BRPI0411009B1 - Substrato metálico revestido e processos para escurecer e conceder resistência à corrosão à superfície de zinco e para conferir propriedades de inibição de corrosão a um substrato de um metal ativo - Google Patents
Substrato metálico revestido e processos para escurecer e conceder resistência à corrosão à superfície de zinco e para conferir propriedades de inibição de corrosão a um substrato de um metal ativo Download PDFInfo
- Publication number
- BRPI0411009B1 BRPI0411009B1 BRPI0411009-9A BRPI0411009A BRPI0411009B1 BR PI0411009 B1 BRPI0411009 B1 BR PI0411009B1 BR PI0411009 A BRPI0411009 A BR PI0411009A BR PI0411009 B1 BRPI0411009 B1 BR PI0411009B1
- Authority
- BR
- Brazil
- Prior art keywords
- percent
- composition
- coating
- ammonium chloride
- coated
- Prior art date
Links
- 238000005260 corrosion Methods 0.000 title claims description 85
- 230000007797 corrosion Effects 0.000 title claims description 78
- 229910052751 metal Inorganic materials 0.000 title claims description 70
- 239000002184 metal Substances 0.000 title claims description 70
- 238000000034 method Methods 0.000 title claims description 49
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims description 39
- 229910052725 zinc Inorganic materials 0.000 title claims description 39
- 239000011701 zinc Substances 0.000 title claims description 39
- 239000000758 substrate Substances 0.000 title claims description 37
- 230000008569 process Effects 0.000 title claims description 31
- 230000002401 inhibitory effect Effects 0.000 title claims description 16
- 239000000203 mixture Substances 0.000 claims description 147
- 238000000576 coating method Methods 0.000 claims description 82
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 72
- 239000011248 coating agent Substances 0.000 claims description 62
- 235000019270 ammonium chloride Nutrition 0.000 claims description 36
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims description 33
- 239000011609 ammonium molybdate Substances 0.000 claims description 33
- 235000018660 ammonium molybdate Nutrition 0.000 claims description 33
- 229940010552 ammonium molybdate Drugs 0.000 claims description 33
- 229910045601 alloy Inorganic materials 0.000 claims description 8
- 239000000956 alloy Substances 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
- 239000011230 binding agent Substances 0.000 claims description 4
- 238000013007 heat curing Methods 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 239000011777 magnesium Substances 0.000 claims description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 239000011572 manganese Substances 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 32
- BULVZWIRKLYCBC-UHFFFAOYSA-N phorate Chemical compound CCOP(=S)(OCC)SCSCC BULVZWIRKLYCBC-UHFFFAOYSA-N 0.000 description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 26
- 238000012360 testing method Methods 0.000 description 21
- 239000002562 thickening agent Substances 0.000 description 21
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 19
- 239000007921 spray Substances 0.000 description 17
- 239000008199 coating composition Substances 0.000 description 15
- -1 molybdate compound Chemical class 0.000 description 15
- 239000007788 liquid Substances 0.000 description 14
- 230000003647 oxidation Effects 0.000 description 13
- 238000007254 oxidation reaction Methods 0.000 description 13
- 238000009835 boiling Methods 0.000 description 12
- 150000003839 salts Chemical class 0.000 description 12
- 150000002739 metals Chemical class 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 8
- 238000001723 curing Methods 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 239000000080 wetting agent Substances 0.000 description 8
- 238000004140 cleaning Methods 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 6
- 239000000049 pigment Substances 0.000 description 6
- 238000005507 spraying Methods 0.000 description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 238000007598 dipping method Methods 0.000 description 5
- 229910052709 silver Inorganic materials 0.000 description 5
- 239000004332 silver Substances 0.000 description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 4
- QGAVSDVURUSLQK-UHFFFAOYSA-N ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 4
- 239000011651 chromium Substances 0.000 description 4
- 238000004040 coloring Methods 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 239000003002 pH adjusting agent Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XAEWLETZEZXLHR-UHFFFAOYSA-N zinc;dioxido(dioxo)molybdenum Chemical compound [Zn+2].[O-][Mo]([O-])(=O)=O XAEWLETZEZXLHR-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 238000010411 cooking Methods 0.000 description 3
- 238000003618 dip coating Methods 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- 231100000331 toxic Toxicity 0.000 description 3
- 230000002588 toxic effect Effects 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 229910001297 Zn alloy Inorganic materials 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000000712 assembly Effects 0.000 description 2
- 238000000429 assembly Methods 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000005238 degreasing Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 150000004679 hydroxides Chemical class 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- NMHMDUCCVHOJQI-UHFFFAOYSA-N lithium molybdate Chemical compound [Li+].[Li+].[O-][Mo]([O-])(=O)=O NMHMDUCCVHOJQI-UHFFFAOYSA-N 0.000 description 2
- MODMKKOKHKJFHJ-UHFFFAOYSA-N magnesium;dioxido(dioxo)molybdenum Chemical compound [Mg+2].[O-][Mo]([O-])(=O)=O MODMKKOKHKJFHJ-UHFFFAOYSA-N 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000005078 molybdenum compound Substances 0.000 description 2
- 150000002752 molybdenum compounds Chemical class 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 238000007761 roller coating Methods 0.000 description 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
- 239000011684 sodium molybdate Substances 0.000 description 2
- 235000015393 sodium molybdate Nutrition 0.000 description 2
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 238000001029 thermal curing Methods 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- QQYSPMBMXXCTGQ-UHFFFAOYSA-N 1,4-dioxo-1,4-di(tridecoxy)butane-2-sulfonic acid;sodium Chemical compound [Na].CCCCCCCCCCCCCOC(=O)CC(S(O)(=O)=O)C(=O)OCCCCCCCCCCCCC QQYSPMBMXXCTGQ-UHFFFAOYSA-N 0.000 description 1
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 229920000896 Ethulose Polymers 0.000 description 1
- 239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- XUFUCDNVOXXQQC-UHFFFAOYSA-L azane;hydroxy-(hydroxy(dioxo)molybdenio)oxy-dioxomolybdenum Chemical compound N.N.O[Mo](=O)(=O)O[Mo](O)(=O)=O XUFUCDNVOXXQQC-UHFFFAOYSA-L 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229940065285 cadmium compound Drugs 0.000 description 1
- 150000001662 cadmium compounds Chemical class 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000003486 chemical etching Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000009500 colour coating Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- AGNOBAWAZFBMMI-UHFFFAOYSA-N dicesium dioxido(dioxo)molybdenum Chemical compound [Cs+].[Cs+].[O-][Mo]([O-])(=O)=O AGNOBAWAZFBMMI-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 description 1
