CA2059281A1 - Process for purification of exhaust gases, in particular from waste incinerators - Google Patents
Process for purification of exhaust gases, in particular from waste incineratorsInfo
- Publication number
- CA2059281A1 CA2059281A1 CA002059281A CA2059281A CA2059281A1 CA 2059281 A1 CA2059281 A1 CA 2059281A1 CA 002059281 A CA002059281 A CA 002059281A CA 2059281 A CA2059281 A CA 2059281A CA 2059281 A1 CA2059281 A1 CA 2059281A1
- Authority
- CA
- Canada
- Prior art keywords
- adsorber
- process according
- gas
- exhaust gas
- regeneration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000034 method Methods 0.000 title claims abstract description 73
- 230000008569 process Effects 0.000 title claims abstract description 62
- 238000000746 purification Methods 0.000 title claims abstract description 19
- 239000007789 gas Substances 0.000 title claims description 130
- 239000002699 waste material Substances 0.000 title abstract description 9
- 239000000571 coke Substances 0.000 claims abstract description 76
- 238000001179 sorption measurement Methods 0.000 claims abstract description 65
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 45
- 230000008929 regeneration Effects 0.000 claims abstract description 39
- 238000011069 regeneration method Methods 0.000 claims abstract description 39
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 16
- 239000011780 sodium chloride Substances 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims description 47
- 150000002240 furans Chemical class 0.000 claims description 31
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 29
- 150000002013 dioxins Chemical class 0.000 claims description 29
- 239000000428 dust Substances 0.000 claims description 26
- 229910001385 heavy metal Inorganic materials 0.000 claims description 23
- 229910000069 nitrogen hydride Inorganic materials 0.000 claims description 11
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 9
- 239000012717 electrostatic precipitator Substances 0.000 claims description 9
- 239000002341 toxic gas Substances 0.000 claims description 7
- 238000011144 upstream manufacturing Methods 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000011261 inert gas Substances 0.000 claims description 4
- 238000010791 quenching Methods 0.000 claims description 4
- 229910021529 ammonia Inorganic materials 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 238000003421 catalytic decomposition reaction Methods 0.000 claims 1
- 239000003344 environmental pollutant Substances 0.000 abstract description 41
- 231100000719 pollutant Toxicity 0.000 abstract description 41
- 230000001143 conditioned effect Effects 0.000 abstract 1
- 229960000443 hydrochloric acid Drugs 0.000 abstract 1
- 235000011167 hydrochloric acid Nutrition 0.000 abstract 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 18
- 229910052753 mercury Inorganic materials 0.000 description 18
- 229940041669 mercury Drugs 0.000 description 18
- 239000000047 product Substances 0.000 description 14
- 239000003546 flue gas Substances 0.000 description 11
- 238000000926 separation method Methods 0.000 description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 239000007795 chemical reaction product Substances 0.000 description 8
- 239000002737 fuel gas Substances 0.000 description 8
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 7
- 238000003795 desorption Methods 0.000 description 7
- 230000008018 melting Effects 0.000 description 7
- 238000002844 melting Methods 0.000 description 7
- 238000002485 combustion reaction Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000011084 recovery Methods 0.000 description 6
- OGBQILNBLMPPDP-UHFFFAOYSA-N 2,3,4,7,8-Pentachlorodibenzofuran Chemical class O1C2=C(Cl)C(Cl)=C(Cl)C=C2C2=C1C=C(Cl)C(Cl)=C2 OGBQILNBLMPPDP-UHFFFAOYSA-N 0.000 description 5
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 235000011941 Tilia x europaea Nutrition 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 239000004571 lime Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- 238000003723 Smelting Methods 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 235000011149 sulphuric acid Nutrition 0.000 description 3
- 238000005200 wet scrubbing Methods 0.000 description 3
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- XUKUURHRXDUEBC-KAYWLYCHSA-N Atorvastatin Chemical compound C=1C=CC=CC=1C1=C(C=2C=CC(F)=CC=2)N(CC[C@@H](O)C[C@@H](O)CC(O)=O)C(C(C)C)=C1C(=O)NC1=CC=CC=C1 XUKUURHRXDUEBC-KAYWLYCHSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 235000008645 Chenopodium bonus henricus Nutrition 0.000 description 1
- 244000138502 Chenopodium bonus henricus Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- -1 S03 forms ammonium salts Chemical class 0.000 description 1
- 108091006629 SLC13A2 Proteins 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000002802 bituminous coal Substances 0.000 description 1
- 238000009530 blood pressure measurement Methods 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 235000011148 calcium chloride Nutrition 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100001234 toxic pollutant Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/75—Multi-step processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/404—Nitrogen oxides other than dinitrogen oxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/60—Heavy metals or heavy metal compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/60—Heavy metals or heavy metal compounds
- B01D2257/602—Mercury or mercury compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Treating Waste Gases (AREA)
- Incineration Of Waste (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP4012887.3 | 1990-04-23 | ||
DE4012887A DE4012887A1 (de) | 1990-04-23 | 1990-04-23 | Verfahren zur reinigung von abgasen, insbesondere aus abfallverbrennungsanlagen |
Publications (1)
Publication Number | Publication Date |
---|---|
CA2059281A1 true CA2059281A1 (en) | 1991-10-24 |
Family
ID=6404898
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002059281A Abandoned CA2059281A1 (en) | 1990-04-23 | 1991-04-13 | Process for purification of exhaust gases, in particular from waste incinerators |
Country Status (8)
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9242860B2 (en) | 2007-04-27 | 2016-01-26 | Bayer Materialscience Ag | Process for the oxidation of a gas mixture containing hydrogen chloride |
CN108219857A (zh) * | 2018-02-02 | 2018-06-29 | 绍兴亮点信息科技有限公司 | 一种焦炉烟尘治理工艺 |
CN109794135A (zh) * | 2019-01-15 | 2019-05-24 | 北京科技大学 | 基于余热利用的烟气多污染物吸附脱除及资源化方法 |
CN109794137A (zh) * | 2019-01-15 | 2019-05-24 | 北京科技大学 | 一种吸附净化并富集回收烟气氮氧化物的方法及系统 |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4120277A1 (de) * | 1991-06-19 | 1992-12-24 | Krupp Polysius Ag | Verfahren und vorrichtung zum reinigen von abgasen aus ofenanlagen |
DE4127075A1 (de) * | 1991-08-16 | 1993-02-18 | Nymic Anstalt | Verfahren zum reinigen von belasteten abgasen von verbrennungsanlagen |
DE4342669A1 (de) * | 1993-12-15 | 1995-06-22 | Bfi Entsorgungstech | Verfahren und Vorrichtung zur Verwertung eines bei einer Vergasung von Kohlenstoff enthaltenden Materialien anfallenden Gases und darin enthaltener Verunreinigungen |
DE4425471A1 (de) * | 1994-07-19 | 1996-01-25 | Fpr Holding Ag | Verfahren zum Reinigen von Abgasen |
DE4431558C2 (de) * | 1994-09-05 | 2002-01-17 | Krupp Uhde Gmbh | Verfahren zur Entfernung von Schadstoffen aus Verbrennungsabgasen |
DE10338752B9 (de) * | 2003-08-23 | 2006-06-29 | Forschungszentrum Karlsruhe Gmbh | Verfahren und Vorrichtung zur Reduzierung von polyhalogenierten Verbindungen in Verbrennungsanlagen |
DE102007020146A1 (de) | 2007-04-26 | 2008-10-30 | Bayer Materialscience Ag | Verfahren zur Reinigung und Oxidation eines Chlorwasserstoff enthaltenden Gases |
CN103611516B (zh) * | 2013-11-26 | 2015-09-02 | 中电投远达环保工程有限公司 | 可连续走料的活性焦烟气脱硫再生装置及其控制方法 |
CN110755999B (zh) * | 2019-11-05 | 2021-02-05 | 山东大学 | 一种全流程流态化活性焦脱汞回收工艺及系统 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3426059A1 (de) * | 1984-07-14 | 1986-01-16 | Hugo Petersen Gesellschaft für verfahrenstechnischen Anlagenbau mbH & Co KG, 6200 Wiesbaden | Verfahren zur abscheidung und beseitigung von organischen schadstoffen, insbesondere von polychlorierten dibenzodioxinen (pcdd) aus rauchgasen |
DE3601917A1 (de) * | 1986-01-23 | 1987-07-30 | Taetzner Wolfgang | Verfahren fuer die reinigung von rauchgasen |
DE3706131A1 (de) * | 1987-02-26 | 1988-09-08 | Rheinische Braunkohlenw Ag | Verfahren zur entfernung von schadstoffen aus rauchgas |
DE3723381A1 (de) * | 1987-07-15 | 1989-01-26 | Krantz H Gmbh & Co | Verfahren zum entfernen von staub und flugasche sowie schwefeloxiden und stickstoffoxiden aus rauchgasen |
DE3844422A1 (de) * | 1988-12-30 | 1990-07-05 | Steag Ag | Verfahren und vorrichtung zum abtrennen unerwuenschter bestandteile aus einem abgas |
DE3919124A1 (de) * | 1989-06-12 | 1990-01-18 | Haji Javad Mehdi Dr Ing | Verfahren zur abscheidung von polyzylkischen kohlenwasserstoffen und schwermetallen aus abgasen |
-
1990
- 1990-04-23 DE DE4012887A patent/DE4012887A1/de active Granted
-
1991
- 1991-04-13 DE DE59108071T patent/DE59108071D1/de not_active Expired - Fee Related
- 1991-04-13 KR KR1019910701880A patent/KR920702632A/ko not_active Withdrawn
- 1991-04-13 AU AU76512/91A patent/AU7651291A/en not_active Abandoned
- 1991-04-13 WO PCT/DE1991/000314 patent/WO1991016122A1/de active IP Right Grant
- 1991-04-13 HU HU914082A patent/HU210398B/hu unknown
- 1991-04-13 CA CA002059281A patent/CA2059281A1/en not_active Abandoned
- 1991-04-13 AT AT91907737T patent/ATE141182T1/de active
- 1991-04-13 EP EP91907737A patent/EP0478744B1/de not_active Expired - Lifetime
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9242860B2 (en) | 2007-04-27 | 2016-01-26 | Bayer Materialscience Ag | Process for the oxidation of a gas mixture containing hydrogen chloride |
CN108219857A (zh) * | 2018-02-02 | 2018-06-29 | 绍兴亮点信息科技有限公司 | 一种焦炉烟尘治理工艺 |
CN108219857B (zh) * | 2018-02-02 | 2021-04-06 | 绍兴亮点信息科技有限公司 | 一种焦炉烟尘治理工艺 |
CN109794135A (zh) * | 2019-01-15 | 2019-05-24 | 北京科技大学 | 基于余热利用的烟气多污染物吸附脱除及资源化方法 |
CN109794137A (zh) * | 2019-01-15 | 2019-05-24 | 北京科技大学 | 一种吸附净化并富集回收烟气氮氧化物的方法及系统 |
CN109794137B (zh) * | 2019-01-15 | 2021-04-16 | 北京科技大学 | 一种吸附净化并富集回收烟气氮氧化物的方法及系统 |
Also Published As
Publication number | Publication date |
---|---|
EP0478744A1 (de) | 1992-04-08 |
ATE141182T1 (de) | 1996-08-15 |
DE59108071D1 (de) | 1996-09-19 |
EP0478744B1 (de) | 1996-08-14 |
KR920702632A (ko) | 1992-10-06 |
WO1991016122A1 (de) | 1991-10-31 |
DE4012887C2 (enrdf_load_stackoverflow) | 1992-07-16 |
HU914082D0 (en) | 1992-03-30 |
DE4012887A1 (de) | 1991-10-31 |
AU7651291A (en) | 1991-11-11 |
HU210398B (en) | 1995-04-28 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FZDE | Discontinued |