CA1257478A - Process and equipment for the generation of a product gas containing hydrogen and carbon oxides - Google Patents
Process and equipment for the generation of a product gas containing hydrogen and carbon oxidesInfo
- Publication number
- CA1257478A CA1257478A CA000442092A CA442092A CA1257478A CA 1257478 A CA1257478 A CA 1257478A CA 000442092 A CA000442092 A CA 000442092A CA 442092 A CA442092 A CA 442092A CA 1257478 A CA1257478 A CA 1257478A
- Authority
- CA
- Canada
- Prior art keywords
- gas
- reaction tubes
- reactor
- lower chamber
- product gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000007789 gas Substances 0.000 title claims abstract description 77
- 238000000034 method Methods 0.000 title claims abstract description 31
- 239000001257 hydrogen Substances 0.000 title claims abstract description 12
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 12
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 9
- 229910002090 carbon oxide Inorganic materials 0.000 title claims abstract description 6
- 238000006243 chemical reaction Methods 0.000 claims abstract description 51
- 239000003054 catalyst Substances 0.000 claims abstract description 16
- 238000002485 combustion reaction Methods 0.000 claims abstract description 14
- 238000005192 partition Methods 0.000 claims abstract description 12
- 230000003197 catalytic effect Effects 0.000 claims abstract description 8
- 239000012530 fluid Substances 0.000 claims abstract description 7
- 238000002407 reforming Methods 0.000 claims abstract description 7
- 239000000919 ceramic Substances 0.000 claims abstract description 4
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 239000000047 product Substances 0.000 claims description 20
- 229930195733 hydrocarbon Natural products 0.000 claims description 13
- 150000002430 hydrocarbons Chemical class 0.000 claims description 13
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 12
- 239000001301 oxygen Substances 0.000 claims description 12
- 229910052760 oxygen Inorganic materials 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 230000003647 oxidation Effects 0.000 claims description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 8
- 239000000567 combustion gas Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- 239000003345 natural gas Substances 0.000 claims description 6
- 239000002737 fuel gas Substances 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 150000002431 hydrogen Chemical class 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 239000011449 brick Substances 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 238000009413 insulation Methods 0.000 claims description 2
- 239000013589 supplement Substances 0.000 claims description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- 238000001816 cooling Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 239000003570 air Substances 0.000 description 4
- 239000003546 flue gas Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- VMXUWOKSQNHOCA-UKTHLTGXSA-N ranitidine Chemical compound [O-][N+](=O)\C=C(/NC)NCCSCC1=CC=C(CN(C)C)O1 VMXUWOKSQNHOCA-UKTHLTGXSA-N 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000000629 steam reforming Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
- B01J8/062—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes being installed in a furnace
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Carbon And Carbon Compounds (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP3244252.1 | 1982-11-30 | ||
DE19823244252 DE3244252A1 (de) | 1982-11-30 | 1982-11-30 | Verfahren und vorrichtung zur erzeugung von produktgas mit wasserstoff- und kohlenoxyde-gehalten |
Publications (1)
Publication Number | Publication Date |
---|---|
CA1257478A true CA1257478A (en) | 1989-07-18 |
Family
ID=6179426
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA000442092A Expired CA1257478A (en) | 1982-11-30 | 1983-11-28 | Process and equipment for the generation of a product gas containing hydrogen and carbon oxides |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP0110093B1 (enrdf_load_stackoverflow) |
JP (1) | JPS59107901A (enrdf_load_stackoverflow) |
AT (1) | ATE44717T1 (enrdf_load_stackoverflow) |
AU (1) | AU579990B2 (enrdf_load_stackoverflow) |
CA (1) | CA1257478A (enrdf_load_stackoverflow) |
DE (2) | DE3244252A1 (enrdf_load_stackoverflow) |
DK (1) | DK162935C (enrdf_load_stackoverflow) |
MX (1) | MX161814A (enrdf_load_stackoverflow) |
NO (1) | NO163732C (enrdf_load_stackoverflow) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105143099A (zh) * | 2014-01-13 | 2015-12-09 | 气体化学技术有限责任公司 | 用于烃类气体部分氧化的反应器 |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3480192D1 (en) * | 1983-03-25 | 1989-11-23 | Ici Plc | Steam reforming |
US4666680A (en) * | 1984-01-30 | 1987-05-19 | Fluor Corporation | Autothermal production of synthesis gas |
GB2163449B (en) * | 1984-07-18 | 1988-06-02 | Shell Int Research | Production of gas mixtures containing hydrogen and carbon monoxide |
US4919844A (en) * | 1984-08-16 | 1990-04-24 | Air Products And Chemicals, Inc. | Enhanced heat transfer reformer and method |
DK165946C (da) * | 1985-03-21 | 1993-07-05 | Haldor Topsoe As | Reformingproces under varmeudveksling og reaktor dertil |
DE3532413A1 (de) * | 1985-09-11 | 1987-03-12 | Uhde Gmbh | Vorrichtung zur erzeugung von synthesegas |
DE3605811A1 (de) * | 1986-02-22 | 1987-08-27 | Uhde Gmbh | Vorrichtung zum einsetzen in einem verfahren zur erzeugung von produktgas mit wasserstoff- und kohlenoxidgehalten |
DE3719780A1 (de) * | 1987-06-13 | 1988-12-22 | Uhde Gmbh | Verfahren zur herstellung von ammoniak aus erdgas |
DE8816548U1 (de) * | 1988-02-03 | 1989-10-26 | Uhde Gmbh, 4600 Dortmund | Vorrichtung zur Durchführung einer mehrstufigen Synthesegaserzeugung |
DE3806408A1 (de) * | 1988-02-29 | 1989-09-07 | Uhde Gmbh | Verfahren und vorrichtung zur erzeugung eines h(pfeil abwaerts)2(pfeil abwaerts) und co-enthaltenden synthesegases |
JPH01261201A (ja) * | 1988-04-12 | 1989-10-18 | Mitsubishi Gas Chem Co Inc | 炭化水素改質反応器 |
DE3813863A1 (de) * | 1988-04-23 | 1989-11-02 | Uhde Gmbh | Einrichtung zur aufnahme von katalysatoren, insbesondere bei der erzeugung von synthesegas |
DE3813864A1 (de) * | 1988-04-23 | 1989-11-02 | Uhde Gmbh | Vorrichtung, insbesondere zur erzeugung von synthesegas in einem reformer |
DE3813861C1 (enrdf_load_stackoverflow) * | 1988-04-23 | 1989-09-28 | Uhde Gmbh, 4600 Dortmund, De | |
GB2217728B (en) * | 1988-04-28 | 1992-02-26 | Humphreys & Glasgow Ltd | Combined reformer |
DE4221837C1 (en) * | 1992-07-03 | 1993-08-19 | Uhde Gmbh, 4600 Dortmund, De | Shrouded catalytic reformer tube - with partially enclosed gas mixing zone, for prodn. of synthesis gas |
US5720901A (en) * | 1993-12-27 | 1998-02-24 | Shell Oil Company | Process for the catalytic partial oxidation of hydrocarbons |
MY139324A (en) * | 2001-06-25 | 2009-09-30 | Shell Int Research | Integrated process for hydrocarbon synthesis |
US20060260194A1 (en) * | 2003-04-15 | 2006-11-23 | Tio Thian H | Process to prepare synthesis gas |
DE10345902B4 (de) * | 2003-10-02 | 2005-07-07 | Lurgi Ag | Verfahren zur Herstellung von Synthesegas aus Erdgas und Reaktor zur Durchführung des Verfahrens |
