CA1186485A - Method of using high concentration sulfuric acid for stripping and precipitation of adsorbed magnesium - Google Patents
Method of using high concentration sulfuric acid for stripping and precipitation of adsorbed magnesiumInfo
- Publication number
- CA1186485A CA1186485A CA000405627A CA405627A CA1186485A CA 1186485 A CA1186485 A CA 1186485A CA 000405627 A CA000405627 A CA 000405627A CA 405627 A CA405627 A CA 405627A CA 1186485 A CA1186485 A CA 1186485A
- Authority
- CA
- Canada
- Prior art keywords
- resin
- concentration
- sulfuric acid
- h2so4
- column
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 title claims abstract description 120
- 239000011777 magnesium Substances 0.000 title claims abstract description 38
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 229910052749 magnesium Inorganic materials 0.000 title claims abstract description 37
- 238000000034 method Methods 0.000 title claims abstract description 23
- 238000001556 precipitation Methods 0.000 title abstract description 9
- 239000011347 resin Substances 0.000 claims abstract description 65
- 229920005989 resin Polymers 0.000 claims abstract description 65
- 239000000243 solution Substances 0.000 claims abstract description 57
- 239000002253 acid Substances 0.000 claims abstract description 28
- 230000001172 regenerating effect Effects 0.000 claims abstract description 27
- 239000003729 cation exchange resin Substances 0.000 claims abstract description 10
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 235000011149 sulphuric acid Nutrition 0.000 claims description 47
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 26
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 22
- 230000008929 regeneration Effects 0.000 claims description 21
- 238000011069 regeneration method Methods 0.000 claims description 21
- 239000002244 precipitate Substances 0.000 claims description 13
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 229910001425 magnesium ion Inorganic materials 0.000 claims description 11
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 11
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 11
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 claims description 10
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 9
- 229910052791 calcium Inorganic materials 0.000 claims description 9
- 239000011575 calcium Substances 0.000 claims description 9
- 238000002288 cocrystallisation Methods 0.000 claims description 5
- 239000005416 organic matter Substances 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- 239000010414 supernatant solution Substances 0.000 claims description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims 2
- 229910001424 calcium ion Inorganic materials 0.000 claims 2
- 230000001376 precipitating effect Effects 0.000 claims 2
- 239000002367 phosphate rock Substances 0.000 abstract description 7
- 238000010828 elution Methods 0.000 abstract description 4
- 238000010790 dilution Methods 0.000 abstract description 3
- 239000012895 dilution Substances 0.000 abstract description 3
- 239000002699 waste material Substances 0.000 abstract description 3
- 239000006227 byproduct Substances 0.000 abstract 1
- 235000011007 phosphoric acid Nutrition 0.000 description 12
- 239000012508 resin bead Substances 0.000 description 12
- 239000007788 liquid Substances 0.000 description 6
- 238000012546 transfer Methods 0.000 description 6
- 229910021645 metal ion Inorganic materials 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 150000001768 cations Chemical class 0.000 description 4
- -1 hydrochloric Chemical class 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 3
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000004901 spalling Methods 0.000 description 3
- 239000006228 supernatant Substances 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 238000010899 nucleation Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- ZPEZUAAEBBHXBT-WCCKRBBISA-N (2s)-2-amino-3-methylbutanoic acid;2-amino-3-methylbutanoic acid Chemical compound CC(C)C(N)C(O)=O.CC(C)[C@H](N)C(O)=O ZPEZUAAEBBHXBT-WCCKRBBISA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- LEHOTFFKMJEONL-UHFFFAOYSA-N Uric Acid Chemical compound N1C(=O)NC(=O)C2=C1NC(=O)N2 LEHOTFFKMJEONL-UHFFFAOYSA-N 0.000 description 1
- TVWHNULVHGKJHS-UHFFFAOYSA-N Uric acid Natural products N1C(=O)NC(=O)C2NC(=O)NC21 TVWHNULVHGKJHS-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 229910052925 anhydrite Inorganic materials 0.000 description 1
- 125000005228 aryl sulfonate group Chemical group 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229940023913 cation exchange resins Drugs 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000012492 regenerant Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000006163 transport media Substances 0.000 description 1
- 229940116269 uric acid Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F5/00—Compounds of magnesium
- C01F5/40—Magnesium sulfates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
- B01D15/08—Selective adsorption, e.g. chromatography
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
- B01J49/10—Regeneration or reactivation of ion-exchangers; Apparatus therefor of moving beds
- B01J49/12—Regeneration or reactivation of ion-exchangers; Apparatus therefor of moving beds containing cationic exchangers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
- B01J49/50—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents
- B01J49/53—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents for cationic exchangers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Geochemistry & Mineralogy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Environmental & Geological Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Analytical Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Treatment Of Water By Ion Exchange (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Removal Of Specific Substances (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US27565181A | 1981-06-22 | 1981-06-22 | |
| US275,651 | 1981-06-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1186485A true CA1186485A (en) | 1985-05-07 |
Family
ID=23053274
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000405627A Expired CA1186485A (en) | 1981-06-22 | 1982-06-21 | Method of using high concentration sulfuric acid for stripping and precipitation of adsorbed magnesium |
Country Status (16)
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4210403B2 (ja) * | 1999-12-20 | 2009-01-21 | オルガノ株式会社 | 混床式糖液精製装置の再生法 |
| JP2009520662A (ja) * | 2005-12-22 | 2009-05-28 | ビーエイチピー・ビリトン・エスエスエム・ディベロプメント・ピーティーワイ・エルティーディー | 固体酸化マグネシウム水和物の回収 |
| US10910722B2 (en) | 2018-01-15 | 2021-02-02 | Rogers Corporation | Dielectric resonator antenna having first and second dielectric portions |
| EP4168362A1 (en) * | 2020-06-18 | 2023-04-26 | Ionic Water Technologies, LLC | Regeneratable system for contaminant removal |
| CN116899258B (zh) * | 2023-06-30 | 2025-08-22 | 中石化南京工程有限公司 | 一种离子交换净化磷酸后处理的系统及方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1709398A (en) * | 1925-02-23 | 1929-04-16 | Dow Chemical Co | Method of preparing epsom salts |
| US1977560A (en) * | 1932-03-19 | 1934-10-16 | Texaco Salt Products Company | Preparation of magnesium sulphate |
| GB532786A (en) * | 1939-09-20 | 1941-01-30 | Ocean Salts Products Ltd | Preparation of magnesium sulphate from magnesium hydroxide prepared from sea water and the like |
| US4263145A (en) * | 1980-06-10 | 1981-04-21 | The Dow Chemical Company | Recovery of ammonia or amine from a cation exchange resin |
-
1982
- 1982-06-02 IN IN422/DEL/82A patent/IN158260B/en unknown
- 1982-06-08 AU AU84676/82A patent/AU536149B2/en not_active Ceased
- 1982-06-09 ZA ZA824044A patent/ZA824044B/xx unknown
- 1982-06-10 IL IL66033A patent/IL66033A/xx unknown
- 1982-06-17 BR BR8203538A patent/BR8203538A/pt unknown
- 1982-06-18 PT PT75080A patent/PT75080B/pt not_active IP Right Cessation
- 1982-06-18 DK DK276282A patent/DK158567C/da not_active IP Right Cessation
- 1982-06-21 FR FR8210794A patent/FR2507912B1/fr not_active Expired
- 1982-06-21 KR KR8202767A patent/KR860001660B1/ko not_active Expired
- 1982-06-21 CA CA000405627A patent/CA1186485A/en not_active Expired
- 1982-06-21 ES ES513320A patent/ES8304450A1/es not_active Expired
- 1982-06-21 MA MA19712A patent/MA19505A1/fr unknown
- 1982-06-22 GR GR68505A patent/GR76509B/el unknown
- 1982-06-22 DE DE8282105467T patent/DE3266182D1/de not_active Expired
- 1982-06-22 JP JP57106271A patent/JPS583647A/ja active Granted
- 1982-06-22 EP EP82105467A patent/EP0068413B1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| MA19505A1 (fr) | 1982-12-31 |
| JPS583647A (ja) | 1983-01-10 |
| IN158260B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1986-10-04 |
| FR2507912B1 (fr) | 1985-11-08 |
| ES513320A0 (es) | 1983-03-01 |
| IL66033A (en) | 1985-04-30 |
| DK158567C (da) | 1990-11-12 |
| DK158567B (da) | 1990-06-11 |
| JPS6110177B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1986-03-28 |
| EP0068413A3 (en) | 1983-05-04 |
| PT75080A (en) | 1982-07-01 |
| KR860001660B1 (ko) | 1986-10-16 |
| DE3266182D1 (en) | 1985-10-17 |
| AU536149B2 (en) | 1984-04-19 |
| ZA824044B (en) | 1983-04-27 |
| EP0068413A2 (en) | 1983-01-05 |
| FR2507912A1 (fr) | 1982-12-24 |
| PT75080B (en) | 1984-05-09 |
| ES8304450A1 (es) | 1983-03-01 |
| BR8203538A (pt) | 1983-06-07 |
| KR840000278A (ko) | 1984-02-18 |
| GR76509B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1984-08-10 |
| AU8467682A (en) | 1983-01-06 |
| EP0068413B1 (en) | 1985-09-11 |
| DK276282A (da) | 1982-12-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEC | Expiry (correction) | ||
| MKEX | Expiry |