CA1068641A - Method and apparatus for the electrodeposition of metal - Google Patents
Method and apparatus for the electrodeposition of metalInfo
- Publication number
- CA1068641A CA1068641A CA219,196A CA219196A CA1068641A CA 1068641 A CA1068641 A CA 1068641A CA 219196 A CA219196 A CA 219196A CA 1068641 A CA1068641 A CA 1068641A
- Authority
- CA
- Canada
- Prior art keywords
- cathodes
- cathode
- anode
- anodes
- faces
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 63
- 239000002184 metal Substances 0.000 title claims abstract description 63
- 238000004070 electrodeposition Methods 0.000 title claims abstract description 28
- 238000000034 method Methods 0.000 title claims description 45
- 239000003792 electrolyte Substances 0.000 claims abstract description 61
- 239000010949 copper Substances 0.000 claims abstract description 40
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 34
- 229910052802 copper Inorganic materials 0.000 claims abstract description 34
- 238000005363 electrowinning Methods 0.000 claims abstract description 21
- 238000013019 agitation Methods 0.000 claims description 33
- 238000000151 deposition Methods 0.000 claims description 25
- 230000008021 deposition Effects 0.000 claims description 24
- 230000008569 process Effects 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 13
- 230000008602 contraction Effects 0.000 claims description 9
- 230000007480 spreading Effects 0.000 claims description 9
- 238000003892 spreading Methods 0.000 claims description 9
- 230000008093 supporting effect Effects 0.000 claims description 9
- 230000001174 ascending effect Effects 0.000 claims description 7
- 229910021645 metal ion Inorganic materials 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 230000004087 circulation Effects 0.000 claims 2
- 206010001497 Agitation Diseases 0.000 description 29
- 239000007789 gas Substances 0.000 description 28
- 230000008901 benefit Effects 0.000 description 18
- 238000007688 edging Methods 0.000 description 10
- 239000002253 acid Substances 0.000 description 8
- 239000007858 starting material Substances 0.000 description 8
- 239000012535 impurity Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000008030 elimination Effects 0.000 description 4
- 239000011810 insulating material Substances 0.000 description 4
- 238000005304 joining Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- UOACKFBJUYNSLK-XRKIENNPSA-N Estradiol Cypionate Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H](C4=CC=C(O)C=C4CC3)CC[C@@]21C)C(=O)CCC1CCCC1 UOACKFBJUYNSLK-XRKIENNPSA-N 0.000 description 3
- 229910000978 Pb alloy Inorganic materials 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 229910052787 antimony Inorganic materials 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 238000003379 elimination reaction Methods 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 235000010210 aluminium Nutrition 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- 239000011133 lead Substances 0.000 description 2
- 238000002161 passivation Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229910000619 316 stainless steel Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229910001245 Sb alloy Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 239000002140 antimony alloy Substances 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 210000001217 buttock Anatomy 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 230000001609 comparable effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 210000005069 ears Anatomy 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 229910001447 ferric ion Inorganic materials 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 210000002414 leg Anatomy 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000028161 membrane depolarization Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012811 non-conductive material Substances 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- BALXUFOVQVENIU-KXNXZCPBSA-N pseudoephedrine hydrochloride Chemical compound [H+].[Cl-].CN[C@@H](C)[C@@H](O)C1=CC=CC=C1 BALXUFOVQVENIU-KXNXZCPBSA-N 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/12—Electrolytic production, recovery or refining of metals by electrolysis of solutions of copper
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Electroplating Methods And Accessories (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US445435A US3875041A (en) | 1974-02-25 | 1974-02-25 | Apparatus for the electrolytic recovery of metal employing improved electrolyte convection |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1068641A true CA1068641A (en) | 1979-12-25 |
Family
ID=23768890
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA219,196A Expired CA1068641A (en) | 1974-02-25 | 1975-02-03 | Method and apparatus for the electrodeposition of metal |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US3875041A (ja) |
| JP (1) | JPS5830393B2 (ja) |
| BE (1) | BE825794A (ja) |
| CA (1) | CA1068641A (ja) |
| DE (1) | DE2508094A1 (ja) |
| GB (1) | GB1504332A (ja) |
| SE (1) | SE419240B (ja) |
| ZA (1) | ZA75696B (ja) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4033839A (en) * | 1975-02-26 | 1977-07-05 | Kennecott Copper Corporation | Method for series electrowinning and electrorefining of metals |
| US4062755A (en) * | 1976-05-03 | 1977-12-13 | Bell Telephone Laboratories, Incorporated | Electroplating anode plenum |
| JPS54115645A (en) * | 1978-02-28 | 1979-09-08 | Ngk Insulators Ltd | Electrochemical treatment |
| JPS5594492A (en) * | 1979-01-12 | 1980-07-17 | Nippon Kokan Kk <Nkk> | Fluidizing method for liquid by jet stream between parallel flat board |
| DE2912524C2 (de) * | 1979-03-29 | 1985-08-29 | Hüttenwerke Kayser AG, 4670 Lünen | Arbeitsverfahren und Vorrichtung zum elektrolytischen Abscheiden von Metallen, insbesondere Kupfer |
| MX171716B (es) * | 1982-12-10 | 1993-11-11 | Dextec Metallurg | Un electrodo para una celda electrolitica para la recuperacion de metales de minerales metaliferos o concentrados y metodo para fabricarlo |
| GB8327300D0 (en) * | 1983-10-12 | 1983-11-16 | Deso Inc | Acid mist reduction |
| US4668353A (en) * | 1984-10-10 | 1987-05-26 | Desom Engineered Systems Limited | Method and apparatus for acid mist reduction |
| JPS6233800A (ja) * | 1985-08-02 | 1987-02-13 | Asahi Chem Ind Co Ltd | 平板めつき用エア撹拌装置 |
| US5085730A (en) * | 1990-11-16 | 1992-02-04 | Macdermid, Incorporated | Process for regenerating ammoniacal chloride etchants |
| US5248398A (en) * | 1990-11-16 | 1993-09-28 | Macdermid, Incorporated | Process for direct electrolytic regeneration of chloride-based ammoniacal copper etchant bath |
| GB9411063D0 (en) * | 1994-06-02 | 1994-07-20 | British Nuclear Fuels Plc | Electrolytic treatment of material |
| WO1997015702A2 (de) * | 1995-10-26 | 1997-05-01 | Lea Ronal Gmbh | Vorrichtung zur chemischen oder elektrolytischen oberflächenbehandlung plattenförmiger gegenstände |
| AUPQ520600A0 (en) * | 2000-01-21 | 2000-02-17 | Waterpower Systems Pty Ltd | Improvements in electrolysis cells |
| US20030089619A1 (en) * | 2000-02-22 | 2003-05-15 | Sunil Jayasekera | Process and apparatus for recovery of cyanide and metals |
| US7085125B2 (en) * | 2002-03-21 | 2006-08-01 | Chien-Min Sung | Carbon nanotube devices and uses therefor |
| FI113280B (fi) * | 2002-04-03 | 2004-03-31 | Outokumpu Oy | Elektrolyysissä käytettävä siirto- ja eristyslaite |
| DE10261493A1 (de) * | 2002-12-23 | 2004-07-08 | METAKEM Gesellschaft für Schichtchemie der Metalle mbH | Anode zur Galvanisierung |
| JP2007503525A (ja) * | 2003-08-22 | 2007-02-22 | ビー・エイチ・ピー・ビリトン・イノベイション・プロプライエタリー・リミテッド | ガス散布 |
| GB0618025D0 (en) | 2006-09-13 | 2006-10-25 | Enpar Technologies Inc | Electrochemically catalyzed extraction of metals from sulphide minerals |
| CN102149854A (zh) * | 2008-09-09 | 2011-08-10 | 斯提奥摩有限公司 | 阴极和阴极形成方法 |
| CN106521562A (zh) * | 2016-09-30 | 2017-03-22 | 云南铜业股份有限公司 | 一种铜电解永久不锈钢阴极的修复方法 |
| JP7398395B2 (ja) | 2018-05-16 | 2023-12-14 | アウルビス ベーアセ | 銅電解精製の改善 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US846526A (en) * | 1902-04-18 | 1907-03-12 | Elmer A Sperry | Apparatus for the production of pigments. |
| US1365032A (en) * | 1918-04-29 | 1921-01-11 | William E Greenawalt | Electrolytic apparatus |
| US1700178A (en) * | 1923-09-01 | 1929-01-29 | Porzel Joseph | Device for controlling electrolytic operations |
| US1805920A (en) * | 1927-11-07 | 1931-05-19 | Muschler Fred | Making copper plated shingles |
| US2675348A (en) * | 1950-09-16 | 1954-04-13 | Greenspan Lawrence | Apparatus for metal plating |
-
1974
- 1974-02-25 US US445435A patent/US3875041A/en not_active Expired - Lifetime
-
1975
- 1975-02-03 CA CA219,196A patent/CA1068641A/en not_active Expired
- 1975-02-03 ZA ZA00750696A patent/ZA75696B/xx unknown
- 1975-02-10 GB GB4667/75A patent/GB1504332A/en not_active Expired
- 1975-02-12 JP JP50016989A patent/JPS5830393B2/ja not_active Expired
- 1975-02-21 BE BE153570A patent/BE825794A/xx not_active IP Right Cessation
- 1975-02-24 SE SE7502038A patent/SE419240B/xx unknown
- 1975-02-25 DE DE19752508094 patent/DE2508094A1/de not_active Ceased
-
1977
- 1977-12-14 US US05/860,511 patent/USRE30005E/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| USRE30005E (en) | 1979-05-22 |
| US3875041A (en) | 1975-04-01 |
| ZA75696B (en) | 1976-01-28 |
| JPS5830393B2 (ja) | 1983-06-29 |
| BE825794A (fr) | 1975-08-21 |
| DE2508094A1 (de) | 1975-08-28 |
| JPS50115615A (ja) | 1975-09-10 |
| SE7502038L (ja) | 1975-08-26 |
| SE419240B (sv) | 1981-07-20 |
| GB1504332A (en) | 1978-03-22 |
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