CA1102478A - Coupled resinous diene copolymer with good integral hinge flex life and high hardness - Google Patents
Coupled resinous diene copolymer with good integral hinge flex life and high hardnessInfo
- Publication number
- CA1102478A CA1102478A CA274,950A CA274950A CA1102478A CA 1102478 A CA1102478 A CA 1102478A CA 274950 A CA274950 A CA 274950A CA 1102478 A CA1102478 A CA 1102478A
- Authority
- CA
- Canada
- Prior art keywords
- monovinyl
- aromatic compound
- substituted aromatic
- molecular weight
- range
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001577 copolymer Polymers 0.000 title claims abstract description 12
- 239000003999 initiator Substances 0.000 claims abstract description 44
- 229920000642 polymer Polymers 0.000 claims abstract description 41
- 150000001491 aromatic compounds Chemical class 0.000 claims abstract description 39
- 150000001993 dienes Chemical class 0.000 claims abstract description 34
- 239000000178 monomer Substances 0.000 claims abstract description 26
- 229920001400 block copolymer Polymers 0.000 claims abstract description 12
- 238000005859 coupling reaction Methods 0.000 claims abstract description 7
- 230000008878 coupling Effects 0.000 claims abstract description 5
- 238000010168 coupling process Methods 0.000 claims abstract description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 85
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 8
- 239000007822 coupling agent Substances 0.000 claims description 4
- 235000012424 soybean oil Nutrition 0.000 claims description 3
- 239000003549 soybean oil Substances 0.000 claims description 3
- 125000003700 epoxy group Chemical group 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims 6
- 230000000379 polymerizing effect Effects 0.000 claims 5
- 125000002897 diene group Chemical group 0.000 claims 2
- 238000007792 addition Methods 0.000 abstract description 30
- 125000003118 aryl group Chemical class 0.000 abstract description 14
- 239000012467 final product Substances 0.000 abstract description 2
- 239000000047 product Substances 0.000 abstract description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 abstract 1
- 239000004793 Polystyrene Substances 0.000 description 8
- 238000006116 polymerization reaction Methods 0.000 description 8
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 7
- 229920002223 polystyrene Polymers 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 6
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 6
- 239000000306 component Substances 0.000 description 6
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 239000004471 Glycine Substances 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical group [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 150000002641 lithium Chemical group 0.000 description 3
- 229910052744 lithium Inorganic materials 0.000 description 3
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- HIBWGGKDGCBPTA-UHFFFAOYSA-N C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 Chemical compound C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 HIBWGGKDGCBPTA-UHFFFAOYSA-N 0.000 description 1
- OPFTUNCRGUEPRZ-QLFBSQMISA-N Cyclohexane Natural products CC(=C)[C@@H]1CC[C@@](C)(C=C)[C@H](C(C)=C)C1 OPFTUNCRGUEPRZ-QLFBSQMISA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 244000228957 Ferula foetida Species 0.000 description 1
- 102100040304 GDNF family receptor alpha-like Human genes 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 108010008488 Glycylglycine Proteins 0.000 description 1
- 101001038371 Homo sapiens GDNF family receptor alpha-like Proteins 0.000 description 1
- MMPOTNFPDMJTRR-UHFFFAOYSA-N OOOOOOOOOOO Chemical compound OOOOOOOOOOO MMPOTNFPDMJTRR-UHFFFAOYSA-N 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- YMAWOPBAYDPSLA-UHFFFAOYSA-N glycylglycine Chemical compound [NH3+]CC(=O)NCC([O-])=O YMAWOPBAYDPSLA-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 125000001979 organolithium group Chemical group 0.000 description 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N phthalic acid di-n-butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000011414 polymer cement Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
- C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
- C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C08G81/021—Block or graft polymers containing only sequences of polymers of C08C or C08F
- C08G81/022—Block or graft polymers containing only sequences of polymers of C08C or C08F containing sequences of polymers of conjugated dienes and of polymers of alkenyl aromatic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/699,731 US4091053A (en) | 1976-06-24 | 1976-06-24 | Coupled resinous diene copolymer with good integral hinge flex life and high hardness |
| US699,731 | 1976-06-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1102478A true CA1102478A (en) | 1981-06-02 |
Family
ID=24810655
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA274,950A Expired CA1102478A (en) | 1976-06-24 | 1977-03-28 | Coupled resinous diene copolymer with good integral hinge flex life and high hardness |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4091053A (OSRAM) |
| JP (1) | JPS53286A (OSRAM) |
| AU (1) | AU500247B2 (OSRAM) |
| BE (1) | BE856066A (OSRAM) |
| BR (1) | BR7703793A (OSRAM) |
| CA (1) | CA1102478A (OSRAM) |
| ES (1) | ES459990A1 (OSRAM) |
| GB (1) | GB1586233A (OSRAM) |
| MX (1) | MX148218A (OSRAM) |
Families Citing this family (73)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4180530A (en) * | 1979-02-05 | 1979-12-25 | Arco Polymers, Inc. | Clear impact resistant thermoplastic star-block copolymers |
| US4221884A (en) * | 1979-05-14 | 1980-09-09 | Arco Polymers, Inc. | Clear impact resistant thermoplastic star-block copolymers |
| US4412941A (en) * | 1981-10-22 | 1983-11-01 | Phillips Petroleum Company | Recording disc compositions comprising polymers of monovinyl-substituted hydrocarbons, conductive carbon black and lubricants |
| US4403074A (en) * | 1982-01-13 | 1983-09-06 | Phillips Petroleum Company | Clear haze-free impact-resistant resinous polymers |
| US4405754A (en) * | 1982-01-13 | 1983-09-20 | Phillips Petroleum Company | Haze-free, clear, impact-resistant resinous polymers |
| US4562222A (en) * | 1982-09-23 | 1985-12-31 | General Electric Company | Polycarbonate resin mixtures |
| US4514588A (en) * | 1982-12-28 | 1985-04-30 | Phillips Petroleum Company | Encapsulated electronic components and encapsulation compositions |
| US4584346A (en) * | 1984-02-29 | 1986-04-22 | Phillips Petroleum Company | Craze-resistant transparent resinous polymodal block copolymers |
| US4574134A (en) * | 1984-11-09 | 1986-03-04 | Phillips Petroleum Company | Antihaze compositions and process |
| US4788232A (en) * | 1985-03-11 | 1988-11-29 | Phillips Petroleum Company | Pigment concentrates for resins |
| US4600736A (en) * | 1985-03-11 | 1986-07-15 | Phillips Petroleum Company | Pigment concentrates for resins |
| JPS63118343A (ja) * | 1986-11-07 | 1988-05-23 | Japan Synthetic Rubber Co Ltd | 共役ジエン系ゴム組成物 |
| LU86698A1 (fr) * | 1986-12-04 | 1988-07-14 | Labofina Sa | Procede pour fabriquer des copolymeres blocs transparents |
| DE3714710A1 (de) * | 1987-05-02 | 1988-11-17 | Basf Ag | Thermoplastische formmassen auf basis von polyphenylenether |
| BE1000914A4 (fr) * | 1987-09-21 | 1989-05-16 | Labofina Sa | Procede de decoloration de polymeres resineux du type vinylaromatique-diene conjugue. |
| US4956408A (en) * | 1988-06-13 | 1990-09-11 | Phillips Petroleum Company | Complex acrylates as stabilizer for conjugated diene/monovinyl aromatic copolymers |
| DE3910259A1 (de) * | 1989-03-30 | 1990-10-04 | Basf Ag | Antiblockend ausgeruestete thermoplastische formmasse, verfahren zu ihrer herstellung und ihre verwendung |
| US5237006A (en) * | 1990-09-28 | 1993-08-17 | General Electric Company | Thermoplastic resin compositions containing polyphenylene ethers and polyesters |
| CA2082765A1 (en) * | 1991-12-31 | 1993-07-01 | Jay K. Gianchandai | Compositions which contain polyphenylene ether and polyamide resin |
| US5296547A (en) * | 1993-01-28 | 1994-03-22 | Minnesota Mining And Manufacturing Company | Block copolymer having mixed molecular weight endblocks |
| US5412031A (en) * | 1993-05-25 | 1995-05-02 | Minnesota Mining & Manufacturing Company | Multi-arm block copolymers, and pressure sensitive adhesive and tape employing a multi-arm elastomeric block copolymer |
| US5360875A (en) * | 1993-09-10 | 1994-11-01 | Shell Oil Company | Method for producing coupled asymmetric polymers |
| US6153695A (en) | 1994-02-14 | 2000-11-28 | Fina Research, S.A. | Process for the preparation of block copolymers |
| CA2193131A1 (en) * | 1994-06-16 | 1995-12-21 | Konrad Knoll | Thermoplastic molding compound |
| US6835778B2 (en) * | 1995-08-29 | 2004-12-28 | Chevron Phillips Chemical Company Lp | Conjugated diene/monovinylarene block copolymers blends |
| DE19621734A1 (de) | 1996-05-30 | 1997-12-04 | Basf Ag | Flammwidrige thermoplastische Formmassen auf Basis von Polyphenylenethern |
| DE19621732A1 (de) | 1996-05-30 | 1997-12-04 | Basf Ag | Flammwidrige thermoplastische Formmassen mit verbesserter Tropffestigkeit |
| DE19642491A1 (de) | 1996-10-15 | 1998-04-16 | Basf Ag | Flammwidrige thermoplastische Formmassen auf Basis von Polyphenylenethern und vinylaromatischen Polymeren |
| US6127487A (en) * | 1998-10-14 | 2000-10-03 | Phillips Petroleum Company | Process to produce coupled block copolymers and said copolymers |
| EP1116742A1 (en) * | 2000-01-12 | 2001-07-18 | Fina Research S.A. | S-B-S compositions |
| US6630531B1 (en) | 2000-02-02 | 2003-10-07 | 3M Innovative Properties Company | Adhesive for bonding to low surface energy surfaces |
| US20030211308A1 (en) * | 2001-02-02 | 2003-11-13 | Khandpur Ashish K | Adhesive for bonding to low surface energy surfaces |
| EP1138604A1 (en) | 2000-03-30 | 2001-10-04 | Fina Research S.A. | Glossy plastic containers |
| DE602004021570D1 (de) * | 2003-03-19 | 2009-07-30 | Denki Kagaku Kogyo Kk | Sternförmig verzweigtes blockcopolymer enthaltende blockcopolymermischung |
| KR101023000B1 (ko) | 2003-07-28 | 2011-03-22 | 덴끼 가가꾸 고교 가부시키가이샤 | 블록 공중합체 조성물 |
| US20050090587A1 (en) * | 2003-10-28 | 2005-04-28 | Dunn John E. | Ultraviolet light stability of monovinylarene-conjugated diene copolymer compositions |
| US7037980B2 (en) * | 2003-11-10 | 2006-05-02 | Chevron Phillips Chemical Company, Lp | Monovinylarene/conjugated diene copolymers having lower glass transition temperatures |
| US20050166551A1 (en) * | 2004-02-02 | 2005-08-04 | Keane J. A. | Multilayer high clarity shrink film comprising monovinylarene-conjugated diene copolymer |
| US7351767B2 (en) * | 2004-02-20 | 2008-04-01 | Chevron Phillips Chemical Company, Lp | Composition for monovinylrenic-based shrink label films |
| US20060235118A1 (en) * | 2005-04-18 | 2006-10-19 | Selby Larry M | Antiblock additives for monovinylarene-conjugated diene block copolymers |
| US7737216B2 (en) * | 2006-01-26 | 2010-06-15 | Chevron Phillips Chemical Company Lp | Monovinylarene conjugated diene block copolymer compositions for shrinkable films |
| WO2007136513A1 (en) * | 2006-05-17 | 2007-11-29 | Nova Chemicals Inc. | Multilayered structures and their use as optical storage media |
| JP5431153B2 (ja) | 2006-07-26 | 2014-03-05 | ビーエーエスエフ ソシエタス・ヨーロピア | 高剛性の熱可塑性成形材料 |
| US20080045656A1 (en) * | 2006-08-18 | 2008-02-21 | General Electric Company | Poly(arylene ether) composition, method, and article |
| US20080045655A1 (en) * | 2006-08-18 | 2008-02-21 | General Electric Company | Poly(arylene ether) composition, method, and article |
| US20080081874A1 (en) * | 2006-09-29 | 2008-04-03 | Kim Balfour | Poly(arylene ether) composition, method, and article |
| US20080081879A1 (en) * | 2006-09-29 | 2008-04-03 | Kim Balfour | Crosslinked block copolymer composition and method |
| US8415429B2 (en) | 2006-12-11 | 2013-04-09 | Chervron Phillips Chemical Company LP | Styrene butadiene block copolymers for film applications |
| ATE547474T1 (de) * | 2007-07-10 | 2012-03-15 | Basf Se | Flammgeschütztes, elastisches blockcopolymerisat |
| ES2476740T3 (es) * | 2008-03-13 | 2014-07-15 | Kraton Polymers Us Llc | Composiciones de miktopol�meros nuevas |
| US20100272975A1 (en) * | 2009-04-23 | 2010-10-28 | Chevron Phillips Chemical Company Lp | System and method for the production and use of lamination films |
| US20120208909A1 (en) | 2009-10-09 | 2012-08-16 | Basf Se | Polymer mixtures of polystyrene having styrene butadiene block copolymers |
| KR101934127B1 (ko) | 2010-10-27 | 2018-12-31 | 이네오스 스티롤루션 유럽 게엠베하 | 적어도 2개의 상이한 별 아암을 갖는 별형 분자 구조를 갖는 엘라스토머 블록 공중합체 |
| CN103254544B (zh) * | 2012-02-21 | 2015-10-21 | 中国石油化工股份有限公司 | 单乙烯基芳烃-共轭二烯烃共聚物组合物和聚合方法及由该方法制备的聚合物 |
| CN104395365B (zh) * | 2012-06-29 | 2017-01-18 | 苯领欧洲股份公司 | 一种制备不对称型的、星形‑支链乙烯基芳香族‑二烯嵌段共聚物的方法 |
| US11130276B2 (en) | 2013-12-18 | 2021-09-28 | Ineos Styrolution Group Gmbh | Use of molding materials based on vinyl aromatic/diene block copolymers for 3-D-printing |
| US9441090B1 (en) | 2015-03-12 | 2016-09-13 | Chevron Phillips Chemical Company Lp | Methods for controlling hardness of styrene-butadiene block copolymers |
| US9598524B1 (en) | 2015-09-18 | 2017-03-21 | Chevron Phillips Chemical Company Lp | Styrene-butadiene block copolymers with a terminal butadiene block for tubing applications |
| US9540475B2 (en) | 2015-03-12 | 2017-01-10 | Chevron Phillips Chemical Company Lp | Styrene-butadiene block copolymers for tubing applications |
| US9738781B2 (en) | 2015-09-03 | 2017-08-22 | Ineos Styrolution Group Gmbh | Blends of styrene-butadiene block copolymer with styrenic thermoplastic elastomers for tubing applications |
| US9828455B2 (en) | 2016-02-24 | 2017-11-28 | Ineos Styrolution Group Gmbh | Styrene-butadiene block copolymers with an internal butadiene block for tubing applications |
| US10023676B2 (en) | 2016-02-24 | 2018-07-17 | Ineos Styrolution Group Gmbh | Styrene-butadiene block copolymers with an internal butadiene block for tubing applications |
| EP3445815B1 (en) | 2016-04-21 | 2021-06-09 | INEOS Styrolution Group GmbH | Abs molding composition having improved crack and chemical resistance and its use |
| CN109790354B (zh) | 2016-06-29 | 2021-12-28 | 英力士苯领集团股份公司 | 含至少一种乙烯基芳族二烯嵌段共聚物和特定量油的聚合物组合物 |
| EP3585837B1 (en) | 2017-02-21 | 2020-11-18 | INEOS Styrolution Group GmbH | Intrinsically non-blocking shrink sleeve material |
| WO2018154513A1 (en) * | 2017-02-24 | 2018-08-30 | Zeus Industrial Products, Inc. | Polymer blends |
| EP3434697B1 (en) * | 2017-07-27 | 2021-09-01 | Trinseo Europe GmbH | In-situ polymer blend for a tire |
| US11603464B2 (en) | 2018-02-16 | 2023-03-14 | Ineos Styrolution Group Gmbh | High heat resistant ABS molding composition |
| EP3781628B1 (en) | 2018-04-16 | 2021-11-17 | INEOS Styrolution Group GmbH | Ultra-high flow acrylonitrile butadiene styrene copolymer compositions |
| WO2019201782A1 (en) | 2018-04-16 | 2019-10-24 | Ineos Styrolution Group Gmbh | Ultra-high flow styrene acrylonitrile copolymer compositions |
| KR20220051210A (ko) | 2019-08-21 | 2022-04-26 | 이네오스 스티롤루션 그룹 게엠베하 | 높은 escr, 높은 색상 및 열 안정성 및 낮은 박리 경향을 갖는 시트 압출 및 열성형을 위한 abs 성형 조성물 |
| KR102726783B1 (ko) | 2021-09-16 | 2024-11-07 | 주식회사 에스켐 | 2차 알코올을 이용한 소듐 알콕사이드의 제조방법 |
| CN114106272B (zh) * | 2021-12-27 | 2023-10-13 | 广东众和高新科技有限公司 | 一种抗指刮性丁苯树脂及其制备方法 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3639517A (en) * | 1969-09-22 | 1972-02-01 | Phillips Petroleum Co | Resinous branched block copolymers |
-
1976
- 1976-06-24 US US05/699,731 patent/US4091053A/en not_active Expired - Lifetime
-
1977
- 1977-03-28 CA CA274,950A patent/CA1102478A/en not_active Expired
- 1977-06-02 AU AU25793/77A patent/AU500247B2/en not_active Expired
- 1977-06-17 MX MX169520A patent/MX148218A/es unknown
- 1977-06-17 JP JP7197477A patent/JPS53286A/ja active Granted
- 1977-06-17 BR BR7703793A patent/BR7703793A/pt unknown
- 1977-06-21 GB GB25876/77A patent/GB1586233A/en not_active Expired
- 1977-06-22 ES ES459990A patent/ES459990A1/es not_active Expired
- 1977-06-24 BE BE178740A patent/BE856066A/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| BR7703793A (pt) | 1978-04-18 |
| ES459990A1 (es) | 1978-05-01 |
| GB1586233A (en) | 1981-03-18 |
| US4091053A (en) | 1978-05-23 |
| BE856066A (fr) | 1977-12-27 |
| JPS53286A (en) | 1978-01-05 |
| MX148218A (es) | 1983-03-28 |
| AU500247B2 (en) | 1979-05-17 |
| JPS54954B2 (OSRAM) | 1979-01-18 |
| AU2579377A (en) | 1978-12-07 |
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Effective date: 19980602 |