BRPI0617591A2 - sistemas para iniciar polimerização via radical livre, composição polimerizável de duas partes, método de polimerização, método para ligar dois ou mais substratos entre si, método para modificar a superfìcie de um polìmero de baixa energia superficial, método para revestir um substrato, composição de revestimento e laminado - Google Patents
sistemas para iniciar polimerização via radical livre, composição polimerizável de duas partes, método de polimerização, método para ligar dois ou mais substratos entre si, método para modificar a superfìcie de um polìmero de baixa energia superficial, método para revestir um substrato, composição de revestimento e laminado Download PDFInfo
- Publication number
- BRPI0617591A2 BRPI0617591A2 BRPI0617591-0A BRPI0617591A BRPI0617591A2 BR PI0617591 A2 BRPI0617591 A2 BR PI0617591A2 BR PI0617591 A BRPI0617591 A BR PI0617591A BR PI0617591 A2 BRPI0617591 A2 BR PI0617591A2
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- BR
- Brazil
- Prior art keywords
- occurrence
- independently
- borate
- starch
- composition
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 163
- 239000000758 substrate Substances 0.000 title claims abstract description 61
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 28
- 238000000034 method Methods 0.000 title claims abstract description 26
- 238000010526 radical polymerization reaction Methods 0.000 title claims abstract description 23
- 229920000642 polymer Polymers 0.000 title claims abstract description 19
- 230000000977 initiatory effect Effects 0.000 title claims abstract description 11
- 238000000576 coating method Methods 0.000 title claims description 12
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- 150000001875 compounds Chemical class 0.000 claims abstract description 107
- 229920002472 Starch Polymers 0.000 claims abstract description 86
- 239000008107 starch Substances 0.000 claims abstract description 86
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- 125000005842 heteroatom Chemical group 0.000 claims abstract description 56
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 36
- 125000004433 nitrogen atom Chemical group N* 0.000 claims abstract description 26
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910052796 boron Inorganic materials 0.000 claims abstract description 22
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- 125000000129 anionic group Chemical group 0.000 claims abstract description 4
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- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 75
- 150000001412 amines Chemical class 0.000 claims description 36
- 125000003118 aryl group Chemical group 0.000 claims description 32
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 26
- 125000000217 alkyl group Chemical group 0.000 claims description 25
- 125000002947 alkylene group Chemical group 0.000 claims description 23
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- 125000000623 heterocyclic group Chemical group 0.000 description 15
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- LALRXNPLTWZJIJ-UHFFFAOYSA-N triethylborane Chemical compound CCB(CC)CC LALRXNPLTWZJIJ-UHFFFAOYSA-N 0.000 description 10
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- YNCPXBIZAPNQIJ-UHFFFAOYSA-N 1h-imidazole;sodium Chemical compound [Na].C1=CNC=N1 YNCPXBIZAPNQIJ-UHFFFAOYSA-N 0.000 description 6
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- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 4
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 4
- FAXDZWQIWUSWJH-UHFFFAOYSA-N 3-methoxypropan-1-amine Chemical compound COCCCN FAXDZWQIWUSWJH-UHFFFAOYSA-N 0.000 description 4
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- 239000002253 acid Substances 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 229910000085 borane Inorganic materials 0.000 description 4
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
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- OKIZCWYLBDKLSU-UHFFFAOYSA-M N,N,N-Trimethylmethanaminium chloride Chemical compound [Cl-].C[N+](C)(C)C OKIZCWYLBDKLSU-UHFFFAOYSA-M 0.000 description 3
