CA2214363C - Method of producing synthetic silicates and use thereof in glass production - Google Patents
Method of producing synthetic silicates and use thereof in glass production Download PDFInfo
- Publication number
- CA2214363C CA2214363C CA002214363A CA2214363A CA2214363C CA 2214363 C CA2214363 C CA 2214363C CA 002214363 A CA002214363 A CA 002214363A CA 2214363 A CA2214363 A CA 2214363A CA 2214363 C CA2214363 C CA 2214363C
- Authority
- CA
- Canada
- Prior art keywords
- calcium
- cndot
- silicate
- source
- glass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims abstract description 38
- 239000011521 glass Substances 0.000 title abstract description 47
- 238000004519 manufacturing process Methods 0.000 title description 11
- 150000004760 silicates Chemical class 0.000 title description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 61
- 239000000463 material Substances 0.000 claims abstract description 50
- 239000002243 precursor Substances 0.000 claims abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000000378 calcium silicate Substances 0.000 claims abstract description 27
- 229910052918 calcium silicate Inorganic materials 0.000 claims abstract description 27
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 15
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract description 15
- 239000011575 calcium Substances 0.000 claims description 49
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 47
- 229910052791 calcium Inorganic materials 0.000 claims description 47
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 29
- 239000000377 silicon dioxide Substances 0.000 claims description 26
- 229910052681 coesite Inorganic materials 0.000 claims description 12
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 12
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 12
- 229910052682 stishovite Inorganic materials 0.000 claims description 12
- 229910052905 tridymite Inorganic materials 0.000 claims description 12
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 11
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 11
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 11
- 239000004571 lime Substances 0.000 claims description 11
- 239000006060 molten glass Substances 0.000 claims description 10
- 235000012239 silicon dioxide Nutrition 0.000 claims description 10
- YLUIKWVQCKSMCF-UHFFFAOYSA-N calcium;magnesium;oxygen(2-) Chemical compound [O-2].[O-2].[Mg+2].[Ca+2] YLUIKWVQCKSMCF-UHFFFAOYSA-N 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 239000010459 dolomite Substances 0.000 claims description 5
- 229910000514 dolomite Inorganic materials 0.000 claims description 5
- 239000000395 magnesium oxide Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 2
- 235000012255 calcium oxide Nutrition 0.000 abstract description 11
- 238000006243 chemical reaction Methods 0.000 abstract description 8
- 230000015572 biosynthetic process Effects 0.000 abstract description 7
- 235000012245 magnesium oxide Nutrition 0.000 abstract description 6
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical class [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 abstract description 5
- 238000005816 glass manufacturing process Methods 0.000 abstract description 4
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical class [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract description 4
- 235000019351 sodium silicates Nutrition 0.000 abstract description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 26
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 19
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 12
- 239000011734 sodium Substances 0.000 description 12
- 239000000203 mixture Substances 0.000 description 11
- 238000002156 mixing Methods 0.000 description 9
- 239000002002 slurry Substances 0.000 description 9
- 235000017550 sodium carbonate Nutrition 0.000 description 9
- 229910000029 sodium carbonate Inorganic materials 0.000 description 9
- 239000000292 calcium oxide Substances 0.000 description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
- 239000003607 modifier Substances 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- 101100348017 Drosophila melanogaster Nazo gene Proteins 0.000 description 6
- 235000019738 Limestone Nutrition 0.000 description 6
- 239000006028 limestone Substances 0.000 description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- DEPUMLCRMAUJIS-UHFFFAOYSA-N dicalcium;disodium;dioxido(oxo)silane Chemical compound [Na+].[Na+].[Ca+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O DEPUMLCRMAUJIS-UHFFFAOYSA-N 0.000 description 3
- 239000000543 intermediate Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 229910052814 silicon oxide Inorganic materials 0.000 description 3
- 229910021532 Calcite Inorganic materials 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- -1 cleaners Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000006066 glass batch Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- NEMFQSKAPLGFIP-UHFFFAOYSA-N magnesiosodium Chemical compound [Na].[Mg] NEMFQSKAPLGFIP-UHFFFAOYSA-N 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000000391 magnesium silicate Substances 0.000 description 2
- 229910052919 magnesium silicate Inorganic materials 0.000 description 2
- 235000019792 magnesium silicate Nutrition 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000005361 soda-lime glass Substances 0.000 description 2
- 229910001948 sodium oxide Inorganic materials 0.000 description 2
- 241001633942 Dais Species 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229910017625 MgSiO Inorganic materials 0.000 description 1
- 241000872931 Myoporum sandwicense Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 239000006105 batch ingredient Substances 0.000 description 1
- JZKFIPKXQBZXMW-UHFFFAOYSA-L beryllium difluoride Chemical compound F[Be]F JZKFIPKXQBZXMW-UHFFFAOYSA-L 0.000 description 1
- 229910001633 beryllium fluoride Inorganic materials 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- NWXHSRDXUJENGJ-UHFFFAOYSA-N calcium;magnesium;dioxido(oxo)silane Chemical compound [Mg+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O NWXHSRDXUJENGJ-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 229910052637 diopside Inorganic materials 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000035876 healing Effects 0.000 description 1
- 239000004572 hydraulic lime Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 150000004686 pentahydrates Chemical class 0.000 description 1
- CZAKJJUNKNPTTO-AJFJRRQVSA-N precursor Z hydrate Chemical compound C([C@H]1O2)OP(O)(=O)O[C@@H]1C(O)(O)[C@H]1[C@@H]2NC(N=C(NC2=O)N)=C2N1 CZAKJJUNKNPTTO-AJFJRRQVSA-N 0.000 description 1
- 229910052705 radium Inorganic materials 0.000 description 1
- HCWPIIXVSYCSAN-UHFFFAOYSA-N radium atom Chemical compound [Ra] HCWPIIXVSYCSAN-UHFFFAOYSA-N 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910001720 Åkermanite Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/02—Pretreated ingredients
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/24—Alkaline-earth metal silicates
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/078—Glass compositions containing silica with 40% to 90% silica, by weight containing an oxide of a divalent metal, e.g. an oxide of zinc
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/11—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Glass Compositions (AREA)
- Glass Melting And Manufacturing (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US70824696A | 1996-09-03 | 1996-09-03 | |
| US08/708,246 | 1996-09-03 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2214363A1 CA2214363A1 (en) | 1998-03-03 |
| CA2214363C true CA2214363C (en) | 2005-11-08 |
Family
ID=24845001
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002214363A Expired - Fee Related CA2214363C (en) | 1996-09-03 | 1997-09-02 | Method of producing synthetic silicates and use thereof in glass production |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0826630B1 (enExample) |
| JP (2) | JP3246722B2 (enExample) |
| KR (1) | KR100351232B1 (enExample) |
| BR (1) | BR9704592A (enExample) |
| CA (1) | CA2214363C (enExample) |
| DE (2) | DE69708789T2 (enExample) |
| ES (1) | ES2116958T3 (enExample) |
| IL (1) | IL121641A0 (enExample) |
| PL (1) | PL188364B1 (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6287378B1 (en) * | 1996-09-03 | 2001-09-11 | Minerals Technologies, Inc. | Method of producing synthetic silicates and use thereof in glass production |
| US6211103B1 (en) | 1999-10-12 | 2001-04-03 | Minerals Technologies Inc. | Synthetic silicate pellet compositions |