- 235000010944 ethyl methyl cellulose Nutrition 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 229940071826 hydroxyethyl cellulose Drugs 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 229940071676 hydroxypropylcellulose Drugs 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000006115 industrial coating Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 229920003087 methylethyl cellulose Polymers 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 150000002751 molybdenum Chemical class 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 231100000916 relative toxicity Toxicity 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- LJRGBERXYNQPJI-UHFFFAOYSA-M sodium;3-nitrobenzenesulfonate Chemical compound [Na+].[O-][N+](=O)C1=CC=CC(S([O-])(=O)=O)=C1 LJRGBERXYNQPJI-UHFFFAOYSA-M 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- CDVLCTOFEIEUDH-UHFFFAOYSA-K tetrasodium;phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])([O-])=O CDVLCTOFEIEUDH-UHFFFAOYSA-K 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/68—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous solutions with pH between 6 and 8
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K13/00—Etching, surface-brightening or pickling compositions
- C09K13/04—Etching, surface-brightening or pickling compositions containing an inorganic acid
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/40—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates
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- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Chemical Treatment Of Metals (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US47611903P | 2003-06-05 | 2003-06-05 | |
| US60/476.119 | 2003-06-05 | ||
| PCT/US2004/017786 WO2004108407A1 (en) | 2003-06-05 | 2004-06-04 | Compositions and methods for darkening and imparting corrosion-resistant properties to zinc or other active metals |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0411009A BRPI0411009A (pt) | 2006-07-04 |
| BRPI0411009B1 true BRPI0411009B1 (pt) | 2015-04-07 |
Family
ID=33511758
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0411009-9A BRPI0411009B1 (pt) | 2003-06-05 | 2004-06-04 | Substrato metálico revestido e processos para escurecer e conceder resistência à corrosão à superfície de zinco e para conferir propriedades de inibição de corrosão a um substrato de um metal ativo |
Country Status (14)
| Country | Link |
|---|---|
| US (2) | US7641743B2 (enExample) |
| EP (1) | EP1633557A4 (enExample) |
| JP (1) | JP5100118B2 (enExample) |
| KR (1) | KR101210192B1 (enExample) |
| CN (2) | CN1802250A (enExample) |
| AU (2) | AU2004245553A1 (enExample) |
| BR (1) | BRPI0411009B1 (enExample) |
| CA (1) | CA2526230C (enExample) |
| EA (1) | EA008802B1 (enExample) |
| MX (1) | MXPA05012348A (enExample) |
| NO (1) | NO20060048L (enExample) |
| UA (1) | UA88144C2 (enExample) |
| WO (1) | WO2004108407A1 (enExample) |
| ZA (1) | ZA200509357B (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040206266A1 (en) * | 2001-02-14 | 2004-10-21 | Metal Coatings International Inc. | Particulate metal alloy coating for providing corrosion protection |
| CN1802250A (zh) * | 2003-06-05 | 2006-07-12 | 金属涂层国际公司 | 暗化锌或其它活性金属并向其提供耐腐蚀性的组合物和方法 |
| US7273337B2 (en) | 2003-06-30 | 2007-09-25 | Illinois Tool Works Inc. | Partially coated fastener assembly and method for coating |
| US8691346B2 (en) * | 2008-05-09 | 2014-04-08 | Birchwood Laboratories, Inc. | Methods and compositions for coating aluminum substrates |
| US10259973B2 (en) | 2009-03-13 | 2019-04-16 | Hi-Shear Corporation | Anti-corrosion and low friction metal pigmented coating |
| CN101629288B (zh) * | 2009-08-21 | 2011-06-22 | 攀钢集团钢铁钒钛股份有限公司 | 热镀铝锌板用钝化处理剂及其制备方法 |
| US10876211B2 (en) | 2011-09-16 | 2020-12-29 | Prc-Desoto International, Inc. | Compositions for application to a metal substrate |
| CN103710722B (zh) * | 2013-12-30 | 2016-03-02 | 新疆通奥油田技术服务有限公司 | 一种水煮式稠油油管清洁系统及清洁方法 |
| KR101824880B1 (ko) | 2015-09-30 | 2018-02-02 | 삼화페인트공업주식회사 | 거푸집 판넬 에지용 코팅 도료 |
| MX2019003084A (es) * | 2016-09-15 | 2019-08-12 | Chemetall Gmbh | Proceso mejorado para un pretratamiento contra la corrosion de una superficie metalica que contiene acero, acero galvanizado, aluminio, una aleacion de aluminio y/o una aleacion de zinc y magnesio. |
| CN112517912A (zh) * | 2020-11-11 | 2021-03-19 | 西安理工大学 | 一种针对粉末冶金铁基零件的表面防腐处理的方法 |
| CN119281585B (zh) * | 2024-12-10 | 2025-03-14 | 天津华源时代金属制品有限公司 | 一种达克罗涂层钝化设备及其控制方法 |
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| US3127279A (en) * | 1964-03-31 | Aqueous black coating composition con- | ||
| GB419469A (en) * | 1932-07-18 | 1934-11-13 | Heinz Tichauer | Improvements in and relating to the coating of objects made of zinc or covered with zinc |
| DE613024C (de) * | 1932-07-19 | 1935-05-10 | Heinz Tichauer | Verfahren zur Herstellung von Schutzueberzuegen auf Zink und verzinkten Gegenstaenden |
| DE615665C (de) * | 1933-03-30 | 1935-07-09 | Heinz Tichauer | Verfahren zur Herstellung von Schutzueberzuegen auf Zink und verzinkten Gegenstaenden |
| DE721755C (de) * | 1939-08-12 | 1942-06-18 | Vdo Tachometer A G | Verfahren zum Faerben von Aluminium und Aluminiumlegierungen |
| US2432286A (en) * | 1944-07-19 | 1947-12-09 | California Research Corp | Preparation of a coprecipitated alumina-molybdena catalyst |
| US2554256A (en) * | 1948-05-15 | 1951-05-22 | Westinghouse Electric Corp | Process for treating aluminum to provide selective coloration of portions thereof |
| US2679474A (en) * | 1949-12-31 | 1954-05-25 | Pajes Wolf Szmul | Process of making optical zone plates |
| US2679475A (en) * | 1952-01-21 | 1954-05-25 | Joseph C Singler | Metal blackening composition and method |
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| US3314811A (en) * | 1964-01-02 | 1967-04-18 | Mitchell Bradford Chemical Co | Metal treating compositions and processes |
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| DE2546018A1 (de) * | 1974-10-18 | 1976-04-22 | Alusuisse | Verfahren zum faerben von aluminium |
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| US4217216A (en) * | 1977-04-01 | 1980-08-12 | The Mogul Corporation | Corrosion inhibiting compositions |
| SU827613A1 (ru) * | 1978-05-04 | 1981-05-07 | Всесоюзный Научно-Исследовательскийинститут Метизной Промышленности | Способ пассивировани цинковой по-ВЕРХНОСТи |
| US4176059A (en) | 1978-06-08 | 1979-11-27 | Quatic Chemicals Limited | Anti-corrosion composition for use in aqueous systems |
| JPS6050228B2 (ja) * | 1979-04-06 | 1985-11-07 | 株式会社 日本ダクロシヤムロツク | 防食被覆組成物 |
| US4409121A (en) * | 1980-07-21 | 1983-10-11 | Uop Inc. | Corrosion inhibitors |
| US4440721A (en) * | 1981-10-26 | 1984-04-03 | Basf Wyandotte Corporation | Aqueous liquids containing metal cavitation-erosion corrosion inhibitors |
| US4548787A (en) * | 1981-10-26 | 1985-10-22 | Basf Wyandotte Corporation | Aqueous liquids containing metal cavitation-erosion corrosion inhibitors |
| US4640793A (en) | 1984-02-14 | 1987-02-03 | Calgon Corporation | Synergistic scale and corrosion inhibiting admixtures containing carboxylic acid/sulfonic acid polymers |
| JPS6160886A (ja) * | 1984-08-31 | 1986-03-28 | Nippon Kokan Kk <Nkk> | 防錆潤滑鋼板 |
| US4798683A (en) * | 1988-04-21 | 1989-01-17 | Calgon Corporation | Method for controlling corrosion using molybdate compositions |
| SU1678900A1 (ru) * | 1989-12-11 | 1991-09-23 | Московский институт теплотехники | Раствор дл химического оксидировани алюмини и его сплавов |
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| JP3325334B2 (ja) * | 1993-04-28 | 2002-09-17 | 日本パーカライジング株式会社 | 溶融亜鉛−アルミニウム合金めっき鋼板の光輝性青色処理方法 |
| US5700334A (en) * | 1993-04-28 | 1997-12-23 | Henkel Corporation | Composition and process for imparting a bright blue color to zinc/aluminum alloy |
| US5573556A (en) * | 1994-11-03 | 1996-11-12 | Exxon Research And Engineering Company | Conversion of solid carbonaceous material using polyoxoanions |
| JPH09228066A (ja) * | 1996-02-27 | 1997-09-02 | Nippon Parkerizing Co Ltd | アルミニウム含有金属材料の耐食性・塑性加工性増進表面処理用水性組成物、処理液、および処理方法 |
| US5868819A (en) * | 1996-05-20 | 1999-02-09 | Metal Coatings International Inc. | Water-reducible coating composition for providing corrosion protection |
| FR2764225B1 (fr) | 1997-06-05 | 1999-07-23 | Uranie International | Piece metallique ayant une surface externe presentant un profil particulier, procede de polissage pour sa realisation et dispositif de mise en oeuvre du procede |
| JP2000199088A (ja) * | 1998-12-28 | 2000-07-18 | Paiorakkusu:Kk | 金属部材の防錆被膜および防錆被膜付金属部材 |
| FR2816641B1 (fr) * | 2000-11-13 | 2003-08-01 | Dacral Sa | UTILISATION DE MoO3, COMME AGENT ANTICORROSION, ET COMPOSITION DE REVETEMENT CONTENANT UN TEL AGENT |
| US7078076B2 (en) * | 2001-02-14 | 2006-07-18 | Metal Coatings International Inc. | Particulate metal alloy coating for providing corrosion protection |
| US6957939B2 (en) * | 2001-04-05 | 2005-10-25 | Industrial And Automotive Fasteners, L.L.C. | Decorative capped wheel nut and method of assembly |
| US6866457B2 (en) * | 2001-04-05 | 2005-03-15 | Industrial And Automotive Fasteners, L.L.C. | Decorative capped wheel nut or bolt assembly and method |
| KR100490901B1 (ko) * | 2002-12-02 | 2005-05-24 | 한국전자통신연구원 | 이더넷 수동 광통신망에서 서비스 등급별 동적대역 할당방법 및 대역할당장치 |
| US20040191555A1 (en) * | 2003-02-06 | 2004-09-30 | Metal Coatings International Inc. | Coating systems having an anti-corrosion layer and a powder coating layer |
| CN1802250A (zh) * | 2003-06-05 | 2006-07-12 | 金属涂层国际公司 | 暗化锌或其它活性金属并向其提供耐腐蚀性的组合物和方法 |
-
2004
- 2004-06-04 CN CNA2004800155933A patent/CN1802250A/zh active Pending
- 2004-06-04 CA CA2526230A patent/CA2526230C/en not_active Expired - Fee Related
- 2004-06-04 US US10/559,197 patent/US7641743B2/en active Active
- 2004-06-04 MX MXPA05012348A patent/MXPA05012348A/es active IP Right Grant
- 2004-06-04 EP EP04754397A patent/EP1633557A4/en not_active Withdrawn
- 2004-06-04 WO PCT/US2004/017786 patent/WO2004108407A1/en not_active Ceased
- 2004-06-04 JP JP2006515205A patent/JP5100118B2/ja not_active Expired - Fee Related
- 2004-06-04 EA EA200501752A patent/EA008802B1/ru not_active IP Right Cessation
- 2004-06-04 BR BRPI0411009-9A patent/BRPI0411009B1/pt not_active IP Right Cessation
- 2004-06-04 ZA ZA200509357A patent/ZA200509357B/en unknown
- 2004-06-04 UA UAA200511450A patent/UA88144C2/ru unknown
- 2004-06-04 CN CN201510010002.3A patent/CN104532227A/zh active Pending
- 2004-06-04 AU AU2004245553A patent/AU2004245553A1/en not_active Abandoned
-
2005
- 2005-12-01 KR KR1020057023038A patent/KR101210192B1/ko not_active Expired - Fee Related
-
2006
- 2006-01-04 NO NO20060048A patent/NO20060048L/no not_active Application Discontinuation
-
2009
- 2009-11-19 US US12/621,601 patent/US20100297354A1/en not_active Abandoned
-
2010
- 2010-10-15 AU AU2010235869A patent/AU2010235869A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| KR20060005416A (ko) | 2006-01-17 |
| MXPA05012348A (es) | 2006-02-08 |
| WO2004108407A1 (en) | 2004-12-16 |
| US20100297354A1 (en) | 2010-11-25 |
| CN1802250A (zh) | 2006-07-12 |
| CA2526230C (en) | 2013-11-26 |
| WO2004108407B1 (en) | 2005-02-24 |
| BRPI0411009A (pt) | 2006-07-04 |
| EP1633557A1 (en) | 2006-03-15 |
| NO20060048L (no) | 2006-01-04 |
| JP2006526710A (ja) | 2006-11-24 |
| CN104532227A (zh) | 2015-04-22 |
| ZA200509357B (en) | 2007-06-27 |
| EP1633557A4 (en) | 2010-08-25 |
| UA88144C2 (ru) | 2009-09-25 |
| US20060213389A1 (en) | 2006-09-28 |
| AU2010235869A1 (en) | 2010-11-11 |
| CA2526230A1 (en) | 2004-12-16 |
| EA008802B1 (ru) | 2007-08-31 |
| KR101210192B1 (ko) | 2012-12-07 |
| EA200501752A1 (ru) | 2006-06-30 |
| AU2004245553A1 (en) | 2004-12-16 |
| US7641743B2 (en) | 2010-01-05 |
| JP5100118B2 (ja) | 2012-12-19 |
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