CA1088246A - Modification of vinylchloride polymers - Google Patents
Modification of vinylchloride polymersInfo
- Publication number
- CA1088246A CA1088246A CA270,832A CA270832A CA1088246A CA 1088246 A CA1088246 A CA 1088246A CA 270832 A CA270832 A CA 270832A CA 1088246 A CA1088246 A CA 1088246A
- Authority
- CA
- Canada
- Prior art keywords
- weight
- parts
- copolymer
- vinylchloride
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 229920000642 polymer Polymers 0.000 title claims abstract description 28
- 238000012986 modification Methods 0.000 title abstract description 3
- 230000004048 modification Effects 0.000 title abstract description 3
- 229920000578 graft copolymer Polymers 0.000 claims abstract description 32
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000000203 mixture Substances 0.000 claims abstract description 22
- 229920001577 copolymer Polymers 0.000 claims abstract description 20
- 229920000126 latex Polymers 0.000 claims abstract description 19
- 239000000178 monomer Substances 0.000 claims abstract description 18
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000004816 latex Substances 0.000 claims abstract description 14
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000003054 catalyst Substances 0.000 claims abstract description 10
- 239000002245 particle Substances 0.000 claims abstract description 10
- 238000001556 precipitation Methods 0.000 claims abstract description 10
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 7
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000004132 cross linking Methods 0.000 claims abstract description 6
- 239000003792 electrolyte Substances 0.000 claims abstract description 6
- 239000000839 emulsion Substances 0.000 claims abstract description 6
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims abstract description 6
- 238000002955 isolation Methods 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 15
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 12
- 239000004800 polyvinyl chloride Substances 0.000 claims description 12
- 150000002148 esters Chemical class 0.000 claims description 5
- 229920001519 homopolymer Polymers 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- 150000002688 maleic acid derivatives Chemical class 0.000 claims description 3
- 150000002825 nitriles Chemical class 0.000 claims description 3
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 3
- 229920001567 vinyl ester resin Polymers 0.000 claims description 3
- 229940044603 styrene Drugs 0.000 abstract 2
- 230000014759 maintenance of location Effects 0.000 abstract 1
- 208000006379 syphilis Diseases 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical group C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- -1 ethylene, propylene Chemical group 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229940102838 methylmethacrylate Drugs 0.000 description 3
- BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical compound CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 description 2
- BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 235000013872 montan acid ester Nutrition 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229960004418 trolamine Drugs 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- SRBSSROHORQGBO-UHFFFAOYSA-N 11-methyldodecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCC(C)C SRBSSROHORQGBO-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 101100353161 Drosophila melanogaster prel gene Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 229940114077 acrylic acid Drugs 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001412 amines Chemical group 0.000 description 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- JXSJBGJIGXNWCI-UHFFFAOYSA-N diethyl 2-[(dimethoxyphosphorothioyl)thio]succinate Chemical compound CCOC(=O)CC(SP(=S)(OC)OC)C(=O)OCC JXSJBGJIGXNWCI-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 229940063559 methacrylic acid Drugs 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229940061319 ovide Drugs 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- 229940117958 vinyl acetate Drugs 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2603992A DE2603992A1 (de) | 1976-02-03 | 1976-02-03 | Modifizierung von vinylchloridpolymerisaten |
| DEP2603992.9 | 1976-02-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1088246A true CA1088246A (en) | 1980-10-21 |
Family
ID=5968893
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA270,832A Expired CA1088246A (en) | 1976-02-03 | 1977-02-01 | Modification of vinylchloride polymers |
Country Status (11)
| Country | Link |
|---|---|
| JP (1) | JPS5295760A (show.php) |
| AU (1) | AU502479B2 (show.php) |
| BE (1) | BE851041A (show.php) |
| BR (1) | BR7700616A (show.php) |
| CA (1) | CA1088246A (show.php) |
| DE (1) | DE2603992A1 (show.php) |
| ES (1) | ES455416A1 (show.php) |
| FR (1) | FR2340345A1 (show.php) |
| GB (1) | GB1541193A (show.php) |
| IT (1) | IT1083468B (show.php) |
| NL (1) | NL7701043A (show.php) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60108454A (ja) * | 1983-11-18 | 1985-06-13 | Japan Synthetic Rubber Co Ltd | 塩化ビニル系樹脂組成物の製造方法 |
| JP2896378B2 (ja) * | 1989-03-23 | 1999-05-31 | ジェイエスアール株式会社 | ゴム変性スチレン系樹脂組成物 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL300635A (show.php) * | 1962-11-19 | |||
| DE1470866B2 (de) * | 1962-12-24 | 1971-01-21 | Kanegafuchi Chemical Industry Co, Ltd, Osaka (Japan) | Thermoplastische Formmassen |
| GB1086888A (en) * | 1965-01-25 | 1967-10-11 | Kanegafuchi Chemical Ind | Vinyl chloride-butadiene resin compositions and method of manufacture |
| US3670052A (en) * | 1965-01-25 | 1972-06-13 | Kanegafuchi Chemical Ind | Thermoplastic vinyl resin compositions, and method of manufacture |
| BE719425A (show.php) * | 1967-08-19 | 1969-01-16 | ||
| US3842144A (en) * | 1971-10-07 | 1974-10-15 | Kureha Chemical Ind Co Ltd | Process for producing blends of vinyl chloride resin composition |
| JPS5337908B2 (show.php) * | 1973-07-26 | 1978-10-12 |
-
1976
- 1976-02-03 DE DE2603992A patent/DE2603992A1/de not_active Withdrawn
-
1977
- 1977-01-01 BR BR7700616A patent/BR7700616A/pt unknown
- 1977-01-27 AU AU21717/77A patent/AU502479B2/en not_active Expired
- 1977-01-28 ES ES455416A patent/ES455416A1/es not_active Expired
- 1977-01-31 GB GB3828/77A patent/GB1541193A/en not_active Expired
- 1977-02-01 IT IT47864/77A patent/IT1083468B/it active
- 1977-02-01 JP JP932477A patent/JPS5295760A/ja active Pending
- 1977-02-01 NL NL7701043A patent/NL7701043A/xx not_active Application Discontinuation
- 1977-02-01 CA CA270,832A patent/CA1088246A/en not_active Expired
- 1977-02-03 BE BE174619A patent/BE851041A/xx not_active IP Right Cessation
- 1977-02-03 FR FR7703063A patent/FR2340345A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| GB1541193A (en) | 1979-02-21 |
| BR7700616A (pt) | 1977-10-04 |
| BE851041A (fr) | 1977-08-03 |
| JPS5295760A (en) | 1977-08-11 |
| FR2340345A1 (fr) | 1977-09-02 |
| ES455416A1 (es) | 1978-01-01 |
| AU2171777A (en) | 1978-08-03 |
| FR2340345B1 (show.php) | 1983-08-19 |
| NL7701043A (nl) | 1977-08-05 |
| AU502479B2 (en) | 1979-07-26 |
| DE2603992A1 (de) | 1977-08-04 |
| IT1083468B (it) | 1985-05-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3954913A (en) | Stabilized nitrile polymers | |
| US4009226A (en) | Abs moulding compositions | |
| US3497571A (en) | Acrylic ester-cyclic ester elastomeric compositions | |
| US2802809A (en) | Compositions of vinyl chloride resins and graft copolymers of acrylonitrile-type monomer compositions upon diene polymers and articles formed therefrom | |
| US2538779A (en) | Mixture of acrylonitrile polymer and butadiene copolymer | |
| US3403122A (en) | Emulsion polymerization of water insoluble omega-(n-perfluoroalkanesulfonyl) aminoalkyl acrylates or methacrylates | |
| US2925399A (en) | Composition comprising a mixture of an elastomeric copolymer of butadiene and a thermoplastic copolymer of styrene and acrylonitrile and process for producing same | |
| CA1071798A (en) | Thermally stable high nitrile resins and method for producing the same | |
| US4144286A (en) | Thermoplastic PVC resin compositions | |
| US3538194A (en) | Preparation of rubber modified plastics | |
| CA1088246A (en) | Modification of vinylchloride polymers | |
| US3600465A (en) | Thermoplastic moulding compositions | |
| EP0155897B1 (en) | Incorporation of functionalized monomers | |
| EP0045132A1 (en) | Blends of high nitrile resins and hydrophobic nylons and production thereof | |
| JPH05265250A (ja) | トナー用樹脂の製造方法、トナー用樹脂およびトナー組成物 | |
| JPS58210942A (ja) | 耐スコーチ性の改善されたカルボキシル化ゴム組成物 | |
| US4859744A (en) | Process for the production of graft polymers of high rubber content | |
| US3821348A (en) | Process for recovering nitrile polymer solids from latex | |
| US2384569A (en) | Copolymers of dienes and olefinic dicarboxylic acid esters | |
| EP0180985B1 (en) | Process for preparing thermoplastic resin | |
| JP2634397B2 (ja) | 熱可塑性樹脂組成物の製造方法 | |
| JPS62290701A (ja) | 官能化されたモノマ−の改良された導入法 | |
| US3759859A (en) | Emulsion copolymerization | |
| CA1070043A (en) | Process for producing thermoplastic resin | |
| JPH01256506A (ja) | α―メチルスチレン及びアクリロニトリルの共重合体及びその製造方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |