CA1288375C - Process for the conversion of heavy hydrocarbon feedstocks characterized by high molecular weight, low reactivity and high metal contents - Google Patents

Process for the conversion of heavy hydrocarbon feedstocks characterized by high molecular weight, low reactivity and high metal contents

Info

Publication number
CA1288375C
CA1288375C CA000518970A CA518970A CA1288375C CA 1288375 C CA1288375 C CA 1288375C CA 000518970 A CA000518970 A CA 000518970A CA 518970 A CA518970 A CA 518970A CA 1288375 C CA1288375 C CA 1288375C
Authority
CA
Canada
Prior art keywords
weight
zone
surface concentration
process according
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CA000518970A
Other languages
English (en)
French (fr)
Inventor
Roberto E. Galiasso
R. Beatriz Arias
Juan Garcia
Humberto Kum
Lino Caprioli
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Petroleos de Venezuela SA
Original Assignee
Petroleos de Venezuela SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Petroleos de Venezuela SA filed Critical Petroleos de Venezuela SA
Application granted granted Critical
Publication of CA1288375C publication Critical patent/CA1288375C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CA000518970A 1985-09-26 1986-09-24 Process for the conversion of heavy hydrocarbon feedstocks characterized by high molecular weight, low reactivity and high metal contents Expired - Lifetime CA1288375C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US780,589 1977-03-27
US06/780,589 US4626340A (en) 1985-09-26 1985-09-26 Process for the conversion of heavy hydrocarbon feedstocks characterized by high molecular weight, low reactivity and high metal contents

Publications (1)

Publication Number Publication Date
CA1288375C true CA1288375C (en) 1991-09-03

Family

ID=25120019

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000518970A Expired - Lifetime CA1288375C (en) 1985-09-26 1986-09-24 Process for the conversion of heavy hydrocarbon feedstocks characterized by high molecular weight, low reactivity and high metal contents

Country Status (5)

Country Link
US (1) US4626340A (en, 2012)
JP (1) JPS62109889A (en, 2012)
CA (1) CA1288375C (en, 2012)
DE (1) DE3632880A1 (en, 2012)
FR (1) FR2587715B1 (en, 2012)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7556715B2 (en) 2004-01-09 2009-07-07 Suncor Energy, Inc. Bituminous froth inline steam injection processing

Families Citing this family (29)

* Cited by examiner, † Cited by third party
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US4846961A (en) * 1986-12-05 1989-07-11 Union Oil Company Of California Hydroprocessing catalyst with a Ni-P-Mo
FR2617498B1 (fr) * 1987-07-02 1989-12-08 Inst Francais Du Petrole Procede d'hydroconversion thermocatalytique d'une charge lourde hydrocarbonee
US4792390A (en) * 1987-09-21 1988-12-20 Uop Inc. Combination process for the conversion of a distillate hydrocarbon to produce middle distillate product
US5009768A (en) * 1989-12-19 1991-04-23 Intevep, S.A. Hydrocracking high residual contained in vacuum gas oil
JP2966985B2 (ja) * 1991-10-09 1999-10-25 出光興産株式会社 重質炭化水素油の接触水素化処理方法
JP3520319B2 (ja) 1999-12-21 2004-04-19 大阪大学長 化石燃料の脱メタル方法
EP2272938B9 (en) 2004-04-28 2015-12-30 Headwaters Heavy Oil, LLC Hydroprocessing method for upgrading heavy hydrocarbon feedstock using a colloidal catalyst
US10941353B2 (en) 2004-04-28 2021-03-09 Hydrocarbon Technology & Innovation, Llc Methods and mixing systems for introducing catalyst precursor into heavy oil feedstock
CA2564359C (en) 2004-04-28 2014-06-10 Headwaters Heavy Oil, Llc Fixed bed hydroprocessing methods and systems and methods for upgrading an existing fixed bed system
KR101493631B1 (ko) 2004-04-28 2015-02-13 헤드워터스 헤비 오일, 엘엘씨 에뷸레이트 베드 하이드로프로세싱 방법 및 시스템 및 기존의 에뷸레이트 베드 시스템을 개량하는 방법
US8034232B2 (en) 2007-10-31 2011-10-11 Headwaters Technology Innovation, Llc Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker
WO2009073436A2 (en) 2007-11-28 2009-06-11 Saudi Arabian Oil Company Process for catalytic hydrotreating of sour crude oils
US8142645B2 (en) 2008-01-03 2012-03-27 Headwaters Technology Innovation, Llc Process for increasing the mono-aromatic content of polynuclear-aromatic-containing feedstocks
US7943037B2 (en) * 2008-03-11 2011-05-17 Exxonmobil Research & Engineering Company Hydroconversion process for petroleum resids using selective membrane separation followed by hydroconversion over carbon supported metal catalyst
US7931798B2 (en) * 2008-03-11 2011-04-26 Exxonmobil Research And Engineering Company Hydroconversion process for petroleum resids by hydroconversion over carbon supported metal catalyst followed by selective membrane separation
EP2300566B1 (en) * 2008-07-14 2016-09-07 Saudi Arabian Oil Company Process for the treatment of heavy oils using light hydrocarbon components as a diluent
WO2010009082A1 (en) * 2008-07-14 2010-01-21 Saudi Arabian Oil Company A prerefining process for the hydrodesulfurization of heavy sour crude oils to produce sweeter lighter crudes using moving catalyst system
US8372267B2 (en) * 2008-07-14 2013-02-12 Saudi Arabian Oil Company Process for the sequential hydroconversion and hydrodesulfurization of whole crude oil
US8163168B2 (en) * 2008-07-25 2012-04-24 Exxonmobil Research And Engineering Company Process for flexible vacuum gas oil conversion
US8491779B2 (en) 2009-06-22 2013-07-23 Saudi Arabian Oil Company Alternative process for treatment of heavy crudes in a coking refinery
US9169449B2 (en) 2010-12-20 2015-10-27 Chevron U.S.A. Inc. Hydroprocessing catalysts and methods for making thereof
US9790440B2 (en) 2011-09-23 2017-10-17 Headwaters Technology Innovation Group, Inc. Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker
US9644157B2 (en) 2012-07-30 2017-05-09 Headwaters Heavy Oil, Llc Methods and systems for upgrading heavy oil using catalytic hydrocracking and thermal coking
US11414608B2 (en) 2015-09-22 2022-08-16 Hydrocarbon Technology & Innovation, Llc Upgraded ebullated bed reactor used with opportunity feedstocks
US11414607B2 (en) 2015-09-22 2022-08-16 Hydrocarbon Technology & Innovation, Llc Upgraded ebullated bed reactor with increased production rate of converted products
US11421164B2 (en) 2016-06-08 2022-08-23 Hydrocarbon Technology & Innovation, Llc Dual catalyst system for ebullated bed upgrading to produce improved quality vacuum residue product
US11732203B2 (en) 2017-03-02 2023-08-22 Hydrocarbon Technology & Innovation, Llc Ebullated bed reactor upgraded to produce sediment that causes less equipment fouling
JP7336831B2 (ja) 2017-03-02 2023-09-01 ハイドロカーボン テクノロジー アンド イノベーション、エルエルシー ファウリングが少ない堆積物を伴う改良された沸騰床リアクター
CA3057131C (en) 2018-10-17 2024-04-23 Hydrocarbon Technology And Innovation, Llc Upgraded ebullated bed reactor with no recycle buildup of asphaltenes in vacuum bottoms

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3730875A (en) * 1971-02-16 1973-05-01 Universal Oil Prod Co Combination process for black oil conversion
US3775293A (en) * 1972-08-09 1973-11-27 Universal Oil Prod Co Desulfurization of asphaltene-containing hydrocarbonaceous black oils
GB2003916B (en) * 1977-09-02 1982-05-19 Hitachi Ltd Process for hydrodesulphurizing hydrocarbon oil
US4176048A (en) * 1978-10-31 1979-11-27 Standard Oil Company (Indiana) Process for conversion of heavy hydrocarbons
JPS601056B2 (ja) * 1980-02-19 1985-01-11 千代田化工建設株式会社 アスファルテンを含む重質炭化水素油の水素化処理
CA1163222A (en) * 1981-02-12 1984-03-06 Her Majesty The Queen, In Right Of Canada As Represented By The Minister Of Natural Resources Canada Simultaneous demetalization and hydrocracking of heavy hydrocarbon oils
US4421633A (en) * 1981-03-13 1983-12-20 Mobil Oil Corporation Low pressure cyclic hydrocracking process using multi-catalyst bed reactor for heavy liquids
US4366047A (en) * 1981-06-02 1982-12-28 Exxon Research And Engineering Co. Combination hydrorefining, heat-treating and hydrocracking process
US4368113A (en) * 1981-08-31 1983-01-11 Exxon Research And Engineering Co. Hydrocarbon hydrocracking process
US4447313A (en) * 1981-12-01 1984-05-08 Mobil Oil Corporation Deasphalting and hydrocracking
US4434045A (en) * 1982-01-04 1984-02-28 Exxon Research And Engineering Co. Process for converting petroleum residuals
US4431525A (en) * 1982-04-26 1984-02-14 Standard Oil Company (Indiana) Three-catalyst process for the hydrotreating of heavy hydrocarbon streams
US4431526A (en) * 1982-07-06 1984-02-14 Union Oil Company Of California Multiple-stage hydroprocessing of hydrocarbon oil
FR2538811A1 (fr) * 1982-12-30 1984-07-06 Inst Francais Du Petrole Procede de traitement d'une huile lourde ou d'une fraction d'huile lourde pour les convertir en fractions plus legeres
US4451354A (en) * 1983-01-03 1984-05-29 Exxon Research And Engineering Co. Process for upgrading hydrocarbonaceous oils
US4525472A (en) * 1983-02-23 1985-06-25 Intevep, S.A. Process for catalyst preparation for the hydrodemetallization of heavy crudes and residues
US4490483A (en) * 1983-05-19 1984-12-25 Gulf Research & Development Company Process for preparing catalysts
US4520128A (en) * 1983-12-19 1985-05-28 Intevep, S.A. Catalyst having high metal retention capacity and good stability for use in the demetallization of heavy crudes and method of preparation of same
US4572778A (en) * 1984-01-19 1986-02-25 Union Oil Company Of California Hydroprocessing with a large pore catalyst

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7556715B2 (en) 2004-01-09 2009-07-07 Suncor Energy, Inc. Bituminous froth inline steam injection processing
US7914670B2 (en) 2004-01-09 2011-03-29 Suncor Energy Inc. Bituminous froth inline steam injection processing
US8685210B2 (en) 2004-01-09 2014-04-01 Suncor Energy Inc. Bituminous froth inline steam injection processing

Also Published As

Publication number Publication date
JPH0115559B2 (en, 2012) 1989-03-17
JPS62109889A (ja) 1987-05-21
DE3632880A1 (de) 1987-04-23
FR2587715A1 (fr) 1987-03-27
FR2587715B1 (fr) 1993-04-09
DE3632880C2 (en, 2012) 1988-10-06
US4626340A (en) 1986-12-02

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