RU2266252C2 (ru) * | 2003-10-13 | 2005-12-20 | Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук | Способ получения синтез-газа |
JP2020158191A (ja) * | 2019-03-28 | 2020-10-01 | 大日本印刷株式会社 | 基材、積層体、包装材料、包装袋およびスタンドパウチ |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2529630A (en) * | 1947-04-25 | 1950-11-14 | Stanolind Oil & Gas Co | Process for the manufacture of synthesis gases |
US2579843A (en) * | 1947-12-10 | 1951-12-25 | Method foe the manufacture of | |
DE1021121B (de) * | 1955-06-07 | 1957-12-19 | Max Gerhold Dipl Ing Dr Techn | Verfahren zur thermisch-katalytischen Umwandlung von hoeher- und hochmolekularen, gasfoermigen oder fluessigen Kohlenwasserstoffen in im wesentlichen aus niedermolekularen Kohlenstoffverbindungen und Wasserstoff bestehende Gase |
GB845401A (en) * | 1955-07-15 | 1960-08-24 | Gas Council | Improved process for the production of gases containing hydrogen |
US3030092A (en) * | 1958-04-10 | 1962-04-17 | Degussa | Device for a gastight fixing of ceramic tubes in high temperature furnaces |
DE1667573B2 (de) * | 1967-08-10 | 1976-10-21 | Krupp-Koppers Gmbh, 4300 Essen | Verfahren und vorrichtung zur erzeugung eines wasserstoffreichen gases durch spaltung eines gemisches aus gasfoermigen und/oder fluessigen kohlenwasserstoffen und wasserdampf |
US3751228A (en) * | 1970-12-16 | 1973-08-07 | V Semenov | Apparatus for reforming hydrocarbons under pressure |
DE2412841C2 (de) * | 1974-03-18 | 1982-11-11 | Metallgesellschaft Ag, 6000 Frankfurt | Reaktor zum Spalten von Kohlenwasserstoffen an einem indirekt beheizten Katalysator |
JPS52112607A (en) * | 1976-03-09 | 1977-09-21 | Agency Of Ind Science & Technol | Reformers |
JPS5382691A (en) * | 1976-12-29 | 1978-07-21 | Chiyoda Chem Eng & Constr Co Ltd | Preparation of synthetic gas for ammonia without using external heat type steam modifying device |
FR2372116A1 (fr) * | 1977-03-22 | 1978-06-23 | Banquy David | Procede de production de gaz de synthese |
-
1982
- 1982-11-30 DE DE19823244252 patent/DE3244252A1/de active Granted
-
1983
- 1983-10-18 EP EP83110367A patent/EP0110093B1/de not_active Expired
- 1983-10-18 AT AT83110367T patent/ATE44717T1/de not_active IP Right Cessation
- 1983-10-18 DE DE8383110367T patent/DE3380212D1/de not_active Expired
- 1983-11-18 NO NO834244A patent/NO163732C/no unknown
- 1983-11-23 AU AU21604/83A patent/AU579990B2/en not_active Expired
- 1983-11-28 CA CA000442092A patent/CA1257478A/en not_active Expired
- 1983-11-29 DK DK546683A patent/DK162935C/da not_active IP Right Cessation
- 1983-11-30 MX MX199586A patent/MX161814A/es unknown
- 1983-11-30 JP JP58224594A patent/JPS59107901A/ja active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105143099A (zh) * | 2014-01-13 | 2015-12-09 | 气体化学技术有限责任公司 | 用于烃类气体部分氧化的反应器 |
Also Published As
Publication number | Publication date |
---|---|
DK162935B (da) | 1991-12-30 |
AU579990B2 (en) | 1988-12-22 |
JPS59107901A (ja) | 1984-06-22 |
AU2160483A (en) | 1984-06-07 |
EP0110093A3 (en) | 1986-07-02 |
NO834244L (no) | 1984-06-01 |
DK546683D0 (da) | 1983-11-29 |
MX161814A (es) | 1990-12-28 |
EP0110093A2 (de) | 1984-06-13 |
EP0110093B1 (de) | 1989-07-19 |
DK162935C (da) | 1992-05-25 |
DK546683A (da) | 1984-05-31 |
ATE44717T1 (de) | 1989-08-15 |
DE3380212D1 (en) | 1989-08-24 |
NO163732C (no) | 1990-07-11 |
DE3244252A1 (de) | 1984-05-30 |
JPH0450245B2 (enrdf_load_stackoverflow) | 1992-08-13 |
NO163732B (no) | 1990-04-02 |
DE3244252C2 (enrdf_load_stackoverflow) | 1990-10-31 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MKEX | Expiry |