CA2189035A1 - Hydrazones de perhaloalcoxybenzenophenone et leur utilisation en tant que pesticides - Google Patents

Hydrazones de perhaloalcoxybenzenophenone et leur utilisation en tant que pesticides

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Publication number
CA2189035A1
CA2189035A1 CA002189035A CA2189035A CA2189035A1 CA 2189035 A1 CA2189035 A1 CA 2189035A1 CA 002189035 A CA002189035 A CA 002189035A CA 2189035 A CA2189035 A CA 2189035A CA 2189035 A1 CA2189035 A1 CA 2189035A1
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CA
Canada
Prior art keywords
formula
c8alkyl
compound
halo
isomer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
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CA002189035A
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English (en)
Inventor
Alfons Pascual
Roger Graham Hall
Dieter Durr
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Novartis AG
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Individual
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Publication of CA2189035A1 publication Critical patent/CA2189035A1/fr
Abandoned legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/86—Hydrazides; Thio or imino analogues thereof
    • C07D213/87—Hydrazides; Thio or imino analogues thereof in position 3
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
    • A01N35/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical at least one of the bonds to hetero atoms is to nitrogen
    • A01N35/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical at least one of the bonds to hetero atoms is to nitrogen containing a carbon-to-nitrogen double bond
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/28—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/52—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing groups, e.g. carboxylic acid amidines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04—Sulfonic acids; Derivatives thereof
    • A01N41/06—Sulfonic acid amides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/10—Sulfones; Sulfoxides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/10—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with sulfur as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/12—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings condensed with a carbocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/72—Hydrazones
    • C07C251/86—Hydrazones having doubly-bound carbon atoms of hydrazone groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/72—Hydrazones
    • C07C251/88—Hydrazones having also the other nitrogen atom doubly-bound to a carbon atom, e.g. azines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C311/01—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms
    • C07C311/02—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C311/03—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton having the nitrogen atoms of the sulfonamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C311/05—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton having the nitrogen atoms of the sulfonamide groups bound to hydrogen atoms or to acyclic carbon atoms to acyclic carbon atoms of hydrocarbon radicals substituted by nitrogen atoms, not being part of nitro or nitroso groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/26—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D333/38—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/50—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
    • C07D333/52—Benzo[b]thiophenes; Hydrogenated benzo[b]thiophenes
    • C07D333/62—Benzo[b]thiophenes; Hydrogenated benzo[b]thiophenes with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to carbon atoms of the hetero ring
    • C07D333/68—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
    • C07D333/70—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen attached in position 2

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Environmental Sciences (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

Composés de la formule (I), ainsi que, si nécessaire, leurs isomères E/Z et leurs tautomères, dans chaque cas sous forme libre ou sous forme de sel. Dans cette formule, X représente (a) ou (b), n vaut 0, 1, 2, 3, 4 ou 5, et, dans le cas où il est supérieur à 1, les radicaux R¿2? sont identiques ou différents; o vaut 0, 1, 2, 3 ou 4, et dans le cas où il est supérieur à 1, les radicaux R¿3? sont identiques ou différents; R¿1? représente perhalo-alcoxy C¿1?-C¿4?; R¿2? représente halogène, alcoyle C¿1?-C¿8?, halo-alcoyle C¿1?-C¿8?, alcoxy C¿1?-C¿8?, halo-alcoxy C¿1?-C¿8?, alcoylthio C¿1?-C¿8?, halo-alcoylthio C¿1?-C¿8?, alcoylsulfynyle C¿1?-C¿8?, halo-alcoylsulfynyle C¿1?-C¿8?, alcoylsulfonyle C¿1?-C¿8?, halo-alcoylsulfonyle C¿1?-C¿8?, CN ou phényle; R¿3? représente halogène, alcoyle C¿1?-C¿8?, halo-alcoyle C¿1?-C¿8? ou halo-alcoxy C¿1?-C¿8?; R¿4? représente H, halogène, alcoyle C¿1?-C¿8?, cycloalcoyle C¿3?-C¿6?, halo-alcoyle C¿1?-C¿8?, alcoxy C¿1?-C¿8?, alcoxy C¿1?-C¿8?-alcoyle C¿1?-C¿8?, alcoxy C¿1?-C¿8?-alcoxy C¿1?-C¿8?, alcoylthio C¿1?-C¿8?, ou NR¿8?R¿9?; R¿5? représente alcoyle C¿1?-C¿8?, NR¿10?R¿11?, OR¿20?, SR¿20? ou SO¿2?R¿20?; R¿6? représente H, alcoyle C¿1?-C¿8?, cycloalcoyle C¿3?-C¿6?, halo-alcoyle C¿1?-C¿8?, alcényle C¿1?-C¿8?, alcynyle C¿1?-C¿8?, acyle C¿1?-C¿8? ou phényle; R¿7? représente H, un groupe non substitué ou substitué parmi alcoyle C¿1?-C¿8?, cycloalcoyle C¿3?-C¿6?, cycloalcoyle C¿3?-C¿6?-alcoyle C¿1?-C¿8?, alcényle C¿1?-C¿8?, alcynyle C¿1?-C¿8?, cycloalcényle C¿3?-C¿6?, cycloalcényle C¿3?-C¿6?-alcoyle C¿1?-C¿8? ou cycloalcoyle C¿3?-C¿6?-alcényle C¿1?-C¿8?, les substituants pouvant être choisis dans le groupe consistant en halogène, alcoyle C¿1?-C¿8?, halo-alcoyle C¿1?-C¿8?, alcoxy C¿1?-C¿8?, halo-alcoxy C¿1?-C¿8?, alcoyle C¿1?-C¿8?-S(O)¿p?, p pouvant valoir 0, 1 ou 2, alcoxycarbonyle C¿1?-C¿8?, di(alcoyle C¿1?-C¿8?)amino et alcanoyloxy C¿1?-C¿8?; un groupe phényle ou hétéroaryle non substitué ou substitué, les substituants pouvant être choisis dans le groupe consistant en alcoyle C¿1?-C¿6? et halogène; alcoxy C¿1?-C¿8?, NR¿16?R¿17?, COOR¿6? ou SR¿6?; R¿8? et R¿9? représentent indépendamment l'un de l'autre H, alcoyle C¿1?-C¿8? ou OH; R¿10? représente H, alcoyle C¿1?-C¿8?, cycloalcoyle C¿3?-C¿6?, halo-alcoyle C¿1?-C¿8?, halo-alcoxy C¿1?-C¿8?-alcoyle C¿1?-C¿8?, phényle, OR¿12?, S(O)¿m?R¿13?, m valant 0, 1 ou 2, ou NR¿14?R¿15?; R¿11? représente H, alcoyle C¿1?-C¿8?, cycloalcoyle C¿3?-C¿6?, halo-alcoyle C¿1?-C¿8?, alcoxy C¿1?-C¿8?-alcoyle C¿1?-C¿8?, allyle, alcoylallyle C¿1?-C¿8?, haloallyle ou propargyle; R¿12? représente H, alcoyle C¿1?-C¿8?, halo-alcoyle C¿1?-C¿8?, alcoxy C¿1?-C¿8?-alcoyle C¿1?-C¿8?, cycloalcoyle C¿3?-C¿6?, alcényle C¿2?-C¿8?, halo-alcényle C¿2?-C¿8? ou propargyle; R¿13? représente H, alcoyle C¿1?-C¿8?, halogène-alcoyle C¿1?-C¿8?, phényle ou NR¿14?R¿15?; R¿14? et R¿15? représentent indépendamment l'un de l'autre H, alcoyle C¿1?-C¿8?, halo-alcoyle C¿1?-C¿8?, phényle, alcoylamido C¿1?-C¿8?, di(alcoyle C¿1?-C¿8?)amido ou NH¿2?; R¿16? et R¿17? représentent indépendamment l'un de l'autre H, alcoyle C¿1?-C¿8?, halo-alcoyle C¿1?-C¿8?, alcényle C¿2?-C¿8?, alcoxy C¿1?-C¿8? ou NH¿2?; R¿18? représente S(O)¿m?R¿19?, m valant 0, 1 ou 2, NO¿2? ou CN; R¿19? représente alcoyle C¿1?-C¿8?, halo-alcoyle C¿1?-C¿8?, cycloalcoyle C¿3?-C¿6?, phényle, benzyle ou NR¿14?R¿15?; R¿20? représente alcoyle C¿1?-C¿8?, halo-alcoyle C¿1?-C¿8?, ou cycloalcoyle C¿3?-C¿6?; Y représente O, S NR¿18? ou CHC(O)R¿21?; et R¿21? représente H, alcoyle C¿1?-C¿8?, halo-alcoyle C¿1?-C¿8?, alcoxy C¿1?-C¿8? ou phényle. On peut utiliser ces composés en tant que principes actifs agrochimiques et on peut les préparer d'une manière connue en soi.
CA002189035A 1994-04-29 1995-04-15 Hydrazones de perhaloalcoxybenzenophenone et leur utilisation en tant que pesticides Abandoned CA2189035A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH1344/94-6 1994-04-29
CH134494 1994-04-29

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Publication Number Publication Date
CA2189035A1 true CA2189035A1 (fr) 1995-11-09

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CA002189035A Abandoned CA2189035A1 (fr) 1994-04-29 1995-04-15 Hydrazones de perhaloalcoxybenzenophenone et leur utilisation en tant que pesticides

Country Status (12)

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EP (1) EP0757671A1 (fr)
JP (1) JPH10504799A (fr)
CN (1) CN1147246A (fr)
AU (1) AU2446595A (fr)
BR (1) BR9501849A (fr)
CA (1) CA2189035A1 (fr)
CZ (1) CZ313996A3 (fr)
HU (1) HUT75200A (fr)
IL (1) IL113435A0 (fr)
SK (1) SK138396A3 (fr)
WO (1) WO1995029889A1 (fr)
ZA (1) ZA953446B (fr)

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US3732307A (en) * 1970-09-24 1973-05-08 Du Pont Benzophenone hydrazones containing perfluoroalkyl,perfluoroalkoxy,and perfluoroalkylthio substituents
DE3070271D1 (en) * 1979-08-31 1985-04-18 Fbc Ltd Substituted benzophenone hydrazones, pesticidal compositions containing them and method of combating pests
IL105310A0 (en) * 1992-04-16 1993-08-18 Ciba Geigy Ag Benzophenone derivatives
TW268881B (fr) * 1992-07-07 1996-01-21 Ciba Geigy Ag

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EP0757671A1 (fr) 1997-02-12
AU2446595A (en) 1995-11-29
CZ313996A3 (en) 1997-02-12
WO1995029889A1 (fr) 1995-11-09
MX9605193A (es) 1997-09-30
BR9501849A (pt) 1996-04-09
IL113435A0 (en) 1995-07-31
JPH10504799A (ja) 1998-05-12
CN1147246A (zh) 1997-04-09
HU9602972D0 (en) 1997-01-28
ZA953446B (en) 1995-10-30
HUT75200A (en) 1997-04-28
SK138396A3 (en) 1997-05-07

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