CA1052825A - Stabilized 1,1,1-trichloroethane - Google Patents
Stabilized 1,1,1-trichloroethaneInfo
- Publication number
- CA1052825A CA1052825A CA240,416A CA240416A CA1052825A CA 1052825 A CA1052825 A CA 1052825A CA 240416 A CA240416 A CA 240416A CA 1052825 A CA1052825 A CA 1052825A
- Authority
- CA
- Canada
- Prior art keywords
- volume percent
- nitromethane
- mixture
- trichloroethane
- butyn
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 title claims abstract description 5
- 239000000203 mixture Substances 0.000 claims abstract description 36
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 16
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000003381 stabilizer Substances 0.000 claims abstract description 15
- CEBKHWWANWSNTI-UHFFFAOYSA-N 2-methylbut-3-yn-2-ol Chemical compound CC(C)(O)C#C CEBKHWWANWSNTI-UHFFFAOYSA-N 0.000 claims abstract description 12
- MSXVEPNJUHWQHW-UHFFFAOYSA-N 2-methylbutan-2-ol Chemical compound CCC(C)(C)O MSXVEPNJUHWQHW-UHFFFAOYSA-N 0.000 claims abstract description 12
- MCSAJNNLRCFZED-UHFFFAOYSA-N nitroethane Chemical compound CC[N+]([O-])=O MCSAJNNLRCFZED-UHFFFAOYSA-N 0.000 claims abstract description 9
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 3
- ZWAJLVLEBYIOTI-UHFFFAOYSA-N cyclohexene oxide Chemical compound C1CCCC2OC21 ZWAJLVLEBYIOTI-UHFFFAOYSA-N 0.000 claims abstract description 3
- FWFSEYBSWVRWGL-UHFFFAOYSA-N cyclohexene oxide Natural products O=C1CCCC=C1 FWFSEYBSWVRWGL-UHFFFAOYSA-N 0.000 claims abstract description 3
- RBACIKXCRWGCBB-UHFFFAOYSA-N 1,2-Epoxybutane Chemical compound CCC1CO1 RBACIKXCRWGCBB-UHFFFAOYSA-N 0.000 claims description 13
- 125000004971 nitroalkyl group Chemical group 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims description 2
- 238000005238 degreasing Methods 0.000 abstract description 3
- 230000000087 stabilizing effect Effects 0.000 abstract description 3
- JQZGUQIEPRIDMR-UHFFFAOYSA-N 3-methylbut-1-yn-1-ol Chemical compound CC(C)C#CO JQZGUQIEPRIDMR-UHFFFAOYSA-N 0.000 abstract 1
- DBAMUTGXJAWDEA-UHFFFAOYSA-N Butynol Chemical compound CCC#CO DBAMUTGXJAWDEA-UHFFFAOYSA-N 0.000 abstract 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 description 12
- 235000010210 aluminium Nutrition 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 10
- 238000004140 cleaning Methods 0.000 description 7
- 238000009472 formulation Methods 0.000 description 7
- 239000000243 solution Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 230000006641 stabilisation Effects 0.000 description 5
- 238000011105 stabilization Methods 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000000443 aerosol Substances 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 3
- 241001550224 Apha Species 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 229910001250 2024 aluminium alloy Inorganic materials 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- 229910001361 White metal Inorganic materials 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- -1 butyl alcohols Chemical group 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- NKDDWNXOKDWJAK-UHFFFAOYSA-N dimethoxymethane Chemical compound COCOC NKDDWNXOKDWJAK-UHFFFAOYSA-N 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 150000002924 oxiranes Chemical class 0.000 description 2
- 238000000638 solvent extraction Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 239000010969 white metal Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 description 1
- USCSRAJGJYMJFZ-UHFFFAOYSA-N 3-methyl-1-butyne Chemical compound CC(C)C#C USCSRAJGJYMJFZ-UHFFFAOYSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 238000005727 Friedel-Crafts reaction Methods 0.000 description 1
- UIQWBVPFHHQZHH-UHFFFAOYSA-N OOOOOOOOOOOOOO Chemical compound OOOOOOOOOOOOOO UIQWBVPFHHQZHH-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000013527 degreasing agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229960000443 hydrochloric acid Drugs 0.000 description 1
- 235000011167 hydrochloric acid Nutrition 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000009916 joint effect Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- LYGJENNIWJXYER-BJUDXGSMSA-N nitromethane Chemical group [11CH3][N+]([O-])=O LYGJENNIWJXYER-BJUDXGSMSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000003822 preparative gas chromatography Methods 0.000 description 1
- 230000005180 public health Effects 0.000 description 1
- 239000005297 pyrex Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
- C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
- C23G5/028—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing halogenated hydrocarbons
- C23G5/02854—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing halogenated hydrocarbons characterised by the stabilising or corrosion inhibiting additives
- C23G5/02883—Nitrogen-containing compounds
- C23G5/02887—Nitro-compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
- C07C17/42—Use of additives, e.g. for stabilisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/530,588 US3974230A (en) | 1974-12-09 | 1974-12-09 | Stabilized 1,1,1-trichloroethane |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1052825A true CA1052825A (en) | 1979-04-17 |
Family
ID=24114194
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA240,416A Expired CA1052825A (en) | 1974-12-09 | 1975-11-25 | Stabilized 1,1,1-trichloroethane |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US3974230A (enExample) |
| JP (1) | JPS5182205A (enExample) |
| AU (1) | AU500181B2 (enExample) |
| BE (1) | BE836456A (enExample) |
| BR (1) | BR7508139A (enExample) |
| CA (1) | CA1052825A (enExample) |
| DE (1) | DE2554776C3 (enExample) |
| FR (1) | FR2294247A1 (enExample) |
| GB (1) | GB1528958A (enExample) |
| IT (1) | IT1052514B (enExample) |
| NL (1) | NL188467C (enExample) |
| SE (1) | SE426056B (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2429767A1 (fr) * | 1978-06-30 | 1980-01-25 | Rhone Poulenc Ind | Procede de stabilisation du trichloro-1,1,1 ethane |
| JPS588364B2 (ja) * | 1979-01-31 | 1983-02-15 | 関東電化工業株式会社 | １，１，１↓−トリクロルエタンの安定化方法 |
| JPS55102526A (en) * | 1979-01-31 | 1980-08-05 | Kanto Denka Kogyo Kk | Stabilization of 1,1,1-trichloroethane |
| US4324928A (en) * | 1980-12-03 | 1982-04-13 | The Dow Chemical Company | Stabilized methylchloroform formulation containing cyclopropyl methyl carbinol |
| US4394284A (en) * | 1981-02-03 | 1983-07-19 | The Dow Chemical Company | Stabilized methylchloroform composition |
| US4327232A (en) * | 1981-02-19 | 1982-04-27 | The Dow Chemical Company | Cyclopropane ring-containing compounds as inhibitor components in methylchloroform |
| US4524011A (en) * | 1982-11-08 | 1985-06-18 | The Dow Chemical Company | Flux removal solvent blend |
| EP0108422A1 (en) * | 1982-11-08 | 1984-05-16 | The Dow Chemical Company | Flux removal solvent blend |
| JPS6119700A (ja) * | 1984-07-05 | 1986-01-28 | 東亞合成株式会社 | 銀製物品用洗浄剤組成物 |
| US4597890A (en) * | 1985-02-15 | 1986-07-01 | The Dow Chemical Company | Solvent blend for removing flux residues |
| US5124503A (en) * | 1990-12-13 | 1992-06-23 | Allied-Signal Inc. | Dichlorotrifluoroethane stabilized to minimize hydrolysis thereof |
| US8858820B2 (en) | 2011-10-07 | 2014-10-14 | American Pacific Corporation | Bromofluorocarbon compositions |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3549715A (en) * | 1959-05-13 | 1970-12-22 | Ppg Industries Inc | Stabilization |
| US3281480A (en) * | 1961-08-09 | 1966-10-25 | Pittsburgh Plate Glass Co | Stabilization of methyl chloroform |
| US3326989A (en) * | 1964-08-18 | 1967-06-20 | Pittsburgh Plate Glass Co | Stabilized methyl chloroform compositions with improved evaporation characteristics |
| BE756710A (fr) * | 1970-09-28 | 1971-03-01 | Solvay | Procede de stabilisation du 1,1,1-trichlorethane. |
-
1974
- 1974-12-09 US US05/530,588 patent/US3974230A/en not_active Expired - Lifetime
-
1975
- 1975-11-25 CA CA240,416A patent/CA1052825A/en not_active Expired
- 1975-11-27 AU AU87038/75A patent/AU500181B2/en not_active Expired
- 1975-12-05 IT IT52545/75A patent/IT1052514B/it active
- 1975-12-05 DE DE2554776A patent/DE2554776C3/de not_active Expired
- 1975-12-08 JP JP50145177A patent/JPS5182205A/ja active Pending
- 1975-12-08 FR FR7537436A patent/FR2294247A1/fr active Granted
- 1975-12-08 SE SE7513810A patent/SE426056B/xx not_active IP Right Cessation
- 1975-12-09 BE BE162596A patent/BE836456A/xx not_active IP Right Cessation
- 1975-12-09 NL NLAANVRAGE7514323,A patent/NL188467C/xx not_active IP Right Cessation
- 1975-12-09 BR BR7508139*A patent/BR7508139A/pt unknown
- 1975-12-09 GB GB50512/75A patent/GB1528958A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| US3974230A (en) | 1976-08-10 |
| SE426056B (sv) | 1982-12-06 |
| FR2294247B1 (enExample) | 1979-02-16 |
| GB1528958A (en) | 1978-10-18 |
| BE836456A (fr) | 1976-06-09 |
| JPS5182205A (en) | 1976-07-19 |
| NL188467C (nl) | 1992-07-01 |
| NL7514323A (nl) | 1976-06-11 |
| NL188467B (nl) | 1992-02-03 |
| IT1052514B (it) | 1981-07-20 |
| DE2554776A1 (de) | 1976-06-10 |
| SE7513810L (sv) | 1976-06-10 |
| AU8703875A (en) | 1977-06-02 |
| FR2294247A1 (fr) | 1976-07-09 |
| BR7508139A (pt) | 1976-08-24 |
| AU500181B2 (en) | 1979-05-10 |
| DE2554776C3 (de) | 1981-01-15 |
| DE2554776B2 (de) | 1980-04-24 |
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