CA1046203A - Silicate-containing flame-resistant adhesive composition - Google Patents
Silicate-containing flame-resistant adhesive compositionInfo
- Publication number
- CA1046203A CA1046203A CA234,839A CA234839A CA1046203A CA 1046203 A CA1046203 A CA 1046203A CA 234839 A CA234839 A CA 234839A CA 1046203 A CA1046203 A CA 1046203A
- Authority
- CA
- Canada
- Prior art keywords
- composition
- weight
- silicate
- total composition
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 80
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 title claims abstract description 20
- 239000000853 adhesive Substances 0.000 title claims abstract description 9
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 9
- 239000000243 solution Substances 0.000 claims abstract description 30
- 239000010425 asbestos Substances 0.000 claims abstract description 18
- 229910052895 riebeckite Inorganic materials 0.000 claims abstract description 18
- 239000007864 aqueous solution Substances 0.000 claims abstract description 10
- 229920002472 Starch Polymers 0.000 claims abstract description 9
- 239000008107 starch Substances 0.000 claims abstract description 9
- 235000019698 starch Nutrition 0.000 claims abstract description 9
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 7
- 239000004375 Dextrin Substances 0.000 claims abstract description 7
- 229920001353 Dextrin Polymers 0.000 claims abstract description 7
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 7
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract description 7
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract description 7
- 235000019425 dextrin Nutrition 0.000 claims abstract description 7
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims abstract description 6
- 239000006185 dispersion Substances 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims abstract description 4
- 239000012258 stirred mixture Substances 0.000 claims abstract description 3
- 239000011256 inorganic filler Substances 0.000 claims description 11
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 239000010451 perlite Substances 0.000 claims description 9
- 235000019362 perlite Nutrition 0.000 claims description 9
- 239000005995 Aluminium silicate Substances 0.000 claims description 8
- 235000012211 aluminium silicate Nutrition 0.000 claims description 8
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 230000008961 swelling Effects 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 239000010445 mica Substances 0.000 claims description 5
- 229910052618 mica group Inorganic materials 0.000 claims description 5
- 229920001296 polysiloxane Polymers 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- MWRWFPQBGSZWNV-UHFFFAOYSA-N Dinitrosopentamethylenetetramine Chemical compound C1N2CN(N=O)CN1CN(N=O)C2 MWRWFPQBGSZWNV-UHFFFAOYSA-N 0.000 claims description 4
- 239000004115 Sodium Silicate Substances 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 4
- 239000004111 Potassium silicate Substances 0.000 claims description 3
- 229910052913 potassium silicate Inorganic materials 0.000 claims description 3
- 235000019353 potassium silicate Nutrition 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 229920000877 Melamine resin Polymers 0.000 claims description 2
- 239000004640 Melamine resin Substances 0.000 claims description 2
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 229910052745 lead Inorganic materials 0.000 claims description 2
- 229920001568 phenolic resin Polymers 0.000 claims description 2
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 229940105329 carboxymethylcellulose Drugs 0.000 claims 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims 1
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 239000012530 fluid Substances 0.000 claims 1
- 229910052748 manganese Inorganic materials 0.000 claims 1
- 239000004927 clay Substances 0.000 abstract description 10
- 150000002148 esters Chemical class 0.000 abstract description 4
- 239000000306 component Substances 0.000 description 18
- 238000000576 coating method Methods 0.000 description 12
- 239000011248 coating agent Substances 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000002023 wood Substances 0.000 description 5
- 239000008199 coating composition Substances 0.000 description 4
- 239000011120 plywood Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- YKYOUMDCQGMQQO-UHFFFAOYSA-L cadmium dichloride Chemical compound Cl[Cd]Cl YKYOUMDCQGMQQO-UHFFFAOYSA-L 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- WTEVQBCEXWBHNA-YFHOEESVSA-N neral Chemical compound CC(C)=CCC\C(C)=C/C=O WTEVQBCEXWBHNA-YFHOEESVSA-N 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 239000002341 toxic gas Substances 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920002522 Wood fibre Polymers 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- WTEVQBCEXWBHNA-JXMROGBWSA-N citral A Natural products CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000004794 expanded polystyrene Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 229920006327 polystyrene foam Polymers 0.000 description 1
- 229910021332 silicide Inorganic materials 0.000 description 1
- 125000005625 siliconate group Chemical group 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J1/00—Adhesives based on inorganic constituents
- C09J1/02—Adhesives based on inorganic constituents containing water-soluble alkali silicates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/92—Fire or heat protection feature
- Y10S428/921—Fire or flameproofing
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paints Or Removers (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7433915A FR2295104A1 (fr) | 1974-10-09 | 1974-10-09 | Composition adhesive ininflammable contenant un silicate |
Publications (1)
Publication Number | Publication Date |
---|---|
CA1046203A true CA1046203A (en) | 1979-01-16 |
Family
ID=9143888
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA234,839A Expired CA1046203A (en) | 1974-10-09 | 1975-09-05 | Silicate-containing flame-resistant adhesive composition |
Country Status (14)
Country | Link |
---|---|
US (1) | US4066463A (en:Method) |
JP (1) | JPS5163836A (en:Method) |
BR (1) | BR7506576A (en:Method) |
CA (1) | CA1046203A (en:Method) |
CH (1) | CH610925A5 (en:Method) |
DD (1) | DD127876A5 (en:Method) |
DE (1) | DE2541555C3 (en:Method) |
ES (1) | ES441638A1 (en:Method) |
FR (1) | FR2295104A1 (en:Method) |
GB (1) | GB1493478A (en:Method) |
IN (1) | IN144766B (en:Method) |
IT (1) | IT1056140B (en:Method) |
LU (1) | LU73538A1 (en:Method) |
OA (1) | OA05281A (en:Method) |
Families Citing this family (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2712826B2 (de) * | 1977-03-23 | 1981-07-23 | Woellner-Werke, 6700 Ludwigshafen | Klebstoff zum Verkleben von Kunststoffschaumplatten |
DE2734839C2 (de) * | 1977-08-02 | 1986-05-28 | Wöllner-Werke, 6700 Ludwigshafen | Verwendung eines Klebers auf der Basis einer Alkalisilikatlösung zur Spritzisolierung unter Einsatz von Mineralfasern |
US4162169A (en) * | 1977-12-21 | 1979-07-24 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Alkali-metal silicate binders and methods of manufacture |
US4212920A (en) * | 1978-07-10 | 1980-07-15 | Seamans Winthrop W | Fireproofing composition comprising sodium silicate, gum arabic or other gum, and a water dispersible polymer selected from the class of epoxy polymers, natural latices and synthetic latices |
IT1122846B (it) * | 1978-09-25 | 1986-04-23 | Woellner Werke | Procedimento per isolare a spruzzo oggetti metallici e/o non metallici |
US4263048A (en) * | 1980-01-25 | 1981-04-21 | High Efficiency Insulation Technologies, Inc. | Self-hardening composition and composite therefrom |
FR2482123B1 (fr) * | 1980-05-08 | 1985-08-09 | Venditti Gaetan | Composition formant colle ou enduit de ratissage |
US4424867A (en) | 1981-03-31 | 1984-01-10 | Fiberglas Canada Inc. | Heat hardening sealant-gel for flexible couplings |
US4722960A (en) * | 1983-01-18 | 1988-02-02 | Loctite Corporation | Aluminum filled compositions |
US4574138A (en) * | 1984-01-09 | 1986-03-04 | Moran Jr James P | Rapid cure acrylic monomer systems containing elemental aluminum metal |
CA1201858A (en) * | 1983-03-18 | 1986-03-18 | Mitsui & Co, (U.S.A.), Inc. | Adhesive for fireproofing and fiber encapsulation |
US4600437A (en) * | 1984-03-29 | 1986-07-15 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Inorganic material, a process for producing same and a solidifying method thereof |
NO162339C (no) * | 1986-01-10 | 1989-12-13 | Norsk Proco As | Vannfast og ildsikkert bygningsmateriale og fremgangsmaatefor fremstilling derav. |
CA1258328A (en) * | 1986-04-04 | 1989-08-08 | John S. Luckanuck | Fire retardant composition |
JPS62270450A (ja) * | 1986-05-16 | 1987-11-24 | イソライト工業株式会社 | ケ−ブル延焼防止用耐火充填材 |
US4909845A (en) * | 1988-07-22 | 1990-03-20 | Ray Charles E | Mine sealant composition |
US5035951A (en) * | 1988-10-20 | 1991-07-30 | Firestop Chemical Corporation | Fire resistant coatings |
US5236499A (en) * | 1989-08-29 | 1993-08-17 | Sandvik Rock Tools, Inc. | Sprayable wall sealant |
US5043019A (en) * | 1989-08-29 | 1991-08-27 | Sandvik Rock Tools, Inc. | Sealant for concrete or cinder block walls |
DE4020771C2 (de) * | 1990-06-29 | 1995-08-10 | Porextherm Daemmstoffe Gmbh | Hochtemperaturbeständiger Klebstoff aus Kieselsol, einem Ton und einem Bindemittel und dessen Verwendung |
US5366550A (en) * | 1993-04-02 | 1994-11-22 | Tec Incorporated | Latex modified cement-based thin set adhesive |
DE4434627C1 (de) * | 1994-09-28 | 1996-03-14 | Murjahn Amphibolin Werke | Verwendung eines Zweikomponenten-Silikatklebers für Baumaterialien und hiernach hergestellte Baumaterialplatten |
US5571316A (en) * | 1996-02-28 | 1996-11-05 | Pq Corporation | Silicate-dextrin adhesive compositions |
PL359173A1 (en) * | 2000-06-14 | 2004-08-23 | Fosroc Mining International Limited | Fire retardant coating |
US6833188B2 (en) * | 2001-03-16 | 2004-12-21 | Blaine K. Semmens | Lightweight cementitious composite material |
KR100712645B1 (ko) | 2005-11-30 | 2007-05-02 | 전창호 | 미네랄 기포 접착제의 조성물 |
US20090156403A1 (en) * | 2007-12-14 | 2009-06-18 | Kelly Green | Turf mold remediation |
GB2460818A (en) * | 2008-05-06 | 2009-12-16 | Seat It Services Ltd | Composition for treating a concrete surface comprising a metal silicate and a metal siliconate |
DE102010009234B4 (de) * | 2010-02-25 | 2015-05-13 | Jadecor Gmbh | Nichtbrennbare Beschichtungszusammensetzung, Verfahren zu deren Herstellung und Verwendung |
KR101705068B1 (ko) * | 2012-06-12 | 2017-02-09 | 코닝정밀소재 주식회사 | 무기접착 조성물 및 이를 이용한 기밀 밀봉 방법 |
PL413174A1 (pl) * | 2015-07-17 | 2017-01-30 | Andrzej Sroczyński | Tynk gliniany oraz sposób jego wykonania |
CN107880808B (zh) * | 2017-11-11 | 2019-12-20 | 蚌埠承永玻璃制品有限公司 | 一种复合玻璃阻燃夹层凝胶的制备方法 |
WO2022255933A1 (en) * | 2021-05-31 | 2022-12-08 | Matwerkz Technologies Pte. Ltd. | Fire protection and insulation coating and method of use thereof |
US12018180B2 (en) | 2022-02-11 | 2024-06-25 | Awi Licensing Llc | Fire resistant adhesive compositions and methods of preparing and using the same |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA798212A (en) * | 1968-11-05 | W. A. Kurz Fredrik | Bonding- or impregnating means on the basis of sodium silicate | |
US2323029A (en) * | 1939-01-31 | 1943-06-29 | Gladding Mcbean & Company | Acidproof cement |
US2536871A (en) * | 1942-03-02 | 1951-01-02 | Minnesota Mining & Mfg | Coated abrasive articles |
US2736678A (en) * | 1953-05-13 | 1956-02-28 | Diamond Alkali Co | Adhesive silicate composition and method of using the same |
US3009829A (en) * | 1957-03-25 | 1961-11-21 | Johns Manville | Impregnating composition, method of applying same to asbestos, and article produced thereby |
US3150989A (en) * | 1962-04-23 | 1964-09-29 | Chicago Fire Brick Co | Lightweight refractory aggregate and process for making same |
GB1393246A (en) * | 1971-06-02 | 1975-05-07 | Foseco Int | High temperature adhesives |
US3767440A (en) * | 1972-04-24 | 1973-10-23 | Diamond Shamrock Corp | Dextrin-clay-silicate adhesive |
JPS4910545A (en:Method) * | 1972-05-30 | 1974-01-30 | ||
JPS5128100B2 (en:Method) * | 1972-07-22 | 1976-08-17 |
-
1974
- 1974-10-09 FR FR7433915A patent/FR2295104A1/fr active Granted
-
1975
- 1975-09-05 CA CA234,839A patent/CA1046203A/en not_active Expired
- 1975-09-16 US US05/613,857 patent/US4066463A/en not_active Expired - Lifetime
- 1975-09-18 DE DE2541555A patent/DE2541555C3/de not_active Expired
- 1975-10-03 JP JP50120223A patent/JPS5163836A/ja active Pending
- 1975-10-07 LU LU73538A patent/LU73538A1/xx unknown
- 1975-10-07 IT IT51673/75A patent/IT1056140B/it active
- 1975-10-08 BR BR7506576*A patent/BR7506576A/pt unknown
- 1975-10-08 CH CH1307275A patent/CH610925A5/xx not_active IP Right Cessation
- 1975-10-08 GB GB41277/75A patent/GB1493478A/en not_active Expired
- 1975-10-09 DD DD7500188777A patent/DD127876A5/xx unknown
- 1975-10-09 ES ES441638A patent/ES441638A1/es not_active Expired
-
1976
- 1976-03-10 IN IN432/CAL/76A patent/IN144766B/en unknown
- 1976-03-24 OA OA55776A patent/OA05281A/xx unknown
Also Published As
Publication number | Publication date |
---|---|
IT1056140B (it) | 1982-01-30 |
DE2541555A1 (de) | 1976-04-22 |
LU73538A1 (en:Method) | 1976-04-13 |
DD127876A5 (de) | 1977-10-19 |
CH610925A5 (en:Method) | 1979-05-15 |
US4066463A (en) | 1978-01-03 |
DE2541555B2 (de) | 1979-07-12 |
AU8551375A (en) | 1976-11-04 |
JPS5163836A (en:Method) | 1976-06-02 |
ES441638A1 (es) | 1977-07-01 |
FR2295104A1 (fr) | 1976-07-16 |
FR2295104B1 (en:Method) | 1977-11-10 |
GB1493478A (en) | 1977-11-30 |
OA05281A (fr) | 1981-02-28 |
DE2541555C3 (de) | 1980-03-20 |
BR7506576A (pt) | 1976-08-17 |
IN144766B (en:Method) | 1978-07-01 |
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