CA1285686C - Curable compositions containing metallocene complexes, the activated precursors obtainable therefrom and the use thereof - Google Patents

Curable compositions containing metallocene complexes, the activated precursors obtainable therefrom and the use thereof

Info

Publication number
CA1285686C
CA1285686C CA000428306A CA428306A CA1285686C CA 1285686 C CA1285686 C CA 1285686C CA 000428306 A CA000428306 A CA 000428306A CA 428306 A CA428306 A CA 428306A CA 1285686 C CA1285686 C CA 1285686C
Authority
CA
Canada
Prior art keywords
arene
formula
metal
organic material
anion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CA000428306A
Other languages
English (en)
French (fr)
Inventor
Kurt Meier
Godwin Berner
Friedrich Lohse
Hans Zweifel
Niklaus Buhler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Priority to CA000615843A priority Critical patent/CA1307002C/en
Application granted granted Critical
Publication of CA1285686C publication Critical patent/CA1285686C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G85/00—General processes for preparing compounds provided for in this subclass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
    • G03F7/029—Inorganic compounds; Onium compounds; Organic compounds having hetero atoms other than oxygen, nitrogen or sulfur

Landscapes

  • Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Inorganic Chemistry (AREA)
  • Polymerization Catalysts (AREA)
  • Epoxy Resins (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Paints Or Removers (AREA)
CA000428306A 1982-05-19 1983-05-17 Curable compositions containing metallocene complexes, the activated precursors obtainable therefrom and the use thereof Expired - Lifetime CA1285686C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA000615843A CA1307002C (en) 1982-05-19 1990-08-27 Process for preparing metallocene complexes

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8214610 1982-05-19
GB8214610 1982-05-19

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CA000615843A Division CA1307002C (en) 1982-05-19 1990-08-27 Process for preparing metallocene complexes

Publications (1)

Publication Number Publication Date
CA1285686C true CA1285686C (en) 1991-07-02

Family

ID=10530465

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000428306A Expired - Lifetime CA1285686C (en) 1982-05-19 1983-05-17 Curable compositions containing metallocene complexes, the activated precursors obtainable therefrom and the use thereof

Country Status (8)

Country Link
US (1) US4868288A (enrdf_load_html_response)
EP (1) EP0094915B1 (enrdf_load_html_response)
JP (1) JPS58210904A (enrdf_load_html_response)
AU (1) AU578590B2 (enrdf_load_html_response)
CA (1) CA1285686C (enrdf_load_html_response)
DE (1) DE3369398D1 (enrdf_load_html_response)
HK (1) HK95187A (enrdf_load_html_response)
SG (1) SG67887G (enrdf_load_html_response)

Families Citing this family (101)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3369398D1 (en) * 1982-05-19 1987-02-26 Ciba Geigy Ag Curable compositions containing metallocen complexes, activated primers obtained therefrom and their use
US5191101A (en) * 1982-11-22 1993-03-02 Minnesota Mining And Manufacturing Company Energy polymerizable compositions containing organometallic initiators
US5073476A (en) * 1983-05-18 1991-12-17 Ciba-Geigy Corporation Curable composition and the use thereof
DE3565013D1 (en) * 1984-02-10 1988-10-20 Ciba Geigy Ag Process for the preparation of a protection layer or a relief pattern
EP0152377B1 (de) * 1984-02-10 1987-12-09 Ciba-Geigy Ag Härtbare Zusammensetzung und deren Verwendung
EP0182744B1 (de) * 1984-11-14 1992-08-12 Ciba-Geigy Ag Photohärtbare gefüllte Expoxidharz-Zusammensetzungen und deren Verwendung
US4677137A (en) * 1985-05-31 1987-06-30 Minnesota Mining And Manufacturing Company Supported photoinitiator
US5082952A (en) * 1985-06-06 1992-01-21 Ciba-Geigy Corporation Process for the preparation of metallocene complexes
CH678897A5 (enrdf_load_html_response) * 1986-05-10 1991-11-15 Ciba Geigy Ag
EP0250364B1 (de) * 1986-06-17 1991-10-23 Ciba-Geigy Ag Verfahren zur Härtung von Polyurethanlacken
DE3768605D1 (de) * 1986-09-19 1991-04-18 Ciba Geigy Ag Verfahren zur haertung von polyisocyanat-beschichtungen.
EP0270490B1 (de) * 1986-11-10 1990-10-10 Ciba-Geigy Ag Verbessertes Verfahren zur Herstellung von metallorganischen Verbindungen
US4857437A (en) * 1986-12-17 1989-08-15 Ciba-Geigy Corporation Process for the formation of an image
DE3702999C2 (de) * 1987-02-02 2003-03-06 Siemens Ag Vorrichtung zur Verarbeitung von UV-härtbaren Reaktionsharzmassen und deren Anwendung
EP0284064B1 (de) * 1987-03-27 1995-01-04 Ciba-Geigy Ag Photohärtbare Schleifmittel
US4997717A (en) * 1987-03-27 1991-03-05 Ciba-Geigy Corporation Photocurable abrasives
DE3879278D1 (enrdf_load_html_response) * 1987-06-05 1993-04-22 Ciba-Geigy Ag, Basel, Ch
US4740577A (en) * 1987-08-28 1988-04-26 Minnesota Mining And Manufacturing Company Energy polymerizable polyurethane precursors
US4952612A (en) * 1987-08-28 1990-08-28 Minnesota Mining And Manufacturing Company Energy-induced curable compositions
US5086086A (en) * 1987-08-28 1992-02-04 Minnesota Mining And Manufacturing Company Energy-induced curable compositions
US4950696A (en) * 1987-08-28 1990-08-21 Minnesota Mining And Manufacturing Company Energy-induced dual curable compositions
US4992572A (en) * 1987-10-26 1991-02-12 Ciba-Geigy Corporation Process for the preparation of organometallic compounds
US4920182A (en) * 1987-12-18 1990-04-24 Ciba-Geigy Corporation Epoxy resin compositions containing polyester flexibilizer and metallocene complex initiator
CA1340758C (en) * 1988-06-01 1999-09-21 Robert J. Devoe Energy curable compositions: single component curing agents
US4985340A (en) * 1988-06-01 1991-01-15 Minnesota Mining And Manufacturing Company Energy curable compositions: two component curing agents
US5215860A (en) * 1988-08-19 1993-06-01 Minnesota Mining And Manufacturing Company Energy-curable cyanate compositions
US5130406A (en) * 1989-03-21 1992-07-14 Ciba-Geigy Corporation Initiators for materials which can be polymerized cationically
KR0147813B1 (ko) * 1989-05-16 1998-08-01 월터 클리웨인, 한스-피터 위트린 적층 구조물 및 그의 제조방법
KR930701561A (ko) * 1990-06-08 1993-06-12 게리 엘. 그리스울드 전자 용품용 재처리가능한 접착제
US5143785A (en) * 1990-08-20 1992-09-01 Minnesota Mining And Manufacturing Company Cyanate ester adhesives for electronic applications
US5059701A (en) * 1990-09-20 1991-10-22 Minnesota Mining And Manufacturing Company Methods for preparation of cyclopentadienyliron (II) arenes
JPH0662692B2 (ja) * 1991-10-30 1994-08-17 オーテックス株式会社 光重合反応開始剤
US5212210A (en) * 1992-03-18 1993-05-18 Minnesota Mining And Manufacturing Company Energy curable compositions having improved cure speeds
US5354784A (en) * 1992-08-10 1994-10-11 Arakawa Kagaku Kogyo Kabushiki Kaisha Cyclopentadienyliron complex salt, process for preparing the same and photopolymerizable composition containing the same
DE4237132C1 (de) * 1992-11-03 1994-07-07 Siemens Ag UV-aktiviert thermisch härtendes einkomponentiges Reaktionsharzsystem
US5514728A (en) * 1993-07-23 1996-05-07 Minnesota Mining And Manufacturing Company Catalysts and initiators for polymerization
ES2147777T3 (es) * 1993-09-16 2000-10-01 Ciba Sc Holding Ag Compuestos vinileter con grupos funcionales adicionales, distintos de vinileter, y su utilizacion en la formulacion de compuestos reticulables.
DE4340949A1 (de) * 1993-12-01 1995-06-08 Thera Ges Fuer Patente Lichtinitiiert kationisch härtende Epoxidmasse und ihre Verwendung
EP0673104B1 (de) 1994-03-16 1999-07-07 Ciba SC Holding AG Ein-Komponenten-Epoxidharz-Systeme für das Träufelverfahren und Heisstauchrollierverfahren
US5670590A (en) * 1994-05-06 1997-09-23 Minnesota Mining And Manufacturing Company Energy polymerizable compositions, homopolymers and copolymers of oxazolines
US6124230A (en) * 1995-07-13 2000-09-26 Exxon Chemical Patents, Inc. Polymerization catalyst systems, their production and use
US6140432A (en) * 1995-07-13 2000-10-31 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
TW418215B (en) 1995-03-13 2001-01-11 Ciba Sc Holding Ag A process for the production of three-dimensional articles in a stereolithography bath comprising the step of sequentially irradiating a plurality of layers of a liquid radiation-curable composition
TW466256B (en) 1995-11-24 2001-12-01 Ciba Sc Holding Ag Borate photoinitiator compounds and compositions comprising the same
EP0808670A4 (en) * 1995-12-06 2003-07-02 Kansai Paint Co Ltd PROCESS FOR FORMING A PAINT FILM
ATE191090T1 (de) * 1996-07-29 2000-04-15 Ciba Sc Holding Ag Flüssige, strahlungshärtbare zusammensetzung, insbesondere für die stereolithographie
US5789333A (en) * 1997-03-05 1998-08-04 Iowa State University Research Foundation, Inc. Catalyst system comprising a first catalyst system tethered to a supported catalyst
US6309502B1 (en) 1997-08-19 2001-10-30 3M Innovative Properties Company Conductive epoxy resin compositions, anisotropically conductive adhesive films and electrical connecting methods
US6100007A (en) 1998-04-06 2000-08-08 Ciba Specialty Chemicals Corp. Liquid radiation-curable composition especially for producing cured articles by stereolithography having high heat deflection temperatures
US6255507B1 (en) 1998-09-18 2001-07-03 3M Innovative Properties Company Process for preparing cyclopentadienyliron (II) arene complex
US6133335A (en) * 1998-12-31 2000-10-17 3M Innovative Properties Company Photo-polymerizable compositions and articles made therefrom
US6265459B1 (en) 1998-12-31 2001-07-24 3M Innovative Properties Company Accelerators useful for energy polymerizable compositions
US6482868B1 (en) 1998-12-31 2002-11-19 3M Innovative Properties Company Accelerators useful for energy polymerizable compositions
DE19936730A1 (de) * 1999-08-06 2001-02-22 Sca Schucker Gmbh Vorrichtung und Verfahren zum Aufbringen eines Kunststoffstrangs auf eine Unterlage
US6565969B1 (en) 1999-10-21 2003-05-20 3M Innovative Properties Company Adhesive article
US6376590B2 (en) 1999-10-28 2002-04-23 3M Innovative Properties Company Zirconia sol, process of making and composite material
US6572693B1 (en) 1999-10-28 2003-06-03 3M Innovative Properties Company Aesthetic dental materials
US6730156B1 (en) 1999-10-28 2004-05-04 3M Innovative Properties Company Clustered particle dental fillers
US6387981B1 (en) 1999-10-28 2002-05-14 3M Innovative Properties Company Radiopaque dental materials with nano-sized particles
DE60022667T2 (de) 1999-10-28 2006-06-14 3M Innovative Properties Co Dentalmaterialien mit siliciumdioxid-nanoteilchen
US6635689B1 (en) 2000-06-26 2003-10-21 3M Innovative Properties Company Accelerators for cationic polymerization catalyzed by iron-based catalysts
DE20122692U1 (de) * 2000-09-01 2007-03-01 Digiglass Pty. Ltd., Clayton South Laminiertes Bildträgermaterial
AU2003209430B2 (en) 2002-01-31 2008-09-11 3M Innovative Properties Company Dental pastes, dental articles, and methods
JP2005529200A (ja) 2002-05-03 2005-09-29 ディーエスエム アイピー アセッツ ビー．ブイ． 照射硬化可能な樹脂組成物及びそれを用いるラピッドプロトタイピング法
US20030221770A1 (en) * 2002-05-28 2003-12-04 3M Innovative Properties Company Segmented curable transfer tapes
US7713604B2 (en) * 2002-06-17 2010-05-11 3M Innovative Properties Company Curable adhesive articles having topographical features therein
US6989225B2 (en) 2002-07-18 2006-01-24 3D Systems, Inc. Stereolithographic resins with high temperature and high impact resistance
US20040062682A1 (en) * 2002-09-30 2004-04-01 Rakow Neal Anthony Colorimetric sensor
US7449146B2 (en) * 2002-09-30 2008-11-11 3M Innovative Properties Company Colorimetric sensor
US6841333B2 (en) * 2002-11-01 2005-01-11 3M Innovative Properties Company Ionic photoacid generators with segmented hydrocarbon-fluorocarbon sulfonate anions
EP1646493B1 (en) 2003-07-23 2011-11-16 DSM IP Assets B.V. Viscosity reducible radiation curable resin composition
EP1557449A1 (en) * 2004-01-22 2005-07-27 3M Innovative Properties Company Adhesive tape for structural bonding
US7553670B2 (en) * 2004-04-28 2009-06-30 3M Innovative Properties Company Method for monitoring a polymerization in a three-dimensional sample
ATE432328T1 (de) * 2004-10-19 2009-06-15 3M Innovative Properties Co Klebeartikel mit kern/mantelstruktur
US8287611B2 (en) 2005-01-28 2012-10-16 Saint-Gobain Abrasives, Inc. Abrasive articles and methods for making same
US7591865B2 (en) 2005-01-28 2009-09-22 Saint-Gobain Abrasives, Inc. Method of forming structured abrasive article
SE529306C2 (sv) 2005-03-18 2007-06-26 Perstorp Specialty Chem Ab Ultravioletthärdande hartskomposition
EP1710286A1 (en) * 2005-04-04 2006-10-11 3M Innovative Properties Company Reinforcement Pad
US8871335B2 (en) 2005-08-31 2014-10-28 Kuraray America Inc. Solar control laminate
US20070172636A1 (en) * 2005-12-30 2007-07-26 Smith Rebecca L Decorative sheets having enhanced adhesion and laminates prepared therefrom
US20070196630A1 (en) * 2005-12-30 2007-08-23 Hayes Richard A Decorative solar control laminates
US20070172637A1 (en) * 2005-12-30 2007-07-26 Hayes Richard A Decorative sheets having enhanced adhesion and penetration resistant laminates prepared therefrom
US8435098B2 (en) 2006-01-27 2013-05-07 Saint-Gobain Abrasives, Inc. Abrasive article with cured backsize layer
US7767143B2 (en) * 2006-06-27 2010-08-03 3M Innovative Properties Company Colorimetric sensors
US20080103226A1 (en) 2006-10-31 2008-05-01 Dsm Ip Assets B.V. Photo-curable resin composition
CN101939140B (zh) 2006-12-21 2012-11-28 圣戈本磨料股份有限公司 低腐蚀磨料制品及其制备方法
WO2008083275A2 (en) 2006-12-28 2008-07-10 3M Innovative Properties Company Dental filler and methods
US20100190881A1 (en) 2009-01-28 2010-07-29 3D Systems, Incorporated Radiation Curable Compositions Useful in Solid Freeform Fabrication Systems
KR101714798B1 (ko) 2009-03-13 2017-03-09 디에스엠 아이피 어셋츠 비.브이. 방사선-경화성 수지 조성물 및 이를 이용한 쾌속 3차원 이미지화 방법
US9034236B2 (en) 2009-12-17 2015-05-19 Dsm Ip Assets B.V. Substrate-based additive fabrication process
CN102725689B (zh) 2010-01-22 2014-10-08 帝斯曼知识产权资产管理有限公司 能固化成具有选择性视觉效果的层的液体可辐射固化树脂及其使用方法
EP2502728B1 (en) 2011-03-23 2017-01-04 DSM IP Assets B.V. Lightweight and high strength three-dimensional articles producible by additive fabrication processes
KR20150103068A (ko) 2012-12-27 2015-09-09 쓰리엠 이노베이티브 프로퍼티즈 컴파니 벤족사진 및 산 형성 퍼옥사이드 촉매를 포함하는 중합성 조성물, 용품, 및 방법
JP6444376B2 (ja) 2013-04-30 2018-12-26 スリーエム イノベイティブ プロパティズ カンパニー ポリ（ベンゾオキサジン）を調製するための方法
DE102013211047B4 (de) 2013-06-13 2015-04-30 MTU Aero Engines AG Verfahren zum Verschließen von Kühlluftbohrungen
JP6419172B2 (ja) 2013-10-16 2018-11-07 スリーエム イノベイティブ プロパティズ カンパニー ベンゾオキサジン重合
CN107735427B (zh) 2015-06-09 2021-06-04 3M创新有限公司 铵盐催化的苯并噁嗪聚合
JP6603127B2 (ja) 2015-12-29 2019-11-06 サンアプロ株式会社 感光性組成物
US20190153226A1 (en) 2016-04-08 2019-05-23 Solvay Specialty Polymers Usa, Llc Photocurable polymers, photocurable polymer compositions and lithographic processes including the same
EP4166529A4 (en) 2020-06-12 2024-08-07 San-Apro Ltd. NEW ONIUM SALT AND PHOTOACID GENERATOR
JPWO2022130796A1 (enrdf_load_html_response) 2020-12-14 2022-06-23

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3130214A (en) * 1961-05-15 1964-04-21 Ethyl Corp Ionic aromatic compounds of transition metals having atomic numbers from 7 to 14 less than that of the next higher rare gas
US3190902A (en) * 1963-07-02 1965-06-22 Ethyl Corp Preparation of aromatic iron subgroup metal coordination compounds
GB1285284A (en) * 1969-05-26 1972-08-16 Hitachi Ltd Epoxy resin composition
GB1516352A (en) * 1974-05-02 1978-07-05 Gen Electric Halonium salts
US4077904A (en) * 1976-06-29 1978-03-07 Union Carbide Corporation Olefin polymerization process and catalyst therefor
US4273668A (en) * 1977-09-14 1981-06-16 General Electric Company Arylsulfonium salt-solvent mixtures
US4225691A (en) * 1979-07-17 1980-09-30 General Electric Company Low temperature curable organic resin compositions
DE3369398D1 (en) * 1982-05-19 1987-02-26 Ciba Geigy Ag Curable compositions containing metallocen complexes, activated primers obtained therefrom and their use
US5073476A (en) * 1983-05-18 1991-12-17 Ciba-Geigy Corporation Curable composition and the use thereof

Also Published As

Publication number Publication date
DE3369398D1 (en) 1987-02-26
EP0094915A3 (en) 1984-02-22
JPS58210904A (ja) 1983-12-08
HK95187A (en) 1987-12-24
SG67887G (en) 1988-09-23
EP0094915B1 (de) 1987-01-21
JPH058203B2 (enrdf_load_html_response) 1993-02-01
AU2058883A (en) 1985-05-02
EP0094915A2 (de) 1983-11-23
AU578590B2 (en) 1988-11-03
US4868288A (en) 1989-09-19

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