CA1096533A - Process for improving the processability of polyolefins, improved polyolefin compositions, and modifier compositions - Google Patents
Process for improving the processability of polyolefins, improved polyolefin compositions, and modifier compositionsInfo
- Publication number
- CA1096533A CA1096533A CA253,099A CA253099A CA1096533A CA 1096533 A CA1096533 A CA 1096533A CA 253099 A CA253099 A CA 253099A CA 1096533 A CA1096533 A CA 1096533A
- Authority
- CA
- Canada
- Prior art keywords
- acrylic
- methacrylates
- acrylic polymer
- polyolefins
- polyolefin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000098 polyolefin Polymers 0.000 title claims abstract description 32
- 239000000203 mixture Substances 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims abstract description 9
- 239000003607 modifier Substances 0.000 title abstract description 4
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 29
- -1 C22 methacrylates Chemical class 0.000 claims abstract description 23
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 20
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 17
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 150000001253 acrylic acids Chemical class 0.000 claims abstract description 4
- 239000004743 Polypropylene Substances 0.000 claims description 12
- 239000000178 monomer Substances 0.000 claims description 10
- 150000002734 metacrylic acid derivatives Chemical class 0.000 claims description 9
- 229920001155 polypropylene Polymers 0.000 claims description 8
- IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 claims description 4
- 229940119545 isobornyl methacrylate Drugs 0.000 claims description 4
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 239000011347 resin Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 239000006057 Non-nutritive feed additive Substances 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000000071 blow moulding Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- COCLLEMEIJQBAG-UHFFFAOYSA-N 8-methylnonyl 2-methylprop-2-enoate Chemical compound CC(C)CCCCCCCOC(=O)C(C)=C COCLLEMEIJQBAG-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 235000019399 azodicarbonamide Nutrition 0.000 description 1
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002666 chemical blowing agent Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US58748275A | 1975-06-16 | 1975-06-16 | |
| US587,482 | 1975-06-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1096533A true CA1096533A (en) | 1981-02-24 |
Family
ID=24349982
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA253,099A Expired CA1096533A (en) | 1975-06-16 | 1976-05-21 | Process for improving the processability of polyolefins, improved polyolefin compositions, and modifier compositions |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US4094927A (online.php) |
| JP (1) | JPS51151791A (online.php) |
| AU (1) | AU1496976A (online.php) |
| BE (1) | BE843003A (online.php) |
| CA (1) | CA1096533A (online.php) |
| DE (1) | DE2626320A1 (online.php) |
| ES (1) | ES448965A1 (online.php) |
| FR (1) | FR2314934A1 (online.php) |
| GB (1) | GB1549015A (online.php) |
| NL (1) | NL7606431A (online.php) |
| SE (1) | SE7606820L (online.php) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2572410B1 (fr) * | 1984-10-25 | 1987-09-04 | Elf Aquitaine | Copolymeres d'ethylene greffes utilisables notamment comme additifs pour l'inhibition du depot de paraffines dans les huiles brutes et compositions renfermant les huiles et lesdits additifs |
| US5229456A (en) * | 1988-03-29 | 1993-07-20 | Rohm And Haas Company | Graft copolymers and blends thereof with polyolefins |
| US5300570A (en) * | 1989-03-01 | 1994-04-05 | Rohm And Haas Company | Plastic articles with compatibilized barrier resin |
| CA1339231C (en) * | 1989-03-30 | 1997-08-05 | Ratana Kanluen | Polyfunctional polymers as deinking agents |
| US5506307A (en) * | 1995-04-25 | 1996-04-09 | Rohm And Haas Company | Modifier for polypropylene imparting improved melt strength |
| US6300407B1 (en) * | 1998-03-06 | 2001-10-09 | Rohm And Haas Company | Polymeric (meth)acrylate plasticizers and processing aids for elastomers |
| JP4441151B2 (ja) * | 2000-09-29 | 2010-03-31 | 日本製紙株式会社 | 変性ポリオレフィン樹脂と変性ポリオレフィン樹脂組成物及びその用途 |
| CN114369197B (zh) * | 2022-01-18 | 2022-10-11 | 熵能创新材料(珠海)有限公司 | 一种聚丙烯酸烷烃酯类加工助剂以及包含该加工助剂的可熔融加工组合物 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3156743A (en) * | 1959-12-21 | 1964-11-10 | Eastman Kodak Co | Dyeable polypropylene fibers containing acrylate and methacrylate units in polymeric form |
| FR1310847A (fr) * | 1961-03-10 | 1962-11-30 | Toyo Rayon Co Ltd | Compositions polyoléfiniques aptes à la teinture |
| US3240552A (en) * | 1961-05-15 | 1966-03-15 | Eastman Kodak Co | Crystalline polymerized alpha-monoolefinic hydrocarbons containing an organic addition polymer and a metal compound to improve their dyeability |
| US3228790A (en) * | 1961-05-26 | 1966-01-11 | Johnson & Johnson | Nonwoven fabric containing polyolefin fibers bonded together with a mixture of polyolefin and acrylic resins |
| US3554913A (en) * | 1969-08-15 | 1971-01-12 | Us Army | Friction reduction by copolymer of n-alkyl methacrylates and methacrylic acid in solution |
| US3694388A (en) * | 1970-07-02 | 1972-09-26 | Canadian Ind | Acrylic polymers |
| US3764587A (en) * | 1971-04-02 | 1973-10-09 | Du Pont | Acrylic interpolymers for flexographic inks |
| US3890292A (en) * | 1973-05-23 | 1975-06-17 | Daubert Chemical Co | Adhesive compositions and tapes |
| CA1096532A (en) * | 1974-07-01 | 1981-02-24 | Rohm And Haas Company | Process for improving the processability of polyolefins and improved polyolefin compositions |
-
1976
- 1976-05-21 CA CA253,099A patent/CA1096533A/en not_active Expired
- 1976-05-31 JP JP51063468A patent/JPS51151791A/ja active Pending
- 1976-06-10 GB GB24021/76A patent/GB1549015A/en not_active Expired
- 1976-06-11 DE DE19762626320 patent/DE2626320A1/de not_active Withdrawn
- 1976-06-14 NL NL7606431A patent/NL7606431A/xx not_active Application Discontinuation
- 1976-06-15 SE SE7606820A patent/SE7606820L/xx unknown
- 1976-06-16 AU AU14969/76A patent/AU1496976A/en not_active Expired
- 1976-06-16 FR FR7618282A patent/FR2314934A1/fr active Granted
- 1976-06-16 BE BE167968A patent/BE843003A/xx unknown
- 1976-06-16 ES ES448965A patent/ES448965A1/es not_active Expired
-
1977
- 1977-02-14 US US05/768,514 patent/US4094927A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE2626320A1 (de) | 1977-01-13 |
| ES448965A1 (es) | 1978-03-16 |
| FR2314934A1 (fr) | 1977-01-14 |
| NL7606431A (nl) | 1976-12-20 |
| JPS51151791A (en) | 1976-12-27 |
| BE843003A (fr) | 1976-12-16 |
| GB1549015A (en) | 1979-08-01 |
| SE7606820L (sv) | 1976-12-17 |
| FR2314934B1 (online.php) | 1981-09-25 |
| AU1496976A (en) | 1978-02-09 |
| US4094927A (en) | 1978-06-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |