BRPI0418926A - sìntese de sìlica gel micro-porosa e sua aplicação para a preparação de catalisadores para sìntese de c2 oxigenados a partir das singas - Google Patents

sìntese de sìlica gel micro-porosa e sua aplicação para a preparação de catalisadores para sìntese de c2 oxigenados a partir das singas

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Publication number
BRPI0418926A
BRPI0418926A BRPI0418926-4A BRPI0418926A BRPI0418926A BR PI0418926 A BRPI0418926 A BR PI0418926A BR PI0418926 A BRPI0418926 A BR PI0418926A BR PI0418926 A BRPI0418926 A BR PI0418926A
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BR
Brazil
Prior art keywords
synthesis
oxygenated
micro
salts
preparation
Prior art date
Application number
BRPI0418926-4A
Other languages
English (en)
Inventor
Hongyuan Luo
Yunjie Ding
Hongmei Yin
Original Assignee
Bp Plc
Dalian Chemical Physics Inst
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bp Plc, Dalian Chemical Physics Inst filed Critical Bp Plc
Publication of BRPI0418926A publication Critical patent/BRPI0418926A/pt

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/124—Preparation of adsorbing porous silica not in gel form and not finely divided, i.e. silicon skeletons, by acidic treatment of siliceous materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/464—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8986—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C07C29/157—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof
    • C07C29/158—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof containing rhodium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B01J37/033—Using Hydrolysis

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Silicon Compounds (AREA)

Abstract

SìNTESE DE SìLICA GEL MICRO-POROSA E SUA APLICAçãO PARA A PREPARAçãO DE CATALISADORES PARA SìNTESE DE C2 OXIGENADOS A PARTIR DAS SINGAS. Uma síntese do gel de sílica micro-porosa e de sua aplicação à preparação dos catalisadores para C 2 oxigenados síntese das singas é inventada. As partículas pequenas do gel de sílica que são, produzidas pelo processo do gel do solenóide são aquecidas em uma solução básica, seguida de secagem e/ou calcinação, e dão forma assim à sílica micro-porosa como a sustentação do catalisador. A solução básica pode ser um ou uma solução misturada dos hidróxidos, dos carbonatos, dos bicarbonatos, dos formates e dos acetatos do metal alcalino e do amónio. A sílica micro-porosa obtido pode ser impregnado com as soluções do sal do ródio e dos outros sais do elemento da transição (como precursores do promotor), seguidas de secagem e/ou calcinação, assim dando forma sílica micro-porosa a um catalisador baseado ródio suportado. O sal do ródio pode ser RhCl 3 ou Rh(NO 3) 3. Os precursores do promoter podem ser sais água-water-dissolvable do metal da transição, sais dos metais da terra rara, sais alcalinos e sais do metal da terra do alcalóide. Os catalisadores obtidos mostram a atividade e a seletividade elevados na síntese de C2 oxigenados por hidrogenação do CO sob circunstâncias processo suaves.
BRPI0418926-4A 2004-06-23 2004-06-23 sìntese de sìlica gel micro-porosa e sua aplicação para a preparação de catalisadores para sìntese de c2 oxigenados a partir das singas BRPI0418926A (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/GB2004/002701 WO2006000734A1 (en) 2004-06-23 2004-06-23 The synthesis of the micro-porous silica gel and its application to the preparation of catalysts for c2 oxygenates synthesis from syngas

Publications (1)

Publication Number Publication Date
BRPI0418926A true BRPI0418926A (pt) 2007-11-27

Family

ID=34957799

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0418926-4A BRPI0418926A (pt) 2004-06-23 2004-06-23 sìntese de sìlica gel micro-porosa e sua aplicação para a preparação de catalisadores para sìntese de c2 oxigenados a partir das singas

Country Status (10)

Country Link
US (1) US20070249874A1 (pt)
EP (1) EP1771245A1 (pt)
JP (1) JP2008503440A (pt)
AU (1) AU2004320979A1 (pt)
BR (1) BRPI0418926A (pt)
CA (1) CA2586418A1 (pt)
EA (1) EA200602293A1 (pt)
NO (1) NO20070161L (pt)
RS (1) RS20060683A (pt)
WO (1) WO2006000734A1 (pt)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2003287585B2 (en) 2002-11-12 2009-05-07 Mallinckrodt Inc. Cannabinoid crystalline derivatives and process of cannabinoid purification
JP2010116328A (ja) * 2008-11-11 2010-05-27 Nippon Oil Corp 不飽和炭化水素および含酸素化合物の製造方法、触媒およびその製造方法
TWI473652B (zh) 2008-12-26 2015-02-21 Nippon Oil Corp Hydrogenated isomerization catalyst, method for producing the same, dewaxing method for hydrocarbon oil and method for producing lubricating base oil
KR101404214B1 (ko) 2011-12-28 2014-06-10 한국에너지기술연구원 동시 용융함침에 의한 혼성 합금 촉매 담지체 제조 방법 및 그 혼성 합금 촉매 담지체
WO2013129614A1 (ja) 2012-02-28 2013-09-06 積水化学工業株式会社 Ｃ２酸素化物合成用の触媒、ｃ２酸素化物の製造装置及びｃ２酸素化物の製造方法
JP6037305B2 (ja) * 2012-12-27 2016-12-07 積水化学工業株式会社 Ｃ２酸素化物合成用の触媒、ｃ２酸素化物の製造装置及びｃ２酸素化物の製造方法
ES2546118B1 (es) 2013-01-24 2016-08-09 Abengoa Bioenergía Nuevas Tecnologías, S.A Catalizador de rodio promovido para la conversión selectiva de gas de síntesis en etanol
JP2015178101A (ja) * 2014-02-28 2015-10-08 積水化学工業株式会社 酸素化物合成用の触媒、酸素化物合成用の触媒の製造方法、酸素化物の製造装置及び酸素化物の製造方法
WO2018162709A2 (en) * 2017-03-10 2018-09-13 Basf Se A catalyst for converting synthesis gas to alcohols
CN113842905B (zh) * 2020-06-28 2023-08-29 中国石油化工股份有限公司 一种载体和催化剂及其制备方法和应用

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6049617B2 (ja) * 1983-08-03 1985-11-02 工業技術院長 エタノ−ルなどの含酸素化合物を製造する方法
US5256386A (en) * 1987-06-29 1993-10-26 Eka Nobel Ab Method for preparation of silica particles
DE3803895C1 (pt) * 1988-02-09 1989-04-13 Degussa Ag, 6000 Frankfurt, De
DE3803899C1 (pt) * 1988-02-09 1989-04-13 Degussa Ag, 6000 Frankfurt, De
CN1074306C (zh) * 1996-09-25 2001-11-07 中国科学院大连化学物理研究所 一种用于一氧化碳加氢合成乙醇乙酸乙醛的铑基催化剂
DE19929281A1 (de) * 1999-06-25 2000-12-28 Basf Ag Verfahren und Katalysator zur Herstellung von C¶2¶-Oxygenaten aus Synthesegas

Also Published As

Publication number Publication date
RS20060683A (en) 2008-06-05
AU2004320979A1 (en) 2006-01-05
CA2586418A1 (en) 2006-01-05
US20070249874A1 (en) 2007-10-25
EP1771245A1 (en) 2007-04-11
NO20070161L (no) 2007-01-09
EA200602293A1 (ru) 2007-06-29
WO2006000734A1 (en) 2006-01-05
JP2008503440A (ja) 2008-02-07

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B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE AS 5A, 6A, 7A E 8A ANUIDADES.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 2158 DE 15/05/2012.