BRPI0418977B8 - processo para converter material carbonífero em gases energéticos e sistema para produzir um gás sintético - Google Patents

processo para converter material carbonífero em gases energéticos e sistema para produzir um gás sintético

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Publication number
BRPI0418977B8
BRPI0418977B8 BRPI0418977A BRPI0418977A BRPI0418977B8 BR PI0418977 B8 BRPI0418977 B8 BR PI0418977B8 BR PI0418977 A BRPI0418977 A BR PI0418977A BR PI0418977 A BRPI0418977 A BR PI0418977A BR PI0418977 B8 BRPI0418977 B8 BR PI0418977B8
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BR
Brazil
Prior art keywords
hydrogen
steam
synthetic gas
liquid fuel
fed
Prior art date
Application number
BRPI0418977A
Other languages
English (en)
Inventor
Colin E Hackett
Joseph N Norbeck
Original Assignee
Univ Califórnia
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Filing date
Publication date
Application filed by Univ Califórnia filed Critical Univ Califórnia
Publication of BRPI0418977A publication Critical patent/BRPI0418977A/pt
Publication of BRPI0418977B1 publication Critical patent/BRPI0418977B1/pt
Publication of BRPI0418977B8 publication Critical patent/BRPI0418977B8/pt

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    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
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    • C10J2300/0953Gasifying agents
    • C10J2300/0966Hydrogen
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    • C10J2300/0973Water
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    • C10J2300/0983Additives
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10J2300/164Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1643Conversion of synthesis gas to energy
    • C10J2300/165Conversion of synthesis gas to energy integrated with a gas turbine or gas motor
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    • C10J2300/164Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656Conversion of synthesis gas to chemicals
    • C10J2300/1659Conversion of synthesis gas to chemicals to liquid hydrocarbons
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    • C10J2300/1671Integration of gasification processes with another plant or parts within the plant with the production of electricity
    • C10J2300/1675Integration of gasification processes with another plant or parts within the plant with the production of electricity making use of a steam turbine
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    • C10J2300/1693Integration of gasification processes with another plant or parts within the plant with storage facilities for intermediate, feed and/or product
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    • C10J2300/1807Recycle loops, e.g. gas, solids, heating medium, water
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    • C10J2300/1853Steam reforming, i.e. injection of steam only
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    • C10J2300/00Details of gasification processes
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    • C10J2300/1861Heat exchange between at least two process streams
    • C10J2300/1884Heat exchange between at least two process streams with one stream being synthesis gas
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    • C10J2300/00Details of gasification processes
    • C10J2300/18Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1861Heat exchange between at least two process streams
    • C10J2300/1892Heat exchange between at least two process streams with one stream being water/steam
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/16Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/32Hydrogen storage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/141Feedstock
    • Y02P20/145Feedstock the feedstock being materials of biological origin
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/20Technologies relating to oil refining and petrochemical industry using bio-feedstock

Abstract

processo para converter material carbonífero em gases energéticos, processos para a produção de gás sintético e de combustível líquido; aparelhos para produção de um gás sintético e de combustível líquido em um processo substancialmente auto-sustentável um processo e aparelho para produção de um gás sintético para uso como um combustível gasoso ou um alimento dentro de um reator fischer-tropsch para produzir um combustível líquido em um processo substancialmente auto-sustentável. em uma configuração, uma pasta fluida de partículas de material carbonífero na água, e hidrogênio de uma fonte interna, são alimentados dentro de um reator de hidro-gasificação sob condições por meio das quais gases produtos ricos em metano são gerados e alimentados dentro de um reformador pirolítico a vapor sob condições por meio das quais o gás sintético compreendendo hidrogênio e monóxido de carbono são gerados. uma porção do hidrogênio gerado pelo reformador pirolítico a vapor é alimentado através de um filtro de purificação de hidrogênio dentro do reator de hidro-gasificação, o hidrogênio distro constituindo o hidrogênio de uma fonte interna. o gás sintético remanescente gerado pelo reformador pirolitico a vapor é igualmente usado como combustível gasoso para um motor abastecido para produzir eletricidade e/ou transformador calor ou é alimentado dentro de um reator fischer-tropsch sob condições por meio das quais um combustível líquido é produzido. circuitos de sal fundido são usados para transferir calor do reator de hidro-gasificação, e o reator fischer-tropsch se o combustível liquido é produzido, para o gerador a vapor e o reformador pirolitico a vapor. em outra configuração da invenção, material carbonífero pode ser aquecido simultaneamente na presença de ambos hidrogênio e vapor para ser submetido a pirólise a vapor e hidro-gasificação em uma etapa única.
BRPI0418977A 2004-08-03 2004-08-04 processo para converter material carbonífero em gases energéticos e sistema para produzir um gás sintético BRPI0418977B8 (pt)

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US10/911,348 US7500997B2 (en) 2002-02-05 2004-08-03 Steam pyrolysis as a process to enhance the hydro-gasification of carbonaceous materials
US10/911.348 2004-08-03
PCT/US2004/025254 WO2006022687A2 (en) 2004-08-03 2004-08-04 Steam pyrolysis as a process to enhance the hydro-gasification of carbonaceous materials

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EP (1) EP1792134A2 (pt)
JP (1) JP2008525532A (pt)
KR (1) KR20070042571A (pt)
CN (1) CN101218018B (pt)
AU (1) AU2004322730B2 (pt)
BR (1) BRPI0418977B8 (pt)
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