CA1072071A - Polysulphide rubbers - Google Patents
Polysulphide rubbersInfo
- Publication number
- CA1072071A CA1072071A CA247,433A CA247433A CA1072071A CA 1072071 A CA1072071 A CA 1072071A CA 247433 A CA247433 A CA 247433A CA 1072071 A CA1072071 A CA 1072071A
- Authority
- CA
- Canada
- Prior art keywords
- weight
- sulphur
- composition
- zinc carbonate
- polysulphide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 40
- 239000005060 rubber Substances 0.000 title claims abstract description 40
- 229920001021 polysulfide Polymers 0.000 title claims abstract description 39
- 239000000203 mixture Substances 0.000 claims abstract description 45
- 239000005864 Sulphur Substances 0.000 claims abstract description 42
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000003054 catalyst Substances 0.000 claims abstract description 27
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 claims abstract description 25
- 239000011667 zinc carbonate Substances 0.000 claims abstract description 25
- 229910000010 zinc carbonate Inorganic materials 0.000 claims abstract description 25
- 235000004416 zinc carbonate Nutrition 0.000 claims abstract description 25
- 150000001412 amines Chemical class 0.000 claims abstract description 24
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229960002447 thiram Drugs 0.000 claims abstract description 6
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 claims abstract description 4
- 125000005265 dialkylamine group Chemical group 0.000 claims abstract description 4
- 239000012990 dithiocarbamate Substances 0.000 claims abstract description 4
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 claims abstract 3
- 239000004014 plasticizer Substances 0.000 claims description 15
- 239000000945 filler Substances 0.000 claims description 7
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- -1 sulphur amine Chemical class 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 7
- DMYOHQBLOZMDLP-UHFFFAOYSA-N 1-[2-(2-hydroxy-3-piperidin-1-ylpropoxy)phenyl]-3-phenylpropan-1-one Chemical compound C1CCCCN1CC(O)COC1=CC=CC=C1C(=O)CCC1=CC=CC=C1 DMYOHQBLOZMDLP-UHFFFAOYSA-N 0.000 description 5
- 229920001079 Thiokol (polymer) Polymers 0.000 description 5
- 239000001055 blue pigment Substances 0.000 description 4
- 239000010941 cobalt Substances 0.000 description 4
- 229910017052 cobalt Inorganic materials 0.000 description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
- 239000002978 dental impression material Substances 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 4
- 229910002014 Aerosil® 130 Inorganic materials 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- VFGRALUHHHDIQI-UHFFFAOYSA-N butyl 2-hydroxyacetate Chemical compound CCCCOC(=O)CO VFGRALUHHHDIQI-UHFFFAOYSA-N 0.000 description 3
- 241000239290 Araneae Species 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical group C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 2
- 229960002380 dibutyl phthalate Drugs 0.000 description 2
- YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical group O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 1
- NWGVPSIRAIBOHT-UHFFFAOYSA-L C(C)S(=C(N)[S-])(CC)(CC)CC.[Zn+2].C(C)S(=C(N)[S-])(CC)(CC)CC Chemical compound C(C)S(=C(N)[S-])(CC)(CC)CC.[Zn+2].C(C)S(=C(N)[S-])(CC)(CC)CC NWGVPSIRAIBOHT-UHFFFAOYSA-L 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 101150050192 PIGM gene Proteins 0.000 description 1
- 241000452638 Parasaissetia nigra Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- CSNJTIWCTNEOSW-UHFFFAOYSA-N carbamothioylsulfanyl carbamodithioate Chemical compound NC(=S)SSC(N)=S CSNJTIWCTNEOSW-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- DLINORNFHVEIFE-UHFFFAOYSA-N hydrogen peroxide;zinc Chemical compound [Zn].OO DLINORNFHVEIFE-UHFFFAOYSA-N 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 125000001557 phthalyl group Chemical group C(=O)(O)C1=C(C(=O)*)C=CC=C1 0.000 description 1
- 230000000485 pigmenting effect Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229940105296 zinc peroxide Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB11057/75A GB1547372A (en) | 1975-03-17 | 1975-03-17 | Polysulphide rubbers |
| GB1253375 | 1975-03-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1072071A true CA1072071A (en) | 1980-02-19 |
Family
ID=26248002
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA247,433A Expired CA1072071A (en) | 1975-03-17 | 1976-03-09 | Polysulphide rubbers |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4067842A (https=) |
| JP (1) | JPS51145485A (https=) |
| AU (1) | AU506120B2 (https=) |
| CA (1) | CA1072071A (https=) |
| CH (1) | CH630104A5 (https=) |
| DE (1) | DE2610685A1 (https=) |
| DK (1) | DK112176A (https=) |
| FR (1) | FR2304641A1 (https=) |
| IE (1) | IE42656B1 (https=) |
| IT (1) | IT1062256B (https=) |
| NL (1) | NL7602633A (https=) |
| NO (2) | NO148675C (https=) |
| SE (1) | SE7603239L (https=) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4224200A (en) * | 1978-10-23 | 1980-09-23 | Phillips Petroleum Company | Polymer curing system, air-curable composition and method of preparing the composition |
| US4298508A (en) * | 1978-10-23 | 1981-11-03 | Phillips Petroleum Company | Polymer curing system, air-curable composition and method of preparing the composition |
| DE3120993A1 (de) * | 1981-05-26 | 1982-12-16 | Bayer Ag, 5090 Leverkusen | Verwendung von organischen schwefelverbindungen, carboxylate und/oder organische komplexverbindungen von metallen, sowie organische basen enthaltenden katalysatorsystemen fuer die oxidative haertung von mercaptogruppen aufweisenden kunststoffvorlaeufern |
| US4663416A (en) * | 1986-03-31 | 1987-05-05 | The Dow Chemical Company | Novel condensation polymers containing units from 8,9-bis(hydroxyalkyl)-exo-3,4,5-trithiatricyclo[5.2.1.02,6 ]decane |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3046248A (en) * | 1959-06-10 | 1962-07-24 | Coe Lab Inc | Method of preparing solid elastomers from uncured liquid organic polythiopolymercaptan polymers |
| US3455854A (en) * | 1963-06-21 | 1969-07-15 | Thiokol Chemical Corp | Method for regulating pot life of curable liquid polysulfide polymer |
| US3362927A (en) * | 1965-10-23 | 1968-01-09 | Teledyne Dental Corp | Liquid polysulfide, dimethyl sulfoxide and zinc oxide containing dental impression material |
| US3637574A (en) * | 1969-01-16 | 1972-01-25 | Thiokol Chemical Corp | Sulfur modified zinc compound/tetraalkylthiuram polysulfide cure system for liquid polythiol polymers |
| US3637612A (en) * | 1970-01-27 | 1972-01-25 | Thiokol Chemical Corp | Fast curing of polysulfide polymers |
| US3923754A (en) * | 1973-11-12 | 1975-12-02 | Denton Ind Inc | Curing of liquid polythiopolymercaptan polymers |
-
1976
- 1976-03-09 CA CA247,433A patent/CA1072071A/en not_active Expired
- 1976-03-11 FR FR7606915A patent/FR2304641A1/fr active Granted
- 1976-03-11 AU AU11874/76A patent/AU506120B2/en not_active Expired
- 1976-03-12 NL NL7602633A patent/NL7602633A/xx not_active Application Discontinuation
- 1976-03-12 SE SE7603239A patent/SE7603239L/ not_active Application Discontinuation
- 1976-03-13 DE DE19762610685 patent/DE2610685A1/de not_active Ceased
- 1976-03-15 IE IE542/76A patent/IE42656B1/en unknown
- 1976-03-15 NO NO760899A patent/NO148675C/no unknown
- 1976-03-16 IT IT21258/76A patent/IT1062256B/it active
- 1976-03-16 CH CH324576A patent/CH630104A5/de not_active IP Right Cessation
- 1976-03-16 DK DK112176A patent/DK112176A/da not_active Application Discontinuation
- 1976-03-17 JP JP51029075A patent/JPS51145485A/ja active Pending
- 1976-03-17 US US05/667,743 patent/US4067842A/en not_active Expired - Lifetime
-
1979
- 1979-01-15 NO NO790128A patent/NO790128L/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JPS51145485A (en) | 1976-12-14 |
| AU1187476A (en) | 1977-09-29 |
| NL7602633A (nl) | 1976-09-21 |
| DE2610685A1 (de) | 1976-09-30 |
| IT1062256B (it) | 1984-02-01 |
| NO148675C (no) | 1983-11-23 |
| NO148675B (no) | 1983-08-15 |
| NO790128L (no) | 1976-09-20 |
| IE42656L (en) | 1976-09-17 |
| FR2304641B1 (https=) | 1981-03-20 |
| FR2304641A1 (fr) | 1976-10-15 |
| DK112176A (da) | 1976-09-18 |
| US4067842A (en) | 1978-01-10 |
| SE7603239L (sv) | 1976-09-18 |
| IE42656B1 (en) | 1980-09-24 |
| AU506120B2 (en) | 1979-12-13 |
| CH630104A5 (de) | 1982-05-28 |
| NO760899L (https=) | 1976-09-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |