CA1065119A - Production of phosphine - Google Patents
Production of phosphineInfo
- Publication number
- CA1065119A CA1065119A CA264,383A CA264383A CA1065119A CA 1065119 A CA1065119 A CA 1065119A CA 264383 A CA264383 A CA 264383A CA 1065119 A CA1065119 A CA 1065119A
- Authority
- CA
- Canada
- Prior art keywords
- alcohol
- phosphine
- hydroxide solution
- alkali metal
- phosphorus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 title claims abstract description 61
- 229910000073 phosphorus hydride Inorganic materials 0.000 title claims abstract description 36
- 238000004519 manufacturing process Methods 0.000 title abstract description 3
- 238000006243 chemical reaction Methods 0.000 claims abstract description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 18
- OBSZRRSYVTXPNB-UHFFFAOYSA-N tetraphosphorus Chemical compound P12P3P1P32 OBSZRRSYVTXPNB-UHFFFAOYSA-N 0.000 claims abstract description 16
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 13
- 239000011574 phosphorus Substances 0.000 claims abstract description 13
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims abstract description 11
- 239000000725 suspension Substances 0.000 claims abstract description 5
- 238000009835 boiling Methods 0.000 claims abstract description 4
- 238000013019 agitation Methods 0.000 claims abstract description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 18
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 claims description 10
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims description 4
- 239000012071 phase Substances 0.000 claims description 4
- 230000001476 alcoholic effect Effects 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 239000008346 aqueous phase Substances 0.000 claims description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 241000518994 Conta Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/06—Hydrogen phosphides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2549084A DE2549084C3 (de) | 1975-11-03 | 1975-11-03 | Verfahren zur Herstellung von Phosphin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1065119A true CA1065119A (en) | 1979-10-30 |
Family
ID=5960691
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA264,383A Expired CA1065119A (en) | 1975-11-03 | 1976-10-28 | Production of phosphine |
Country Status (10)
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2632316C3 (de) * | 1976-07-17 | 1981-12-24 | Hoechst Ag, 6000 Frankfurt | Verfahren zur kontinuierlichen Herstellung von Phosphin |
| DE2840147A1 (de) * | 1978-09-15 | 1980-03-27 | Hoechst Ag | Verfahren zur kontinuierlichen herstellung von phosphan |
| US4816238A (en) * | 1986-05-01 | 1989-03-28 | The Dow Chemical Company | Method and composition for the removal of hydrogen sulfide from gaseous streams |
| CN114620695B (zh) * | 2022-02-23 | 2023-07-07 | 沧州华宇特种气体科技有限公司 | 一种制备磷化氢的系统及其制备方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH322981A (fr) * | 1956-09-10 | 1957-07-15 | Fonte Electr S A | Procédé pour la préparation d'hypophosphites. |
| US2977192A (en) * | 1958-08-26 | 1961-03-28 | Fmc Corp | Process for the production of phosphine and sodium hypophosphite |
| GB943281A (en) * | 1961-01-19 | 1963-12-04 | Albright & Wilson Mfg Ltd | Manufacture of phosphine |
| US3116109A (en) * | 1961-03-10 | 1963-12-31 | Fmc Corp | Process for production of phosphine and phosphite-free phosphates |
| GB990918A (en) * | 1962-04-04 | 1965-05-05 | Albright & Wilson M F G Ltd | Improvements in the production of phosphine |
| US3387934A (en) * | 1964-10-12 | 1968-06-11 | Hooker Chemical Corp | Manufacture of phosphine |
| DE2125587C3 (de) * | 1971-05-24 | 1974-08-15 | Knapsack Ag, 5033 Huerth-Knapsack | Verfahren zur Herstellung von Hypophosphiten |
-
1975
- 1975-11-03 DE DE2549084A patent/DE2549084C3/de not_active Expired
-
1976
- 1976-10-27 CH CH1355076A patent/CH599899A5/xx not_active IP Right Cessation
- 1976-10-28 US US05/736,556 patent/US4091078A/en not_active Expired - Lifetime
- 1976-10-28 CA CA264,383A patent/CA1065119A/en not_active Expired
- 1976-10-29 IT IT51953/76A patent/IT1066755B/it active
- 1976-11-01 DD DD195544A patent/DD127464A5/xx unknown
- 1976-11-01 GB GB45286/76A patent/GB1509107A/en not_active Expired
- 1976-11-02 NL NLAANVRAGE7612144,A patent/NL184830C/xx not_active IP Right Cessation
- 1976-11-03 BE BE172003A patent/BE847899A/xx not_active IP Right Cessation
- 1976-11-03 FR FR7633152A patent/FR2329588A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| FR2329588B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1981-07-31 |
| DE2549084C3 (de) | 1981-04-30 |
| US4091078A (en) | 1978-05-23 |
| FR2329588A1 (fr) | 1977-05-27 |
| IT1066755B (it) | 1985-03-12 |
| NL184830B (nl) | 1989-06-16 |
| DE2549084B2 (de) | 1980-07-24 |
| GB1509107A (en) | 1978-04-26 |
| NL7612144A (nl) | 1977-05-05 |
| CH599899A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1978-06-15 |
| BE847899A (fr) | 1977-05-03 |
| NL184830C (nl) | 1989-11-16 |
| DE2549084A1 (de) | 1977-05-05 |
| DD127464A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1977-09-28 |
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