CA1117962A - Catalytic oxidation of formamides to form isocyanates - Google Patents

Catalytic oxidation of formamides to form isocyanates

Info

Publication number
CA1117962A
CA1117962A CA000308524A CA308524A CA1117962A CA 1117962 A CA1117962 A CA 1117962A CA 000308524 A CA000308524 A CA 000308524A CA 308524 A CA308524 A CA 308524A CA 1117962 A CA1117962 A CA 1117962A
Authority
CA
Canada
Prior art keywords
isocyanate
reaction
reaction mixture
solvent
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA000308524A
Other languages
English (en)
French (fr)
Inventor
Nico Heyboer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Akzona Inc
Original Assignee
Akzona Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Akzona Inc filed Critical Akzona Inc
Application granted granted Critical
Publication of CA1117962A publication Critical patent/CA1117962A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C263/00—Preparation of derivatives of isocyanic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C263/00—Preparation of derivatives of isocyanic acid
    • C07C263/18—Separation; Purification; Stabilisation; Use of additives
    • C07C263/20—Separation; Purification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CA000308524A 1977-08-02 1978-08-01 Catalytic oxidation of formamides to form isocyanates Expired CA1117962A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL7708510 1977-08-02
NL7,708,510 1977-08-02

Publications (1)

Publication Number Publication Date
CA1117962A true CA1117962A (en) 1982-02-09

Family

ID=19828957

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000308524A Expired CA1117962A (en) 1977-08-02 1978-08-01 Catalytic oxidation of formamides to form isocyanates

Country Status (6)

Country Link
US (1) US4207251A (esLanguage)
EP (1) EP0000602B1 (esLanguage)
JP (1) JPS5439018A (esLanguage)
CA (1) CA1117962A (esLanguage)
DE (1) DE2860856D1 (esLanguage)
IT (1) IT1097592B (esLanguage)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4430262A (en) * 1981-06-05 1984-02-07 Shell Oil Company Preparation of isocyanates and/or derivatives thereof
DE3229323A1 (de) * 1982-08-06 1984-02-09 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung aliphatischer isocyanate durch oxidative dehydrierung von formamiden
US4469640A (en) * 1983-03-14 1984-09-04 E. I. Du Pont De Nemours And Company Catalytic conversion of formamides to isocyanates
US4824991A (en) * 1984-08-09 1989-04-25 E. I. Du Pont De Nemours And Company Process for separating methyl isocyanate
US4694101A (en) * 1984-08-09 1987-09-15 E. I. Du Pont De Nemours And Company Process for separating methyl isocyanate
US4537726A (en) * 1984-11-09 1985-08-27 E. I. Du Pont De Nemours And Company Multi-stage process with adiabatic reactors for the preparation of isocyanates
US4698438A (en) * 1985-04-26 1987-10-06 E. I. Du Pont De Nemours And Company Process for the preparation of methyl carbamates and thioimidates
US4603016A (en) * 1985-11-14 1986-07-29 E. I. Du Pont De Nemours And Company Cryogenic brine separation of water and isocyanates
DE3573111D1 (en) * 1985-12-12 1989-10-26 Du Pont Process for separating methyl isocyanate
US4683329A (en) * 1986-04-16 1987-07-28 E. I. Dupont De Nemours And Company Beneficial use of water in catalytic conversion of formamides to isocyanates
US4795830A (en) * 1986-09-02 1989-01-03 E. I. Du Pont De Nemours And Company Use of water to inhibit decomposition of monoalkylformamides
US5126480A (en) * 1990-06-01 1992-06-30 Arco Chemical Technology, L.P. Isocyanate preparation
US5155267A (en) * 1991-10-24 1992-10-13 Arco Chemical Technology, L.P. Synthesis of isocyanate precursors from primary formamides
JP2012509868A (ja) * 2008-11-24 2012-04-26 リライアンス ライフ サイエンシズ ピーヴィーティー リミティッド テトラジン誘導体の製造方法
WO2011067242A1 (de) * 2009-12-01 2011-06-09 Basf Se Verfahren zur herstellung von isocyanaten durch thermische spaltung von carbamaten
US8835673B2 (en) * 2009-12-04 2014-09-16 Basf Se Process for preparing isocyanates
PL2701841T3 (pl) * 2011-04-26 2015-11-30 Basf Se Sposób utleniającego odwodorniania metanolu do formaldehydu na dzianinach zawierających srebro
CN107473989B (zh) * 2016-06-08 2020-04-28 中国科学院大连化学物理研究所 一种催化甲醇转化制氨基甲酸甲酯的方法
US20240336561A1 (en) 2021-06-28 2024-10-10 MAX-PLANCK-Gesellschaft zur Förderung der Wissenschaften e.V. Catalytic synthesis of free isocyanates
KR102806436B1 (ko) * 2024-03-29 2025-05-09 한화솔루션 주식회사 이소시아네이트 조성물, 이를 포함하는 광학렌즈 및 이를 이용한 이소시아네이트 조성물 보관방법

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3099673A (en) * 1959-08-19 1963-07-30 Bayer Ag Process for the production of organic isocyanates
US3277140A (en) * 1963-07-16 1966-10-04 Air Prod & Chem Preparation of aliphatic isocyanates
DE1277851B (de) 1966-04-20 1968-09-19 Bayer Ag Verfahren zur Herstellung von 2-Chlorcarbonylphenylisocyanaten
US3929859A (en) * 1974-11-18 1975-12-30 Standard Oil Co Ohio Manufacture of dinitriles from thiodinitriles
US3960914A (en) * 1975-05-06 1976-06-01 Sun Ventures, Inc. Conversion of formamides to isocyanates
DE2520219C3 (de) 1975-05-07 1983-02-24 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Formaldehyd

Also Published As

Publication number Publication date
EP0000602A1 (en) 1979-02-07
JPS5439018A (en) 1979-03-24
DE2860856D1 (en) 1981-10-29
IT7826324A0 (it) 1978-07-31
JPH0118067B2 (esLanguage) 1989-04-03
US4207251A (en) 1980-06-10
EP0000602B1 (en) 1981-07-22
IT1097592B (it) 1985-08-31

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Legal Events

Date Code Title Description
MKEX Expiry