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- 230000015572 biosynthetic process Effects 0.000 description 3
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- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
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- NHGXDBSUJJNIRV-UHFFFAOYSA-M tetrabutylammonium chloride Chemical group [Cl-].CCCC[N+](CCCC)(CCCC)CCCC NHGXDBSUJJNIRV-UHFFFAOYSA-M 0.000 description 3
- BJQWBACJIAKDTJ-UHFFFAOYSA-N tetrabutylphosphanium Chemical compound CCCC[P+](CCCC)(CCCC)CCCC BJQWBACJIAKDTJ-UHFFFAOYSA-N 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
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- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 2
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- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- 239000002562 thickening agent Substances 0.000 description 2
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- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
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- JSJVLOHJGMWSOG-UHFFFAOYSA-N B([O-])([O-])[O-].[C+4].B([O-])([O-])[O-].B([O-])([O-])[O-].B([O-])([O-])[O-].[C+4].[C+4] Chemical group B([O-])([O-])[O-].[C+4].B([O-])([O-])[O-].B([O-])([O-])[O-].B([O-])([O-])[O-].[C+4].[C+4] JSJVLOHJGMWSOG-UHFFFAOYSA-N 0.000 description 1
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- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
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- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
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- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
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- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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- Y10T428/00—Stock material or miscellaneous articles
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/31855—Of addition polymer from unsaturated monomers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/31909—Next to second addition polymer from unsaturated monomers
- Y10T428/31913—Monoolefin polymer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
- Y10T428/31928—Ester, halide or nitrile of addition polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polymerization Catalysts (AREA)
- Paints Or Removers (AREA)
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PCT/US2006/039575 WO2007044730A1 (en) | 2005-10-07 | 2006-10-06 | Amido-organoborate initiator systems |
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BRPI0617591-0A BRPI0617591A2 (pt) | 2005-10-07 | 2006-10-06 | sistemas para iniciar polimerização via radical livre, composição polimerizável de duas partes, método de polimerização, método para ligar dois ou mais substratos entre si, método para modificar a superfìcie de um polìmero de baixa energia superficial, método para revestir um substrato, composição de revestimento e laminado |
BRPI0617975-4A BRPI0617975A2 (pt) | 2005-10-07 | 2006-10-06 | composto de amido-borato |
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US20090090454A1 (en) * | 2003-08-13 | 2009-04-09 | Lutz William G | Method for joining piping systems and piping to equipment, fixtures, devices, structures, and appliances |
US7534843B2 (en) | 2003-12-22 | 2009-05-19 | Dow Global Technoloigies, Inc. | Accelerated organoborane amine complex initiated polymerizable compositions |
CA2624322A1 (en) * | 2005-10-07 | 2007-04-19 | Dow Global Technologies Inc. | Amido-organoborate initiator systems |
US20080103274A1 (en) * | 2006-10-12 | 2008-05-01 | Jialanella Gary L | Accelerated organoborane initiated polymerizable compositions |
US7524907B2 (en) * | 2006-10-12 | 2009-04-28 | Dow Global Technologies, Inc. | Accelerated organoborane initiated polymerizable compositions |
US8377852B2 (en) | 2007-10-26 | 2013-02-19 | Dow Corning Corporation | Method of preparing a substrate with a composition including an organoborane initiator |
WO2010014537A1 (en) * | 2008-07-28 | 2010-02-04 | Dow Corning Corporation | Radical polymerizable composition |
JP2011529526A (ja) | 2008-07-28 | 2011-12-08 | ダウ コーニング コーポレーション | 複合物品 |
US20110104508A1 (en) * | 2008-08-29 | 2011-05-05 | Dow Global Technologies Inc. | Adhesive for bonding to flexible polymer surfaces |
TW201026513A (en) * | 2009-01-08 | 2010-07-16 | Univ Nat Cheng Kung | Imprinting process of polyimide |
CN102369226B (zh) | 2009-02-04 | 2013-12-25 | 道康宁公司 | 形成非无规共聚物的方法 |
WO2012085169A1 (en) * | 2010-12-22 | 2012-06-28 | Haag Benjamin | Metallic amidoborates for functionalizing organic compounds |
CN103547606B (zh) | 2011-05-03 | 2016-01-20 | 陶氏环球技术有限责任公司 | 可用于粘合玻璃的双重固化粘合剂 |
JP2014511931A (ja) | 2011-05-03 | 2014-05-19 | ダウ グローバル テクノロジーズ エルエルシー | イソシアネート官能性プレポリマーを含有する促進された硬化組成物 |
US9416301B2 (en) | 2012-11-08 | 2016-08-16 | Dow Global Technologies Llc | Ultrafast dual cure adhesive useful for bonding to glass |
US9382452B2 (en) * | 2013-02-07 | 2016-07-05 | Illinois Tool Works, Inc. | Low surface energy bonding adhesive formulation and process for the use thereof |
CA2968549C (en) | 2014-11-24 | 2020-03-10 | Ppg Industries Ohio, Inc. | Coreactive materials and methods for three-dimensional printing |
JP2016169297A (ja) * | 2015-03-12 | 2016-09-23 | 日東電工株式会社 | 架橋剤および硬化性樹脂組成物、偏光フィルムおよびその製造方法、光学フィルムならびに画像表示装置 |
KR101889714B1 (ko) * | 2016-03-08 | 2018-08-20 | 대우조선해양 주식회사 | 글라스 버블 혼성 구조의 고난연성 코팅제 |
KR102258062B1 (ko) * | 2017-04-13 | 2021-05-27 | 주식회사 엘지화학 | 아크릴 접착제 조성물 |
WO2018227149A1 (en) | 2017-06-09 | 2018-12-13 | Prc-Desoto International, Inc. | Dual cure sealants |
US10434704B2 (en) | 2017-08-18 | 2019-10-08 | Ppg Industries Ohio, Inc. | Additive manufacturing using polyurea materials |
US11332571B2 (en) * | 2017-09-18 | 2022-05-17 | Aditya Birla Chemicals (Thailand) Ltd. | Epoxy resin system for structural composites |
US11015057B2 (en) | 2019-04-03 | 2021-05-25 | Prc-Desoto International, Inc. | Dual-cure compositions |
US11173692B2 (en) | 2019-12-19 | 2021-11-16 | Prc-Desoto International, Inc. | Free radical polymerizable adhesion-promoting interlayer compositions and methods of use |
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- 2006-10-06 CA CA 2624322 patent/CA2624322A1/en not_active Abandoned
- 2006-10-06 CN CNA2006800368820A patent/CN101278023A/zh active Pending
- 2006-10-06 CN CNA200680036700XA patent/CN101501043A/zh active Pending
- 2006-10-06 BR BRPI0617591-0A patent/BRPI0617591A2/pt not_active IP Right Cessation
- 2006-10-06 RU RU2008116620/04A patent/RU2008116620A/ru not_active Application Discontinuation
- 2006-10-06 EP EP20060825707 patent/EP1934264A2/en not_active Withdrawn
- 2006-10-06 WO PCT/US2006/039584 patent/WO2007044735A2/en active Application Filing
- 2006-10-06 EP EP20060825699 patent/EP1934296A1/en not_active Withdrawn
- 2006-10-06 JP JP2008534773A patent/JP2009531468A/ja active Pending
- 2006-10-06 JP JP2008534776A patent/JP2009511502A/ja active Pending
- 2006-10-06 CA CA 2625023 patent/CA2625023A1/en not_active Abandoned
- 2006-10-06 RU RU2008118139/04A patent/RU2008118139A/ru not_active Application Discontinuation
- 2006-10-06 BR BRPI0617975-4A patent/BRPI0617975A2/pt not_active IP Right Cessation
- 2006-10-06 US US11/544,521 patent/US7816562B2/en not_active Expired - Fee Related
- 2006-10-06 KR KR1020087008150A patent/KR20080053348A/ko active IP Right Grant
- 2006-10-06 WO PCT/US2006/039575 patent/WO2007044730A1/en active Search and Examination
- 2006-10-06 KR KR1020087008145A patent/KR20080053486A/ko not_active Application Discontinuation
- 2006-10-06 US US11/544,502 patent/US7737241B2/en not_active Expired - Fee Related
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WO2007044730A1 (en) | 2007-04-19 |
RU2008118139A (ru) | 2009-11-20 |
JP2009531468A (ja) | 2009-09-03 |
WO2007044735A3 (en) | 2009-04-23 |
CN101501043A (zh) | 2009-08-05 |
CN101278023A (zh) | 2008-10-01 |
EP1934296A1 (en) | 2008-06-25 |
US7737241B2 (en) | 2010-06-15 |
CA2624322A1 (en) | 2007-04-19 |
CA2625023A1 (en) | 2007-04-19 |
KR20080053348A (ko) | 2008-06-12 |
KR20080053486A (ko) | 2008-06-13 |
US20070079931A1 (en) | 2007-04-12 |
WO2007044735A2 (en) | 2007-04-19 |
US20070083051A1 (en) | 2007-04-12 |
EP1934264A2 (en) | 2008-06-25 |
US7816562B2 (en) | 2010-10-19 |
BRPI0617975A2 (pt) | 2011-08-09 |
RU2008116620A (ru) | 2009-11-20 |
JP2009511502A (ja) | 2009-03-19 |
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