CA1054130A - Hydrodesulphurisation catalyst and method of manufacture and use thereof - Google Patents
Hydrodesulphurisation catalyst and method of manufacture and use thereofInfo
- Publication number
- CA1054130A CA1054130A CA229,995A CA229995A CA1054130A CA 1054130 A CA1054130 A CA 1054130A CA 229995 A CA229995 A CA 229995A CA 1054130 A CA1054130 A CA 1054130A
- Authority
- CA
- Canada
- Prior art keywords
- metal compound
- group vib
- group
- extrudate
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims description 19
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 229910052751 metal Inorganic materials 0.000 claims abstract description 18
- 239000002184 metal Substances 0.000 claims abstract description 18
- -1 VIB metal compound Chemical class 0.000 claims abstract description 15
- 150000002736 metal compounds Chemical class 0.000 claims abstract description 13
- 229910052809 inorganic oxide Inorganic materials 0.000 claims abstract description 7
- 150000001875 compounds Chemical class 0.000 claims description 17
- 238000001354 calcination Methods 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical group O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 claims description 7
- 229910052750 molybdenum Inorganic materials 0.000 claims description 7
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- 229910017052 cobalt Inorganic materials 0.000 claims description 6
- 239000010941 cobalt Substances 0.000 claims description 6
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 239000011733 molybdenum Substances 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims description 5
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical group O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 229910017604 nitric acid Inorganic materials 0.000 claims description 4
- 230000001590 oxidative effect Effects 0.000 claims description 4
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- 239000011593 sulfur Substances 0.000 claims description 4
- 229910021446 cobalt carbonate Inorganic materials 0.000 claims description 3
- ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 239000000295 fuel oil Substances 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 150000002430 hydrocarbons Chemical class 0.000 claims description 2
- 239000000306 component Substances 0.000 claims 2
- 239000012876 carrier material Substances 0.000 abstract description 4
- 230000003197 catalytic effect Effects 0.000 abstract description 3
- 239000002131 composite material Substances 0.000 abstract description 3
- 238000006477 desulfuration reaction Methods 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- 239000003209 petroleum derivative Substances 0.000 abstract description 2
- 239000002245 particle Substances 0.000 description 17
- 239000000243 solution Substances 0.000 description 14
- 239000000203 mixture Substances 0.000 description 8
- 238000005470 impregnation Methods 0.000 description 7
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 description 7
- 239000002253 acid Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- PHFQLYPOURZARY-UHFFFAOYSA-N chromium trinitrate Chemical compound [Cr+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PHFQLYPOURZARY-UHFFFAOYSA-N 0.000 description 4
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 4
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 3
- 239000000908 ammonium hydroxide Substances 0.000 description 3
- QGUAJWGNOXCYJF-UHFFFAOYSA-N cobalt dinitrate hexahydrate Chemical compound O.O.O.O.O.O.[Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O QGUAJWGNOXCYJF-UHFFFAOYSA-N 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- PMJNEQWWZRSFCE-UHFFFAOYSA-N 3-ethoxy-3-oxo-2-(thiophen-2-ylmethyl)propanoic acid Chemical compound CCOC(=O)C(C(O)=O)CC1=CC=CS1 PMJNEQWWZRSFCE-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910021554 Chromium(II) chloride Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XBWRJSSJWDOUSJ-UHFFFAOYSA-L chromium(ii) chloride Chemical compound Cl[Cr]Cl XBWRJSSJWDOUSJ-UHFFFAOYSA-L 0.000 description 2
- 229940109126 chromous chloride Drugs 0.000 description 2
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 2
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 2
- 230000023556 desulfurization Effects 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 238000007580 dry-mixing Methods 0.000 description 2
- 239000010763 heavy fuel oil Substances 0.000 description 2
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 2
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 2
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 2
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 2
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 2
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical compound O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 description 2
- QIJNJJZPYXGIQM-UHFFFAOYSA-N 1lambda4,2lambda4-dimolybdacyclopropa-1,2,3-triene Chemical compound [Mo]=C=[Mo] QIJNJJZPYXGIQM-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- AVCTVGHRGNADJG-UHFFFAOYSA-L OO[Cr](O)(=O)=O.N.N Chemical compound OO[Cr](O)(=O)=O.N.N AVCTVGHRGNADJG-UHFFFAOYSA-L 0.000 description 1
- 208000036366 Sensation of pressure Diseases 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- MQRWBMAEBQOWAF-UHFFFAOYSA-N acetic acid;nickel Chemical compound [Ni].CC(O)=O.CC(O)=O MQRWBMAEBQOWAF-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 1
- 239000011609 ammonium molybdate Substances 0.000 description 1
- 229940010552 ammonium molybdate Drugs 0.000 description 1
- 235000018660 ammonium molybdate Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- WYYQVWLEPYFFLP-UHFFFAOYSA-K chromium(3+);triacetate Chemical compound [Cr+3].CC([O-])=O.CC([O-])=O.CC([O-])=O WYYQVWLEPYFFLP-UHFFFAOYSA-K 0.000 description 1
- YCYBZKSMUPTWEE-UHFFFAOYSA-L cobalt(ii) fluoride Chemical compound F[Co]F YCYBZKSMUPTWEE-UHFFFAOYSA-L 0.000 description 1
- 229940045032 cobaltous nitrate Drugs 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- PVFSDGKDKFSOTB-UHFFFAOYSA-K iron(3+);triacetate Chemical compound [Fe+3].CC([O-])=O.CC([O-])=O.CC([O-])=O PVFSDGKDKFSOTB-UHFFFAOYSA-K 0.000 description 1
- WHRBSMVATPCWLU-UHFFFAOYSA-K iron(3+);triformate Chemical compound [Fe+3].[O-]C=O.[O-]C=O.[O-]C=O WHRBSMVATPCWLU-UHFFFAOYSA-K 0.000 description 1
- SHXXPRJOPFJRHA-UHFFFAOYSA-K iron(iii) fluoride Chemical compound F[Fe](F)F SHXXPRJOPFJRHA-UHFFFAOYSA-K 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- 229940078494 nickel acetate Drugs 0.000 description 1
- UQPSGBZICXWIAG-UHFFFAOYSA-L nickel(2+);dibromide;trihydrate Chemical compound O.O.O.Br[Ni]Br UQPSGBZICXWIAG-UHFFFAOYSA-L 0.000 description 1
- HZPNKQREYVVATQ-UHFFFAOYSA-L nickel(2+);diformate Chemical compound [Ni+2].[O-]C=O.[O-]C=O HZPNKQREYVVATQ-UHFFFAOYSA-L 0.000 description 1
- DBJLJFTWODWSOF-UHFFFAOYSA-L nickel(ii) fluoride Chemical compound F[Ni]F DBJLJFTWODWSOF-UHFFFAOYSA-L 0.000 description 1
- BFSQJYRFLQUZKX-UHFFFAOYSA-L nickel(ii) iodide Chemical compound I[Ni]I BFSQJYRFLQUZKX-UHFFFAOYSA-L 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 229940095574 propionic acid Drugs 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
- FEONEKOZSGPOFN-UHFFFAOYSA-K tribromoiron Chemical compound Br[Fe](Br)Br FEONEKOZSGPOFN-UHFFFAOYSA-K 0.000 description 1
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Hydrogen, Water And Hydrids (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/484,519 US3935127A (en) | 1974-07-01 | 1974-07-01 | Method of catalyst manufacture |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1054130A true CA1054130A (en) | 1979-05-08 |
Family
ID=23924482
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA229,995A Expired CA1054130A (en) | 1974-07-01 | 1975-06-24 | Hydrodesulphurisation catalyst and method of manufacture and use thereof |
Country Status (23)
| Country | Link |
|---|---|
| JP (1) | JPS536113B2 (en, 2012) |
| AR (1) | AR230200A1 (en, 2012) |
| AT (1) | AT343609B (en, 2012) |
| BR (1) | BR7504093A (en, 2012) |
| CA (1) | CA1054130A (en, 2012) |
| CS (1) | CS193516B2 (en, 2012) |
| DK (1) | DK296375A (en, 2012) |
| EG (1) | EG11809A (en, 2012) |
| ES (1) | ES438979A1 (en, 2012) |
| FI (1) | FI61413C (en, 2012) |
| GB (1) | GB1502915A (en, 2012) |
| IE (1) | IE41780B1 (en, 2012) |
| IL (1) | IL47524A (en, 2012) |
| IN (1) | IN143296B (en, 2012) |
| IT (1) | IT1041769B (en, 2012) |
| NO (1) | NO752379L (en, 2012) |
| PL (1) | PL102107B1 (en, 2012) |
| RO (1) | RO69555A (en, 2012) |
| SE (1) | SE7507459L (en, 2012) |
| SU (1) | SU640641A3 (en, 2012) |
| TR (1) | TR18782A (en, 2012) |
| YU (1) | YU167275A (en, 2012) |
| ZA (1) | ZA753963B (en, 2012) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11136513B2 (en) | 2017-02-12 | 2021-10-05 | Magëmä Technology LLC | Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials |
| US11203722B2 (en) | 2017-02-12 | 2021-12-21 | Magëmä Technology LLC | Multi-stage process and device for treatment heavy marine fuel oil and resultant composition including ultrasound promoted desulfurization |
| US11788017B2 (en) | 2017-02-12 | 2023-10-17 | Magëmã Technology LLC | Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil |
| US12025435B2 (en) | 2017-02-12 | 2024-07-02 | Magēmã Technology LLC | Multi-stage device and process for production of a low sulfur heavy marine fuel oil |
| US12071592B2 (en) | 2017-02-12 | 2024-08-27 | Magēmā Technology LLC | Multi-stage process and device utilizing structured catalyst beds and reactive distillation for the production of a low sulfur heavy marine fuel oil |
| US12281266B2 (en) | 2017-02-12 | 2025-04-22 | Magẽmã Technology LLC | Heavy marine fuel oil composition |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61138537A (ja) * | 1984-12-11 | 1986-06-26 | Nikki Universal Co Ltd | 水素化脱硫触媒の製造方法 |
| JPH03281595A (ja) * | 1990-03-28 | 1991-12-12 | Cosmo Sogo Kenkyusho:Kk | 炭化水素油用水素化脱硫触媒組成物およびその製法ならびにそれを用いた水素化脱硫法 |
| JP3272384B2 (ja) * | 1991-10-24 | 2002-04-08 | 財団法人石油産業活性化センター | 触媒組成物及びその製造方法ならびに該触媒組成物を用いる含硫炭化水素の水素化脱硫方法 |
-
1975
- 1975-06-19 AT AT473175A patent/AT343609B/de not_active IP Right Cessation
- 1975-06-19 IL IL47524A patent/IL47524A/xx unknown
- 1975-06-20 ZA ZA00753963A patent/ZA753963B/xx unknown
- 1975-06-23 IN IN1236/CAL/75A patent/IN143296B/en unknown
- 1975-06-24 CA CA229,995A patent/CA1054130A/en not_active Expired
- 1975-06-25 FI FI751887A patent/FI61413C/fi not_active IP Right Cessation
- 1975-06-28 EG EG366A patent/EG11809A/xx active
- 1975-06-30 SE SE7507459A patent/SE7507459L/xx unknown
- 1975-06-30 CS CS754609A patent/CS193516B2/cs unknown
- 1975-06-30 TR TR18782A patent/TR18782A/xx unknown
- 1975-06-30 DK DK296375A patent/DK296375A/da not_active Application Discontinuation
- 1975-06-30 PL PL1975181663A patent/PL102107B1/pl unknown
- 1975-06-30 NO NO752379A patent/NO752379L/no unknown
- 1975-06-30 BR BR5248/75D patent/BR7504093A/pt unknown
- 1975-06-30 AR AR259387A patent/AR230200A1/es active
- 1975-06-30 YU YU01672/75A patent/YU167275A/xx unknown
- 1975-06-30 ES ES438979A patent/ES438979A1/es not_active Expired
- 1975-06-30 IT IT24963/75A patent/IT1041769B/it active
- 1975-06-30 SU SU752149603A patent/SU640641A3/ru active
- 1975-06-30 GB GB27449/75A patent/GB1502915A/en not_active Expired
- 1975-07-01 RO RO7582726A patent/RO69555A/ro unknown
- 1975-07-01 IE IE1455/75A patent/IE41780B1/en unknown
- 1975-07-01 JP JP8135475A patent/JPS536113B2/ja not_active Expired
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11136513B2 (en) | 2017-02-12 | 2021-10-05 | Magëmä Technology LLC | Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials |
| US11203722B2 (en) | 2017-02-12 | 2021-12-21 | Magëmä Technology LLC | Multi-stage process and device for treatment heavy marine fuel oil and resultant composition including ultrasound promoted desulfurization |
| US11345863B2 (en) | 2017-02-12 | 2022-05-31 | Magema Technology, Llc | Heavy marine fuel oil composition |
| US11441084B2 (en) | 2017-02-12 | 2022-09-13 | Magēmā Technology LLC | Multi-stage device and process for production of a low sulfur heavy marine fuel oil |
| US11447706B2 (en) | 2017-02-12 | 2022-09-20 | Magēmā Technology LLC | Heavy marine fuel compositions |
| US11492559B2 (en) | 2017-02-12 | 2022-11-08 | Magema Technology, Llc | Process and device for reducing environmental contaminates in heavy marine fuel oil |
| US11530360B2 (en) | 2017-02-12 | 2022-12-20 | Magēmā Technology LLC | Process and device for treating high sulfur heavy marine fuel oil for use as feedstock in a subsequent refinery unit |
| US11560520B2 (en) | 2017-02-12 | 2023-01-24 | Magēmā Technology LLC | Multi-stage process and device for treatment heavy marine fuel oil and resultant composition and the removal of detrimental solids |
| US11788017B2 (en) | 2017-02-12 | 2023-10-17 | Magëmã Technology LLC | Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil |
| US11795406B2 (en) | 2017-02-12 | 2023-10-24 | Magemä Technology LLC | Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials |
| US11884883B2 (en) | 2017-02-12 | 2024-01-30 | MagêmãTechnology LLC | Multi-stage device and process for production of a low sulfur heavy marine fuel oil |
| US11912945B2 (en) | 2017-02-12 | 2024-02-27 | Magēmā Technology LLC | Process and device for treating high sulfur heavy marine fuel oil for use as feedstock in a subsequent refinery unit |
| US12025435B2 (en) | 2017-02-12 | 2024-07-02 | Magēmã Technology LLC | Multi-stage device and process for production of a low sulfur heavy marine fuel oil |
| US12071592B2 (en) | 2017-02-12 | 2024-08-27 | Magēmā Technology LLC | Multi-stage process and device utilizing structured catalyst beds and reactive distillation for the production of a low sulfur heavy marine fuel oil |
| US12139672B2 (en) | 2017-02-12 | 2024-11-12 | Magēmā Technology LLC | Multi-stage device and process for production of a low sulfur heavy marine fuel oil |
| US12281266B2 (en) | 2017-02-12 | 2025-04-22 | Magẽmã Technology LLC | Heavy marine fuel oil composition |
Also Published As
| Publication number | Publication date |
|---|---|
| IT1041769B (it) | 1980-01-10 |
| JPS5124593A (en, 2012) | 1976-02-27 |
| GB1502915A (en) | 1978-03-08 |
| FI751887A7 (en, 2012) | 1976-01-02 |
| CS193516B2 (en) | 1979-10-31 |
| SU640641A3 (ru) | 1978-12-30 |
| DK296375A (da) | 1976-01-02 |
| IN143296B (en, 2012) | 1977-10-29 |
| PL102107B1 (pl) | 1979-03-31 |
| EG11809A (en) | 1977-11-30 |
| IL47524A (en) | 1978-06-15 |
| ATA473175A (de) | 1977-10-15 |
| AR230200A1 (es) | 1984-03-01 |
| BR7504093A (pt) | 1976-06-29 |
| YU167275A (en) | 1982-02-28 |
| FI61413C (fi) | 1982-08-10 |
| JPS536113B2 (en, 2012) | 1978-03-04 |
| RO69555A (ro) | 1980-06-15 |
| ES438979A1 (es) | 1977-05-16 |
| NO752379L (en, 2012) | 1976-01-05 |
| ZA753963B (en) | 1976-05-26 |
| AT343609B (de) | 1978-06-12 |
| IE41780B1 (en) | 1980-03-26 |
| FI61413B (fi) | 1982-04-30 |
| IL47524A0 (en) | 1975-08-31 |
| SE7507459L (sv) | 1976-01-02 |
| TR18782A (tr) | 1977-08-24 |
| IE41780L (en) | 1976-01-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3935127A (en) | Method of catalyst manufacture | |
| US4036784A (en) | Method of producing an extruded catalyst composition | |
| US4152250A (en) | Demetallation of hydrocarbons with catalysts supported on sepiolite | |
| US4196102A (en) | Catalysts for demetallization treatment of _hydrocarbons supported on sepiolite | |
| US3232887A (en) | Stabilized aqueous solutions for use in impregnating catalyst carriers and method of making same | |
| JP4210336B2 (ja) | 高活性触媒の調製方法ならびに触媒およびその使用方法 | |
| US4124537A (en) | Coextruded catalytic composite | |
| US4289653A (en) | Comulled silica-alumina base denitrification catalyst | |
| US4082652A (en) | Process for improved carbon-supported hydrodesulfurization catalysts | |
| US4444905A (en) | Hydrotreating catalyst preparation and process | |
| CA1054130A (en) | Hydrodesulphurisation catalyst and method of manufacture and use thereof | |
| US3873470A (en) | Method of manufacturing a hydrodesulfurization catalyst | |
| WO2000044856A1 (en) | Hydroprocessing catalyst and use thereof | |
| US4615999A (en) | Method for preparing hydrodesulfurization catalyst | |
| US4394302A (en) | Hydrodesulfurization catalyst on lithium-containing support and method for its preparation | |
| US4083771A (en) | Hydrorefining of petroleum fraction utilizing a catalyst prepared with an anion complex of a group VI-B and a group VIII metal component | |
| US4046714A (en) | Method of manufacturing a hydrorefining catalyst | |
| US4908344A (en) | Hydroprocessing catalyst and support having bidisperse pore structure | |
| US4501655A (en) | Hydrocracking process | |
| US4791090A (en) | Hydroprocessing catalyst and support having bidisperse pore structure | |
| US4464481A (en) | Hydrocracking catalyst | |
| EP0243894A2 (en) | Hydroprocessing catalyst and support having bidisperse pore structure | |
| USRE31036E (en) | Catalysts for demetallization treatment of hydrocarbons supported on sepiolite | |
| US5035793A (en) | Hydrotreating catalyst and process | |
| US4447317A (en) | Hydroprocessing with lithium-containing catalyst |