CA1113444A - Manufacture of catalysts for polymerisation of olefins - Google Patents
Manufacture of catalysts for polymerisation of olefinsInfo
- Publication number
- CA1113444A CA1113444A CA270,621A CA270621A CA1113444A CA 1113444 A CA1113444 A CA 1113444A CA 270621 A CA270621 A CA 270621A CA 1113444 A CA1113444 A CA 1113444A
- Authority
- CA
- Canada
- Prior art keywords
- titanium
- titanium tetrachloride
- moles
- polymerisation
- ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 58
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 150000001336 alkenes Chemical class 0.000 title abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 51
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims abstract description 33
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 26
- 150000002899 organoaluminium compounds Chemical class 0.000 claims abstract description 19
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 claims abstract description 10
- 239000002244 precipitate Substances 0.000 claims description 31
- 239000012442 inert solvent Substances 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 230000015572 biosynthetic process Effects 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000004711 α-olefin Substances 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 239000003153 chemical reaction reagent Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 4
- 125000005843 halogen group Chemical group 0.000 claims description 3
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 229930195734 saturated hydrocarbon Natural products 0.000 claims 1
- 235000020354 squash Nutrition 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 22
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract description 22
- -1 propylene Chemical class 0.000 abstract description 20
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract description 20
- 229920000642 polymer Polymers 0.000 abstract description 13
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 90
- 239000010936 titanium Substances 0.000 description 30
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 29
- 229910052719 titanium Inorganic materials 0.000 description 29
- 229940095050 propylene Drugs 0.000 description 20
- AQZGPSLYZOOYQP-UHFFFAOYSA-N Diisoamyl ether Chemical compound CC(C)CCOCCC(C)C AQZGPSLYZOOYQP-UHFFFAOYSA-N 0.000 description 17
- 239000004743 Polypropylene Substances 0.000 description 16
- 238000009835 boiling Methods 0.000 description 16
- 229920001155 polypropylene Polymers 0.000 description 16
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 12
- 239000002245 particle Substances 0.000 description 12
- 229910010066 TiC14 Inorganic materials 0.000 description 11
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000003426 co-catalyst Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 150000002902 organometallic compounds Chemical class 0.000 description 3
- 239000012429 reaction media Substances 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000007792 gaseous phase Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 125000002524 organometallic group Chemical group 0.000 description 2
- 239000011555 saturated liquid Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 229910010061 TiC13 Inorganic materials 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- MGDOJPNDRJNJBK-UHFFFAOYSA-N ethylaluminum Chemical compound [Al].C[CH2] MGDOJPNDRJNJBK-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7602898 | 1976-02-03 | ||
| FR7602898A FR2340131A1 (fr) | 1976-02-03 | 1976-02-03 | Procede de fabrication de catalyseurs pour la polymerisation des olefines |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1113444A true CA1113444A (en) | 1981-12-01 |
Family
ID=9168686
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA270,621A Expired CA1113444A (en) | 1976-02-03 | 1977-01-28 | Manufacture of catalysts for polymerisation of olefins |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4110248A (show.php) |
| JP (1) | JPS5295591A (show.php) |
| BE (1) | BE851009A (show.php) |
| CA (1) | CA1113444A (show.php) |
| DE (1) | DE2703911C2 (show.php) |
| FR (1) | FR2340131A1 (show.php) |
| GB (1) | GB1531673A (show.php) |
| IT (1) | IT1074821B (show.php) |
| LU (1) | LU76679A1 (show.php) |
| NL (1) | NL183725C (show.php) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2381565A1 (fr) * | 1977-02-23 | 1978-09-22 | Naphtachimie Sa | Catalyseurs de polymerisation des olefines |
| DE2861689D1 (en) * | 1977-08-31 | 1982-04-29 | Ici Plc | Titanium trichloride compositions, preparation thereof, catalyst system containing them and polymerisation of olefins using this system |
| DE2861357D1 (en) * | 1977-08-31 | 1982-01-28 | Ici Plc | Titanium trichloride compositions, preparation thereof, catalyst system containing them and polymerisation of olefins using this system |
| US4192774A (en) * | 1978-01-27 | 1980-03-11 | Shell Oil Company | Preparation of an active TiCl3 catalyst |
| DE2906036A1 (de) * | 1978-02-17 | 1979-08-23 | Exxon Research Engineering Co | Verfahren zur herstellung von titankatalysatoren und verwendung dieser katalysatoren |
| CA1121329A (en) * | 1978-07-25 | 1982-04-06 | Andras G.T.G. Kortbeek | Olefin polymerization catalysts |
| FR2460965A1 (fr) * | 1979-07-06 | 1981-01-30 | Naphtachimie Sa | Procede et utilisation dudit procede pour la fabrication de terpolymeres elastomeres d'ethylene, de propylene et de dienes |
| FR2460964A1 (fr) * | 1979-07-06 | 1981-01-30 | Naphtachimie Sa | Copolymeres elastomeres d'ethylene et de propylene, leur fabrication et leurs applications |
| FR2462449A1 (fr) * | 1979-07-30 | 1981-02-13 | Naphtachimie Sa | Procede de fabrication de copolymeres de propylene et de butene-1, produits en resultant et leurs applications |
| IT1134011B (it) * | 1979-10-23 | 1986-07-24 | Japan Ep Rubber Co | Procedimento per la produzione di gomma di un copolimero olefinico |
| JPS5928573B2 (ja) * | 1980-02-05 | 1984-07-13 | チッソ株式会社 | α−オレフイン重合体の製造方法 |
| WO1989000584A1 (en) * | 1987-07-10 | 1989-01-26 | Quantum Chemical Corporation | Propylene polymerization catalyst and method |
| JP4085733B2 (ja) | 2002-08-06 | 2008-05-14 | 住友化学株式会社 | α−オレフィン重合触媒およびα−オレフィン共重合体の製造方法 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL213771A (show.php) * | 1956-01-18 | |||
| US3129256A (en) * | 1959-12-01 | 1964-04-14 | Gulf Research Development Co | Alkylation of benzene with propylene in the presence of a catalyst containing titanium tetrachloride, alkyl aluminum sesquichloride, and oxygen |
| US3652705A (en) * | 1968-10-03 | 1972-03-28 | Mitsui Petrochemical Ind | Process for the oligomerization of ethylene |
| BE765033R (fr) * | 1970-04-06 | 1971-09-30 | Inst Francais Du Petrole | Nouveau procede d'hydrogenation et catalyseurs d'hydrogenation correspondants |
| US3813374A (en) * | 1970-10-19 | 1974-05-28 | Goodyear Tire & Rubber | Polymerization of conjugated diolefins with catalysts containing carbon oxysulfide |
| JPS4933957B1 (show.php) * | 1970-12-25 | 1974-09-11 | ||
| CH543546A (fr) * | 1971-03-23 | 1973-10-31 | Solvay | Système catalytique de polymérisation des alpha-oléfines |
| US3917575A (en) * | 1972-11-11 | 1975-11-04 | Nippon Oil Co Ltd | Process for production of polyolefins |
| GB1408620A (en) * | 1972-12-04 | 1975-10-01 | Shell Int Research | Isoprene polymerization and catalyst therefor |
| JPS558452B2 (show.php) * | 1974-07-31 | 1980-03-04 | ||
| JPS5247594A (en) * | 1975-10-15 | 1977-04-15 | Mitsubishi Chem Ind Ltd | Process for the production of titanium trichloride for alpha-olefin polymerization |
| JPS5269892A (en) * | 1975-12-08 | 1977-06-10 | Mitsubishi Chem Ind Ltd | Production of solid titanium trichloride |
| JPS5282987A (en) * | 1975-12-30 | 1977-07-11 | Mitsubishi Chem Ind Ltd | Preparation of polyolefins |
| JPS5285279A (en) * | 1976-01-09 | 1977-07-15 | Mitsubishi Chem Ind Ltd | Polymerization of ethylene |
-
1976
- 1976-02-03 FR FR7602898A patent/FR2340131A1/fr active Granted
-
1977
- 1977-01-28 CA CA270,621A patent/CA1113444A/en not_active Expired
- 1977-01-31 DE DE2703911A patent/DE2703911C2/de not_active Expired
- 1977-02-01 NL NLAANVRAGE7701019,A patent/NL183725C/xx not_active IP Right Cessation
- 1977-02-01 US US05/764,566 patent/US4110248A/en not_active Expired - Lifetime
- 1977-02-01 LU LU76679A patent/LU76679A1/xx unknown
- 1977-02-01 JP JP1019677A patent/JPS5295591A/ja active Granted
- 1977-02-02 GB GB4213/77A patent/GB1531673A/en not_active Expired
- 1977-02-02 BE BE174594A patent/BE851009A/xx not_active IP Right Cessation
- 1977-02-02 IT IT19871/77A patent/IT1074821B/it active
Also Published As
| Publication number | Publication date |
|---|---|
| NL7701019A (nl) | 1977-08-05 |
| JPS5295591A (en) | 1977-08-11 |
| DE2703911C2 (de) | 1986-07-31 |
| FR2340131A1 (fr) | 1977-09-02 |
| US4110248A (en) | 1978-08-29 |
| LU76679A1 (show.php) | 1977-06-27 |
| FR2340131B1 (show.php) | 1981-12-24 |
| BE851009A (fr) | 1977-08-02 |
| GB1531673A (en) | 1978-11-08 |
| JPS5650889B2 (show.php) | 1981-12-02 |
| NL183725B (nl) | 1988-08-01 |
| DE2703911A1 (de) | 1977-08-11 |
| NL183725C (nl) | 1989-01-02 |
| IT1074821B (it) | 1985-04-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |