CA1062285A - Conversion of synthesis gas to hydrocarbon mixtures - Google Patents

Conversion of synthesis gas to hydrocarbon mixtures

Info

Publication number
CA1062285A
CA1062285A CA223,659A CA223659A CA1062285A CA 1062285 A CA1062285 A CA 1062285A CA 223659 A CA223659 A CA 223659A CA 1062285 A CA1062285 A CA 1062285A
Authority
CA
Canada
Prior art keywords
catalyst
metal
process according
zsm
hydrocarbons
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA223,659A
Other languages
English (en)
French (fr)
Inventor
Anthony J. Silvestri
Clarence D. Chang
William H. Lang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Application granted granted Critical
Publication of CA1062285A publication Critical patent/CA1062285A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46—Iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CA223,659A 1974-04-24 1975-04-02 Conversion of synthesis gas to hydrocarbon mixtures Expired CA1062285A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US46371174A 1974-04-24 1974-04-24

Publications (1)

Publication Number Publication Date
CA1062285A true CA1062285A (en) 1979-09-11

Family

ID=23841061

Family Applications (1)

Application Number Title Priority Date Filing Date
CA223,659A Expired CA1062285A (en) 1974-04-24 1975-04-02 Conversion of synthesis gas to hydrocarbon mixtures

Country Status (16)

Country Link
JP (1) JPS5839131B2 (nl)
AR (1) AR211847A1 (nl)
BE (1) BE828228A (nl)
CA (1) CA1062285A (nl)
CS (1) CS188951B2 (nl)
DE (1) DE2518097A1 (nl)
DK (1) DK145460C (nl)
EG (1) EG14618A (nl)
FR (1) FR2268771B1 (nl)
GB (1) GB1495794A (nl)
IT (1) IT1037539B (nl)
MY (1) MY7800260A (nl)
NL (1) NL183181C (nl)
NO (1) NO144631C (nl)
PL (1) PL97789B1 (nl)
ZA (1) ZA752561B (nl)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4096163A (en) * 1975-04-08 1978-06-20 Mobil Oil Corporation Conversion of synthesis gas to hydrocarbon mixtures
US4016218A (en) * 1975-05-29 1977-04-05 Mobil Oil Corporation Alkylation in presence of thermally modified crystalline aluminosilicate catalyst
GB1489357A (en) * 1975-06-02 1977-10-19 Mobil Oil Corp Conversion of synthesis gas to hydrocarbon mixtures
NZ183608A (en) * 1976-03-31 1978-12-18 Mobil Oil Corp Aluminosilicate zeolite catalyst for selectine production of para-diakyl substituted benzenes
US4139550A (en) * 1976-09-10 1979-02-13 Suntech, Inc. Aromatics from synthesis gas
US4086262A (en) * 1976-09-20 1978-04-25 Mobil Oil Corporation Conversion of synthesis gas to hydrocarbon mixtures
US4304871A (en) * 1976-10-15 1981-12-08 Mobil Oil Corporation Conversion of synthesis gas to hydrocarbon mixtures utilizing a dual catalyst bed
US4180516A (en) * 1977-08-18 1979-12-25 Mobil Oil Corporation Conversion of synthesis gas to aromatic hydrocarbons
US4159995A (en) * 1977-08-22 1979-07-03 Mobil Oil Corporation Conversion of synthesis gas to hydrocarbon mixtures utilizing dual reactors
NL7711350A (nl) * 1977-10-17 1979-04-19 Shell Int Research Werkwijze voor de bereiding van koolwaterstoffen.
CA1113508A (en) * 1978-05-05 1981-12-01 Clarence D. Chang Conversion of synthesis gas to aromatic hydrocarbons
NL7811736A (nl) * 1978-11-30 1980-06-03 Shell Int Research Werkwijze voor de bereiding van koolwaterstoffen.
US4207250A (en) * 1978-12-18 1980-06-10 Mobil Oil Corporation Conversion of synthesis gas with iron-containing fluid catalyst
US4255349A (en) * 1978-12-18 1981-03-10 Mobil Oil Corporation Conversion of synthesis gas with iron-containing catalyst
US4418155A (en) * 1980-03-24 1983-11-29 Mobil Oil Corporation Conversion of synthesis gas to hydrocarbons enriched in linear alpha-olefins
DE3267754D1 (en) * 1981-06-19 1986-01-16 Coal Industry Patents Ltd Amorphous silica-based catalyst and process for its production
CA1173064A (en) * 1981-07-17 1984-08-21 Malcolm P. Heyward Catalyst composition for conversion of synthesis gas to hydrocarbons
CA1177464A (en) * 1981-10-09 1984-11-06 V. Udaya S. Rao Process and catalyst for converting synthesis gas to liquid hydrocarbon mixture
JPS5881671A (ja) * 1981-11-11 1983-05-17 ユニチカ株式会社 立毛調編物の製造方法
DE3201457A1 (de) * 1982-01-19 1983-07-28 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von olefinen
JPS58192834A (ja) * 1982-05-04 1983-11-10 Res Assoc Petroleum Alternat Dev<Rapad> 炭化水素の製造方法
JPS5910527A (ja) * 1982-07-09 1984-01-20 Res Assoc Petroleum Alternat Dev<Rapad> 炭化水素類の製造法
JPS5927836A (ja) * 1982-08-06 1984-02-14 Res Assoc Petroleum Alternat Dev<Rapad> 炭化水素の製造方法
US4472535A (en) * 1982-11-22 1984-09-18 Mobil Oil Corporation Conversion of synthesis gas to ethane
EP0112064B1 (en) * 1982-12-10 1986-08-13 Coal Industry (Patents) Limited Improved catalysts
JPH0633357B2 (ja) * 1983-12-27 1994-05-02 智行 乾 合成ガスから軽質炭化水素を製造する方法
EP0153517A1 (en) * 1984-03-01 1985-09-04 The Standard Oil Company Novel catalysts and their preparation and process for the production of liquid paraffins
EP0154063A1 (en) * 1984-03-01 1985-09-11 The Standard Oil Company Modified silicalite catalysts and their preparation and process for the use thereof
JPH0316511Y2 (nl) * 1985-11-13 1991-04-09
JP2841500B2 (ja) * 1989-07-19 1998-12-24 日本鋼管株式会社 二酸化炭素の水素化によるプロパンの製造方法
CN103521249B (zh) * 2012-07-05 2016-08-24 中国科学院大连化学物理研究所 一种用于合成气转化的磷化物催化剂和制备方法及其应用
JP2015044926A (ja) * 2013-08-28 2015-03-12 独立行政法人産業技術総合研究所 炭化水素製造方法及び炭化水素製造装置

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3832449A (en) * 1971-03-18 1974-08-27 Mobil Oil Corp Crystalline zeolite zsm{14 12

Also Published As

Publication number Publication date
DK145460B (da) 1982-11-22
FR2268771B1 (nl) 1980-01-04
AR211847A1 (es) 1978-03-31
NL183181C (nl) 1988-08-16
ZA752561B (en) 1976-11-24
DK145460C (da) 1983-04-25
BE828228A (fr) 1975-10-22
DE2518097C2 (nl) 1988-05-26
GB1495794A (en) 1977-12-21
NO144631C (no) 1981-10-07
IT1037539B (it) 1979-11-20
PL97789B1 (pl) 1978-03-30
JPS50142502A (nl) 1975-11-17
NL7504832A (nl) 1975-10-28
DE2518097A1 (de) 1975-11-13
NL183181B (nl) 1988-03-16
NO144631B (no) 1981-06-29
JPS5839131B2 (ja) 1983-08-27
DK175175A (da) 1975-10-25
EG14618A (en) 1984-06-30
CS188951B2 (en) 1979-03-30
FR2268771A1 (nl) 1975-11-21
NO751457L (nl) 1975-10-27
MY7800260A (en) 1978-12-31
AU8048775A (en) 1976-10-28

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