CA1073041A - Secondary battery with separate charge and discharge zones - Google Patents
Secondary battery with separate charge and discharge zonesInfo
- Publication number
- CA1073041A CA1073041A CA263,564A CA263564A CA1073041A CA 1073041 A CA1073041 A CA 1073041A CA 263564 A CA263564 A CA 263564A CA 1073041 A CA1073041 A CA 1073041A
- Authority
- CA
- Canada
- Prior art keywords
- zone
- cathodic
- reactant
- charge
- discharge
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000376 reactant Substances 0.000 claims abstract description 155
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 95
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 91
- 239000011593 sulfur Substances 0.000 claims abstract description 89
- 239000005077 polysulfide Substances 0.000 claims abstract description 56
- 150000008117 polysulfides Polymers 0.000 claims abstract description 56
- 229920001021 polysulfide Polymers 0.000 claims abstract description 54
- 238000003860 storage Methods 0.000 claims abstract description 53
- 239000000463 material Substances 0.000 claims abstract description 34
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 33
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 32
- 150000003839 salts Chemical class 0.000 claims abstract description 29
- 229910052751 metal Inorganic materials 0.000 claims description 51
- 239000002184 metal Substances 0.000 claims description 51
- 239000004020 conductor Substances 0.000 claims description 41
- 238000010349 cathodic reaction Methods 0.000 claims description 39
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 35
- 230000004888 barrier function Effects 0.000 claims description 34
- 239000000203 mixture Substances 0.000 claims description 34
- 229910002804 graphite Inorganic materials 0.000 claims description 32
- 239000010439 graphite Substances 0.000 claims description 32
- 238000006243 chemical reaction Methods 0.000 claims description 25
- 238000012546 transfer Methods 0.000 claims description 13
- 150000002739 metals Chemical class 0.000 claims description 12
- 229920006395 saturated elastomer Polymers 0.000 claims description 12
- 239000006260 foam Substances 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 9
- 239000003513 alkali Substances 0.000 claims description 8
- 239000010935 stainless steel Substances 0.000 claims description 6
- 229910001220 stainless steel Inorganic materials 0.000 claims description 6
- 238000005086 pumping Methods 0.000 claims description 4
- 229910021397 glassy carbon Inorganic materials 0.000 claims description 3
- 230000007704 transition Effects 0.000 claims description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 2
- 229910052787 antimony Inorganic materials 0.000 claims 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims 2
- 229910052797 bismuth Inorganic materials 0.000 claims 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims 2
- 230000000737 periodic effect Effects 0.000 claims 2
- 210000004027 cell Anatomy 0.000 description 102
- 238000000034 method Methods 0.000 description 12
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 10
- 239000007784 solid electrolyte Substances 0.000 description 10
- 229910000831 Steel Inorganic materials 0.000 description 8
- 238000013461 design Methods 0.000 description 8
- 239000003792 electrolyte Substances 0.000 description 8
- 239000010959 steel Substances 0.000 description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 239000000758 substrate Substances 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 239000007787 solid Substances 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
- 229910002651 NO3 Inorganic materials 0.000 description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 3
- 229910052794 bromium Inorganic materials 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 230000000670 limiting effect Effects 0.000 description 3
- 239000011244 liquid electrolyte Substances 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 3
- 229910000873 Beta-alumina solid electrolyte Inorganic materials 0.000 description 2
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
- 229910015400 FeC13 Inorganic materials 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 102100026933 Myelin-associated neurite-outgrowth inhibitor Human genes 0.000 description 2
- 230000001154 acute effect Effects 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052810 boron oxide Inorganic materials 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 2
- ZLCCLBKPLLUIJC-UHFFFAOYSA-L disodium tetrasulfane-1,4-diide Chemical compound [Na+].[Na+].[S-]SS[S-] ZLCCLBKPLLUIJC-UHFFFAOYSA-L 0.000 description 2
- 239000007772 electrode material Substances 0.000 description 2
- 229910052734 helium Inorganic materials 0.000 description 2
- 239000001307 helium Substances 0.000 description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229910052746 lanthanum Inorganic materials 0.000 description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 150000004763 sulfides Chemical class 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- ODPOAESBSUKMHD-UHFFFAOYSA-L 6,7-dihydrodipyrido[1,2-b:1',2'-e]pyrazine-5,8-diium;dibromide Chemical compound [Br-].[Br-].C1=CC=[N+]2CC[N+]3=CC=CC=C3C2=C1 ODPOAESBSUKMHD-UHFFFAOYSA-L 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000005630 Diquat Substances 0.000 description 1
- HJEINPVZRDJRBY-UHFFFAOYSA-N Disul Chemical compound OS(=O)(=O)OCCOC1=CC=C(Cl)C=C1Cl HJEINPVZRDJRBY-UHFFFAOYSA-N 0.000 description 1
- 241001669573 Galeorhinus galeus Species 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 210000003850 cellular structure Anatomy 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910021525 ceramic electrolyte Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- -1 e.g. Substances 0.000 description 1
- 239000011532 electronic conductor Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 238000010285 flame spraying Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000003574 free electron Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052961 molybdenite Inorganic materials 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H01M10/39—Accumulators not provided for in groups H01M10/05-H01M10/34 working at high temperature
- H01M10/3909—Sodium-sulfur cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
- H01M8/184—Regeneration by electrochemical means
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/653,856 US3994745A (en) | 1976-01-30 | 1976-01-30 | Secondary battery with separate charge and discharge zones |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1073041A true CA1073041A (en) | 1980-03-04 |
Family
ID=24622556
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA263,564A Expired CA1073041A (en) | 1976-01-30 | 1976-10-18 | Secondary battery with separate charge and discharge zones |
Country Status (6)
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2332623A1 (fr) * | 1975-11-20 | 1977-06-17 | Comp Generale Electricite | Generateur electrochimique sodium-soufre |
| US4112203A (en) * | 1976-07-06 | 1978-09-05 | The Dow Chemical Company | Alkali metal/sulfur battery |
| US4104448A (en) * | 1976-10-08 | 1978-08-01 | British Railways Board | Alkali metal-sulphur cells |
| GB1540869A (en) * | 1976-12-20 | 1979-02-14 | Chloride Silent Power Ltd | Electrode structures |
| DE3145112A1 (de) * | 1981-11-13 | 1983-05-26 | Brown, Boveri & Cie Ag, 6800 Mannheim | "elektrochemische speicherzelle" |
| US4456664A (en) * | 1983-04-19 | 1984-06-26 | Ford Motor Company | Electronically conductive magnesia doped oxide ceramics for use in sodium sulfur batteries |
| US4456631A (en) * | 1983-04-19 | 1984-06-26 | Ford Motor Company | Electronically conductive lithia doped oxide ceramics for use in sodium sulfur batteries |
| DE3507697A1 (de) * | 1985-03-05 | 1986-09-11 | Brown, Boveri & Cie Ag, 6800 Mannheim | Elektrochemische speicherzelle |
| JPH0215579A (ja) * | 1988-07-01 | 1990-01-19 | Hitachi Ltd | Ｎａ−Ｓ電池とその運転方法、使用方法及びその製造方法 |
| US5578393A (en) * | 1995-03-10 | 1996-11-26 | United States Advanced Battery Consortium | Thermal contact sheet for high temperature batteries |
| US6093504A (en) * | 1996-12-03 | 2000-07-25 | Bliesner; Wayne Thomas | Electro-chemical-thermal rechargeable energy storage cell (ECT cell) |
| US6383360B1 (en) * | 1997-11-24 | 2002-05-07 | Wayne Thomas Bliesner | Electrode and method for use in an electrolysis cell |
| JP3827980B2 (ja) * | 2001-09-21 | 2006-09-27 | 本田技研工業株式会社 | ハイブリッド車両の制御装置 |
| CN102449838B (zh) * | 2009-04-01 | 2015-01-07 | 巴斯夫欧洲公司 | 存储和运输电化学能的方法 |
| US11316199B2 (en) | 2018-01-16 | 2022-04-26 | International Business Machines Corporation | Rechargeable metal halide battery |
| US12288877B2 (en) | 2020-07-13 | 2025-04-29 | International Business Machines Corporation | Rechargeable metal halide battery with intercalation anode |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1137079A (en) * | 1965-10-22 | 1968-12-18 | Ford Motor Co | Batteries |
| US3533848A (en) * | 1967-04-20 | 1970-10-13 | Gen Electric | Sodium-sulfur fuel cell units |
| FR2119117A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1970-12-21 | 1972-08-04 | Comp Generale Electricite | |
| US3672994A (en) * | 1971-01-04 | 1972-06-27 | Gen Electric | Sodium-sulfur cell with third electrode |
| US3740268A (en) * | 1972-01-17 | 1973-06-19 | Gen Electric | Method of charging sodium-sulfur cell |
| US3749603A (en) * | 1972-04-17 | 1973-07-31 | Dow Chemical Co | Alkali metal/sulfur battery having a cathodic current collector coated with molybdenum disulfide |
-
1976
- 1976-01-30 US US05/653,856 patent/US3994745A/en not_active Expired - Lifetime
- 1976-10-18 CA CA263,564A patent/CA1073041A/en not_active Expired
- 1976-10-21 JP JP12558676A patent/JPS5295031A/ja active Granted
- 1976-10-22 FR FR7632007A patent/FR2339964A1/fr active Granted
- 1976-10-29 GB GB45053/76A patent/GB1569113A/en not_active Expired
- 1976-10-29 DE DE2649564A patent/DE2649564C3/de not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2339964A1 (fr) | 1977-08-26 |
| DE2649564A1 (de) | 1977-12-15 |
| GB1569113A (en) | 1980-06-11 |
| US3994745A (en) | 1976-11-30 |
| DE2649564B2 (de) | 1981-02-12 |
| DE2649564C3 (de) | 1981-10-08 |
| FR2339964B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1978-12-15 |
| JPS5728461B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1982-06-16 |
| JPS5295031A (en) | 1977-08-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4084041A (en) | Secondary battery or cell with polysulfide wettable electrode - #2 | |
| CA1073040A (en) | Secondary battery or cell with composite electrode | |
| CA1073041A (en) | Secondary battery with separate charge and discharge zones | |
| CA1060090A (en) | Alkali metal/sulfur battery or cell with single phase sulfur electrode | |
| CA1073525A (en) | Secondary battery or cell with dual electrode | |
| CA1054671A (en) | Alkali metal/sulfur cell with gas fuel cell electrode | |
| CA1062773A (en) | Energy conversion devices with improved electrode shapes | |
| AU2008266715B2 (en) | Energy storage device and cell configuration therefor | |
| US3966492A (en) | Sodium sulfur battery or cell with improved ampere-hour capacity | |
| US4069372A (en) | Electric accumulator with a solid electrolyte | |
| US4945012A (en) | Copper chloride cathode for a secondary battery | |
| CA1134318A (en) | Disposing molten electrolyte adjacent aluminium oxide separator in electrochemical metal recovery from salt | |
| US3847667A (en) | Alkali metal-porous conductive carbon battery having a molten alkali metal chloraluminate electrolyte | |
| JP2018511922A (ja) | ナトリウムイオン伝導性セラミックセパレータを有するナトリウムアルミニウム電池 | |
| US4038465A (en) | Sodium sulfur battery or cell with external storage | |
| US4064325A (en) | Electric storage batteries | |
| USRE30353E (en) | Electric accumulator with a solid electrolyte | |
| CA1162980A (en) | Electrochemical storage cell | |
| CA1042066A (en) | Sodium-aluminum halide, sulfur battery | |
| WO2014159542A1 (en) | Low temperature battery with molten sodium-fsa electrolyte | |
| US4002806A (en) | Secondary battery or cell | |
| CA1042982A (en) | Process for recharging secondary batteries | |
| US4166156A (en) | Secondary battery or cell with pyrolytic graphite coated graphite current collector | |
| US4091151A (en) | Secondary battery or cell with improved rechargeability | |
| US4767684A (en) | Method of chargeability improvement and reduced corrosion for sodium-sulfur cells |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |