CA1112397A - Peroxide-catalyzed composition useful for sealing pits and fissures in teeth - Google Patents
Peroxide-catalyzed composition useful for sealing pits and fissures in teethInfo
- Publication number
- CA1112397A CA1112397A CA267,718A CA267718A CA1112397A CA 1112397 A CA1112397 A CA 1112397A CA 267718 A CA267718 A CA 267718A CA 1112397 A CA1112397 A CA 1112397A
- Authority
- CA
- Canada
- Prior art keywords
- parts
- bis
- composition
- weight
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 141
- 238000007789 sealing Methods 0.000 title claims abstract description 20
- 239000003054 catalyst Substances 0.000 claims abstract description 38
- 150000002978 peroxides Chemical class 0.000 claims abstract description 24
- AMFGWXWBFGVCKG-UHFFFAOYSA-N Panavia opaque Chemical compound C1=CC(OCC(O)COC(=O)C(=C)C)=CC=C1C(C)(C)C1=CC=C(OCC(O)COC(=O)C(C)=C)C=C1 AMFGWXWBFGVCKG-UHFFFAOYSA-N 0.000 claims abstract description 23
- DMTMWMUHQLDCKP-UHFFFAOYSA-N 2-[n-(2-hydroxyethyl)-3,4-dimethylanilino]ethanol Chemical compound CC1=CC=C(N(CCO)CCO)C=C1C DMTMWMUHQLDCKP-UHFFFAOYSA-N 0.000 claims abstract description 14
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical group C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 20
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 19
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 19
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000000463 material Substances 0.000 description 43
- 230000014759 maintenance of location Effects 0.000 description 42
- 238000000034 method Methods 0.000 description 24
- 239000003381 stabilizer Substances 0.000 description 20
- 238000002156 mixing Methods 0.000 description 18
- 239000000178 monomer Substances 0.000 description 15
- QUZSUMLPWDHKCJ-UHFFFAOYSA-N bisphenol A dimethacrylate Chemical compound C1=CC(OC(=O)C(=C)C)=CC=C1C(C)(C)C1=CC=C(OC(=O)C(C)=C)C=C1 QUZSUMLPWDHKCJ-UHFFFAOYSA-N 0.000 description 14
- 150000002500 ions Chemical class 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- 239000004615 ingredient Substances 0.000 description 9
- 239000000565 sealant Substances 0.000 description 8
- 238000005530 etching Methods 0.000 description 7
- 239000011230 binding agent Substances 0.000 description 6
- 230000000717 retained effect Effects 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 5
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 5
- 230000007774 longterm Effects 0.000 description 5
- 229920001651 Cyanoacrylate Polymers 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 208000002925 dental caries Diseases 0.000 description 4
- RZXMPPFPUUCRFN-UHFFFAOYSA-N p-toluidine Chemical compound CC1=CC=C(N)C=C1 RZXMPPFPUUCRFN-UHFFFAOYSA-N 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- JUVSRZCUMWZBFK-UHFFFAOYSA-N 2-[n-(2-hydroxyethyl)-4-methylanilino]ethanol Chemical compound CC1=CC=C(N(CCO)CCO)C=C1 JUVSRZCUMWZBFK-UHFFFAOYSA-N 0.000 description 3
- MWCLLHOVUTZFKS-UHFFFAOYSA-N Methyl cyanoacrylate Chemical compound COC(=O)C(=C)C#N MWCLLHOVUTZFKS-UHFFFAOYSA-N 0.000 description 3
- 238000011049 filling Methods 0.000 description 3
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 3
- 230000002028 premature Effects 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- XFCMNSHQOZQILR-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOC(=O)C(C)=C XFCMNSHQOZQILR-UHFFFAOYSA-N 0.000 description 2
- DOLQYFPDPKPQSS-UHFFFAOYSA-N 3,4-dimethylaniline Chemical compound CC1=CC=C(N)C=C1C DOLQYFPDPKPQSS-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 150000001448 anilines Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000012933 diacyl peroxide Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000011256 inorganic filler Substances 0.000 description 2
- 229910003475 inorganic filler Inorganic materials 0.000 description 2
- -1 methyl- Chemical group 0.000 description 2
- 239000002685 polymerization catalyst Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- NSMXQKNUPPXBRG-SECBINFHSA-N (R)-lisofylline Chemical compound O=C1N(CCCC[C@H](O)C)C(=O)N(C)C2=C1N(C)C=N2 NSMXQKNUPPXBRG-SECBINFHSA-N 0.000 description 1
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 1
- AFTBJQDQENGCPC-UHFFFAOYSA-N 2,5-ditert-butyl-4-methylphenol Chemical compound CC1=CC(C(C)(C)C)=C(O)C=C1C(C)(C)C AFTBJQDQENGCPC-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- AFBPFSWMIHJQDM-UHFFFAOYSA-N N-methylaniline Chemical compound CNC1=CC=CC=C1 AFBPFSWMIHJQDM-UHFFFAOYSA-N 0.000 description 1
- 235000014676 Phragmites communis Nutrition 0.000 description 1
- AMUNHMVMESMYQL-UHFFFAOYSA-N [2-hydroxy-3-[4-[2-[4-[2-hydroxy-3-(2-methylprop-2-enoyloxy)propyl]phenyl]propan-2-yl]phenyl]propyl] 2-methylprop-2-enoate Chemical compound C1=CC(CC(O)COC(=O)C(=C)C)=CC=C1C(C)(C)C1=CC=C(CC(O)COC(=O)C(C)=C)C=C1 AMUNHMVMESMYQL-UHFFFAOYSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- QXAITBQSYVNQDR-UHFFFAOYSA-N amitraz Chemical compound C=1C=C(C)C=C(C)C=1N=CN(C)C=NC1=CC=C(C)C=C1C QXAITBQSYVNQDR-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000012612 commercial material Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- MCWXGJITAZMZEV-UHFFFAOYSA-N dimethoate Chemical compound CNC(=O)CSP(=S)(OC)OC MCWXGJITAZMZEV-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 210000005069 ears Anatomy 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000003955 fissure sealant Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- LHGVFZTZFXWLCP-UHFFFAOYSA-N guaiacol Chemical compound COC1=CC=CC=C1O LHGVFZTZFXWLCP-UHFFFAOYSA-N 0.000 description 1
- 229940063557 methacrylate Drugs 0.000 description 1
- 229940102838 methylmethacrylate Drugs 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000000068 pit and fissure sealant Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- NXLOLUFNDSBYTP-UHFFFAOYSA-N retene Chemical compound C1=CC=C2C3=CC=C(C(C)C)C=C3C=CC2=C1C NXLOLUFNDSBYTP-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Health & Medical Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Plastic & Reconstructive Surgery (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dental Preparations (AREA)
- Polymerization Catalysts (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US64100275A | 1975-12-15 | 1975-12-15 | |
| US641,002 | 1975-12-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1112397A true CA1112397A (en) | 1981-11-10 |
Family
ID=24570536
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA267,718A Expired CA1112397A (en) | 1975-12-15 | 1976-12-13 | Peroxide-catalyzed composition useful for sealing pits and fissures in teeth |
Country Status (16)
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59130806A (ja) * | 1983-01-17 | 1984-07-27 | Kuraray Co Ltd | 歯の小窩裂溝封鎖用組成物 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3066112A (en) * | 1959-01-30 | 1962-11-27 | Rafael L Bowen | Dental filling material comprising vinyl silane treated fused silica and a binder consisting of the reaction product of bis phenol and glycidyl acrylate |
| US3256254A (en) * | 1962-08-28 | 1966-06-14 | Du Pont | Oxycarbocyclic ester compositions containing aryl peroxides and tertiary aromatic amines, polymerizable in air |
| BE788670R (fr) * | 1968-04-08 | 1973-03-12 | Johnson & Johnson | Compositions |
| US3580955A (en) * | 1968-04-18 | 1971-05-25 | Pennwalt Corp | Auto-oxidation of aldehydes in the presence of acylating agents |
| US3539533A (en) * | 1968-06-14 | 1970-11-10 | Johnson & Johnson | Dental filling material |
| US3541068A (en) * | 1968-07-12 | 1970-11-17 | Minnesota Mining & Mfg | Dental restorative compositions having enhanced stability |
| US3663501A (en) * | 1970-06-11 | 1972-05-16 | Johnson & Johnson | Adhesive cement |
| US3799985A (en) * | 1971-11-15 | 1974-03-26 | Erickson W Co | N,n-bis(2-hydroxyethyl)-3,4,5-trimethylaniline |
| ZA728928B (en) * | 1972-01-03 | 1973-09-26 | Lee Pharmaceuticals | Dental adhesive composites |
| US3835090A (en) * | 1972-02-03 | 1974-09-10 | Johnson & Johnson | Dental restorative cement compositions |
| NO754397L (enrdf_load_stackoverflow) * | 1975-01-02 | 1976-07-05 | Johnson & Johnson |
-
1976
- 1976-12-13 DE DE2656385A patent/DE2656385C3/de not_active Expired - Lifetime
- 1976-12-13 NZ NZ182875A patent/NZ182875A/xx unknown
- 1976-12-13 CA CA267,718A patent/CA1112397A/en not_active Expired
- 1976-12-13 AU AU20513/76A patent/AU511177B2/en not_active Expired
- 1976-12-14 ZA ZA00767432A patent/ZA767432B/xx unknown
- 1976-12-14 SE SE7614051A patent/SE7614051L/ unknown
- 1976-12-14 GB GB52095/76A patent/GB1557263A/en not_active Expired
- 1976-12-14 IL IL51105A patent/IL51105A/xx unknown
- 1976-12-15 CH CH1578676A patent/CH633178A5/de not_active IP Right Cessation
- 1976-12-15 JP JP51149918A patent/JPS5273592A/ja active Granted
- 1976-12-15 PH PH19253A patent/PH12797A/en unknown
- 1976-12-15 FR FR7637789A patent/FR2335194A1/fr active Granted
- 1976-12-15 BE BE173297A patent/BE849447A/xx not_active IP Right Cessation
- 1976-12-15 BR BR7608427A patent/BR7608427A/pt unknown
- 1976-12-15 NL NL7613934A patent/NL7613934A/xx not_active Application Discontinuation
- 1976-12-23 IN IN2254/CAL/76A patent/IN145460B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5273592A (en) | 1977-06-20 |
| GB1557263A (en) | 1979-12-05 |
| PH12797A (en) | 1979-08-17 |
| DE2656385C2 (enrdf_load_stackoverflow) | 1988-09-29 |
| AU2051376A (en) | 1978-06-22 |
| BE849447A (fr) | 1977-06-15 |
| NL7613934A (nl) | 1977-06-17 |
| NZ182875A (en) | 1978-09-20 |
| BR7608427A (pt) | 1977-12-13 |
| FR2335194B1 (enrdf_load_stackoverflow) | 1982-04-30 |
| DE2656385C3 (de) | 1995-03-23 |
| CH633178A5 (en) | 1982-11-30 |
| ZA767432B (en) | 1978-07-26 |
| DE2656385A1 (de) | 1977-06-16 |
| JPS555791B2 (enrdf_load_stackoverflow) | 1980-02-09 |
| AU511177B2 (en) | 1980-07-31 |
| SE7614051L (sv) | 1977-06-16 |
| IL51105A0 (en) | 1977-02-28 |
| IL51105A (en) | 1979-12-30 |
| FR2335194A1 (fr) | 1977-07-15 |
| IN145460B (enrdf_load_stackoverflow) | 1978-10-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |