BRPI0418062A - processo para a produção de biodiesel a partir de óleo renovável na presença de catálise por lipase em um sistema de reação em meio orgánico - Google Patents

processo para a produção de biodiesel a partir de óleo renovável na presença de catálise por lipase em um sistema de reação em meio orgánico

Info

Publication number
BRPI0418062A
BRPI0418062A BRPI0418062-3A BRPI0418062A BRPI0418062A BR PI0418062 A BRPI0418062 A BR PI0418062A BR PI0418062 A BRPI0418062 A BR PI0418062A BR PI0418062 A BRPI0418062 A BR PI0418062A
Authority
BR
Brazil
Prior art keywords
biodiesel
renewable oil
lipase
production
reaction system
Prior art date
Application number
BRPI0418062-3A
Other languages
English (en)
Inventor
Wei Du
Dehua Liu
Lilin Li
Yuanyuan Xu
Li Wang
Original Assignee
Univ Tsinghua
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Tsinghua filed Critical Univ Tsinghua
Publication of BRPI0418062A publication Critical patent/BRPI0418062A/pt
Publication of BRPI0418062B1 publication Critical patent/BRPI0418062B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/64—Fats; Fatty oils; Ester-type waxes; Higher fatty acids, i.e. having at least seven carbon atoms in an unbroken chain bound to a carboxyl group; Oxidised oils or fats
    • C12P7/6436—Fatty acid esters
    • C12P7/649—Biodiesel, i.e. fatty acid alkyl esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/003—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with alcohols
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/62—Carboxylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/64—Fats; Fatty oils; Ester-type waxes; Higher fatty acids, i.e. having at least seven carbon atoms in an unbroken chain bound to a carboxyl group; Oxidised oils or fats
    • C12P7/6436—Fatty acid esters
    • C12P7/6445—Glycerides
    • C12P7/6458—Glycerides by transesterification, e.g. interesterification, ester interchange, alcoholysis or acidolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Microbiology (AREA)
  • Biochemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Biotechnology (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Fats And Perfumes (AREA)
  • Enzymes And Modification Thereof (AREA)
  • Apparatus Associated With Microorganisms And Enzymes (AREA)

Abstract

"PROCESSO PARA A PRODUçãO DE BIODIESEL A PARTIR DE óLEO RENOVáVEL NA PRESENçA DE CATáLISE POR LIPASE EM UM SISTEMA DE REAçãO EM MEIO ORGáNICO". A presente invenção prove um novo processo para a produção de biodiesel a partir de óleo renovável na presença de catálise por lipase em um sistema de reação em meio orgânico. Nesse processo, é usado um álcool de cadeia curta ROH como um receptor de acila, sendo usado como meio de reação um solvente orgânico relativamente hidrofílico sem efeito negativo na reatividade da lipase, e matéria-prima de óleo renovável sendo catalisada por uma lipase para sintetizar o biodiesel por meio de uma reação de transesterificação. No processo da presente invenção, a material-prima de óleo renovável pode ser quase completamente convertida em biodiesel e um subproduto glicerina, e a produção do biodiesel é de 94% ou mais. Esse novo tipo de sistema de reação em meio orgânico promove a solubilidade do álcool de cadeia curta na matéria-prima do óleo renovável e dissolve parte do subproduto glicerina. Como conseqüência, o tempo de reação é reduzido, a produtividade do biodiesel aumenta e a reatividade e tempo de vida da lipase são aperfeiçoadas no processo da presente invenção.
BRPI0418062A 2004-01-16 2004-11-29 processo para a produção de biodiesel a partir de óleo renovável na presença de catálise por lipase em um sistema de reação em meio orgânico BRPI0418062B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CNB2004100006979A CN1238469C (zh) 2004-01-16 2004-01-16 有机介质反应体系中脂肪酶转化油脂生产生物柴油新工艺
PCT/CN2004/001372 WO2005075615A1 (fr) 2004-01-16 2004-11-29 Nouveau procede de production de biodiesel a partir d'huiles et de graisses catalysees par lipase dans un systeme de reaction a milieu organique

Publications (2)

Publication Number Publication Date
BRPI0418062A true BRPI0418062A (pt) 2007-04-17
BRPI0418062B1 BRPI0418062B1 (pt) 2016-06-28

Family

ID=34350467

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0418062A BRPI0418062B1 (pt) 2004-01-16 2004-11-29 processo para a produção de biodiesel a partir de óleo renovável na presença de catálise por lipase em um sistema de reação em meio orgânico

Country Status (9)

Country Link
US (1) US7550278B2 (pt)
EP (1) EP1705238B1 (pt)
CN (1) CN1238469C (pt)
AT (1) ATE446353T1 (pt)
BR (1) BRPI0418062B1 (pt)
CA (1) CA2553653C (pt)
DE (1) DE602004023761D1 (pt)
HK (1) HK1094229A1 (pt)
WO (1) WO2005075615A1 (pt)

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CA2593282C (en) * 2005-01-10 2016-03-15 Novozymes A/S Production of fatty acid alkyl esters by use of two lipolytic enzymes
EP1848787A1 (de) * 2005-02-17 2007-10-31 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Fl]ssige bio-brennstoffmischung sowie verfahren und vorrichtung zur herstellung derselben
CN100375781C (zh) * 2005-11-09 2008-03-19 中国科学院广州能源研究所 一种生产生物柴油的方法
CN100404643C (zh) * 2006-07-07 2008-07-23 清华大学 有机介质反应体系中微生物细胞转化油脂生产生物柴油的工艺
ES2289943B1 (es) * 2006-07-21 2008-12-16 Universidad De Cordoba Procedimiento de produccion de biodiesel mediante el uso de lipasa pancreatica de cerdo como biocatalizador enzimatico.
CN1928116B (zh) * 2006-08-25 2010-07-21 江南大学 一种非水相中脂肪酶合成酶活力的快速测定方法
CN100455656C (zh) * 2006-10-26 2009-01-28 中国农业科学院油料作物研究所 胞内分泌脂肪酶型全细胞催化剂的制备方法
EP2351845A1 (en) * 2007-06-01 2011-08-03 Solazyme, Inc. Renewable chemicals and fuels from oleaginous yeast
US7790429B2 (en) 2007-11-28 2010-09-07 Transbiodiesel Ltd. Robust multi-enzyme preparation for the synthesis of fatty acid alkyl esters
US8617866B2 (en) 2007-11-28 2013-12-31 Sobhi Basheer Robust multi-enzyme preparation for the synthesis of fatty acid alkyl esters
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KR101546885B1 (ko) * 2009-07-17 2015-08-24 한국과학기술원 오일 생성능을 가지는 미생물을 이용한 지방산 알킬에스테르의 제조방법
KR20110035612A (ko) * 2009-09-30 2011-04-06 한국생산기술연구원 액체 이산화탄소 상태에서 효소적 바이오 디젤 제조방법
GB2478137A (en) * 2010-02-25 2011-08-31 Hycagen Ltd Biodiesel compositions
AU2011257982B2 (en) 2010-05-28 2017-05-25 Corbion Biotech, Inc. Tailored oils produced from recombinant heterotrophic microorganisms
CN101838670A (zh) * 2010-06-11 2010-09-22 贵州师范大学 制备生物柴油的方法
ES2909143T3 (es) 2010-11-03 2022-05-05 Corbion Biotech Inc Microbios de Chlorella o Prototheca modificados genéticamente y aceite producido a partir de estos
KR102117225B1 (ko) 2011-02-02 2020-06-02 테라비아 홀딩스 인코포레이티드 재조합 유지성 미생물로부터 생산된 맞춤 오일
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Also Published As

Publication number Publication date
CA2553653A1 (en) 2005-08-18
DE602004023761D1 (de) 2009-12-03
BRPI0418062B1 (pt) 2016-06-28
EP1705238B1 (en) 2009-10-21
CN1557913A (zh) 2004-12-29
US7550278B2 (en) 2009-06-23
EP1705238A4 (en) 2007-04-11
US20080038804A1 (en) 2008-02-14
HK1094229A1 (en) 2007-03-23
CA2553653C (en) 2011-06-28
EP1705238A1 (en) 2006-09-27
ATE446353T1 (de) 2009-11-15
CN1238469C (zh) 2006-01-25
WO2005075615A1 (fr) 2005-08-18

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B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
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B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time
B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)
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