| US6420289B1 (en) | 1999-10-12 | 2002-07-16 | Minerals Technologies Inc. | Synthetic silicate pellet composition and methods of making and using thereof |
| US6569793B2 (en) * | 2001-02-22 | 2003-05-27 | Specialty Minerals (Michigan) Inc. | Fluidized reaction of synthetic silicates |
| WO2003057636A1 (en) * | 2001-12-27 | 2003-07-17 | Specialty Minerals (Michigan) Inc. | Method of manufacturing glass and compositions therefore |
| AU2007267075A1 (en) * | 2006-06-01 | 2007-12-06 | Agc Flat Glass Europe Sa | Lime glass batch composition |
| US20070287624A1 (en) * | 2006-06-13 | 2007-12-13 | Jon Frederick Bauer | Method for preparing glass |
| JP5972050B2 (ja) * | 2012-05-25 | 2016-08-17 | 太平洋セメント株式会社 | リン回収材の製造方法 |
| US9890072B2 (en) | 2015-04-01 | 2018-02-13 | Owens-Brockway Glass Container Inc. | Glass precursor gel |
| US10364176B1 (en) | 2016-10-03 | 2019-07-30 | Owens-Brockway Glass Container Inc. | Glass precursor gel and methods to treat with microwave energy |
| US10479717B1 (en) | 2016-10-03 | 2019-11-19 | Owens-Brockway Glass Container Inc. | Glass foam |
| US10427970B1 (en) | 2016-10-03 | 2019-10-01 | Owens-Brockway Glass Container Inc. | Glass coatings and methods to deposit same |
| JP2025032941A (ja) * | 2023-08-28 | 2025-03-12 | 日本山村硝子株式会社 | カーボンニュートラル生成物、フリント調ガラス、及びガラスの製造方法 |
| CN117945655A (zh) * | 2024-01-10 | 2024-04-30 | 中建材玻璃新材料研究院集团有限公司 | 一种减碳化玻璃配方及其制备方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU340257A1 (ru) * | 1970-07-06 | 1983-05-07 | Научно-Исследовательский Институт Камня И Силикатов | Способ варки силикатного стекла |
| SU644731A1 (ru) * | 1974-05-24 | 1979-01-30 | Институт общей и неорганической химии АН Армянской ССР | Способ получени синтетического диопсида |
| DD121095A1 (enExample) * | 1975-04-18 | 1976-07-12 | ||
| DD141015A1 (de) * | 1978-08-17 | 1980-04-09 | Nikolaus Koschwitz | Verfahren und vorrichtung zur intensivierung des schmelzprozesses fuer alkali-erdalkali-silikatglas |
| DD141512A1 (de) * | 1979-02-02 | 1980-05-07 | Nikolaus Koschwitz | Verfahren zur herstellung silikatischer komplexrohstoffe |
| SU823285A1 (ru) * | 1979-03-07 | 1981-04-23 | Ереванский Отдел Неорганическихматериалов Всесоюзного Ордена Трудовогокрасного Знамени Научно-Исследовательскогоинститута Химических Реактивови Особо Чистых Химических Веществ | Способ получени натрий-кальциевогоСилиКАТА |
| JPS55149122A (en) * | 1979-05-09 | 1980-11-20 | Tokuyama Soda Co Ltd | Manufacture of calcium sodium silicate hydrate |
| SU981217A1 (ru) * | 1980-07-23 | 1982-12-15 | Институт общей и неорганической химии АН АрмССР | Способ получени силикатно-кальциевого продукта |
| DD159987A1 (de) * | 1981-06-26 | 1983-04-20 | Dietmar Petzold | Verfahren zur herstellung von verbessertem glasrohstoffgemenge |
| GB8728892D0 (en) * | 1987-12-10 | 1988-01-27 | Pilkington Plc | Producing molten glass |
-
1997
- 1997-08-27 IL IL12164197A patent/IL121641A0/xx unknown
- 1997-09-02 DE DE69708789T patent/DE69708789T2/de not_active Expired - Lifetime
- 1997-09-02 ES ES97306754T patent/ES2116958T3/es not_active Expired - Lifetime
- 1997-09-02 DE DE0826630T patent/DE826630T1/de active Pending
- 1997-09-02 BR BR9704592A patent/BR9704592A/pt not_active IP Right Cessation
- 1997-09-02 KR KR1019970045575A patent/KR100351232B1/ko not_active Expired - Fee Related
- 1997-09-02 CA CA002214363A patent/CA2214363C/en not_active Expired - Fee Related
- 1997-09-02 EP EP97306754A patent/EP0826630B1/en not_active Expired - Lifetime
- 1997-09-03 PL PL97321920A patent/PL188364B1/pl not_active IP Right Cessation
- 1997-09-03 JP JP23816497A patent/JP3246722B2/ja not_active Expired - Fee Related
-
2001
- 2001-09-25 JP JP2001292049A patent/JP2002128527A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JP3246722B2 (ja) | 2002-01-15 |
| DE69708789D1 (de) | 2002-01-17 |
| KR19980024286A (ko) | 1998-07-06 |
| DE69708789T2 (de) | 2002-07-04 |
| EP0826630A2 (en) | 1998-03-04 |
| PL321920A1 (en) | 1998-03-16 |
| JPH10218638A (ja) | 1998-08-18 |
| EP0826630B1 (en) | 2001-12-05 |
| IL121641A0 (en) | 1998-02-08 |
| DE826630T1 (de) | 1998-09-24 |
| PL188364B1 (pl) | 2005-01-31 |
| KR100351232B1 (ko) | 2002-12-16 |
| BR9704592A (pt) | 1998-11-03 |
| JP2002128527A (ja) | 2002-05-09 |
| EP0826630A3 (en) | 1998-05-06 |
| CA2214363A1 (en) | 1998-03-03 |
| ES2116958T3 (es) | 2002-05-16 |
| ES2116958T1 (es) | 1998-08-01 |
| MX9706682A (es) | 1998-07-31 |
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