'hydrocarbures

Country Status (5)

Country Link
EP (1) EP1060123A1 (fr)
CN (1) CN1291165A (fr)
AU (1) AU2687399A (fr)
CA (1) CA2317395A1 (fr)
WO (1) WO1999043608A1 (fr)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITMI20010138A1 (it) * 2001-01-26 2002-07-26 Lentek S P A Produzione di idrogeno da metano ed impianto utilizzato in tale procedimento
CN100439238C (zh) * 2005-12-14 2008-12-03 微宏科技（湖州）有限公司 金属镁及其掺杂其他金属的混合物催化分解碳氢化合物制氢
CN102274704B (zh) * 2010-06-11 2013-07-17 中国石油化工股份有限公司 甲醇制烯烃失活催化剂的汽提方法
CN104185604A (zh) * 2012-01-23 2014-12-03 阿卜杜拉国王科技大学 氢气制备
CN102583242B (zh) * 2012-03-09 2014-02-05 大连理工大学 一种催化裂解甲烷制备氢气的方法
CN106865498B (zh) * 2017-03-14 2019-05-21 大连理工大学 一种以炭材料为催化剂制备氢气和纤维碳的方法
US20200182405A1 (en) 2017-08-10 2020-06-11 L2 Consultancy B.V. Refueling station for supplying energy carriers to vehicles
NL2019407B1 (en) * 2017-08-10 2019-02-21 L2 Consultancy B V Refueling station for supplying energy carriers to vehicles
JP2019182733A (ja) * 2018-04-01 2019-10-24 株式会社伊原工業 水素生成装置、固体生成物の分離方法、固体生成物の排出回収システムおよびニッケル系金属構造体の製造方法
CN110342462A (zh) * 2019-08-27 2019-10-18 深圳市中科纳米科技有限公司 一种烃类气体无碳排放制氢的方法
US11434132B2 (en) 2019-09-12 2022-09-06 Saudi Arabian Oil Company Process and means for decomposition of sour gas and hydrogen generation
CN111068688A (zh) * 2019-12-19 2020-04-28 南京理工大学 一种以铁的废弃物为催化剂催化甲烷裂解的方法
CN111170764B (zh) * 2019-12-31 2021-11-23 娄底市安地亚斯电子陶瓷有限公司 一种湿氢系统及其工作方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7811278A (nl) * 1978-11-15 1980-05-19 Stamicarbon Werkwijze voor het verwerken van stikstof bevattend aardgas.
US4435376A (en) * 1982-03-26 1984-03-06 Phillips Petroleum Company Fibrous carbon production
DD287015A5 (de) * 1989-08-11 1991-02-14 Leipzig Chemieanlagen Verfahren zur herstellung von reinwasserstoff und russ aus methan
JP3211666B2 (ja) * 1996-06-25 2001-09-25 トヨタ自動車株式会社 水素とカーボンブラックの同時製造方法

Also Published As

Publication number Publication date
EP1060123A1 (fr) 2000-12-20
AU2687399A (en) 1999-09-15
WO1999043608A1 (fr) 1999-09-02
CN1291165A (zh) 2001-04-11

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Date Code Title Description
FZDE Discontinued